CN101463219A - Preparation of fluorine-containing aqueous crackle lacquer and coating method thereof - Google Patents
Preparation of fluorine-containing aqueous crackle lacquer and coating method thereof Download PDFInfo
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- CN101463219A CN101463219A CNA2009100664251A CN200910066425A CN101463219A CN 101463219 A CN101463219 A CN 101463219A CN A2009100664251 A CNA2009100664251 A CN A2009100664251A CN 200910066425 A CN200910066425 A CN 200910066425A CN 101463219 A CN101463219 A CN 101463219A
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Abstract
The invention relates to a preparation of fluorine-containing water-based crackle paint and coating method thereof. The fluorine-containing water-based crackle paint is composed of water-based epoxy primer and water-based fluorine-containing finish paint. Paint, filler and auxiliary are added to a sand mill according to percentages by weight to be grinded to be less than or equal to 40 microns; epoxy resin is added for homogeneous mixing to constitute the water-based epoxy primer; paint, filler and auxiliary are added to water according to percentages by weight to be grinded to be less than or equal to 40 microns after stirring, and are then mixed with fluorine-containing resin emulsion to constitute the water-based fluorine-containing finish paint. The coating method is as follows: the water-based epoxy primer is brush-coated or spray-coated on a substrate, and the thickness of dry film of the water-based primer is controlled; after the surface of the dry film is dry, the water-based fluorine-containing finish paint is spray-coated on the epoxy primer. Compared with the prior art, the fluorine-containing water-based crackle paint has lower content of volatile organic compound, no pollution for the environment, no poison for operating staff, excellent coating performance, strong adhesive attraction, water logging resistance, scrub resistance, simple preparation technology, convenient operation and low cost.
Description
Technical field:
The present invention relates to a kind of artistic coating, especially fluorine-containing water-borne coatings, the preparation of particularly fluorine-containing water-based strain indicating lacquer and coating process thereof.
Background technology:
Strain indicating lacquer (Crackle finish) is a kind of of novelty finish, is made by cellulose nitrate, pigment, stopping composition and solvent etc.The film thing is few in the prescription, and pigment, filler are many, and solvent volatility is big.As bottom, also use the zapon varnish Lacquer finish sometimes with common pyroxylin(e)finish in order to protect the crackle enamelled coating.Nitro-dye is to have in the color development system-NO
2Dye, remove among the branch and contain nitro-NO
2Usually contain simultaneously again-OH or contain simultaneously-SO outward,
3H.If miaow acid is exactly a kind of nitro-dye the earliest, kind is few, mainly is matching stain, and yellow dyes is also arranged, and also has the minority dispersed dye.
Strain indicating lacquer is mainly used in artistic products, artwork, also is used for the decoration protectiveness application of door and window, cement wall surface and wood furniture etc., is widely used in furniture and upholstery.Some pseudo-classic furnitures American-European as the outlet of area, Guangdong are also using strain indicating lacquer.But traditional strain indicating lacquer is solvent type, can discharge volatile organic compounds in the use.CN200610063702.X discloses the spraying method of a kind of strain indicating lacquer and preparation method thereof and this strain indicating lacquer, adopt the strain indicating lacquer of solvent-borne type thermosetting acrylic resin as base-material, but this strain indicating lacquer is solvent type, discharge a large amount of volatile organic compoundss in construction and the curing of coating process, exist to the pollution of environment with to operator's the person and poison.Instrument after its construction cleans and also will adopt corresponding organic solvent, gets final product and adopt clear water to clean after the construction of water-borne coatings instrument.US7273651 (B1)) disclose a kind of strain indicating lacquer, it is coated with membrane preparation method: first application latex primer or tinting material in coating process, solidify dry; The application emulsion paint is dried to surface drying as the crackle media; Application timber sealing latex paint is as the cracking layer on the emulsion paint of surface drying.So at least, to need application three roads, and with the timber seal coat as finish paint, its color dullness, visual effect and washability, weathering resistance, contamination resistance are all unsatisfactory.If at this coating protection layer again above finish paint, though can improve surface effect, need application four roads or multiple tracks more, construction will be complicated more.CN100441645C discloses " a kind of nitro crack lacquer and preparation method thereof and working conditions ", and though more effective than traditional strain indicating lacquer, volatile organic compounds is higher unfriendly to environment,
Along with development of technology and the people attention to environmental protection, more and more stricter to the restriction of volatile organic compounds discharging, people more and more invested free of contamination water-borne coatings to sight in recent years.
Summary of the invention:
Purpose of the present invention is exactly at above-mentioned the deficiencies in the prior art, and a kind of fluorine-containing water-based strain indicating lacquer is provided;
Another object of the present invention provides a kind of fluorine-containing water-based strain indicating lacquer preparation method;
A further object of the present invention provides a kind of fluorine-containing water-based strain indicating lacquer coating process.
The objective of the invention is to be achieved through the following technical solutions:
Fluorine-containing water-based strain indicating lacquer;
Be made up of water-base epoxy priming paint and aqueous fluorine-containing finish paint, wherein water-base epoxy priming paint is coloured aqueous epoxy primer or colorless aqueous epoxy primer:
---coloured aqueous epoxy primer mainly is made of water, pigment, filler, dispersion agent, epoxy resin latex, defoamer, thickening material, defoamer film coalescence aid, propylene glycol, solidifying agent, the weight percent of each component is: pigment 0-20%, filler 0-15%, epoxy resin latex 28-48%, dispersion agent 0-0.6%, defoamer 0.1-0.4%, thickening material 0.4-1%, film coalescence aid 0.5-2.5%, propylene glycol 1-2%, solidifying agent 5-12%, all the other are water 30-58%
---colorless aqueous epoxy primer mainly is made of water, epoxy resin latex, thickening material, defoamer, film coalescence aid, propylene glycol, solidifying agent, the weight percent of each component is: epoxy resin latex 53-75%, thickening material 0.4-1%, defoamer 0.1-0.4%, film coalescence aid 0.5-2.5%, propylene glycol 1-2%, solidifying agent 5-12%, and all the other are water 18-40%;
---the aqueous fluorine-containing finish paint mainly is made of water, pigment, filler, aqueous fluorine-containing emulsion, dispersion agent, defoamer, thickening material, film coalescence aid, propylene glycol, the weight percent of each component is: pigment 5-30%, filler 10-20%, fluorine resin emulsion 30-50%, dispersion agent 0.1-0.6%, defoamer 0.1-0.6%, thickening material 0.4-1%, film coalescence aid 0.5-2.5%, propylene glycol 0.9-2%, and all the other are water 18-33%;
The preparation method of fluorine-containing water-based strain indicating lacquer priming paint may further comprise the steps:
A, in 30-58 water, add dispersion agent 0-0.6%, defoamer 0.1-0.4%, pigment 0-20%, filler 0-15% by weight percentage, put into sand mill and grind, wear into the mill base of granularity≤40 μ m;
B, ground mill base and 28-48% aqueous epoxy resins and 0.5-2.5% film coalescence aid, 0.5-1% thickening material, 1-2% propylene glycol, 5-12% solidifying agent are put into agitator mix and be coloured aqueous epoxy primer; Do not add pigment and be colorless aqueous epoxy primer.
The preparation method of fluorine-containing water-based strain indicating lacquer finish paint, may further comprise the steps: by weight percentage pigment 5-30%, filler 10-20%, defoamer 0.1-0.6%, dispersion agent 0.1-0.6% are joined in the 18-33% water, after being uniformly dispersed with stirrer, be ground to fineness≤40 μ m, get aqueous color paste, mix with the 30-50% water fluoric resin emulsion again, add thickening material 0.4-1%, film coalescence aid 0.5-2.5% and propylene glycol 0.9-2%, stir, be fluorine-containing water-based strain indicating lacquer finish paint.
The coating process of the fluorine-containing water-based strain indicating lacquer of fluorine-containing water-based strain indicating lacquer may further comprise the steps:
1. coloured or colorless aqueous epoxy primer is brushed or, roller coat or spray on the ground, control aqueous priming paint build is between 8-80 μ m;
2. in 15-70 ℃ of film forming, become membrane stage for just at room temperature placing 0-5h again behind surface drying or the surface drying;
3. the aqueous fluorine-containing finish paint for preparing is sprayed on after the film forming just on the coloured or colorless aqueous epoxy primer of surface drying, application is placed on 70-110 ℃ of baking 50-70 minute down, or surface drying is placed under 10-25 ℃ the room temperature and placed 2-5 hour.
Purpose of the present invention can also be achieved through the following technical solutions:
The pigment of coloured aqueous epoxy primer mainly is at least a in titanium dioxide, carbon black, iron oxide red, permanent violet, phthalocyanine blue, phthalocyanine green or the zinc oxide.The filler of coloured aqueous epoxy primer or colorless aqueous epoxy primer mainly is at least a in talcum powder, light calcium carbonate, barium sulfate or the wilkinite.Aqueous fluorine-containing finish paint pigment mainly is at least a in titanium dioxide, carbon black, iron oxide red, permanent violet, phthalocyanine blue, phthalocyanine green or the zinc oxide.Aqueous fluorine-containing finish paint filler mainly is at least a in talcum powder, light calcium carbonate, barium sulfate or the wilkinite.Fluorine resin emulsion in the aqueous fluorine-containing finish paint mainly is A603C or A603; Epoxy resin latex mainly is a kind of in AB-EP-44 aqueous epoxy resin emulsion, AB-EP-37 aqueous epoxy resin emulsion or the AB-EP-20 aqueous epoxy resin emulsion.
Beneficial effect: fluorine-containing water-based strain indicating lacquer of the present invention, content of volatile organic compound and low compared with prior art, environmentally safe is to operator's toxicological harmless, the film performance excellence, strong adhesion, water-fast soaking, scrubbing resistance, preparation technology is simple, and is easy to operate, with low cost.
The film performance table
| Test event | Establishing criteria | Effect |
| The crackle effect | Range estimation | Well |
| Sticking power | GB?1720-1979(1989) | 2 grades |
| The paint film cross cut test | GB/T?9286-1998 | 1 grade |
| Water tolerance | GB/T?1733-1993 | The 48h no change |
| Abrasion resistance | GB/T?9266-1988 | No. 1500 no changes |
Embodiment:
Be described in further detail below in conjunction with embodiment:
Embodiment one
Modulate coloured aqueous priming paint: in the 500mL beaker, add 30g water, again with iron oxide red 18g, titanium dioxide 2g, 1250 order talcum powder 5g, wilkinite 1g, light calcium carbonate 4.8g, process white 4g, the modest DP511 type of moral dispersion agent 0.2g, the modest Defom W-090 of moral type defoamer 0.1g is added to the water, after being uniformly dispersed with stirrer, be ground to fineness 40 μ m, get aqueous color paste, mix with AB-EP-20 aqueous epoxy resin emulsion 28g again, add 0.4g thickening material WT-115,0.5g film coalescence aid TEXANOL, the 1g propylene glycol, stir, add AB-HGA solidifying agent 5g again, stir finished product priming paint;
Prepare coloured aqueous finish paint: in the 500mL beaker, add 33g water, with carbon black 5g, 1250 order talcum powder 5g, wilkinite 1g, light calcium carbonate 2g, process white 1g, nano zine oxide 1g, DP511 type dispersion agent 0.1g, Defom W-090 type defoamer 0.1g is added to the water, after being uniformly dispersed with stirrer, be ground to fineness 40 μ m, get aqueous color paste, mix with 50g water fluoric resin emulsion A603C again, add WT-115 thickening material 0.4g, TEXANOL film coalescence aid 0.5g, propylene glycol 0.9g, stir, get the finished product finish paint.
To have color bottom paint to brush on the glass substrate 10 μ m in half an hour thick with deployed, and in 20 ℃ of film forming, surface drying sprays coloured aqueous finish paint after 1 hour, be put in room temperature, can occur lines crackle clearly after half an hour, in 70 ℃ of bakings 110 minutes, film to do solid work and finish application again.
Embodiment two
Modulate colorless aqueous priming paint: in the 500mL beaker, add 40g water, AB-EP-37 aqueous epoxy resin emulsion 53g, the modest WT-090 type of moral defoamer 0.1g successively, add TEXANOL film coalescence aid 0.5g, thickening material 0.4g, propylene glycol 1g, after being uniformly dispersed with stirrer, add solidifying agent AB-HGA5g again, get colorless aqueous priming paint.
Preparation aqueous finish paint: in the 500mL beaker, add 18g water, add titanium dioxide 30g, 1250 order talcum powder 10g, process white 9.5g, nano zine oxide 0.5g, the modest DP511 type of moral dispersion agent 0.1g successively again, the modest Defom W-090 of moral type defoamer 0.1g, after being uniformly dispersed with stirrer, be ground to fineness 40 μ m, get aqueous color paste, mix with 30g fluorine resin latex A 603 again, mix the back and add WT-115 thickening material 0.4g, TEXANOL film coalescence aid 0.5g, propylene glycol 0.9g, stir, get coloured aqueous finish paint.
Priming paint is sprayed on the glass substrate 30 μ m after 20 minutes thick, and in 35 ℃ of film forming, surface drying sprayed aqueous finish paint after 2 hours, was put in room temperature, can occur lines crackle clearly after half an hour.Placed 10 ℃ of room temperatures again 5 hours, and filmed to do solid work and finish application.
Embodiment three
Modulate coloured aqueous priming paint: in the 500mL beaker, add 30g water, again with phthalocyanine green 18g, titanium dioxide 2g, 1250 order talcum powder 3g, wilkinite 3g, light calcium carbonate 3.8g, process white 5g, the modest DP511 type of moral dispersion agent 0.2g, the modest Defom W-090 of moral type defoamer 0.1g is added to the water, after being uniformly dispersed with stirrer, be ground to fineness 40 μ m, get aqueous color paste, mix with AB-EP-20 aqueous epoxy resin emulsion 30g again, add WT-115 thickening material 0.5g, TEXANOL film coalescence aid 0.4g, propylene glycol 2g, stir, add AB-HGA solidifying agent 4g again, stir finished product priming paint;
Prepare coloured aqueous finish paint: in the 500mL beaker, add 35g water, with permanent violet 4g, 1250 order talcum powder 4g, wilkinite 3g, light calcium carbonate 1g, process white 2g, nano zine oxide 1g, DP511 type dispersion agent 0.1g, Defom W-090 type defoamer 0.1g is added to the water, after being uniformly dispersed with stirrer, be ground to fineness 40 μ m, get aqueous color paste, mix with 50g water fluoric resin emulsion A603C again, add WT-115 thickening material 0.3g, TEXANOL film coalescence aid 0.6g, propylene glycol 0.9g, stir, get the finished product finish paint.
To have color bottom paint to brush on the glass substrate 40 μ m in half an hour thick with deployed, and in 30 ℃ of film forming, surface drying sprays coloured aqueous finish paint after 1 hour, be put in room temperature, can occur lines crackle clearly after half an hour.In 90 ℃ of baking 1h, film to do solid work and finish application again.
Embodiment four
Modulate colorless aqueous priming paint: in the 500mL beaker, add 50g water, add AB-EP-44 aqueous epoxy resin emulsion 50g, the modest WT-090 type of moral defoamer 0.2g, TEXANOL film coalescence aid 0.4g successively again, add thickening material 0.3g again, propylene glycol 2g, after being uniformly dispersed with stirrer, add AB-HGA solidifying agent 6g again, stir colorless aqueous priming paint.
Preparation aqueous finish paint: in the 500mL beaker, add 25g water, add titanium dioxide 25g, 1250 order talcum powder 8g, process white 10g, nano zine oxide 0.6g, the modest DP511 type of moral dispersion agent 0.2g more successively, the modest Defom W-090 of moral type defoamer 0.2g, after being uniformly dispersed with stirrer, be ground to fineness 40 μ m, get aqueous color paste, mix with 40g fluorine resin latex A 603C again, mix the back and add WT-115 thickening material 0.5g, TEXANOL film coalescence aid 0.4g, propylene glycol 1g, stir aqueous finish paint.
The priming paint ageing is sprayed on the glass substrate 60 μ m after 20 minutes thick, and in 45 ℃ of film forming, surface drying sprayed aqueous finish paint after 4 hours, was put in room temperature and can occurs lines crackle clearly after half an hour.Placed 20 ℃ of room temperatures again 3 hours, and filmed to do solid work and finish application.
Embodiment five
Modulate colorless aqueous priming paint: in the 500mL beaker, add 40g water, with AB-EP-37 aqueous epoxy resin emulsion 45g, the modest WT-090 type of moral defoamer 0.3g, add TEXANOL film coalescence aid 0.5g, add thickening material 0.4g again, propylene glycol 1g, after being uniformly dispersed with stirrer, add AB-HGA solidifying agent 5g, colorless aqueous priming paint.
Prepare coloured aqueous finish paint: in the 500mL beaker, add 35g water, with carbon black 5g, 1250 order talcum powder 4g, wilkinite 1g, light calcium carbonate 2g, process white 2g, nano zine oxide 2g, DP511 type dispersion agent 0.2g, Defom W-090 type defoamer 0.1g is added to the water, after being uniformly dispersed with stirrer, be ground to fineness 40 μ m, get aqueous color paste, mix with 53g water fluoric resin emulsion A603C again, add WT-115 thickening material 0.4g, TEXANOL film coalescence aid 0.5g, propylene glycol 0.8g, stir, make coloured aqueous finish paint.
To have color bottom paint to brush on the glass substrate 80 μ m in half an hour thick with deployed, and in 60 ℃ of film forming, surface drying sprays coloured aqueous finish paint after 1 hour, is put in room temperature and can occurs lines crackle clearly after half an hour.In 100 ℃ of bakings 50 minutes, film to do solid work and finish application again.
Claims (10)
1. a fluorine-containing water-based strain indicating lacquer is characterized in that, is made up of water-base epoxy priming paint and aqueous fluorine-containing finish paint, and wherein water-base epoxy priming paint is coloured aqueous epoxy primer or colorless aqueous epoxy primer:
---coloured aqueous epoxy primer mainly is made of water, pigment, filler, dispersion agent, epoxy resin latex, defoamer, thickening material, defoamer film coalescence aid, propylene glycol, solidifying agent, the weight percent of each component is: pigment 0-20%, filler 0-15%, epoxy resin latex 28-48%, dispersion agent 0-0.6%, defoamer 0.1-0.4%, thickening material 0.4-1%, film coalescence aid 0.5-2.5%, propylene glycol 1-2%, solidifying agent 5-12%, water 30-58%;---colorless aqueous epoxy primer mainly is made of water, epoxy resin latex, thickening material, defoamer, film coalescence aid, propylene glycol, solidifying agent, the weight percent of each component is: epoxy resin latex 53-75%, thickening material 0.4-1%, defoamer 0.1-0.4%, film coalescence aid 0.5-2.5%, propylene glycol 1-2%, solidifying agent 5-12%, water 18-40%;
---the aqueous fluorine-containing finish paint mainly is made of water, pigment, filler, aqueous fluorine-containing emulsion, dispersion agent, defoamer, thickening material, film coalescence aid, propylene glycol, the weight percent of each component is: pigment 5-30%, filler 10-20%, fluorine resin emulsion 30-50%, dispersion agent 0.1-0.6%, defoamer 0.1-0.6%, thickening material 0.4-1%, film coalescence aid 0.5-2.5%, propylene glycol 0.9-2%, water 18-33%.
According to the described fluorine-containing water-based strain indicating lacquer of claim 1, it is characterized in that 2, the pigment of coloured aqueous epoxy primer mainly is at least a in titanium dioxide, carbon black, iron oxide red, permanent violet, phthalocyanine blue, phthalocyanine green or the zinc oxide.
According to the described fluorine-containing water-based strain indicating lacquer of claim 1, it is characterized in that 3, the filler of coloured aqueous epoxy primer or colorless aqueous epoxy primer mainly is at least a in talcum powder, light calcium carbonate, barium sulfate or the wilkinite.
According to the described fluorine-containing water-based strain indicating lacquer of claim 1, it is characterized in that 4, aqueous fluorine-containing finish paint pigment mainly is at least a in titanium dioxide, carbon black, iron oxide red, permanent violet, phthalocyanine blue, phthalocyanine green or the zinc oxide.
According to the described fluorine-containing water-based strain indicating lacquer of claim 1, it is characterized in that 5, aqueous fluorine-containing finish paint filler mainly is at least a in talcum powder, light calcium carbonate, barium sulfate or the wilkinite.
6, according to the described fluorine-containing water-based strain indicating lacquer of claim 1, it is characterized in that the fluorine resin emulsion in the aqueous fluorine-containing finish paint mainly is A603C or A603.
7, according to the described fluorine-containing water-based strain indicating lacquer of claim 1, it is characterized in that the epoxy resin latex in the water-base epoxy priming paint mainly is: a kind of in AB-EP-44 aqueous epoxy resin emulsion, AB-EP-37 aqueous epoxy resin emulsion or the AB-EP-20 aqueous epoxy resin emulsion.
8, according to the preparation method of the coloured aqueous epoxy primer of the described fluorine-containing water-based strain indicating lacquer of claim 1, it is characterized in that, may further comprise the steps:
A, in 30-58 water, add dispersion agent 0-0.6%, defoamer 0.1-0.4%, pigment 0-20%, filler 0-15% by weight percentage, put into sand mill and grind, wear into the mill base of granularity≤40 μ m;
B, ground mill base and 28-48% aqueous epoxy resins and 0.5-2.5% film coalescence aid, 0.5-1% thickening material, 1-2% propylene glycol, 5-12% solidifying agent are put into agitator mix and be coloured aqueous epoxy primer; Do not add pigment and be colorless aqueous epoxy primer.
9, aqueous fluorine-containing finish paint preparation method according to the described fluorine-containing water-based strain indicating lacquer of claim 1, it is characterized in that, may further comprise the steps: by weight percentage with pigment 5-30%, filler 10-20%, defoamer 0.1-0.6%, dispersion agent 0.1-0.6% joins in the 18-33% water, after being uniformly dispersed with stirrer, be ground to fineness 40 μ m, get aqueous color paste, mix with the 30-50% water fluoric resin emulsion again, add thickening material 0.4-1%, film coalescence aid 0.5-2.5% and propylene glycol 0.9-2%, stir, be coloured aqueous fluorine-containing finish paint, do not add pigment and be colorless aqueous fluorine-containing finish paint.
10, according to the coating process of the fluorine-containing water-based strain indicating lacquer of the described fluorine-containing water-based strain indicating lacquer of claim 1, it is characterized in that, may further comprise the steps:
1. coloured or colorless aqueous epoxy primer is brushed or, roller coat or spray on the ground control aqueous priming paint build 8-80 μ m;
2. in 15-70 ℃ of film forming, become membrane stage for just at room temperature placing 0-5h again behind surface drying or the surface drying;
3. the aqueous fluorine-containing finish paint for preparing is sprayed on after the film forming just on the coloured or colorless aqueous epoxy primer of surface drying, application is placed on 70-110 ℃ of baking 50-70 minute down, or surface drying is placed under 10-25 ℃ the room temperature and placed 2-5 hour.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2009100664251A CN101463219A (en) | 2009-01-12 | 2009-01-12 | Preparation of fluorine-containing aqueous crackle lacquer and coating method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2009100664251A CN101463219A (en) | 2009-01-12 | 2009-01-12 | Preparation of fluorine-containing aqueous crackle lacquer and coating method thereof |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101962508A (en) * | 2010-07-12 | 2011-02-02 | 深圳市天健涂料科技开发有限公司 | Imitation copper paint and preparation method and construction technology thereof |
| CN103396727A (en) * | 2013-08-06 | 2013-11-20 | 信和新材料股份有限公司 | Aqueous oracle bone line paint and preparation method thereof |
| CN103740208A (en) * | 2014-01-09 | 2014-04-23 | 东周化学工业（昆山）有限公司 | Aqueous crack lacquer and coating method thereof |
| CN104312339A (en) * | 2014-11-19 | 2015-01-28 | 上海展辰涂料有限公司 | Water-based crack lacquer product and manufacturing method thereof |
| CN104438018A (en) * | 2014-11-19 | 2015-03-25 | 上海展辰涂料有限公司 | Water-based crack lacquer construction technology |
| CN105949970A (en) * | 2016-07-08 | 2016-09-21 | 福建华夏蓝新材料科技有限公司 | Waterborne coating with cracking effect |
| CN107189614A (en) * | 2017-05-26 | 2017-09-22 | 吴永芬 | A kind of aqueous crackle paint and preparation method thereof |
| CN109913083A (en) * | 2019-01-16 | 2019-06-21 | 河北晨阳工贸集团有限公司 | Aqueous crackle coating of removing and preparation method thereof may be selected |
| CN114046004A (en) * | 2021-12-03 | 2022-02-15 | 瑞宇建设有限公司 | Construction process of building coating for building construction |
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2009
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101962508A (en) * | 2010-07-12 | 2011-02-02 | 深圳市天健涂料科技开发有限公司 | Imitation copper paint and preparation method and construction technology thereof |
| CN103396727A (en) * | 2013-08-06 | 2013-11-20 | 信和新材料股份有限公司 | Aqueous oracle bone line paint and preparation method thereof |
| CN103396727B (en) * | 2013-08-06 | 2016-03-02 | 信和新材料股份有限公司 | Water-based first bone line paint and preparation method thereof |
| CN103740208A (en) * | 2014-01-09 | 2014-04-23 | 东周化学工业（昆山）有限公司 | Aqueous crack lacquer and coating method thereof |
| CN104312339A (en) * | 2014-11-19 | 2015-01-28 | 上海展辰涂料有限公司 | Water-based crack lacquer product and manufacturing method thereof |
| CN104438018A (en) * | 2014-11-19 | 2015-03-25 | 上海展辰涂料有限公司 | Water-based crack lacquer construction technology |
| CN105949970A (en) * | 2016-07-08 | 2016-09-21 | 福建华夏蓝新材料科技有限公司 | Waterborne coating with cracking effect |
| CN105949970B (en) * | 2016-07-08 | 2018-07-20 | 福建华夏蓝新材料科技有限公司 | Aqueous crazing effect coating |
| CN107189614A (en) * | 2017-05-26 | 2017-09-22 | 吴永芬 | A kind of aqueous crackle paint and preparation method thereof |
| CN107189614B (en) * | 2017-05-26 | 2020-04-10 | 吴永芬 | Water-based crack paint and preparation method thereof |
| CN109913083A (en) * | 2019-01-16 | 2019-06-21 | 河北晨阳工贸集团有限公司 | Aqueous crackle coating of removing and preparation method thereof may be selected |
| CN114046004A (en) * | 2021-12-03 | 2022-02-15 | 瑞宇建设有限公司 | Construction process of building coating for building construction |
| CN114046004B (en) * | 2021-12-03 | 2023-02-03 | 瑞宇建设有限公司 | Construction process of building coating for building construction |
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