CN103145494B - Production method of chemical fertilizer accessory ingredient for prolonging leaf fertilizer lasting period - Google Patents
Production method of chemical fertilizer accessory ingredient for prolonging leaf fertilizer lasting period Download PDFInfo
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- CN103145494B CN103145494B CN201310060766.4A CN201310060766A CN103145494B CN 103145494 B CN103145494 B CN 103145494B CN 201310060766 A CN201310060766 A CN 201310060766A CN 103145494 B CN103145494 B CN 103145494B
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Abstract
The invention aims at providing a novel leaf fertilizer accessory ingredient. A production method of the leaf fertilizer accessory ingredient is as follows: natural nano material compounds such as straw ash in a power plant are physically and chemically modified, so that the surface hydroxyl number is increased, and dispersion performance and absorption performance are improved, the leaf fertilizer nutrient is preferably absorbed by a micro nano structure of an accessory ingredient material and fixed by a coarse plant leaf, the adhesive ability of the leaf fertilizer on the plant leaf is improved, the drifting, eluviation loss and volatilization loss are reduced, the aims of prolonging lasting period and improving the nutrient utilization are achieved. According to the method, the main raw material is natural and environment-friendly and is free from the secondary pollution; and meanwhile, the fertilization dosage and the fertilization times are reduced, the labor and the cost are saved, and the environment pollution is reduced. The technology conforms to the leaf fertilizer development direction and has great market potential.
Description
Technical field
Present method relates to a kind of production method that extends the chemical fertilizer auxiliary agent of foliage fertilizer lasting period, belongs to chemical fertilizers production field.
Background technology
Foliage fertilizer is that nutritive element is applied to farm crop blade surface and by the absorption of blade, brings into play a kind of fertilizer type of its function.Research shows, the nutritive substance that sprays application to plant surface can be absorbed by " gap " in plant leaf surface pore and stratum corneum and enters in plant materials and then be converted and utilize.The many small pores of plant leaf surface arrangement, they are also convenient to entering of nutritive substance in the function of exercising gaseous interchange, are the principal passages that plant absorbs foliage fertilizer.In addition, blade face stratum corneum is comprised of a kind of long chain fatty acid polymkeric substance with hydroxyl and carboxyl, the molecular gap of this polymkeric substance and the hydroxyl on molecule, carboxylated hydrophilic group can allow the aqueous solution penetrate in leaf, become another channel that plant absorbs foliage fertilizer nutritive substance.Leaf leaven, particularly some easily by the element of soil fixing as phosphorus, copper, manganese, iron, zinc etc., there is fast, the effective feature that absorbs, can meet in time the requirement of crop growth, can prevent and treat in time or correct again some nutritional deficiency disease or need to supply with rapidly the remedial measures of nutrient because of natural disaster.Nutrient from Foliage Absorption can directly affect internal metabolism, involved in plant metabolism, and the activity of reinforcement endoenzyme, can improve the resistance of plant, postpones leaf presenility, and can promote precocity etc.Foliage-spray both can be saved expense, can avoid again harm.Foliage-spray consumption is little, especially phosphorus, potash fertilizer and trace element fertilizer, and consumption is only the 1/10-1/5 of soil application amount, both can reduce investment outlay, the problem that also can avoid trace element fertilizer consumption too much to work the mischief.Leaf dressing and root fertilising combination, can play mutually promote, supplementary effect mutually.In a word, foliage fertilizer amount of application is few, effect is obvious rapidly, utilization rate of fertilizer is high, it is a kind of not only economic, but also fertilizer variety efficiently, particularly the reasonable interpolation of some trace elements has promoter action to plant-growth, has become the important supplementary fertilizer variety of large root fertilizer, has the larger market requirement and application prospect.
In the last few years, all take much count of production and the application of foliar nutrient both at home and abroad.The commercialization of China's foliar nutrient is since the 1980s, development through two more than ten years, the production of foliar nutrient obtains huge development, from single component, develops into composite parts, from macronutrient, develops into trace element and beneficial element, from inorganic nutrients, develop into organic nutrient, from mineral nutrient, develop into interpolation plant-growth regulator, foliar nutrient item are various, of a great variety, multifarious, the whole country approximately has thousands of kinds more than.End in May, 2007, China's foliar nutrient is formally registered 737 of products, interim registration product reaches 1398, the annual amount of application in the whole nation is about 600,000 tons of left and right, that product relates to is big or middle, micronutrient element and different organic active substances, product form has comprised the types such as solid, liquid, and product function is also different.
Yet, due to technique and technology still very unripe, foliar nutrient adhesive ability on plant leaf surface is not enough, the nutritive substance that sprays application to plant surface easily in wind, drench with rain, fly away under the effect of Exposure to Sunlight, leaching loss and volatilization, cause that fertilizer loss is serious, the lasting period is short, utilization ratio is low, need to repeatedly use, both waste a large amount of human and material resources and financial resources, cause again environmental pollution.So one of foliar nutrient industry development direction is exactly to improve blade face adhesive ability and extend the lasting period, yet about the technology of this respect, rarely has report at present.This patent provides a kind of raising foliar nutrient adhesive ability for this problem, extends the technology of lasting period.This technology mainly utilizes the micro-nano structure of natural inorganic nano material that foliar nutrient nutrient is fixed on blade face, the volatilization that reduces that it flies away, woods is become estranged, thus extended the lasting period, meet industry development direction, there is larger market potential.
Summary of the invention
The object of this invention is to provide a kind of new foliar fertilizer auxiliary agent, concrete principle is: by power plant straw ash-flyash-attapulgite-xylogen compound is carried out to physically modified and chemically modified, increase its surface hydroxyl quantity, dispersing property and absorption property, thereby foliage fertilizer nutrient is better adsorbed in promoter material micro-nano structure, and fixed by coarse plant leaf surface, thereby reach, improve the adhesive ability of foliage fertilizer on plant leaf surface, reduce and run off, extend the object of lasting period.
The present invention is achieved by the following technical solutions:
1, a production method that extends the chemical fertilizer auxiliary agent of foliage fertilizer lasting period, is characterized in that comprising the following steps:
(1) 200-400 object power plant straw ash, flyash, attapulgite and xylogen are mixed according to 2-4:1-2:1-3:1-2 mass ratio, make matrix material;
(2) above-mentioned matrix material is joined in tap water and be made into the suspension liquid that concentration is 50-200g/L, then utilize 5-10 MeV, the high-energy electron beam irradiation suspension liquid 5-10 minute of 10-50 kGy;
(3) utilize ozonizer to pass into ozone 10-30 minute to the suspension liquid after irradiation, when passing into ozone, utilize the uv light irradiation of 10-30W;
(4) toward through adding the aminopropyl triethoxysilane of 50-60 ℃ in the suspension liquid of above-mentioned processing, stir standing 30-40 minute after 20-30 minute under 150-200rpm, remove supernatant liquor, remaining mud, in 80-100 ℃ of oven dry, is ground into 300-350 order powder;
(5) powder obtaining in (4) is mixed according to the mass ratio of 85-90:5-10:2-10 with 200-400 order sodium-metaphosphate and 200-400 order trisodium phosphate, obtain.
The chemical fertilizer auxiliary agent of described prolongation foliage fertilizer lasting period, its using method is that this chemical fertilizer auxiliary agent is added in foliage fertilizer according to 3-8% massfraction.
Described a kind of production method that extends the chemical fertilizer auxiliary agent of foliage fertilizer lasting period, the thickness that it is characterized in that radiation exposed suspension liquid in step 2 is 10-15 cm.
Described a kind of production method that extends the chemical fertilizer auxiliary agent of foliage fertilizer lasting period, is characterized in that the quality of the aminopropyl triethoxysilane that adds in step 4 is the 1/4-1/3 of dry matter weight in suspension liquid.
Useful achievement of the present invention has:
1, main raw material(s) natural environmental-protective, can not introduce secondary pollution;
2, effectively strengthen foliage fertilizer at the adhesive ability of plant surface, reduce fly away, leaching loss and volatilization loss, extend the lasting period, improve plant recovery of nutrient;
3, reduce fertilising consumption and number of times, save labour and cost, reduce environmental pollution.
Embodiment
embodiment 1
1, order number is to 400 object power plant straw ash, flyash, attapulgite and xylogen and mixes according to 2:1:1:1 mass ratio, make power plant straw ash-flyash-attapulgite-lignin composite material;
2, power plant straw ash-flyash-attapulgite-lignin composite material is joined in tap water and be made into the suspension liquid that concentration is 200 g/L, utilize 10 MeV, the high-energy electron beam irradiation suspension liquid of 50 kGy 10 minutes;
3, utilize ozonizer to pass into ozone 20 minutes to suspension liquid, utilize 30W uv light irradiation simultaneously;
4, toward the aminopropyl triethoxysilane adding in the suspension liquid of processing (quality be in suspension liquid dry matter weight 1/4) temperature is controlled at 60 degrees Celsius, 200rpm stirs 30 minutes, standing 30 minutes afterwards, removes supernatant, remaining mud, in 80 degrees Celsius of oven dry, is ground into 300 orders;
5, the powder obtaining in (4) is mixed according to the mass ratio of 85:10:5 with 300 order sodium-metaphosphates and 300 order trisodium phosphates, obtain foliage fertilizer auxiliary agent described in this patent;
embodiment 2
1, order number is to 300 object power plant straw ash, flyash, attapulgite and xylogen and mixes according to 3:1:2:1 mass ratio, make power plant straw ash-flyash-attapulgite-lignin composite material;
2, power plant straw ash-flyash-attapulgite-lignin composite material is joined and in tap water, be made into the suspension liquid that concentration is 100 g/L, the high-energy electron beam irradiation suspension liquid of utilization (thickness is 7 cm) 60 minutes;
3, utilize ozonizer to pass into ozone 10 minutes to suspension liquid, utilize 30W uv light irradiation simultaneously;
4, toward the aminopropyl triethoxysilane adding in the suspension liquid of processing (quality be in suspension liquid dry matter weight 1/4) temperature is controlled at 50 degrees Celsius, 200rpm stirs 20 minutes, standing 30 minutes afterwards, removes supernatant, remaining mud, in 80 degrees Celsius of oven dry, is ground into 300 orders;
5, the powder obtaining in (4) is mixed according to the mass ratio of 80:15:5 with 400 order sodium-metaphosphates and 400 order trisodium phosphates, obtain foliage fertilizer auxiliary agent described in this patent.
Claims (3)
1. a production method that extends the chemical fertilizer auxiliary agent of foliage fertilizer lasting period, is characterized in that comprising the following steps:
(1) 200-400 object power plant straw ash, flyash, attapulgite and xylogen are mixed according to 2-4:1-2:1-3:1-2 mass ratio, make matrix material;
(2) above-mentioned matrix material is joined in tap water and be made into the suspension liquid that concentration is 50-200g/L, then utilize 5-10 MeV, the high-energy electron beam irradiation suspension liquid 5-10 minute of 10-50 kGy;
(3) utilize ozonizer to pass into ozone 10-30 minute to the suspension liquid after irradiation, when passing into ozone, utilize the uv light irradiation of 10-30W;
(4) toward through adding the aminopropyl triethoxysilane of 50-60 ℃ in the suspension liquid of above-mentioned processing, stir standing 30-40 minute after 20-30 minute under 150-200rpm, remove supernatant liquor, remaining mud, in 80-100 ℃ of oven dry, is ground into 300-350 order powder;
(5) powder obtaining in (4) is mixed according to the mass ratio of 85-90:5-10:2-10 with 200-400 order sodium-metaphosphate and 200-400 order trisodium phosphate, obtain;
The chemical fertilizer auxiliary agent of described prolongation foliage fertilizer lasting period, its using method is that this chemical fertilizer auxiliary agent is added in foliage fertilizer according to 3-8% massfraction.
2. a kind of production method that extends the chemical fertilizer auxiliary agent of foliage fertilizer lasting period according to claim 1, the thickness that it is characterized in that radiation exposed suspension liquid in step 2 is 10-15 cm.
3. a kind of production method that extends the chemical fertilizer auxiliary agent of foliage fertilizer lasting period according to claim 1, is characterized in that the quality of the aminopropyl triethoxysilane that adds in step 4 is the 1/4-1/3 of dry matter weight in suspension liquid.
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| CN103145494B true CN103145494B (en) | 2014-04-02 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106278562A (en) * | 2016-08-01 | 2017-01-04 | 寿县知祝常乐水果种植专业合作社 | A kind of foliar fertilizer of fertilizer efficiency period length |
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| CN103467197B (en) * | 2013-09-10 | 2014-11-05 | 中国科学院合肥物质科学研究院 | Acid-proof, moisture-holding and superactive special fertilizer technology for forestry and additive |
| CN103483070B (en) * | 2013-09-10 | 2014-11-05 | 中国科学院合肥物质科学研究院 | Controlled fertilizer technology and aid |
| CN105646054A (en) * | 2014-11-14 | 2016-06-08 | 中国科学院微生物研究所 | Special potato foliar fertilizer and special potato foliar fertilizer additive |
| CN104973973A (en) * | 2015-07-08 | 2015-10-14 | 杨君 | Fruit tree dedicated foliar fertilizer |
| CN106242674A (en) * | 2016-08-19 | 2016-12-21 | 北海市伟恒生态农业有限公司 | Radix Ipomoeae fertilizer |
| CN106831158A (en) * | 2017-03-01 | 2017-06-13 | 新昌县天姥园艺发展有限公司 | Extend auxiliary agent of Plant leaf fertilizer lasting period and preparation method thereof |
| CN112142513B (en) * | 2020-09-27 | 2022-04-22 | 陕西科技大学 | Chelated foliar fertilizer for vegetables and preparation method and application thereof |
| CN114051894B (en) * | 2021-11-09 | 2023-06-13 | 贺州戎威农业开发有限责任公司 | Passion fruit planting method |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN100413816C (en) * | 2006-05-18 | 2008-08-27 | 中国科学院等离子体物理研究所 | Nitrogen fertilizer solidifying method by active soil, flocculant, adsorbent composite material and fertilizer |
| CN100491500C (en) * | 2006-07-28 | 2009-05-27 | 中国科学院等离子体物理研究所 | Environment friendly composite material for controlling loss of nitrogen fertilizer and applications |
| CN101367689A (en) * | 2007-08-17 | 2009-02-18 | 中国科学院等离子体物理研究所 | Environment friendly composite material for controlling loss of nitrogenous fertilizer, preparation method and use method thereof |
| CN102173962A (en) * | 2011-01-07 | 2011-09-07 | 中国科学院合肥物质科学研究院 | Built-in screen type controlled-release urea as well as production method and application thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106278562A (en) * | 2016-08-01 | 2017-01-04 | 寿县知祝常乐水果种植专业合作社 | A kind of foliar fertilizer of fertilizer efficiency period length |
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