CN103087481B - 一种高强度无卤阻燃pbt纳米复合材料及其制备方法 - Google Patents
一种高强度无卤阻燃pbt纳米复合材料及其制备方法 Download PDFInfo
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- CN103087481B CN103087481B CN201310018859.0A CN201310018859A CN103087481B CN 103087481 B CN103087481 B CN 103087481B CN 201310018859 A CN201310018859 A CN 201310018859A CN 103087481 B CN103087481 B CN 103087481B
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- flame retardant
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 31
- 239000000463 material Substances 0.000 title claims abstract description 13
- 239000002114 nanocomposite Substances 0.000 title claims abstract description 12
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 title abstract 3
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 title abstract 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000002131 composite material Substances 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 239000000314 lubricant Substances 0.000 claims abstract description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 16
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 16
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 9
- -1 nano imvite Substances 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 5
- 239000003112 inhibitor Substances 0.000 claims description 5
- 238000005453 pelletization Methods 0.000 claims description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 4
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- 229920000877 Melamine resin Polymers 0.000 claims description 3
- 229920000388 Polyphosphate Polymers 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 3
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 claims description 3
- XZTOTRSSGPPNTB-UHFFFAOYSA-N phosphono dihydrogen phosphate;1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(N)=N1.OP(O)(=O)OP(O)(O)=O XZTOTRSSGPPNTB-UHFFFAOYSA-N 0.000 claims description 3
- 239000001205 polyphosphate Substances 0.000 claims description 3
- 235000011176 polyphosphates Nutrition 0.000 claims description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 239000003963 antioxidant agent Substances 0.000 claims description 2
- 230000003078 antioxidant effect Effects 0.000 claims description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 2
- 239000008116 calcium stearate Substances 0.000 claims description 2
- 235000013539 calcium stearate Nutrition 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- VKLYZBPBDRELST-UHFFFAOYSA-N ethene;methyl 2-methylprop-2-enoate Chemical compound C=C.COC(=O)C(C)=C VKLYZBPBDRELST-UHFFFAOYSA-N 0.000 claims description 2
- 229920006225 ethylene-methyl acrylate Polymers 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims description 2
- 235000019359 magnesium stearate Nutrition 0.000 claims description 2
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052736 halogen Inorganic materials 0.000 abstract description 2
- 150000002367 halogens Chemical class 0.000 abstract description 2
- 239000003365 glass fiber Substances 0.000 abstract 1
- 239000000383 hazardous chemical Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 16
- 230000000052 comparative effect Effects 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 244000178289 Verbascum thapsus Species 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
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CN201310018859.0A CN103087481B (zh) | 2013-01-18 | 2013-01-18 | 一种高强度无卤阻燃pbt纳米复合材料及其制备方法 |
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CN201310018859.0A CN103087481B (zh) | 2013-01-18 | 2013-01-18 | 一种高强度无卤阻燃pbt纳米复合材料及其制备方法 |
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CN103087481A CN103087481A (zh) | 2013-05-08 |
CN103087481B true CN103087481B (zh) | 2015-02-04 |
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CN201310018859.0A Expired - Fee Related CN103087481B (zh) | 2013-01-18 | 2013-01-18 | 一种高强度无卤阻燃pbt纳米复合材料及其制备方法 |
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Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103923444B (zh) * | 2014-04-30 | 2015-10-14 | 上海瀚氏模具成型有限公司 | 汽车内饰件用无卤阻燃耐热pbt塑料及其制备方法 |
CN104829860B (zh) * | 2015-05-29 | 2017-08-04 | 北京理工大学 | 一种三聚氰胺氰尿酸盐与蒙脱土纳米复合物及其制备方法 |
CN104945867A (zh) * | 2015-06-29 | 2015-09-30 | 苏州荣昌复合材料有限公司 | 一种阻燃型塑料粒子及其制备方法 |
CN105385118B (zh) * | 2015-11-18 | 2016-11-09 | 南通开普乐工程塑料有限公司 | 一种高cti值阻燃增强pbt复合材料 |
CN107011655A (zh) * | 2017-06-21 | 2017-08-04 | 谭国权 | 复合阻隔阻燃材料、其制备方法及应用 |
CN110016211A (zh) * | 2019-04-18 | 2019-07-16 | 南通瑞隆新材料有限公司 | 一种阻燃增强pbt材料及其制备方法 |
CN112852106B (zh) * | 2021-03-03 | 2023-07-21 | 平顶山学院 | 一种环氧树脂-氮化硼导热阻燃复合材料及其制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101003666A (zh) * | 2007-01-09 | 2007-07-25 | 南通星辰合成材料有限公司 | 超高流动、高热稳定性白色无卤阻燃pbt及生产方法 |
CN102617996A (zh) * | 2012-03-19 | 2012-08-01 | 深圳市科聚新材料有限公司 | 一种无卤玻纤增强pbt/pet合金材料及其制备方法 |
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Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101003666A (zh) * | 2007-01-09 | 2007-07-25 | 南通星辰合成材料有限公司 | 超高流动、高热稳定性白色无卤阻燃pbt及生产方法 |
CN102617996A (zh) * | 2012-03-19 | 2012-08-01 | 深圳市科聚新材料有限公司 | 一种无卤玻纤增强pbt/pet合金材料及其制备方法 |
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Address after: 529000 No. 135 Dongsheng Road, Jianghai District, Guangdong, Jiangmen Applicant after: GUANGDONG QIDE ENGINEERING PLASTIC TECHNOLOGY Co.,Ltd. Address before: 529000 No. 135 Dongsheng Road, Jianghai hi tech Industrial Zone, Jianghai District, Guangdong, Jiangmen Applicant before: QIDE ENGINEERING PLASTICS TECHNOLOGY Co.,Ltd. |
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Denomination of invention: High-strength halogen-free flame retardant PBT (Polybutylece Terephthalate) nano composite material and preparation method thereof Effective date of registration: 20170713 Granted publication date: 20150204 Pledgee: Bank of China Limited by Share Ltd. Jiangmen branch Pledgor: GUANGDONG QIDE ENGINEERING PLASTIC TECHNOLOGY Co.,Ltd. Registration number: 2017990000629 |
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Date of cancellation: 20200608 Granted publication date: 20150204 Pledgee: Bank of China Limited by Share Ltd. Jiangmen branch Pledgor: GUANGDONG QIDE ENGINEERING PLASTIC TECHNOLOGY Co.,Ltd. Registration number: 2017990000629 |
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