CN103058591B - Protective coloring material used for concrete surfaces and preparation method thereof - Google Patents
Protective coloring material used for concrete surfaces and preparation method thereof Download PDFInfo
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- CN103058591B CN103058591B CN201210576398.4A CN201210576398A CN103058591B CN 103058591 B CN103058591 B CN 103058591B CN 201210576398 A CN201210576398 A CN 201210576398A CN 103058591 B CN103058591 B CN 103058591B
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- 238000004040 coloring Methods 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title claims description 21
- 239000000463 material Substances 0.000 title abstract description 12
- 230000001681 protective effect Effects 0.000 title abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000000835 fiber Substances 0.000 claims abstract description 20
- 239000000843 powder Substances 0.000 claims abstract description 18
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 13
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 13
- 239000004568 cement Substances 0.000 claims abstract description 11
- 229920002678 cellulose Polymers 0.000 claims abstract description 9
- 239000001913 cellulose Substances 0.000 claims abstract description 9
- 239000000839 emulsion Substances 0.000 claims description 32
- 239000006185 dispersion Substances 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 17
- -1 sanitas Substances 0.000 claims description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 14
- 229920001577 copolymer Polymers 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 239000010881 fly ash Substances 0.000 claims description 12
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 10
- 239000004743 Polypropylene Substances 0.000 claims description 8
- 239000006004 Quartz sand Substances 0.000 claims description 8
- 229920002522 Wood fibre Polymers 0.000 claims description 8
- 229920001155 polypropylene Polymers 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 8
- 238000004090 dissolution Methods 0.000 claims description 6
- 230000000694 effects Effects 0.000 abstract description 11
- 239000004576 sand Substances 0.000 abstract description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 2
- 239000004615 ingredient Substances 0.000 abstract 2
- 239000004816 latex Substances 0.000 abstract 2
- 229920000126 latex Polymers 0.000 abstract 2
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 1
- 239000010883 coal ash Substances 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 abstract 1
- 230000002045 lasting effect Effects 0.000 abstract 1
- 239000003755 preservative agent Substances 0.000 abstract 1
- 230000002335 preservative effect Effects 0.000 abstract 1
- 230000002159 abnormal effect Effects 0.000 description 20
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- 239000011248 coating agent Substances 0.000 description 12
- 238000000576 coating method Methods 0.000 description 12
- 239000000203 mixture Substances 0.000 description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- 238000006253 efflorescence Methods 0.000 description 6
- 206010037844 rash Diseases 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 238000003860 storage Methods 0.000 description 5
- 229920000049 Carbon (fiber) Polymers 0.000 description 4
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 4
- 239000011398 Portland cement Substances 0.000 description 4
- 229910052599 brucite Inorganic materials 0.000 description 4
- 239000004917 carbon fiber Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 238000005338 heat storage Methods 0.000 description 4
- UCNNJGDEJXIUCC-UHFFFAOYSA-L hydroxy(oxo)iron;iron Chemical compound [Fe].O[Fe]=O.O[Fe]=O UCNNJGDEJXIUCC-UHFFFAOYSA-L 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- VUWCWMOCWKCZTA-UHFFFAOYSA-N 1,2-thiazol-4-one Chemical class O=C1CSN=C1 VUWCWMOCWKCZTA-UHFFFAOYSA-N 0.000 description 3
- 230000032683 aging Effects 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 238000007654 immersion Methods 0.000 description 3
- 229920000609 methyl cellulose Polymers 0.000 description 3
- 239000001923 methylcellulose Substances 0.000 description 3
- 238000010422 painting Methods 0.000 description 3
- 229920005646 polycarboxylate Polymers 0.000 description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 3
- 238000010257 thawing Methods 0.000 description 3
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical class [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 description 2
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 description 2
- 229920002873 Polyethylenimine Polymers 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229940069338 potassium sorbate Drugs 0.000 description 2
- 235000010241 potassium sorbate Nutrition 0.000 description 2
- 239000004302 potassium sorbate Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000000549 coloured material Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
Landscapes
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to a protective coloring material used for concrete surfaces. The coloring material is composed of component A and component B, wherein the mass ratio of the component A and the component B is 1:2 to 1:4. The component A is composed of the following ingredients, by mass: 10-20 parts of water, 0.1-0.3 parts of cellulose, 4-8 parts of elastic latex, 5-10 parts of flexible latex, 0.3-0.7 parts of polyvinyl alcohol, 0.1-0.3 parts of anti-crack fiber 1, 0.3-0.8 parts of anti-crack fiber 2, 0.1-0.5 parts of a dispersant, and 0.1-0.2 parts of a preservative; and the component B is composed of the following ingredients, by mass:13-25cement parts of cement, 10-15 parts of coal ash, 20-25 parts of heavy calcium carbonate powder, 15-30 parts of sand, and0-0.2 parts of iron oxide black powder. The protective coloring material used for concrete surfaces of the present invention can has the effect of fair-faced concrete, and has super strong adhesion performance and weather resistance, so the protective coloring material can provided lasting protection to the concrete.
Description
Technical field
The present invention relates to a kind of protection colouring matter, in particular, relate to a kind of protection colouring matter that can be used for concrete surface and preparation method thereof.
Background technology
Along with people pursue the variation of decorative effect, the that pure former chromatic effect of clear-water concrete is more and more subject to people's favor, but during due to cast in situs clear-water concrete, the consistence that needs very high technical requirements, very strong on-the-spot management and control power, very long duration guarantee concrete color, clear-water concrete is promoted at home and is run into certain resistance.So people in onsite concrete batch being coated with the thick coating of imitative clear-water concrete effect, to solve the demand of duration and decorative effect, at present most of anti-Clear Concrete Paint be divided into several procedures, by the primary coat of difference in functionality, in painting, face be coated with and form.A kind of protection colouring matter for concrete surface provided by the invention is a kind of material that collects decoration, protects, is colored as one, forms the effect of clear-water concrete, and have superpower bonding and weather resistance by batch painting, can protect lastingly concrete.
Summary of the invention
A kind of protection colouring matter for concrete surface provided by the invention is a kind of material that collects decoration, protects, is colored as one, forms the effect of clear-water concrete, and have superpower bonding and weather resistance by batch painting, can protect lastingly concrete.
For realizing object of the present invention, technical scheme of the present invention is:
A protection colouring matter for concrete surface, is characterized in that, this colouring matter is comprised of two components of first, second, and its mass ratio is 1:2～1:4, wherein,
First component is comprised of the component of following mass parts:
Water 10-20 part;
Mierocrystalline cellulose 0.1-0.3 part;
Elastic emulsion 4-8 part;
Flexible emulsion 5-10 part;
Polyvinyl alcohol 0.3-0.7 part;
Anti-crack fiber 1 0.1-0.3 part;
Anti-crack fiber 2 0.3-0.8 parts;
Dispersion agent 0.1-0.5 part;
Sanitas 0.1-0.2 part;
Component B is comprised of the component of following mass parts:
Cement 13-25 part;
Flyash 10-15 part;
Dicalcium powder 20-25 part;
Sand 15-30 part;
Iron black powder 0-0.2 part.
In a preferred embodiment of the present invention, described Mierocrystalline cellulose is one or more the mixture in Vltra tears, Natvosol, methylcellulose gum.Before batching, be dissolved in advance in water, its Main Function, for improving workability and water retention property, is realized the self-maintenance of cement.
In a preferred embodiment of the present invention, described elastic emulsion is one or more the mixture in acrylate and the micro-crosslinked emulsions of organosilicon copolymer emulsion, urethane and acrylate, pure-acrylic emulsion.They have excellent elasticity, waterproof and weathering resistance.
In a preferred embodiment of the present invention, described flexible emulsion is one or both the mixture in benzene emulsion, ethene-vinyl acetate copolymer emulsion.They have excellent water-fast, UV resistant and adhesive property.
In a preferred embodiment of the present invention, described anti-crack fiber 1 is the anti-crack fiber of polypropylene material, one or both the mixture in carbon fiber.They can form irregular spatial distribution in coloured material in the present invention, dispersing material stress.
In a preferred embodiment of the present invention, the wood fibre that described anti-crack fiber 2 is ultrashort type, one or both the mixture in brucite fiber.It mainly improves initial stage drying property of the present invention.
In a preferred embodiment of the present invention, described dispersion agent is one or more the mixture in polycarboxylate sodium, sulfonate sodium, polyethylenimine derivates.They have hydrophilic and two kinds of active groups of oleophylic, can make the light stirring of first, second two component form suspension colloid.
In a preferred embodiment of the present invention, described sanitas is one or more the mixture in potassium sorbate, isothiazolinone derivatives, benzimidazole ester class.
In a preferred embodiment of the present invention, described sand is one or both the mixture in 40-80 object quartz sand or river sand.They mainly play filling effect.
In a preferred embodiment of the present invention, the mass ratio of described first and second two components is 1:3.
The polyvinyl alcohol of the protection colouring matter for concrete surface of the present invention, has excellent adhesive property, as binding agent; Flyash can improve the later strength of cement, and dicalcium powder mainly plays filling effect; Iron black powder is mainly toning effect, and its consumption is according to color adjustment.
Another object of the present invention is to provide a kind of preparation method who protects colouring matter, and the method comprises the following steps:
(1) first component preparation:
In high speed dispersor, add water, start dispersion machine, by cellulose dissolution and water, add successively dispersion agent, sanitas, anti-crack fiber 1, anti-crack fiber 2, elastic emulsion, flexible emulsion, polyvinyl alcohol, standby after stirring 3min;
(2) second component preparation: in Agravicmixer, add successively cement, flyash, dicalcium powder, sand, iron black powder, standby after stirring 5min;
First, second component is mixed to rear use according to mass ratio 1:3.
The high strength of the cement not only retaining for the protection colouring matter of concrete surface of the present invention; the high-weatherability also possessing and the flexible new capability that waits; by iron black powder furnishing clear-water concrete effect; criticize and be applied to concrete surface; form imitative clear-water concrete decorative cover, can form the coating of one deck high bond strength, high-weatherability, high tint retention.
Embodiment
Below by specific embodiment, further illustrate the present invention, but the present invention is not limited by the following examples.
Embodiment 1
(1) proportioning raw materials
First component
Water 12%;
Vltra tears (40,000 viscosity) 0.15%;
Acrylate and organosilicon copolymer emulsion 4%;
Ethene-vinyl acetate copolymer emulsion 7.85%;
Polyvinyl alcohol (1788 type) 0.3%;
The anti-crack fiber 0.1% of polypropylene material;
The wood fibre 0.3% of ultrashort type;
Polycarboxylate sodium's type dispersion agent 0.2%;
Isothiazolinone derivatives type sanitas 0.1%;
Component B
Ordinary Portland cement (32.5 grades) 15%;
I level flyash (150-200 order) 10%;
Dicalcium powder (200-400 order) 20%;
Quartz sand (40-80 order) 30%.
(2) preparation method
First component preparation: add water in high speed dispersor, start dispersion machine, by in cellulose dissolution and water, add successively dispersion agent, sanitas, polypropylene fibre, wood fibre, acrylate and organosilicon copolymer emulsion, ethene-vinyl acetate copolymer emulsion, polyvinyl alcohol, standby after stirring 3min.
The preparation of second component: in Agravicmixer, add successively cement, flyash, dicalcium powder, quartz sand, standby after stirring 5min.
First, second component is mixed to rear use according to mass ratio 1:3.
(3) detect data
| Project | Detect data |
| Condition in container | After stirring, without caking, be uniform state |
| Application property | Blade coating is accessible |
| Low tempertaure storage stability, 3 times | Without abnormal |
| Heat-storage stability, 28d | Without abnormal |
| Initial dry cracking resistance, 6h | Without abnormal |
| Surface drying time, h | 3 |
| Water tolerance, 96h | Without abnormal |
| Alkali resistance, 96h | Without abnormal |
| Shock-resistance | Coating flawless, peel off and obviously distortion |
| Freeze-thawing resistant cyclicity (10 times) | Without abnormal |
| Contamination resistance (5 times) | 2 grades |
| Standard bonding strength, MPa | 0.95 |
| Immersion cohesive strength, MPa | 0.78 |
| Artificial ageing resistance, 500h | Coating is without ftractureing, play drum, coming off |
| Efflorescence, level | 0 grade of efflorescence |
| Variable color, level | 1 grade of variable color |
Detection data show, this product performance meets the demands, and cohesive strength superelevation.
(4) detected result
The performance of the present invention of above-mentioned formula meets the W type requirement of JG/T24-2000.
Embodiment 2
(1) proportioning raw materials
First component
Water 12%;
Hydroxyethylmethyl-cellulose 0.15%;
The micro-crosslinked emulsions 4% of urethane and acrylate;
Benzene emulsion 7.85%;
Polyvinyl alcohol (1788 type) 0.3%;
The anti-crack fiber 0.1% of polypropylene material;
The wood fibre 0.3% of ultrashort type;
Polycarboxylate sodium's type dispersion agent 0.2%;
Potassium sorbate sanitas 0.1%;
Component B
Ordinary Portland cement (32.5 grades) 15%;
I level flyash (150-200 order) 10%;
Dicalcium powder (200-400 order) 20%;
Quartz sand (40-80 order) 30%.
(2) preparation method
First component preparation: add water in high speed dispersor, start dispersion machine, by in cellulose dissolution and water, add successively the micro-crosslinked emulsions of dispersion agent, sanitas, polypropylene fibre, wood fibre, urethane and acrylate, benzene emulsion, polyvinyl alcohol, standby after stirring 3min.
The preparation of second component: in Agravicmixer, add successively cement, flyash, dicalcium powder, quartz sand, standby after stirring 5min.
First, second component is mixed to rear use according to mass ratio 1:3.
(3) detect data
| Project | Detect data |
| Condition in container | After stirring, without caking, be uniform state |
| Application property | Blade coating is accessible |
| Low tempertaure storage stability, 3 times | Without abnormal |
| Heat-storage stability, 28d | Without abnormal |
| Initial dry cracking resistance, 6h | Without abnormal |
| Surface drying time, h | 3.5 |
| Water tolerance, 96h | Without abnormal |
| Alkali resistance, 96h | Without abnormal |
| Shock-resistance | Coating flawless, peel off and obviously distortion |
| Freeze-thawing resistant cyclicity (10 times) | Without abnormal |
| Contamination resistance (5 times) | 2 grades |
| Standard bonding strength, MPa | 0.90 |
| Immersion cohesive strength, MPa | 0.70 |
| Artificial ageing resistance, 500h | Coating is without ftractureing, play drum, coming off |
| Efflorescence, level | 0 grade of efflorescence |
| Variable color, level | 1 grade of variable color |
Use instead after the raw materials such as the micro-crosslinked emulsions of hydroxyethylmethyl-cellulose, urethane and acrylate, benzene emulsion, performance still meets the demands.
(4) detected result
The performance of the present invention of above-mentioned formula meets the W type requirement of JG/T24-2000.
Embodiment 3
(1) proportioning raw materials
First component
Water 12%,
Methylcellulose gum 0.15%;
Pure-acrylic emulsion 4%;
Ethene-vinyl acetate copolymer emulsion 7.85%;
Polyvinyl alcohol (1788 type) 0.3%;
Carbon fiber 0.1%;
Brucite fiber 0.3%;
Sulfonate sodium type dispersion agent 0.2%;
Isothiazolinone derivatives type sanitas 0.1%;
Component B
Ordinary Portland cement (32.5 grades) 15%;
I level flyash (150-200 order) 10%;
Dicalcium powder (200-400 order) 20%;
River sand (40-80 order) 30%.
(2) preparation method
First component preparation: add water in high speed dispersor, start dispersion machine, by in cellulose dissolution and water, add successively sulfonate sodium dispersion agent, sanitas, carbon fiber, brucite fiber, pure-acrylic emulsion, ethene-vinyl acetate copolymer emulsion, polyvinyl alcohol, standby after stirring 3min.
The preparation of second component: in Agravicmixer, add successively cement, flyash, dicalcium powder, river sand, standby after stirring 5min.
First, second component is mixed to rear use according to mass ratio 1:3.
(3) detect data
| Project | Detect data |
| Condition in container | After stirring, without caking, be uniform state |
| Application property | Blade coating is accessible |
| Low tempertaure storage stability, 3 times | Without abnormal |
| Heat-storage stability, 28d | Without abnormal |
| Initial dry cracking resistance, 6h | Without abnormal |
| Surface drying time, h | 3.5 |
| Water tolerance, 96h | Without abnormal |
| Alkali resistance, 96h | Without abnormal |
| Shock-resistance | Coating flawless, peel off and obviously distortion |
| Freeze-thawing resistant cyclicity (10 times) | Without abnormal |
| Contamination resistance (5 times) | 2 grades |
| Standard bonding strength, MPa | 0.88 |
| Immersion cohesive strength, MPa | 0.72 |
| Artificial ageing resistance, 500h | Coating is without ftractureing, play drum, coming off |
| Efflorescence, level | 0 grade of efflorescence |
| Variable color, level | 1 grade of variable color |
Use instead after the raw materials such as methylcellulose gum, pure-acrylic emulsion, carbon fiber, brucite fiber, performance still meets the demands.
(4) detected result
The performance of the present invention of above-mentioned formula meets the W type requirement of JG/T24-2000.
Embodiment 4
(1) proportioning raw materials
First component
Water 12%;
Vltra tears (40,000 viscosity) 0.15%;
Acrylate and organosilicon copolymer emulsion 4%;
Ethene-vinyl acetate copolymer emulsion 7.85%;
Polyvinyl alcohol (1788 type) 0.3%;
The anti-crack fiber 0.1% of polypropylene material;
The wood fibre 0.3% of ultrashort type;
Polyethylenimine derivates dispersion agent 0.2%;
Benzimidazole ester class sanitas 0.1%;
Component B
Ordinary Portland cement (32.5 grades) 15%;
I level flyash (150-200 order) 10%;
Dicalcium powder (200-400 order) 20%;
Quartz sand (40-80 order) 30%.
(2) preparation method
First component preparation: add water in high speed dispersor, start dispersion machine, by in cellulose dissolution and water, add successively dispersion agent, sanitas, polypropylene fibre, wood fibre, acrylate and organosilicon copolymer emulsion, ethene-vinyl acetate copolymer emulsion, polyvinyl alcohol, standby after stirring 3min.
The preparation of second component: in Agravicmixer, add successively cement, flyash, dicalcium powder, quartz sand, standby after stirring 5min.
First, second component is mixed to rear use according to mass ratio 1:3.
(3) detect data
| Project | Detect data |
| Condition in container | After stirring, without caking, be uniform state |
| Application property | Blade coating is accessible |
| Low tempertaure storage stability, 3 times | Without abnormal |
| Heat-storage stability, 28d | Without abnormal |
The present embodiment is changed a kind of sanitas, and detected result surface and stability in storage meet the requirements.
More than show and described ultimate principle of the present invention, principal character and advantage of the present invention.The technician of the industry should understand; the present invention is not restricted to the described embodiments; that in above-described embodiment and specification sheets, describes just introduces principle of the present invention; the present invention also has various changes and modifications without departing from the spirit and scope of the present invention, and these changes and improvements all fall in the claimed scope of the invention.The claimed scope of the present invention is defined by appending claims and equivalent thereof.
Claims (1)
1. for a protection colouring matter for concrete surface, it is characterized in that, this colouring matter is comprised of two components of first, second, and wherein, first component is prepared from by following weight percent raw material:
Component B is prepared from by following weight percent raw material:
(2) preparation method
First component preparation: add water in high speed dispersor, start dispersion machine, by in cellulose dissolution and water, add successively dispersion agent, sanitas, polypropylene fibre, wood fibre, acrylate and organosilicon copolymer emulsion, ethene-vinyl acetate copolymer emulsion, polyvinyl alcohol, standby after stirring 3min;
The preparation of second component: in Agravicmixer, add successively cement, flyash, dicalcium powder, quartz sand, standby after stirring 5min;
First, second component is mixed to rear use according to mass ratio 1:3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210576398.4A CN103058591B (en) | 2012-12-26 | 2012-12-26 | Protective coloring material used for concrete surfaces and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210576398.4A CN103058591B (en) | 2012-12-26 | 2012-12-26 | Protective coloring material used for concrete surfaces and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN103058591A CN103058591A (en) | 2013-04-24 |
| CN103058591B true CN103058591B (en) | 2014-09-24 |
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| CN103694830B (en) * | 2013-12-06 | 2017-05-24 | 成都嘉新科技集团有限公司 | Polymer cement waterproof coating |
| CN104788124B (en) * | 2015-04-13 | 2016-11-02 | 哈尔滨中建璟园科技开发有限公司 | Concrete floor coloring agent and preparation method thereof |
| CN104891876B (en) * | 2015-05-08 | 2017-09-22 | 上海贝塔建筑科技有限公司 | Imitative clear-water concrete and preparation method thereof |
| CN105130315B (en) * | 2015-07-03 | 2018-11-02 | 上海贝塔建筑科技有限公司 | A kind of imitative clear-water concrete paint vehicle of organic elastomer |
| CN106349919B (en) * | 2016-08-26 | 2019-01-01 | 青岛展辰新材料有限公司 | Glass reinforced plastic aqueous priming paint |
| CN114685113B (en) * | 2020-12-29 | 2023-01-03 | 孙泉水 | Surface maintenance method for high-strength fair-faced concrete |
| CN114775285A (en) * | 2022-03-17 | 2022-07-22 | 中交四航工程研究院有限公司 | PVA fiber dispersion treatment method for preparing ECC concrete |
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