CN103109805A - Pesticide residue degradation agent for modern Chinese medicines and preparation method thereof - Google Patents
Pesticide residue degradation agent for modern Chinese medicines and preparation method thereof Download PDFInfo
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- CN103109805A CN103109805A CN2013100579931A CN201310057993A CN103109805A CN 103109805 A CN103109805 A CN 103109805A CN 2013100579931 A CN2013100579931 A CN 2013100579931A CN 201310057993 A CN201310057993 A CN 201310057993A CN 103109805 A CN103109805 A CN 103109805A
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- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 41
- 230000015556 catabolic process Effects 0.000 title claims abstract description 40
- 238000006731 degradation reaction Methods 0.000 title claims abstract description 40
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 239000000447 pesticide residue Substances 0.000 title abstract description 7
- 229940126678 chinese medicines Drugs 0.000 title abstract 4
- 239000000575 pesticide Substances 0.000 claims abstract description 44
- 239000007788 liquid Substances 0.000 claims abstract description 38
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 33
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- 238000005516 engineering process Methods 0.000 claims abstract description 17
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 claims abstract description 11
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 11
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000004327 boric acid Substances 0.000 claims abstract description 11
- 239000004202 carbamide Substances 0.000 claims abstract description 11
- -1 compound sodium nitrate Chemical class 0.000 claims abstract description 11
- 235000003891 ferrous sulphate Nutrition 0.000 claims abstract description 11
- 239000011790 ferrous sulphate Substances 0.000 claims abstract description 11
- 229930003944 flavone Natural products 0.000 claims abstract description 11
- 150000002213 flavones Chemical class 0.000 claims abstract description 11
- 235000011949 flavones Nutrition 0.000 claims abstract description 11
- 239000004021 humic acid Substances 0.000 claims abstract description 11
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims abstract description 11
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims abstract description 11
- 239000000843 powder Substances 0.000 claims abstract description 11
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000012452 mother liquor Substances 0.000 claims description 67
- 239000000047 product Substances 0.000 claims description 34
- 238000003756 stirring Methods 0.000 claims description 25
- 241000411851 herbal medicine Species 0.000 claims description 23
- 238000010438 heat treatment Methods 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 16
- 239000006228 supernatant Substances 0.000 claims description 15
- 239000001828 Gelatine Substances 0.000 claims description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 10
- DYUQAZSOFZSPHD-UHFFFAOYSA-N Phenylpropyl alcohol Natural products CCC(O)C1=CC=CC=C1 DYUQAZSOFZSPHD-UHFFFAOYSA-N 0.000 claims description 10
- 241000282894 Sus scrofa domesticus Species 0.000 claims description 10
- 238000013019 agitation Methods 0.000 claims description 10
- 229920000159 gelatin Polymers 0.000 claims description 10
- 235000019322 gelatine Nutrition 0.000 claims description 10
- 210000000496 pancreas Anatomy 0.000 claims description 10
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 10
- 238000000746 purification Methods 0.000 claims description 10
- 229910052708 sodium Inorganic materials 0.000 claims description 10
- 239000011734 sodium Substances 0.000 claims description 10
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 claims description 10
- 235000012141 vanillin Nutrition 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 6
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- 230000008030 elimination Effects 0.000 claims description 5
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- 239000002994 raw material Substances 0.000 claims description 5
- 239000000052 vinegar Substances 0.000 claims description 5
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- 239000000463 material Substances 0.000 abstract description 10
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 5
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- 238000000354 decomposition reaction Methods 0.000 abstract description 2
- 239000013543 active substance Substances 0.000 abstract 1
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- 229940062190 pancreas extract Drugs 0.000 abstract 1
- 239000000779 smoke Substances 0.000 abstract 1
- 239000004317 sodium nitrate Substances 0.000 abstract 1
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Inorganic materials [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 abstract 1
- 235000010344 sodium nitrate Nutrition 0.000 abstract 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 abstract 1
- 230000002459 sustained effect Effects 0.000 abstract 1
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Abstract
The invention relates to a pesticide residue degradation agent for modern Chinese medicines and a preparation method thereof. A micro-nano biotechnology, an enzyme active substance control technology and the like are utilized for the produced pesticide residue degradation agent for the modern Chinese medicines. The plant cell membrane function can be improved by enzyme action and biological decomposition action after the agent is used; an intelligent, sustained and auxiliary agent is also added to improve and change the plant quality; pesticide and heavy metal residues are degraded; the traditional Chinese medicines are strengthened; and agricultural products can be facilitated to achieving the international standard. The pesticide residue degradation agent for the modern Chinese medicines, disclosed by the invention, is prepared from the following materials in parts by weight of: 300-350kg of a pig pancreas extract, 100-150kg of styrene acrylic amino acid concentrate, 50-100kg of plant humic acid, 30-70kg of bone glue, 20-50kg of boric acid, 50-100kg of smoke alkali liquor, 50-200kg of ethanol, 170-500kg of water, 5-10kg of vanillic aldehyde, 1-5kg of compound sodium nitrate powder liquid, 50-150kg of urea, 40-120kg of pyroligneous, 5-10kg of flavones, 5-10kg of ferrous sulfate, and 1-5kg of citric acid by using a certain preparation method.
Description
One, technical field:
The present invention relates to a kind of modern Chinese herbal medicine pesticide residual degradation agent and preparation method thereof.
Two, background technology:
The technology of the art of this patent high activity drought resisting nutrition enzymic activity engineering pesticide residual degradation agent project is extended, and I have obtained country and have authorized utility model patent modern Chinese herbal medicine pesticide residue degeneration system to be used for the production of this product.Chinese medicine is the cultural heritage of China's preciousness, is Chinese nation's disease preventing and treating, rehabilitation, a magic weapon that produces offspring.In recent years, the demand expanding day of countries in the world to natural drug, under the prerequisite that world's green consumption trend, food security, the residual thing of crops exceed standard, people particularly pay close attention to green medicine.Now, the annual Chinese medicine volume of trade in the world has reached 40,000,000,000 dollars, and annual China's Chinese medicine export amount is approximately 600,000,000 dollars a few days ago with 10% speed increment, only accounts for 3%～5% of cosmopolitian plant medicinal material market, and the status of this and China Chinese medicine big country is extremely unbecoming.The residual quantity of the harmful substances such as the uncertain and agricultural chemicals of active ingredients from traditional Chinese medicinal, heavy metal exceeds standard, and is the two large obstacles that Chinese medicine ranks among the world.The Chinese herbal medicine of China's export is is repeatedly checked and detained because of reasons such as residue of pesticide exceed standard on the state markets such as America and Europe, and pesticide residual contamination has become the obstacle that traditional Chinese medicine goes to the world, becomes major issue anxious to be resolved in current traditional Chinese medicine production.
Traditional Chinese medicine is pesticide abuse in planting process, makes a large amount of medicaments be attached directly on plant.Because the grower of traditional Chinese medicine lacks basic plant protection general knowledge, do not pay attention to Pesticide Residue, the phenomenon of pesticide abuse is very serious.The grower of some medicinal material is efficient, cheap to the selection criteria of agricultural chemicals, seldom takes the impact of toxicity of pesticide and high residual effect centering quality of medicinal material into account.Increase income for protecting to produce, grower's spraying times is frequent, and be often the uses that are mixed of several high-toxic pesticides, particularly in insect pest serious period, use the concentration of agricultural chemicals to double, not only killed the natural enemy of a large amount of damage by disease and insect, and make the fall ill increase of worm pesticide resistance, cost accounting and difficulty of prevention and cure increasing, caused simultaneously the traditional Chinese medicine Pesticide Residues to exceed standard, increased the weight of residual in the surrounding enviroment of medicinal material producing region of agricultural chemicals, production has brought the harm of continuation to medicinal material, has formed the vicious circle that is difficult to reverse, and makes quality of medicinal material worse and worse.
China is traditional Chinese medicine big producing country, is also the maximum consumption market of traditional Chinese medicine.Along with the quickening of world economic integration development process, the traditional Chinese medicine of China and Chinese patent drug must move towards the international market and participate in the competition.Only maintain strict control over the gate of the quality monitoring of Chinese medicine and preparation, in strict control, the medicinal herb grower is residual, just can make Chinese medicine really reach the purpose of curing the sickness to save the patient, traditional Chinese medicine is advanced more healthily, could promote the modernization of Chinese medicine and internationalization, just can make China's traditional Chinese medicine production will enter orderly benign development track.China does not still have a kind of product of can scale low-cost effectively degraded Farm chemical of Chinese berbs residue at present, and existing Farm chemical of Chinese berbs residue Study on degradation is many, and product and production technology are seldom.Therefore it is very necessary innovating residual preparation and the processing technology thereof of a kind of easy, effective modern Chinese herbal medicine and Modern Agriculture crop degraded agriculture.
Three, summary of the invention:
The present invention is in order to solve the weak point in the above-mentioned background technology, a kind of modern Chinese herbal medicine pesticide residual degradation agent and preparation method thereof is provided, the modern Chinese herbal medicine pesticide residual degradation agent of its production utilizes the technology such as micro-nano biotechnology, the regulation and control of enzymic activity material, after use, can by enzyme effect, biological decomposition, can improve the plant cell membrane interaction; Be aided with intelligent, slow controlled release adjuvant again, improve and improve plant quality, degrading pesticide and heavy-metal residual are strengthened Chinese medicine and agricultural product product and are reached international standard.
for achieving the above object, the technical solution used in the present invention is: the agent of a kind of modern Chinese herbal medicine pesticide residual degradation, it is characterized in that: described degradation agent is comprised of following weight portion raw material: Pancreas Sus domestica purification thing 300-350kg, phenylpropyl alcohol amino acid primary liquid 100-150 kg, plant humic acid 50-100kg, gelatine 30-70kg, boric acid 20-50kg, nicotinic liquid 50-100kg, ethanol 50-200kg, water 170-500kg, vanillin 5-10kg, multiple nitre powder sodium liquid 1-5kg, urea 50-150kg, pyroligneous liquor 40-120 kg, flavones 5-10 kg, ferrous sulfate 5-10kg, citric acid 1-5kg.
The preparation method of described a kind of modern Chinese herbal medicine pesticide residual degradation agent is characterized in that: described preparation method's step is:
1. get the plant humic acid and put into reactor and add hot water, heating is stirred to CL, and inclusion 20-30min; Get Pancreas Sus domestica purification thing, the phenylpropyl alcohol amino acid primary liquid stirs, and is heated to 75-90 ℃, then gets gelatine, is stirred to CL, and inclusion 20-40min, regulates PH4-5; Get at last boric acid and add, heating is stirred to CL, and inclusion 20-40min, regulates PH4-5, gets the mother liquor first, and is standby;
2. add vanillin in the reactor that can add thermal agitation, till the low-concentration ethanol heating for dissolving with 40% is limpid to solution, get mother liquor second, standby;
3., a, get nicotinic liquid and boil at twice, add for the first time water 30-45kg, 100 ℃ boil and boil 60-80min, collect supernatant, add for the second time water 20-30kg, middle temperature is boiled 40-60min, the elimination residue is collected supernatant, merges the supernatant collection 50-75kg of twice;
B, get multiple nitre powder sodium liquid and put into vessel in heating water 4-20kg, heating is stirred to CL, then adds citric acid, makes it be acid PH＜4;
C, with the product of above-mentioned a step and the product mixing and stirring of b step, get mother liquor the third, standby;
4. the mother liquor first added thermal agitation and progressively add mother liquor second and mother liquor the third, stirring, then add urea and constantly be stirred to whole dissolvings, getting mother liquor 1;
5. mother liquor 1 is lowered the temperature, make its temperature be down to 40 ℃ of left and right; Add ferrous sulfate in temperature-fall period, be stirred to CL, and regulate PH4-6, get mother liquor 2;
6. get Pin vinegar liquid and flavones join mother liquor 2 under constantly stirring in, stir and make it even, add entry and regulate PH5-6, get mother liquor;
7. with the micro-nano technology, the mother liquor for preparing is carried out ultramicronising and process, get product.
It is that mother liquor resolving in dynamic state, high-pressure spray are evenly mixed that described ultramicronising is processed, and strengthens isothermal reaction 3h, after filtration, react, refilter to ultra microstructure and reach 80nm.
Compared with prior art, the present invention has following advantage and effect:
1, the modern Chinese herbal medicine pesticide residual degradation agent characteristics of the present invention's production are: utilize the technology such as micro-nano biotechnology, the regulation and control of enzymic activity material, after use, can stablize the plant cell membrane system, can accelerate crop metabolism after repeatedly using, improve photosynthetic efficiency, accelerate the accumulation of dry matter, improve crop anti-adversity and output; Be aided with intelligent, slow controlled release adjuvant again, improve and improve plant quality, degrading pesticide and heavy-metal residual are strengthened Chinese medicine and agricultural product product and are reached international standard, satisfy high-quality Chinese medicine and the requirement of agricultural product production.
2, the invention belongs to the novel outer source pesticide plant protection technology scope of chemistry, the product that described method is produced and this preparation method have filled up a domestic technique blank of the novel outer source pesticide plant protection technology product of chemistry, for Chinese herbal medicine and other agricultural byproducts production of China, export technical guarantee is provided.
Four, embodiment:
Embodiment one:
The agent of a kind of modern Chinese herbal medicine pesticide residual degradation is comprised of following weight portion raw material: Pancreas Sus domestica purification thing 300kg, phenylpropyl alcohol amino acid primary liquid 100 kg, plant humic acid 50kg, gelatine 30kg, boric acid 20kg, nicotinic liquid 50kg, ethanol 50kg, water 170kg, vanillin 5kg, multiple nitre powder sodium liquid 1kg, urea 50kg, pyroligneous liquor 40 kg, flavones 5 kg, ferrous sulfate 5kg, citric acid 1kg.
The preparation method of a kind of modern Chinese herbal medicine pesticide residual degradation agent comprises the following steps:
1. get the plant humic acid and put into reactor and add hot water, heating is stirred to CL, and inclusion 20-30min; Get Pancreas Sus domestica purification thing, the phenylpropyl alcohol amino acid primary liquid stirs, and is heated to 75-90 ℃, then gets gelatine, is stirred to CL, and inclusion 20-40min, regulates PH4-5; Get at last boric acid and add, heating is stirred to CL, and inclusion 20-40min, regulates PH4-5, gets the mother liquor first, and is standby;
2. add vanillin in the reactor that can add thermal agitation, till the low-concentration ethanol heating for dissolving with 40% is limpid to solution, get mother liquor second, standby;
3., a, get nicotinic liquid and boil at twice, add for the first time water 30-45kg, 100 ℃ boil and boil 60-80min, collect supernatant, add for the second time water 20-30kg, middle temperature is boiled 40-60min, the elimination residue is collected supernatant, merges the supernatant collection 50-75kg of twice;
B, get multiple nitre powder sodium liquid and put into vessel in heating water 4-20kg, heating is stirred to CL, then adds citric acid, makes it be acid PH＜4;
C, with the product of above-mentioned a step and the product mixing and stirring of b step, get mother liquor the third, standby;
4. the mother liquor first added thermal agitation and progressively add mother liquor second and mother liquor the third, stirring, then add urea and constantly be stirred to whole dissolvings, getting mother liquor 1;
5. mother liquor 1 is lowered the temperature, make its temperature be down to 40 ℃ of left and right; Add ferrous sulfate in temperature-fall period, be stirred to CL, and regulate PH4-6, get mother liquor 2;
6. get Pin vinegar liquid and flavones join mother liquor 2 under constantly stirring in, stir and make it even, add entry and regulate PH5-6, get mother liquor;
7. with the micro-nano technology, the mother liquor for preparing is carried out ultramicronising and process, get product.
It is that mother liquor resolving in dynamic state, high-pressure spray are evenly mixed that described ultramicronising is processed, and strengthens isothermal reaction 3h, after filtration, react, refilter to ultra microstructure and reach 80nm.
Embodiment two:
The agent of a kind of modern Chinese herbal medicine pesticide residual degradation is comprised of following weight portion raw material: Pancreas Sus domestica purification thing 350kg, phenylpropyl alcohol amino acid primary liquid 150 kg, plant humic acid 100kg, gelatine 70kg, boric acid 50kg, nicotinic liquid 100kg, ethanol 200kg, water 500kg, vanillin 10kg, multiple nitre powder sodium liquid 5kg, urea 150kg, pyroligneous liquor 120 kg, flavones 10 kg, ferrous sulfate 10kg, citric acid 5kg.
The preparation method of a kind of modern Chinese herbal medicine pesticide residual degradation agent comprises the following steps:
1. get the plant humic acid and put into reactor and add hot water, heating is stirred to CL, and inclusion 20-30min; Get Pancreas Sus domestica purification thing, the phenylpropyl alcohol amino acid primary liquid stirs, and is heated to 75-90 ℃, then gets gelatine, is stirred to CL, and inclusion 20-40min, regulates PH4-5; Get at last boric acid and add, heating is stirred to CL, and inclusion 20-40min, regulates PH4-5, gets the mother liquor first, and is standby;
2. add vanillin in the reactor that can add thermal agitation, till the low-concentration ethanol heating for dissolving with 40% is limpid to solution, get mother liquor second, standby;
3., a, get nicotinic liquid and boil at twice, add for the first time water 30-45kg, 100 ℃ boil and boil 60-80min, collect supernatant, add for the second time water 20-30kg, middle temperature is boiled 40-60min, the elimination residue is collected supernatant, merges the supernatant collection 50-75kg of twice;
B, get multiple nitre powder sodium liquid and put into vessel in heating water 4-20kg, heating is stirred to CL, then adds citric acid, makes it be acid PH＜4;
C, with the product of above-mentioned a step and the product mixing and stirring of b step, get mother liquor the third, standby;
4. the mother liquor first added thermal agitation and progressively add mother liquor second and mother liquor the third, stirring, then add urea and constantly be stirred to whole dissolvings, getting mother liquor 1;
5. mother liquor 1 is lowered the temperature, make its temperature be down to 40 ℃ of left and right; Add ferrous sulfate in temperature-fall period, be stirred to CL, and regulate PH4-6, get mother liquor 2;
6. get Pin vinegar liquid and flavones join mother liquor 2 under constantly stirring in, stir and make it even, add entry and regulate PH5-6, get mother liquor;
7. with the micro-nano technology, the mother liquor for preparing is carried out ultramicronising and process, get product.
It is that mother liquor resolving in dynamic state, high-pressure spray are evenly mixed that described ultramicronising is processed, and strengthens isothermal reaction 3h, after filtration, react, refilter to ultra microstructure and reach 80nm.
Embodiment three:
The agent of a kind of modern Chinese herbal medicine pesticide residual degradation is comprised of following weight portion raw material: Pancreas Sus domestica purification thing 320kg, phenylpropyl alcohol amino acid primary liquid 130 kg, plant humic acid 80kg, gelatine 60kg, boric acid 40kg, nicotinic liquid 70kg, ethanol 100kg, water 300kg, vanillin 8kg, multiple nitre powder sodium liquid 4kg, urea 100kg, pyroligneous liquor 90 kg, flavones 8kg, ferrous sulfate 7kg, citric acid 3kg.
The preparation method of a kind of modern Chinese herbal medicine pesticide residual degradation agent comprises the following steps:
1. get the plant humic acid and put into reactor and add hot water, heating is stirred to CL, and inclusion 20-30min; Get Pancreas Sus domestica purification thing, the phenylpropyl alcohol amino acid primary liquid stirs, and is heated to 75-90 ℃, then gets gelatine, is stirred to CL, and inclusion 20-40min, regulates PH4-5; Get at last boric acid and add, heating is stirred to CL, and inclusion 20-40min, regulates PH4-5, gets the mother liquor first, and is standby;
2. add vanillin in the reactor that can add thermal agitation, till the low-concentration ethanol heating for dissolving with 40% is limpid to solution, get mother liquor second, standby;
3., a, get nicotinic liquid and boil at twice, add for the first time water 30-45kg, 100 ℃ boil and boil 60-80min, collect supernatant, add for the second time water 20-30kg, middle temperature is boiled 40-60min, the elimination residue is collected supernatant, merges the supernatant collection 50-75kg of twice;
B, get multiple nitre powder sodium liquid and put into vessel in heating water 4-20kg, heating is stirred to CL, then adds citric acid, makes it be acid PH＜4;
C, with the product of above-mentioned a step and the product mixing and stirring of b step, get mother liquor the third, standby;
4. the mother liquor first added thermal agitation and progressively add mother liquor second and mother liquor the third, stirring, then add urea and constantly be stirred to whole dissolvings, getting mother liquor 1;
5. mother liquor 1 is lowered the temperature, make its temperature be down to 40 ℃ of left and right; Add ferrous sulfate in temperature-fall period, be stirred to CL, and regulate PH4-6, get mother liquor 2;
6. get Pin vinegar liquid and flavones join mother liquor 2 under constantly stirring in, stir and make it even, add entry and regulate PH5-6, get mother liquor;
7. with the micro-nano technology, the mother liquor for preparing is carried out ultramicronising and process, get product.
It is that mother liquor resolving in dynamic state, high-pressure spray are evenly mixed that described ultramicronising is processed, and strengthens isothermal reaction 3h, after filtration, react, refilter to ultra microstructure and reach 80nm.
Five, test example:
1, test objective
According to correlation test technical regulation, determine the application effect of modern Chinese herbal medicine pesticide residual degradation agent on Radix Angelicae Sinensis of the military emerging war development and production of Yang Ling China shafts biotechnology Co., Ltd.
2, materials and methods
Be the modern Chinese herbal medicine pesticide residual degradation agent that Yang Ling China shafts biotechnology Co., Ltd produces for reagent product.
Be Radix Angelicae Sinensis for studying thing.
Experimental program: four processing are established in test: (CK) do not apply fertilizer (1); (2) mu is executed convention amount chemical fertilizer (according to local custom); (3) the whole bases of Chinese medicine pesticide residual degradation agent are executed; (4) Chinese medicine pesticide residual degradation agent base is executed 70%+ and is divided secondary to topdress 30%.The residential quarter area is 24m
2, triplicate, randomized arrangement.Fertilizer amount is according to local habits fertilization level, fertilizing method, and Chinese medicine pesticide residual degradation agent consumption usage by specification strict implement topdresses and uses fermentation method.Middle fertility uniformity experimental field, output adopt singles, single method of receiving, singly weighing, and carry out statistical analysis.
3, test site
Test is located at the Heyang County and knows Cao Jia slope, fort township, and quality is the Yellow River beach of sandy soil, and soil fertility is medium, and front stubble is mulched maize, broadcasts front base and executes farmyard manure 3000kg/ mu.The row such as plantation density employing only son and heir cultivation, line-spacing 40cm, spacing in the rows 20cm, every hm
212.75 ten thousand strains of keeping a full stand of seedings.Control measures are undertaken by peasant household's custom.
4, test results and analysis
By above test method, the impact of Chinese medicine pesticide residual degradation agent on Radix Angelicae Sinensis output: find out from yield result (seeing Table 1), the output of fresh of amounting to of executing the agent of Chinese medicine pesticide residual degradation has surpassed contrast directly perceived, than contrast field volume increase 206.6kg, volume increase 17.87%.
The impact of Chinese medicine pesticide residual degradation agent on the Radix Angelicae Sinensis major traits: survey by the field and produce acquisition, can improve the grade (seeing Table 2) of product after using, first-class Radix Angelicae Sinensis accounts for 51.9% of total product, increases by 2.1% than contrast; Second-class Radix Angelicae Sinensis, third-class Radix Angelicae Sinensis successively decrease to some extent than contrast, and wherein second-class Radix Angelicae Sinensis reduces 0.6%, and third-class Radix Angelicae Sinensis reduces 4.9%.Illustrate and use the yield and quality that has improved first-class Radix Angelicae Sinensis after the agent of Chinese medicine pesticide residual degradation, the agriculture of degrading after tested is residual on average reaches 95%, has improved commodity rate.
After using the agent of Chinese medicine pesticide residual degradation, can impel ontogeny, according to randomly drawing 10 strain sample measurement results (seeing Table 3).Use the Radix Angelicae Sinensis output of Chinese medicine pesticide residual degradation agent＞contrast, the contrast volume increase 20.6%.The Radix Angelicae Sinensis proportion of using the agent of Chinese medicine pesticide residual degradation accounts for 51.3%, increases by 1.5% than contrast, has improved ratio defective product.The 2nd, to observe in vegetative period, grow not obvious early stage, and the later stage, the Ye Sehei of base fertilising was green, and contrast leaf look yellowish, and the ratio contrast plant height 5cm of base fertilising reduces 8-10d breeding time.Comprehensive each factor analysis all is better than contrasting the field, illustrate Chinese medicine agricultural production degradation agent suitable on Radix Angelicae Sinensis base execute.
The impact of Chinese medicine pesticide residual degradation agent on the Radix Angelicae Sinensis economic benefit: return head, return body, return the tail project according to mensuration, adjust according to the volume increase part, ask to have a net increase of the output value and go into operation ratio.The output value that has a net increase of of executing Chinese medicine agricultural production degradation agent is 316.6 yuan/mu (seeing Table 4), goes into operation than being 1:15.83.Increasing benefit is fairly obvious.
The present invention uses the micro-nano technology to carry out ultramicronising to the above mother liquor for preparing and processes; first solids is melted respectively processing; strict according to floristics and to the standard of nutritional need; carry out above mother liquor and protective plant protecting agent liquid, antistaling agent liquid, plant protection product composite; controlling technique water temperature 50-60 ℃ of resolving in dynamic state, high-pressure spray evenly mixes; strengthen isothermal reaction 3h, after filtration, react, refilter to ultra microstructure and reach very finished product of 80nm, get final product with the quantitative package of environmental protection vessel.The modern Chinese herbal medicine pesticide residual degradation agent that the present invention produces is multi-functional plant protection, nutrition, degeneration-resistant, the growth regulator of a kind of micro-nano science and technology assembling; crop in growth is calculated consumption by the page, the fruit area of plant, repeatedly uses in growing process and can accelerate metabolism.Improve photosynthesis, accelerate dry-matter accumulation, improve crop anti-adversity, balanced nutrients, induce healthy growth, strengthen cell membrane stability, the enzymic activity effect is brought into play, thereby reach the purpose of improving crop quality, improving crop product degrading pesticide and heavy-metal residual.Strengthen Chinese medicine and agricultural product product and reach international standard, satisfy high-quality Chinese medicine and the requirement of agricultural product production, meet international green consumption trend.
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Claims (3)
1. modern Chinese herbal medicine pesticide residual degradation agent is characterized in that: described degradation agent is comprised of following weight portion raw material: Pancreas Sus domestica purification thing 300-350kg, phenylpropyl alcohol amino acid primary liquid 100-150 kg, plant humic acid 50-100kg, gelatine 30-70kg, boric acid 20-50kg, nicotinic liquid 50-100kg, ethanol 50-200kg, water 170-500kg, vanillin 5-10kg, multiple nitre powder sodium liquid 1-5kg, urea 50-150kg, pyroligneous liquor 40-120 kg, flavones 5-10 kg, ferrous sulfate 5-10kg, citric acid 1-5kg.
2. the preparation method of a kind of modern Chinese herbal medicine pesticide residual degradation according to claim 1 agent, it is characterized in that: described preparation method's step is:
1. get the plant humic acid and put into reactor and add hot water, heating is stirred to CL, and inclusion 20-30min; Get Pancreas Sus domestica purification thing, the phenylpropyl alcohol amino acid primary liquid stirs, and is heated to 75-90 ℃, then gets gelatine, is stirred to CL, and inclusion 20-40min, regulates PH4-5; Get at last boric acid and add, heating is stirred to CL, and inclusion 20-40min, regulates PH4-5, gets the mother liquor first, and is standby;
2. add vanillin in the reactor that can add thermal agitation, till the low-concentration ethanol heating for dissolving with 40% is limpid to solution, get mother liquor second, standby;
3., a, get nicotinic liquid and boil at twice, add for the first time water 30-45kg, 100 ℃ boil and boil 60-80min, collect supernatant, add for the second time water 20-30kg, middle temperature is boiled 40-60min, the elimination residue is collected supernatant, merges the supernatant collection 50-75kg of twice;
B, get multiple nitre powder sodium liquid and put into vessel in heating water 4-20kg, heating is stirred to CL, then adds citric acid, makes it be acid PH＜4;
C, with the product of above-mentioned a step and the product mixing and stirring of b step, get mother liquor the third, standby;
4. the mother liquor first added thermal agitation and progressively add mother liquor second and mother liquor the third, stirring, then add urea and constantly be stirred to whole dissolvings, getting mother liquor 1;
5. mother liquor 1 is lowered the temperature, make its temperature be down to 40 ℃ of left and right; Add ferrous sulfate in temperature-fall period, be stirred to CL, and regulate PH4-6, get mother liquor 2;
6. get Pin vinegar liquid and flavones join mother liquor 2 under constantly stirring in, stir and make it even, add entry and regulate PH5-6, get mother liquor;
7. with the micro-nano technology, the mother liquor for preparing is carried out ultramicronising and process, get product.
3. the preparation method of a kind of modern Chinese herbal medicine pesticide residual degradation according to claim 1 agent, it is characterized in that: it is that mother liquor resolving in dynamic state, high-pressure spray are evenly mixed that described ultramicronising is processed, strengthen isothermal reaction 3h, after filtration, react, refilter to ultra microstructure and reach 80nm.
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| CN110141821A (en) * | 2019-06-05 | 2019-08-20 | 零农残食品科技(深圳)有限公司 | A kind of residual implantation methods of zero agriculture |
| CN110818480A (en) * | 2019-11-11 | 2020-02-21 | 成都鼎泰新源农业科技有限公司 | Plant organic converzyme degradation agent and preparation and use methods thereof |
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