CN103169638A - 24-hour moist three-layer moisturizing and repairing system - Google Patents
24-hour moist three-layer moisturizing and repairing system Download PDFInfo
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Abstract
The invention belongs to the field of cosmetics, and relates to a moisturizing technology in skin care products, namely a 24-hour moist three-layer moisturizing and repairing system. The skin care product provided by the invention is characterized in that kelp extractive, deep ocean water, pansy extractive and a water catching factor form a three-layer moisturizing and repairing system; the kelp extractive contains a plurality of minerals, saccharides and amino acid and has the moisturizing effect of reinforcing surface water locking of skin; the pansy extractive promotes synthesis of aquaporins in cell membranes, improves water circulation of dermis and promotes water to transfer from dermis to cuticle; silicon and manganese elements in the deep ocean water can reduce transepidermal water loss and are cooperative to achieve the effect of activating water deeply; and the water catching factor ensures that skin has the moisturizing effect of catching water outside. By means of the three-layer moisturizing and repairing system including surface water locking, water activating deeply and water catching outside, the skin care product provided by the invention can bring an intelligent lasting moisturizing technology to skin, so that bright, smooth, transparent and moist skin is brought.
Description
Technical field
The invention belongs to cosmetic field, relate to a kind of three layers of water and support the maintenance system, especially relate to the skin care item that three layers of water of a kind of 24 full-time water profits are supported the maintenance system.
Background technology
Skin is people's natural coat, and healthy and beautiful skin is mainly manifested in the various aspects of the colour of skin, elasticity, gloss, texture and physiological function, and what these were played crucial influence is exactly the water content of skin.Usually the water content of epidermis and corium is approximately 75%, outmost horny layer generally should be not less than 10%, it is soft and moist, smooth, flexible that water content of stratum corneum is that the skin of 10-20% shows as, if lower than 10%, keratodermatitis too drying squama even occurs or break.Therefore, keeping the full-time water profit of skin to be not only the basic demand of skin protection, is also the basic guarantee of beautiful skin of securing good health.Although the total class of different skin-protection products is various on the market, its effect is many can not be satisfactory.At first, take moisturizing as example, most moisturizing skin care item only can replenish the outer moisture of epidermis, increase the content of water, oil at skin surface, and can't deeply improve the moisture of cortex, and this also fails fundamentally to improve the dry sensation of skin.Secondly, although have at present the skin-protection product of multiple becoming " multi-efficiency ", actual research effect shows, their many effects that possess simple superposition do not have the obvious effect of improving to a plurality of skin problems.Except this, some skin-protection products are more arranged in order to reach whitening effect for the moment, added the harmful materials such as heavy metal.
Macrocystis pyrifera (L.) Ag. belongs to Brown algae, and they are the longest gangs in algae kingdom.Macrocystis pyrifera (L.) Ag. originates in North America bank, and China scientist successfully introduced Macrocystis pyrifera (L.) Ag. from Mexico first in 1978.At present, the Macrocystis pyrifera (L.) Ag. cultivation succeeds in China's Coastal Areas.Macrocystis pyrifera (L.) Ag. for the production of multiple chemical industry, medical product, is the primary raw material of Algin, while or animal feed and the raw material of producing methane.
Deep layer Haiquan water is purer than common sea water, near " zero pollute ", it is carried out the problem that extensive use can solve the global water resources shortage, so deep layer Haiquan water be otherwise known as " yellow gold ".As the deep layer Haiquan water of seabed affluent resources, only in some cosmetics international top-brand such as L ' Oreal, the products such as La Prairie, Lirikos, communications and reports are arranged at present, but yet there are no report for the applied research of deep layer Haiquan water.
Herba Violae Hortensis (Viola tricolor Linn.) has another name called Herba Iridis japonicae, cat face flower etc., originates in Europe, is a kind of common wild flower, supplies to view and admire in the cultivation of park, China various places at present.Herba Violae Hortensis has bactericidal antiphlogistic, anti-acne and hypo-allergenic effect.
There is not yet in the industry at present the skin care item that are used in combination Macrocystis pyrifera (L.) Ag. extract, deep layer Haiquan water and Herba Violae Hortensis extract.
Summary of the invention
The object of the invention is to solve the deficiencies in the prior art, provide three layers of water of a kind of 24 full-time water profits to support maintenance system skin care item, these skin care item provide top layer lock water, deep layer running water and skin " to catch " the foster maintenance of the three layers of water system of water, can keep for a long time moisture of skin, even also can long-acting moisturizing under the environment of dehumidifier.
Above-mentioned purpose of the present invention is achieved by the following technical programs:
Three layers of water of of the present invention 24 full-time water profits are supported maintenance system skin care item, comprise by weight ratio following component: the Macrocystis pyrifera (L.) Ag. extract, and with the Macrocystis pyrifera (L.) Ag. weighing scale, 1～30 part; Deep layer Haiquan water, 0.01～25 part; The Herba Violae Hortensis extract, with the Herba Violae Hortensis weighing scale, 1～15 part; Vegetable oil, 0.001～10 part; Fructus oleae europaeae oil non-saponifiable matter, 0.001～5 part; Hydrogenated vegetable oil, 0.001～5 part; Glyceryl stearate, 0.001～2 part; Phytosterol, 0.001～3 part; And tocopherol, 0.001～3 part.In the one-tenth of these cosmetics was grouped into, the proportioning of Macrocystis pyrifera (L.) Ag. extract and Herba Violae Hortensis extract was according to the weight of raw material and fixed.
According to the further feature of skin care item of the present invention, described Macrocystis pyrifera (L.) Ag. extract prepares by the following method: after the Herb Macrocystis pyrifera (L.) Ag. is pulverized, add ethanol water to extract, extracting solution is concentrated and filter gained after the butanediol dilution.
Preferably, in the preparation method of described Macrocystis pyrifera (L.) Ag. extract, in ethanol water, the mass fraction of ethanol is 60%; The Macrocystis pyrifera (L.) Ag. of every 1 part of weight adds the ethanol water of 5-9 parts of weight.
Preferably, in described preparation method, after adding ethanol water, heating and refluxing extraction 1～3 hour is extracted merge extractive liquid, 2～4 times.
According to the further feature of skin care item of the present invention, described Herba Violae Hortensis extract prepares by the following method: after the Herb Herba Violae Hortensis is pulverized, decoct with water extraction, precipitate with ethanol after the extracting solution evaporation and concentration makes ethanol content reach 60～75%.Through concentrating under reduced pressure, filtration obtains again.
Preferably, in the preparation method of described Herba Violae Hortensis extract, decoct with water and extracted 1～3 hour, extract merge extractive liquid, 2～4 times.
Preferably, in the preparation method of described Herba Violae Hortensis extract, working concentration is that 95% ethanol carries out precipitate with ethanol.
According to a preferred embodiment of the invention, the Macrocystis pyrifera (L.) Ag. extract obtains by the following method: cross 10 eye mesh screens after Macrocystis pyrifera (L.) Ag. is pulverized, obtain the sample that grain diameter is 0.5～2.0mm, the Macrocystis pyrifera (L.) Ag. fine powder that sieves in 1 part of weight mixes (the ethanol mass fraction is 60%) with the ratio of the ethanol-water solution of 5～9 parts of weight, in heating (temperature is between 100～115 ℃) on electric jacket, reflux, extract, 1～3 hour is extracted 2～4 times.Collect the extracting solution of each time, use Rotary Evaporators and vacuum pump using circulatory water to carry out concentrating under reduced pressure as basic device, obtain concentrated solution.Concentrated solution dilutes according to the ratio of 1:1 take butanediol as solvent, standing 24 hours of diluent, and sucking filtration namely gets the Macrocystis pyrifera (L.) Ag. extract.
According to a preferred embodiment of the invention, the Herba Violae Hortensis extract obtains by the following method: cross 10 eye mesh screens after the Herba Violae Hortensis of drying is pulverized, obtain the sample that grain diameter is 0.5～2.0mm, water by sieve Herba Violae Hortensis fine powder and 5～9 parts of weight of 1 part of weight heats decoction, extracted 1～3 hour, and extracted 2～4 times.Collect the extracting solution of each time, evaporation and concentration, volume is to 1/3rd of the extracting solution total amount.After concentrated solution lets cool, adding while stirring 95% ethanol, is 60～75% until alcohol meter records ethanol content, and airtight cold preservation 48 hours filters, and filtrate is reclaimed ethanol through concentrating under reduced pressure, and the gained refined liquid adds phenoxyethanol in 1% ratio, namely gets the Herba Violae Hortensis extract.
Compared with prior art, skin care item provided by the present invention have lasting water profit moistening effect, even in the dehumidifier environment of drying, also can keep for a long time the moisture of skin and moisten degree, and improving skin elasticity.Specifically, comprise following aspect:
At first, provide the water of the skin " top layer lock water " of reinforcement to support effect by the Macrocystis pyrifera (L.) Ag. extract.Macrocystis pyrifera (L.) Ag. extract of the present invention be the butanediol with moisture-keeping function be solvent, contain several mineral materials, saccharide and amino acid whose skin care ingredient in extract.Wherein, saccharide and aminoacid are brought into play the effect of nature moisturizing factor in the process of skin moisture-keeping; Mineral composition participates in consisting of the nature moisturizing factor compound, jointly promotes the synthetic of nature moisturizing factor (NMF) with saccharide and aminoacid.Nature moisturizing factor can be combined with water in horny layer, stores moisture by adjusting and reaches the water content that keeps between horn cell, helps skin to reach the effect of " top layer lock water ".
Secondly, " deep layer running water " effect of reinforcement is provided by deep layer Haiquan water and Herba Violae Hortensis extract.Deep layer Haiquan water of the present invention is the deep layer Haiquan water that is derived from the northern marine site of French Brittany, separates and carries out desalination through electrodialysis, has removed especially Na
+And K
+, and kept other trace element, then process through sterilising filtration, add gentle antiseptic, obtain the deep layer Haiquan water of stable and desalting processing.After measured, deep layer Haiquan water of the present invention contains abundant trace element and mineral salt, has the exchange of moisture of strengthening in skin layer and the lock water effect that reduces the epidermal area water loss.Be rich in the active component of oligosaccharide in the Herba Violae Hortensis extract, be positioned at the water transport protein of cell membrane by stimulation---synthesizing of aquaporin, improve the moisture circulation of corium.Simultaneously, can promote to improve the content of hyaluronic acid and hyaluronic acid synthetase, thereby provide skin to keep the ability of moisture.
At last, one group " catching the water factor " is provided, comprise the compositions such as vegetable oil, Fructus oleae europaeae oil non-saponifiable matter, hydrogenated vegetable oil, glyceryl stearate, phytosterol, tocopherol, performance " skin is caught water " effect has the activity that nutrition, moisturizing and promotion skin are weeded out the old and bring forth the new concurrently.
Except above-mentioned these components, these skin care item can also add the common wetting agents such as Butyrospermum parkii fruit fat, tocopherol acetas, trimethyl glycine, hyaluronate sodium, and the common component in other skin care item.Skin care item that the concrete material basis that adds will be prepared and deciding.The skin care item type that can be used for preparing is extensive, comprises that cold cream frost, emulsion, eye protection elite reveal, clean product, astringent etc.
Description of drawings
Fig. 1,2,3 is respectively the skin moisture content rate of increase change curve that the moisture content of skin of the embodiment of the present invention 10 is tested first, second and third age group;
Fig. 4,5,6 is respectively the per day elasticity increment rate curve chart that the skin elasticity of the embodiment of the present invention 10 is tested first, second and third age group.
The specific embodiment
Replenishing water and preserving moisture skin care item provided by the invention all contain following component: Macrocystis pyrifera (L.) Ag. extract, deep layer Haiquan water, Herba Violae Hortensis extract, " catching the water factor " (vegetable oil, Fructus oleae europaeae oil non-saponifiable matter, hydrogenated vegetable oil, glyceryl stearate, phytosterol, tocopherol).Wherein, deep layer Haiquan water is to be derived from the northern marine site of French Brittany and through the deep layer Haiquan water of desalting processing, for example available from the product of French SOLIANCE company.And the various raw materials of " catching the water factor " are all the existing procucts on market, prepare in following proportion after can buying respectively: 0.001～10 part of vegetable oil; 0.001～5 part of Fructus oleae europaeae oil non-saponifiable matter; 0.001～5 part of hydrogenated vegetable oil; 0.001～2 part of glyceryl stearate; 0.001～3 part of phytosterol; And 0.001～3 part of tocopherol.
Below further set forth technical scheme of the present invention by concrete case study on implementation.
Embodiment 1: protective skin cream 1
The preparation of Macrocystis pyrifera (L.) Ag. extract:
The mistake 10 mesh sieve Macrocystis pyrifera (L.) Ag. fine powders of 1 part of weight are mixed (the ethanol mass fraction is 60%) with the ratio of the ethanol-water solution of 5 parts of weight, in heating (temperature is between 100～115 ℃) on electric jacket, reflux, extract, 2 hours is extracted 3 times.Collect the extracting solution of each time, be evaporated to 1/3rd of total extracting liquid volume.The concentrated solution that obtains take butanediol as solvent, dilutes according to the ratio of 1:1, standing 24 hours of diluent, and sucking filtration namely gets required Macrocystis pyrifera (L.) Ag. extract.
The preparation of Herba Violae Hortensis extract:
The mistake 10 mesh sieve Herba Violae Hortensis fine powders of 1 part of weight and the water of 5 parts of weight are heated decoction, extracted 2 hours, extract 3 times.Collect the extracting solution of each time, evaporation and concentration, volume is to 1/3rd of the extracting solution total amount.After concentrated solution lets cool, adding while stirring 95% ethanol, is 60% until alcohol meter records ethanol content, and airtight cold preservation 48 hours filters, and filtrate is reclaimed ethanol through concentrating under reduced pressure, and the gained refined liquid adds phenoxyethanol in 1% ratio, namely gets the Herba Violae Hortensis extract.
The preparation of protective skin cream 1:
Active component: above-mentioned Macrocystis pyrifera (L.) Ag. extract, deep layer Haiquan water, Herba Violae Hortensis extract are mixed with butanediol (5 parts of weight), glycerol (5 parts of weight), hyaluronate sodium (0.03 part of weight) and trimethyl glycine (1.5 parts of weight), can suitably add water in this operating process, as water miscible active component; Above-mentioned " catching the water factor " and Butyrospermum parkii fruit fat (2 parts of weight), tocopherol acetas (2 parts of weight) are mixed, and suitable heating for dissolving in this process is as oil-soluble active component.
Adjuvant: oil phase has caprylic/capric triglyceride (3 parts of weight), Cyclomethicone (5 parts of weight), glyceryl stearate (1 part of weight), octyl group polymethyl siloxane (2 parts of weight), three mountain Yu essence PEG-20 esters (2 parts of weight), methyl hydroxybenzoate (0.2 part of weight) and ethyl hydroxybenzoate (0.1 part of weight); Water has 2-(Acryloyloxy)ethanol/sodium acryloyldimethyl taurate copolymers (0.3 part of weight), acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters cross linked polymer (0.2 part of weight), EDETATE SODIUM (0.03 part of weight), and it is 100 parts that deionized water is mended ad pond om.
Each adjuvant is heated to respectively 75 ℃, and mix and blend is placed in emulsator fully emulsified, insulated and stirred 20 minutes, cooling.When being down to 45 ℃, temperature adds active component, and the auxiliary element such as aminomethyl propanol (0.12 part of weight), Methylisothiazolinone (0.01 part of weight), essence, stir.
Embodiment 2: protective skin cream 2
The preparation of Macrocystis pyrifera (L.) Ag. extract:
The mistake 10 mesh sieve Macrocystis pyrifera (L.) Ag. fine powders of 1 part of weight are mixed (the ethanol mass fraction is 60%) with the ratio of the ethanol-water solution of 8 parts of weight, in heating (temperature is between 100～115 ℃) on electric jacket, reflux, extract, 2 hours is extracted 3 times.Collect the extracting solution of each time, be evaporated to 1/3rd of total extracting liquid volume.The concentrated solution that obtains take butanediol as solvent, dilutes according to the ratio of 1:1, standing 24 hours of diluent, and sucking filtration namely gets required Macrocystis pyrifera (L.) Ag. extract.
The preparation of Herba Violae Hortensis extract:
The water of sieve Herba Violae Hortensis fine powder and 9 parts of weight of 1 part of weight is heated decoction, extracted 2.5 hours, extract 3 times.Collect the extracting solution of each time, evaporation and concentration, volume is to 1/3rd of the extracting solution total amount.After concentrated solution lets cool, adding while stirring 95% ethanol, is 75% until alcohol meter records ethanol content, and airtight cold preservation 48 hours filters, and filtrate is reclaimed ethanol through concentrating under reduced pressure, and the gained refined liquid adds phenoxyethanol in 1% ratio, namely gets the Herba Violae Hortensis extract.
The preparation of protective skin cream 2:
Active component: above-mentioned Macrocystis pyrifera (L.) Ag. extract, deep layer Haiquan water, Herba Violae Hortensis extract are mixed with butanediol (5 parts of weight), glycerol (5 parts of weight) and trimethyl glycine (1.5 parts of weight), can suitably add water in this operating process, as water miscible active component; Above-mentioned " catching the water factor " and Butyrospermum parkii fruit fat (2 parts of weight), tocopherol acetas (0.5 part of weight) are mixed, and suitable heating for dissolving in this process is as oil-soluble active component.
Adjuvant: oil phase has polyglycereol-3 methyl glucose distearate (2 parts of weight), glyceryl stearate (2 parts of weight), caprylic/capric triglyceride (3 parts of weight), Jojoba seed oil (3 parts of weight), Cyclomethicone (5 parts of weight), methyl hydroxybenzoate (0.2 part of weight) and ethyl hydroxybenzoate (0.1 part of weight); Water has carbomer (0.1 part of weight), AVC (0.1 part of weight), allantoin (0.2 part of weight) and EDETATE SODIUM (0.03 part of weight), and it is 100 parts that deionized water is mended ad pond om.
Each adjuvant is heated to respectively 75 ℃, and mix and blend is placed in emulsator fully emulsified, insulated and stirred 20 minutes, cooling.When being down to 45 ℃, temperature adds active component, and the auxiliary element such as aminomethyl propanol (0.048 part of weight), Methylisothiazolinone (0.01 part of weight), essence, stir.
Embodiment 3: moisturizer
The preparation of Macrocystis pyrifera (L.) Ag. extract:
The mistake 10 mesh sieve Macrocystis pyrifera (L.) Ag. fine powders of 1 part of weight are mixed (the ethanol mass fraction is 60%) with the ratio of the ethanol-water solution of 7 parts of weight, in heating (temperature is between 100～115 ℃) on electric jacket, reflux, extract, 2 hours is extracted 3 times.Collect the extracting solution of each time, be evaporated to 1/3rd of total extracting liquid volume.The concentrated solution that obtains take butanediol as solvent, dilutes according to the ratio of 1:1, standing 24 hours of diluent, and sucking filtration namely gets required Macrocystis pyrifera (L.) Ag. extract.
The preparation of Herba Violae Hortensis extract:
The water of sieve Herba Violae Hortensis fine powder and 7 parts of weight of 1 part of weight is heated decoction, extracted 3 hours, extract 2 times.Collect the extracting solution of each time, evaporation and concentration, volume is to 1/3rd of the extracting solution total amount.After concentrated solution lets cool, adding while stirring 95% ethanol, is 65% until alcohol meter records ethanol content, and airtight cold preservation 48 hours filters, and filtrate is reclaimed ethanol through concentrating under reduced pressure, and the gained refined liquid adds phenoxyethanol in 1% ratio, namely gets the Herba Violae Hortensis extract.
The preparation of moisturizer:
Active component: above-mentioned Macrocystis pyrifera (L.) Ag. extract, deep layer Haiquan water, Herba Violae Hortensis extract are mixed with butanediol (5 parts of weight), glycerol (5 parts of weight), hyaluronate sodium (0.04 part of weight) and trimethyl glycine (1 part of weight), can suitably add water in this operating process, as water miscible active component; Above-mentioned " catching the water factor " and Butyrospermum parkii fruit fat (2 parts of weight), tocopherol acetas (0.5 part of weight) are mixed, and suitable heating for dissolving in this process is as oil-soluble active component.
Adjuvant: oil phase has polyglycereol-3 methyl glucose distearate (2 parts of weight), glyceryl stearate (1 part of weight), ethylhexyl palmitate (3 parts of weight), hydrogenated polydecene (2 parts of weight), Jojoba seed oil (2 parts of weight), methyl hydroxybenzoate (0.2 part of weight) and ethyl hydroxybenzoate (0.1 part of weight); Water has 2-(Acryloyloxy)ethanol/sodium acryloyldimethyl taurate copolymers (0.2 part of weight), allantoin (0.2 part of weight) and EDETATE SODIUM (0.03 part of weight), and it is 100 parts that deionized water is mended ad pond om.
Each adjuvant is heated to respectively 75 ℃, and mix and blend is placed in emulsator fully emulsified, insulated and stirred 20 minutes, cooling.When being down to 45 ℃, temperature adds active component, and the auxiliary element such as Methylisothiazolinone (0.01 part of weight), essence, stir.
Embodiment 4: clean skin Gel mile
The preparation of Macrocystis pyrifera (L.) Ag. extract:
The mistake 10 mesh sieve Macrocystis pyrifera (L.) Ag. fine powders of 1 part of weight are mixed (the ethanol mass fraction is 60%) with the ratio of the ethanol-water solution of 6 parts of weight, in heating (temperature is between 100～115 ℃) on electric jacket, reflux, extract, 2 hours is extracted 3 times.Collect the extracting solution of each time, be evaporated to 1/3rd of total extracting liquid volume.The concentrated solution that obtains take butanediol as solvent, dilutes according to the ratio of 1:1, standing 24 hours of diluent, and sucking filtration namely gets required Macrocystis pyrifera (L.) Ag. extract.
The preparation of Herba Violae Hortensis extract:
The water of sieve Herba Violae Hortensis fine powder and 8 parts of weight of 1 part of weight is heated decoction, extracted 1 hour, extract 4 times.Collect the extracting solution of each time, evaporation and concentration, volume is to 1/3rd of the extracting solution total amount.After concentrated solution lets cool, adding while stirring 95% ethanol, is 70% until alcohol meter records ethanol content, and airtight cold preservation 48 hours filters, and filtrate is reclaimed ethanol through concentrating under reduced pressure, and the gained refined liquid adds phenoxyethanol in 1% ratio, namely gets the Herba Violae Hortensis extract.
The preparation of clean skin Gel mile:
Active component: above-mentioned Macrocystis pyrifera (L.) Ag. extract, deep layer Haiquan water, Herba Violae Hortensis extract are mixed with olive oil PEG-7 esters (2 parts of weight) and PEG-7 glyceryl cocoate (2 parts of weight), can suitably add water in this operating process, as water miscible active component; With above-mentioned " catching the water factor " in good time heating for dissolving, as oil-soluble active component.
Adjuvant: 2 parts of acrylic acid (ester) analog copolymers (3 parts of weight), lauroylamidopropyl betaine (10 parts of weight), coconut oleoyl amine DEA(weight), sodium laureth sulfate (8 parts of weight), methyl hydroxybenzoate (0.2 part of weight), ethyl hydroxybenzoate (0.1 part of weight), EDETATE SODIUM (0.1 part of weight), it is 100 parts that deionized water is mended ad pond om.
With each adjuvant mixing and stirring, be heated to 75 ℃, insulated and stirred 20 minutes, cooling.When temperature is down to 45 ℃, add active component, and the auxiliary element such as aminomethyl propanol (0.024 part of weight), Methylisothiazolinone (0.01 part of weight), essence, stir.
Embodiment 5: Gel mile of moisturizing eye
The preparation of Macrocystis pyrifera (L.) Ag. extract:
The mistake 10 mesh sieve Macrocystis pyrifera (L.) Ag. fine powders of 1 part of weight are mixed (the ethanol mass fraction is 60%) with the ratio of the ethanol-water solution of 9 parts of weight, in heating (temperature is between 100～115 ℃) on electric jacket, reflux, extract, 2 hours is extracted 3 times.Collect the extracting solution of each time, be evaporated to 1/3rd of total extracting liquid volume.The concentrated solution that obtains take butanediol as solvent, dilutes according to the ratio of 1:1, standing 24 hours of diluent, and sucking filtration namely gets required Macrocystis pyrifera (L.) Ag. extract.
The preparation of Herba Violae Hortensis extract:
The water of sieve Herba Violae Hortensis fine powder and 6 parts of weight of 1 part of weight is heated decoction, extracted 2 hours, extract 3 times.Collect the extracting solution of each time, evaporation and concentration, volume is to 1/3rd of the extracting solution total amount.After concentrated solution lets cool, adding while stirring 95% ethanol, is 70% until alcohol meter records ethanol content, and airtight cold preservation 48 hours filters, and filtrate is reclaimed ethanol through concentrating under reduced pressure, and the gained refined liquid adds phenoxyethanol in 1% ratio, namely gets the Herba Violae Hortensis extract.
The preparation that the moisturizing eye is Gel mile:
Active component: above-mentioned Macrocystis pyrifera (L.) Ag. extract, deep layer Haiquan water, Herba Violae Hortensis extract are mixed with butanediol (5 parts of weight), hyaluronate sodium (0.05 part of weight), can suitably add water in this operating process, as water miscible active component; Above-mentioned " catching the water factor " mixed with tocopherol acetas (1.5 parts of weight), and suitable heating for dissolving in this process is as oil-soluble active component.
Adjuvant: ammonium acryloyldime-thyltaurate// behenyl alcohol polyethers-25 methacrylate cross linked polymer (0.8 part of weight), allantoin (0.2 part of weight), glycerol (5 parts of weight), methyl hydroxybenzoate (0.2 part of weight), ethyl hydroxybenzoate (0.1 part of weight), EDETATE SODIUM (0.05 part of weight), it is 100 parts that deionized water is mended ad pond om.
With each adjuvant mixing and stirring, be heated to 75 ℃, insulated and stirred 20 minutes, cooling.When temperature is down to 45 ℃, add active component, and the auxiliary element such as Methylisothiazolinone (0.01 part of weight), essence, stir.
Embodiment 6: moisturizing astringent
The preparation of Macrocystis pyrifera (L.) Ag. extract:
The mistake 10 mesh sieve Macrocystis pyrifera (L.) Ag. fine powders of 1 part of weight are mixed (the ethanol mass fraction is 60%) with the ratio of the ethanol-water solution of 6 parts of weight, in heating (temperature is between 100～115 ℃) on electric jacket, reflux, extract, 2 hours is extracted 3 times.Collect the extracting solution of each time, be evaporated to 1/3rd of total extracting liquid volume.The concentrated solution that obtains take butanediol as solvent, dilutes according to the ratio of 1:1, standing 24 hours of diluent, and sucking filtration namely gets required Macrocystis pyrifera (L.) Ag. extract.
The preparation of Herba Violae Hortensis extract:
The water of sieve Herba Violae Hortensis fine powder and 8 parts of weight of 1 part of weight is heated decoction, extracted 3 hours, extract 3 times.Collect the extracting solution of each time, evaporation and concentration, volume is to 1/3rd of the extracting solution total amount.After concentrated solution lets cool, adding while stirring 95% ethanol, is 60% until alcohol meter records ethanol content, and airtight cold preservation 48 hours filters, and filtrate is reclaimed ethanol through concentrating under reduced pressure, and the gained refined liquid adds phenoxyethanol in 1% ratio, namely gets the Herba Violae Hortensis extract.
The preparation of moisturizing astringent:
Active component: above-mentioned Macrocystis pyrifera (L.) Ag. extract, deep layer Haiquan water, Herba Violae Hortensis extract are mixed with butanediol (5 parts of weight), hyaluronate sodium (0.03 part of weight), can suitably add water in this operating process, as water miscible active component; Above-mentioned " catching the water factor " mixed with American Avocado Tree oil (0.5 part of weight), and suitable heating for dissolving in this process is as oil-soluble active component.
Adjuvant: ammonium acryloyldime-thyltaurate// behenyl alcohol polyethers-25 methacrylate cross linked polymer (0.35 part of weight), glycerol (5 parts of weight), methyl hydroxybenzoate (0.1 part of weight), ethyl hydroxybenzoate (0.03 part of weight), EDETATE SODIUM (0.05 part of weight), it is 100 parts that deionized water is mended ad pond om.
With each adjuvant mixing and stirring, be heated to 75 ℃, insulated and stirred 20 minutes, cooling.When temperature is down to 45 ℃, add active component, and the auxiliary element such as Methylisothiazolinone (0.01 part of weight), essence, stir.
Embodiment 7: common protective skin cream 1
The preparation of common protective skin cream 1:
Lack Macrocystis pyrifera (L.) Ag. extract, deep layer Haiquan water, Herba Violae Hortensis extract and " catching the water factor " the other the same as in Example 1 in batching.
Embodiment 8: common protective skin cream 2
The preparation of common protective skin cream 2:
Lack Macrocystis pyrifera (L.) Ag. extract, deep layer Haiquan water, Herba Violae Hortensis extract and " catching the water factor " the other the same as in Example 2 in batching.
Embodiment 9: common moisturizer
The preparation of common moisturizer:
Lack Macrocystis pyrifera (L.) Ag. extract, deep layer Haiquan water, Herba Violae Hortensis extract and " catching the water factor " the other the same as in Example 3 in batching.
Embodiment 10: common clean skin Gel mile
The preparation of common clean skin Gel mile:
Lack Macrocystis pyrifera (L.) Ag. extract, deep layer Haiquan water, Herba Violae Hortensis extract and " catching the water factor " the other the same as in Example 4 in batching.
Embodiment 11: Gel mile of common moisturizing eye
The preparation that common moisturizing eye is Gel mile:
Lack Macrocystis pyrifera (L.) Ag. extract, deep layer Haiquan water, Herba Violae Hortensis extract and " catching the water factor " the other the same as in Example 5 in batching.
Embodiment 12: common moisturizing astringent
The preparation of common moisturizing astringent:
Lack in batching Macrocystis pyrifera (L.) Ag. extract, deep layer Haiquan water, Herba Violae Hortensis extract and " catching the water factor ", other is with embodiment 6.
Embodiment 13: human body skin moisture and flexibility test under the dehumidifier environment:
Choose 18 of 20～35 years old tested volunteers of women, wherein below 25 years old 6, be numbered 1～6, as First Year age group experimenter; 25～30 years old 6, be numbered 7～12, as Second Year age group experimenter; 30～35 years old 6, be numbered 13～18, as the 3rd age group experimenter.Choose two zones of face's symmetry, respectively as a control group with the test zone of test group, test in dehumidifier environment (20 ℃ of temperature, humidity 50%), test event has moisture and elasticity.Test group is both done same test with the prepared protective skin cream 1 of embodiment 1, matched group under the same conditions with the prepared common protective skin cream 1 of embodiment 7.The moisture test is in the interval of drafting, and test period is 24 hours; The cycle of flexibility test is 28 days, and every day, the interval was tested in 30 minutes after smearing sample.
The moisture content of skin test:
Adopt the test of capacitance method principle, with the moisture measurement probe vertical be pressed in tested skin surface, the probe top is pushed back a segment distance, probe is inner has a spring to make the probe top keep the pressure of 0.16N to be pressed in skin surface, demonstrate result on main frame in one second, and provide voice prompt.
The cleaning skin of face after the experimenter sat quietly in constant environment 30 minutes, uses skinanalysis apparatus (German CK, Cutometer MPA580) to carry out the measurement of tested position blank value.Facial zone subregion according to test group and matched group, smear the protective skin cream 1 of embodiment 1 preparation of equivalent and the common protective skin cream 1 of embodiment 7 preparations respectively at the cheek antimere, the moisture in two zones of test was respectively 30 minutes, 1 hour, 2 hours, 3 hours, 4 hours, 12 hours interval time.Record three groups of experimenters in the skin moisture content in test group and matched group zone, record each test data.The result of skin moisture content represents by the moisture measurement value (Moisture MeasurementValue, MMV) of setting, between 0～150.Each test data is deducted the variation that its blank value is this period MMV value, more namely draw the rate of increase of MMV value divided by blank value.
Skin moisture content Growth Rate Calculation formula is:
Skin moisture content rate of increase %=(MMVt-MMV
0)/MMV
0* 100%
MMV
0---smear front skin MMV
MMVt---smear rear t period skin MMV
The result of the test of test group and matched group moisture rate of increase is as follows:
According to above test data, make the curve chart that the skin moisture content rate of increase changes, as shown in Figure 1, 2, 3.
According to above test data and curve chart, draw following result of the test:
1. due to the difference at skin age, all in all, older group is in long interval, and skin moisture content descends comparatively obvious, and matched group is more obvious than test group.
2. in the grouping of all age group, test group is in long interval, and skin still has moisture preferably, and matched group is under equal conditions obviously low than test group.
in addition, according to above-mentioned test method, according to embodiment 2 prepared protective skin cream 2 and prepared common protective skin cream 2 conduct test and the contrasts of embodiment 8, the prepared common moisturizer of the moisturizer that embodiment 3 is prepared and embodiment 9 is as test and contrast, prepared common clean skin Gel mile of embodiment 4 prepared clean skin Gel mile and embodiment 10 carries out facial cleansing as test and contrast, Gel mile conduct test of common moisturizing eye and contrast that Gel mile of the moisturizing eye that embodiment 5 is prepared and embodiment 11 are prepared, the prepared common moisturizing astringent of the moisturizing astringent that embodiment 6 is prepared and embodiment 12 is as test and contrast, carry out the test that the skin moisture content rate of increase changes, the result that draws is: contain the Macrocystis pyrifera (L.) Ag. extract, three layers of water of deep layer Haiquan water complex and " catching the water factor " are supported the skin care item of maintenance composition, even in the environment of dehumidifier, still can be lasting, input hydrodynamic force endlessly to skin to all the period of time, make skin keep for a long time more water content, skin water profit is plentiful.
The skin elasticity test:
Adopt suction and stretching principle to test, in a tested skin surface constant negative pressure of generation (450mbar) was popped one's head in fc-specific test FC of skin inspiration, the degree of depth that skin is sucked in test probe was to record by a contactless optic testing system.The emitter and the receptor that comprise light in test probe, the ratio of light (ratio of utilizing emitted light and reception light) is directly proportional with the degree of depth that is inhaled into skin, so just obtain length that a skin is stretched and the relation curve of time, then determined the elastic performance of skin by the MPA software analysis.
Skin elasticity test and skin moisture content test are synchronously carried out, different is that flexibility test is done once every day, test period is 28 days, at testing moisture content blank value with when being 30 minutes interval time, and the skin elasticity after testing respectively the blank value of skin elasticity and using product.At the protective skin cream 1 of test group use embodiment 1 preparation, when matched group uses the common protective skin cream 1 test skin moisture content of embodiment 7 preparations, the skin elasticity of testing two zones, equal conditions test 28 days.Elasticity measurement value (the Elasticity Measurement Value of the result of skin elasticity by setting, EMV) represent, skin stretch amount namely, record three groups of experimenters in the skin elasticity in test group and matched group zone, record the test data in whole cycle, and calculate the skin elasticity increment rate.Each test data is deducted the variation that its blank value is this period EMV value, more namely draw the increment rate of EMV value divided by blank value.The result of skin elasticity test represents by the skin elasticity increment rate.
Skin elasticity increment rate computing formula is:
Skin elasticity increment rate %=(EMVt-EMV0)/EMV0 * 100%
EMV0---smear front skin EMV
EMVt---smear rear t period skin EMV
The result of the test of First Year age group skin elasticity increment rate is as follows:
The result of the test of Second Year age group skin elasticity increment rate is as follows:
The result of the test of the 3rd age group skin elasticity increment rate is as follows:
According to above test data, make the curve chart of every group of per day elasticity increment rate of experimenter, respectively as shown in Fig. 4,5,6.
According to above test data and curve chart, draw following result of the test:
1. the trial zone of skin and check plot have all obtained the increase of skin elasticity, and result shows that the trial zone is apparently higher than the check plot.
2. can be found out by three groups of result of the tests, with advancing age, the elasticity of skin increases degree and also weakens gradually, is also consistent with practical situation.
3. result of the test is verified again, and moisture content of skin directly affects the elasticity of skin, only has water content higher, and the plentiful skin of water profit just has skin elasticity preferably.
in addition, according to above-mentioned skin elasticity method of testing, according to embodiment 2 prepared protective skin cream 2 and prepared common protective skin cream 2 conduct test and the contrasts of embodiment 8, the prepared common moisturizer of the moisturizer that embodiment 3 is prepared and embodiment 9 is as test and contrast, prepared common clean skin Gel mile of embodiment 4 prepared clean skin Gel mile and embodiment 10 carries out facial cleansing as test and contrast, Gel mile conduct test of common moisturizing eye and contrast that Gel mile of the moisturizing eye that embodiment 5 is prepared and embodiment 11 are prepared, the prepared common moisturizing astringent of the moisturizing astringent that embodiment 6 is prepared and embodiment 12 is as test and contrast, carry out the test that the skin elasticity increment rate changes, the result that obtains is: contain the Macrocystis pyrifera (L.) Ag. extract, deep layer Haiquan water, three layers of water of Herba Violae Hortensis extract and " catching the water factor " are supported the skin care item of maintenance composition, even in the environment of dehumidifier, still can make skin obtain better elasticity improves.
Claims (7)
1.24 the foster maintenance of three layers of water of full-time water profit system skin care item is characterized in that, comprise by weight ratio following component:
The Macrocystis pyrifera (L.) Ag. extract, with the Macrocystis pyrifera (L.) Ag. weighing scale, 1～30 part;
Deep layer Haiquan water, 0.01～25 part;
The Herba Violae Hortensis extract, with the Herba Violae Hortensis weighing scale, 1～15 part;
Vegetable oil, 0.001～10 part;
Fructus oleae europaeae oil non-saponifiable matter, 0.001～5 part;
Hydrogenated vegetable oil, 0.001～5 part;
Glyceryl stearate, 0.001～2 part;
Phytosterol, 0.001～3 part; And
Tocopherol, 0.001～3 part.
2. skin care item according to claim 1, is characterized in that, described Macrocystis pyrifera (L.) Ag. extract prepares by the following method: after the Herb Macrocystis pyrifera (L.) Ag. is pulverized, add ethanol water to extract, extracting solution is concentrated and filter gained after the butanediol dilution.
3. skin care item according to claim 2, it is characterized in that: in the preparation method of described Macrocystis pyrifera (L.) Ag. extract, in ethanol water, the mass fraction of ethanol is 60%; The Macrocystis pyrifera (L.) Ag. of every 1 part of weight adds the ethanol water of 5-9 parts of weight.
4. skin care item according to claim 2, it is characterized in that: in the preparation method of described Macrocystis pyrifera (L.) Ag. extract, after adding ethanol water, heating and refluxing extraction 1～3 hour is extracted merge extractive liquid, 2～4 times.
5. skin care item according to claim 1, it is characterized in that: described Herba Violae Hortensis extract prepares by the following method: after the Herb Herba Violae Hortensis is pulverized, decoct with water extraction, precipitate with ethanol after the extracting solution evaporation and concentration makes ethanol content reach 60～75%.Through concentrating under reduced pressure, filtration obtains again.
6. skin care item according to claim 5, is characterized in that: in the preparation method of described Herba Violae Hortensis extract, decoct with water and extracted 1～3 hour, extract merge extractive liquid, 2～4 times.
7. skin care item according to claim 5, it is characterized in that: in the preparation method that institute's Herba Violae Hortensis extract is stated, working concentration is that 95% ethanol carries out precipitate with ethanol.
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| CN103385848A (en) * | 2013-06-27 | 2013-11-13 | 安婕妤化妆品科技股份有限公司 | Lotion and preparation method and application |
| CN104498239A (en) * | 2014-12-09 | 2015-04-08 | 韦爱琴 | Washing soap capable of sterilizing and moistening skin |
| CN105012221A (en) * | 2014-04-23 | 2015-11-04 | 广州市白云联佳精细化工厂 | Skin protection system with three-layer moisture nourishing effect |
| CN105078810A (en) * | 2014-05-23 | 2015-11-25 | 广州市白云联佳精细化工厂 | Plant-based active elastin factor (AEF) capable of improving skin elasticity |
| CN105560158A (en) * | 2016-01-22 | 2016-05-11 | 诺斯贝尔化妆品股份有限公司 | Skin whitening and moisturizing snow melting essence emulsion |
| CN106491422A (en) * | 2016-11-03 | 2017-03-15 | 广州法蔓妮化妆品科技有限公司 | A kind of pure and fresh lava sea water spray mist of Herba Violae Hortensiss |
| CN107375047A (en) * | 2017-07-03 | 2017-11-24 | 李剑峰 | Resveratrol cyclodextrin inclusion compound gel and its preparation method and application |
| CN108836905A (en) * | 2018-07-11 | 2018-11-20 | 佛山市奥姿美生物科技有限公司 | The moisturizing maintenance composition for stimulating cell aquaporin to generate |
| CN110151625A (en) * | 2016-08-24 | 2019-08-23 | 田中荣 | A kind of cosmetic composition with moisturizing maintenance effect suitable for whole skin |
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| CN115364000B (en) * | 2022-09-13 | 2024-05-31 | 诺斯贝尔化妆品股份有限公司 | Cosmetic composition with soothing and repairing effects, freeze-dried mask and preparation method |
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| CN103385848A (en) * | 2013-06-27 | 2013-11-13 | 安婕妤化妆品科技股份有限公司 | Lotion and preparation method and application |
| CN103385848B (en) * | 2013-06-27 | 2014-07-30 | 安婕妤化妆品科技股份有限公司 | Lotion and preparation method and application |
| CN105012221A (en) * | 2014-04-23 | 2015-11-04 | 广州市白云联佳精细化工厂 | Skin protection system with three-layer moisture nourishing effect |
| CN105078810A (en) * | 2014-05-23 | 2015-11-25 | 广州市白云联佳精细化工厂 | Plant-based active elastin factor (AEF) capable of improving skin elasticity |
| CN104498239A (en) * | 2014-12-09 | 2015-04-08 | 韦爱琴 | Washing soap capable of sterilizing and moistening skin |
| CN105560158B (en) * | 2016-01-22 | 2019-01-11 | 诺斯贝尔化妆品股份有限公司 | Skin whitening, moisturizing snow melts essence lotion |
| CN105560158A (en) * | 2016-01-22 | 2016-05-11 | 诺斯贝尔化妆品股份有限公司 | Skin whitening and moisturizing snow melting essence emulsion |
| CN110151625A (en) * | 2016-08-24 | 2019-08-23 | 田中荣 | A kind of cosmetic composition with moisturizing maintenance effect suitable for whole skin |
| CN106491422A (en) * | 2016-11-03 | 2017-03-15 | 广州法蔓妮化妆品科技有限公司 | A kind of pure and fresh lava sea water spray mist of Herba Violae Hortensiss |
| CN107375047A (en) * | 2017-07-03 | 2017-11-24 | 李剑峰 | Resveratrol cyclodextrin inclusion compound gel and its preparation method and application |
| CN108836905A (en) * | 2018-07-11 | 2018-11-20 | 佛山市奥姿美生物科技有限公司 | The moisturizing maintenance composition for stimulating cell aquaporin to generate |
| CN115364000A (en) * | 2022-09-13 | 2022-11-22 | 诺斯贝尔化妆品股份有限公司 | Cosmetic composition with soothing and repairing effects, freeze-dried mask and preparation method |
| CN115364000B (en) * | 2022-09-13 | 2024-05-31 | 诺斯贝尔化妆品股份有限公司 | Cosmetic composition with soothing and repairing effects, freeze-dried mask and preparation method |
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