CN102320797A - Respirable high-flame-retardance outer-wall facing material - Google Patents

Respirable high-flame-retardance outer-wall facing material Download PDF

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CN102320797A
CN102320797A CN 201110259980 CN201110259980A CN102320797A CN 102320797 A CN102320797 A CN 102320797A CN 201110259980 CN201110259980 CN 201110259980 CN 201110259980 A CN201110259980 A CN 201110259980A CN 102320797 A CN102320797 A CN 102320797A
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calcium
outer
heat
flame
agent
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CN 201110259980
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CN102320797B (en )
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王瑛
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山东枫煜节能材料制造有限公司
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Abstract

The invention discloses a respirable high-flame-retardance outer-wall facing material, which comprises redispersible latex powder, an organic-silicon water repellent, methylcellulose ether, a defoaming agent, an air-entraining agent, lignocellulose, a thixotropic lubricant, silicate cement, heavy calcium powder, fly ash, calcium hydroxide, starch ether, calcium formate and colored quartz sand. The respirable high-flame-retardance outer-wall facing material has the advantages of reasonable proportion, energy saving and environmental protection, and not only are the quality and the service lifeof an outer-wall heat-preserving system ensured, and heat-preserving heat-absorbing heat-storing performances are enhanced, but also the service life of a building wall body is greatly prolonged.

Description

一种可呼吸高阻燃外墙饰面材料 An external wall finishes respiratory highly flame-retardant material

技术领域 FIELD

[0001] 本发明涉及一种建筑保温技术,尤其是涉及一种可呼吸高阻燃外墙饰面材料。 [0001] The present invention relates to building insulation technology, particularly, to a highly flame-retardant breathable material external wall finishes. 背景技术 Background technique

[0002] 随着国家对节能减排标准的不断提高,人们对外墙外保温系统的关注度不断上升,使外墙外保温系统的技术得到迅猛的发展。 [0002] With the continuous improvement of the national energy conservation standards, attention people outside wall insulation system rising, the exterior insulation system technology has been rapid development. 外墙外保温是一种新兴的保温技术,就是将保温材料置于主体围护结构的外侧,以达到保温隔热目的。 Exterior Insulation Insulation is an emerging technology, the insulation material is placed on the outside of the envelope body, in order to achieve the purpose of thermal insulation. 这种技术可以有效解决我国冬夏两季室内外温差大而造成的能源损失、提高能源使用效率问题,代表我国节能保温技术的发展方向。 This technology can effectively solve the energy loss of summer and winter indoor and outdoor temperature difference caused, improve energy efficiency, the representative of the direction of development of energy-saving insulation technology in China. 外墙外保温不会产生热桥,因此具有良好的建筑节能效果。 Exterior insulation without thermal bridges, so it has good effect on energy efficiency. 冬天,当室内的热量经过墙体保温材料时会被隔绝保存下来,而当室内温度降下来后,墙体内的热量又会释放出来,调节室内的温度;夏天,外保温同样会阻止太阳的辐射和外部热量传入室内,从而使建筑物内冬暖夏凉。 In winter, when the indoor heat passes through the wall insulation will be saved isolated down, and when the indoor temperature is down, the heat will be released within the wall, adjust the indoor temperature; summer, external insulation also prevent the sun radiation and external heat into the room, making the building cool. 随着社会的不断进步,墙体的饰面材料也发生较大的变化,传统的墙体饰面材料通带分为三类:喷涂类如涂料、真石漆;粘帖类如瓷砖、各种石材;板材类如玻璃幕墙、装饰板。 As society progresses, the wall facing material changes have taken place larger, conventional wall decorative materials passband divided into three categories: painting classes such as paint, lacquer; paste type such as tiles, various stone; hydrocarbons such as plate glass curtain wall, the trim panel. 现在的各种装饰基本上是豪华高档材料的堆砌,看似不同实则雷同的风格,人工痕迹明显,把装饰装修看作一种身份、地位的象征,自然质朴的东西越来越少。 Now a variety of decorative basically a pile of luxury materials, but in reality similar seemingly disparate styles, artifacts obviously, the decoration as a kind of identity, status symbol, natural and simple things less and less. 并且由于传统饰面材料均忽视了高阻燃性能和呼吸调节性能,大大减低了外墙外保温系统的安全使用性,保温系统的防水透气性能较差,从而使由于施工外墙保温系统造成的事故频发, 外饰面层与系统无法匹配而出现的质量问题成普遍趋势,反而缩短了建筑物的维修周期。 And decorative materials are ignored since the conventional high flame retardant properties and breathing regulator, greatly reduce the safe use of exterior insulation system, poor performance waterproof breathable insulation system, since the construction such that the resulting EIFS frequent accidents, the outer layer and the system can not match the finish and quality problems to the general trend, but shorten the maintenance cycle of the building.

发明内容 SUMMARY

[0003] 本发明的目的是:提供一种环保节能的可呼吸高阻燃外墙外保温系统,既保证了外墙保温系统的质量和寿命,加强保温吸热蓄热性能,又大大提高了建筑墙体寿命。 [0003] The object of the present invention are: to provide an eco-friendly flame retardant high respirable exterior insulation system, both to ensure the quality and longevity of external wall insulation system, the insulation reinforcing endothermic heat storage properties, and greatly enhanced building wall life.

[0004] 本发明的技术方案是:由下列物质组成,按重量百分比分别为:可再分散乳胶粉15-25%、有机硅憎水剂1-2%、甲基纤维素醚1_2%、消泡剂和引气剂1-2%、木质纤维素1_2%、 触变润滑剂1_5%、硅酸盐水泥25-35%、重钙粉15-25%、粉煤灰4_6%、氢氧化钙2_5%、淀粉醚2-5%、甲酸钙1-2%、彩色石英砂3-30%。 [0004] aspect of the present invention: consisting of, in weight percent are: redispersible powder 15-25% 1-2% silicone hydrophobic agent, methyl cellulose ethers 1_2%, elimination air entraining agent and foam stabilizer 1-2%, lignocellulose% 1_2, 1_5% thixotropic lubricants, Portland cement 25-35%, 15-25% weight of calcium powder, 4_6% fly ash, calcium hydroxide 2_5%, starch ethers 2-5%, 1-2% calcium formate, color silica sand 3-30%.

[0005] 本发明的优选方案是:由下列物质组成,按重量百分比分别为:可再分散乳胶粉20%、有机硅憎水剂1-2%、甲基纤维素醚1_2%、消泡剂和引气剂1-2%、木质纤维素1-2%、触变润滑剂3-4%、硅酸盐水泥30%、重钙粉20%、粉煤灰5%、氢氧化钙3-4%、淀粉醚3_4%、甲酸钙1%、彩色石英砂5-10%。 [0005] The preferred embodiment of the present invention: consisting of, in weight percent are: redispersible polymer powder 20%, 1-2% silicone hydrophobic agent, methyl cellulose ethers 1_2%, an antifoaming agent and entraining agent 1-2%, 1-2%, lignocellulose, thixotropic lubricant 3-4%, 30% Portland cement, 20% of heavy calcium, 5% ash, calcium hydroxide 3- 4%, starch ethers 3_4%, 1% calcium formate, color silica sand 5-10%.

[0006] 本发明的有益效果是:本发明所用物质可再分散乳胶粉是喷雾干燥的聚合物干粉,它能显著提高无机矿物材料粘接性能,提高聚合物砂浆的柔韧性、憎水性、耐候性,消解墙体自身应力应变,从而极大地改善和保障了聚合物砂浆抵抗和消解自身干缩应力应变和外界热雨循环和冻融循环造成温湿应力应变的能力,避免砂浆构造层的开裂、脱落等;有机硅憎水剂可改变材料分子结构,在使水分子无法侵入的前提下又能保证系统的透气性能, 当雨水击打其上时,水滴会自然流淌,阻止水分侵入,同时还可以将建筑物表面尘土冲刷干净,室内使用过程中或抢工期造成的墙体水分饱和淤积可通过外饰面层逐步释放到室外, 避免了水造成的建筑破坏,从而起到使内墙防潮、防霉、外墙洁净及防止风化、减少应变等作用;甲基纤维素醚具有优异的保水性, [0006] Advantageous effects of the present invention is: a substance redispersible polymer powder used in the invention is spray-dried polymer powder, which can significantly improve the adhesion properties of the inorganic mineral material, improving the flexibility of the polymer mortar, water repellency, weatherability resistance, stress-strain digestion wall itself, greatly improved security and the ability of the polymer mortar resistance and self-digestion and the outside heat shrinkage stress and strain cycling rain caused by temperature and humidity and freeze-thaw cycles of stress and strain, to avoid cracking of the mortar layer structure , loss and the like; silicone hydrophobic agent may change the molecular structure of the material, in water molecules can not invade the premise of the system to ensure air permeability, when rainwater hitting on which water droplets will naturally flow, to prevent water intrusion, while also building surface dirt can be washed away, the wall of water used indoors or during rush period siltation caused by saturation can be gradually released to the outside through the outer facing layer to prevent water damage caused by the construction, which play the interior moisture , mildew, wall clean and prevent weathering, strain reducing effect; methyl cellulose ethers have excellent water retention, 锁住水份不向基材和空气中迁移,使聚合物砂浆在施工完毕后仍有足够的水份水化养护,从而减少干缩裂纹的产生和提高聚合物砂浆在施工中的粘结强度;消泡剂能使水凝性粘合剂的建筑用产品减少不希望产生的气泡,提高抗压强度和密度;引气剂能降低砂浆中调配水的表面张力,从而导致更好的分散性,同时也提高了施工性能;木质纤维素是天然木材经过化学处理、机械法加工得到的有机絮状纤维物质,无毒、无味、无污染、无放射性,对防止涂层开裂、提高保水性、提高生产的稳定性和施工的和易性、增加强度、增强对表面的附着力等有良好的效果;触变润滑剂能够加强控制粘度、屈服点、稳定性和施工性能;硅酸盐水泥作为胶凝材料,凝结硬化快,早期强度及后期强度高,抗冻性,抗碳化性能,耐磨性要优于其它水泥;重钙粉是一种惰性 Retain water does not migrate to the substrate and the air, the polymer mortar is still enough water in the hydration curing After construction, thereby reduce shrinkage cracks and improve the bond strength polymer mortar in construction ; defoamer construction enables the hydraulic binder with undesirable products reduce air bubbles to improve the compressive strength and density; entraining agent in a mortar formulation can reduce surface tension of water, resulting in better dispersion , but also improve the workability; lignocellulose is an organic material of natural wood fluff fibers chemically treated mechanical processing method obtained, non-toxic, odorless, non-polluting, non-radioactive, to prevent cracking of the coating, improved water retention, increase production stability and workability of the construction, increase strength, good results have enhanced surface adhesion and the like; a lubricant can enhance the thixotropic control the viscosity, yield point, stability and workability; as Portland cement gelling materials, fast setting and hardening, high early strength and late strength, frost resistance, carbonation resistance, abrasion resistance superior to other cement; heavy calcium is an inert 料,能够增加材料密实度;粉煤灰和氢氧化钙与水泥发生反应都能够增加水泥强度;淀粉醚能够加强控制粘度、稳定性和施工性能;甲酸钙能够使材料快速干燥;石英砂可根据造型不同添加不同目数的砂子配比,添加量依据其它添加剂用量不同平衡到100%,作为填料的同时还能增加材料的强度和工艺性。 Material, the material density can be increased; fly ash and calcium hydroxide can react with the cement to increase the strength of cement; starch ether can enhance the viscosity control, stability and application properties; Calcium material capable of quickly drying; according quartz sand adding sand shapes different number of eyes ratio, based on the amount of other additives added different amounts balance to 100%, while as a filler and the process can increase the strength of the material. 本发明选料先进,配比合理,选料主要为无机材料和保证透气性能的添加剂,相容性好,节能环保,无毒绿色。 The present invention is selected from advanced materials, a reasonable ratio, choice of materials and predominantly inorganic additives to ensure air permeability, good compatibility, energy saving, non-toxic green. 产品除具有保温隔热、吸热蓄热、高阻燃、防水透气、 抗冲击高柔性的防护作用外,还具有立体、质感、自然纯粹的装饰作用,不脱皮、不退色、不脱落的安全作用,施工工艺简单,使用寿命长。 Product in addition to insulation, heat-absorbing heat accumulator, highly flame-retardant, waterproof and breathable, flexible high impact protective effect, but also has a three-dimensional, textured, natural purely decorative effect, no peeling, no fading, no falling safety effect, the construction process is simple, long service life.

具体实施方式 detailed description

[0007] 实施例1 :本发明由下列物质组成,按重量百分比分别为:可再分散乳胶粉20%、有机硅憎水剂1. 5%、甲基纤维素醚1. 5%、消泡剂和引气剂1. 5%、木质纤维素1. 5%、触变润滑剂3%、硅酸盐水泥30%、重钙粉20%、粉煤灰5%、氢氧化钙3%、淀粉醚3%、甲酸钙1%、彩色石英砂9%。 [0007] Example 1: The present invention consisting of, in weight percent are: redispersible polymer powder 20% silicone hydrophobic agent, 1.5%, 1.5% methyl cellulose ethers, defoaming agent, air entraining agent and 1.5%, 1.5% wood cellulose, thixotropic lubricants 3%, 30% Portland cement, 20% of heavy calcium, 5% ash, 3% of calcium hydroxide, starch ether 3%, 1% calcium formate, 9% quartz sand color.

[0008] 生产方法是:开动搅拌机,先加入硅酸盐水泥、重钙粉、50%量的石英砂、可再分散乳胶粉、有机硅憎水剂、甲基纤维素醚、消泡剂、引气剂、木质纤维素、触变润滑剂、淀粉醚、 甲酸钙、氢氧化钙、粉煤灰,搅拌5分钟,再加入剩余石英砂,再进行搅拌,直到搅拌均勻。 [0008] Production method: start a stirrer, was added to Portland cement, heavy calcium, 50% of the amount of quartz sand, redispersible powders, silicone hydrophobic agent, methyl cellulose ethers, defoamers, air-entraining agent, a lignocellulose, thixotropic lubricants, starch ethers, calcium formate, calcium hydroxide, fly ash, stirred for 5 minutes, then add the remaining quartz sand, and then stirred until uniform stirring.

[0009] 实施例2 :本发明由下列物质组成,按重量百分比分别为:可再分散乳胶粉20%、有机硅憎水剂1%、甲基纤维素醚2%、消泡剂和引气剂2%、木质纤维素1%、触变润滑剂4%、硅酸盐水泥30%、重钙粉20%、粉煤灰5%、氢氧化钙4%、淀粉醚4%、甲酸钙1%、彩色石英砂6%。 [0009] Example 2: The present invention is consisting of, in weight percent are: redispersible polymer powder 20% silicone hydrophobic agent 1%, 2% methyl cellulose ethers, defoamers and bleed agent 2%, 1% lignocellulose, thixotropic lubricant 4%, 30% Portland cement, 20% of heavy calcium, 5% ash, 4% of calcium hydroxide, 4% starch ethers, calcium formate 1 %, 6% colored quartz sand.

[0010] 生产方法同实施例1。 [0010] The method of producing the same as in Example 1.

[0011] 实施例3 :本发明由下列物质组成,按重量百分比分别为:可再分散乳胶粉15%、有机硅憎水剂2%、甲基纤维素醚1%、消泡剂和引气剂1%、木质纤维素2%、触变润滑剂5%、硅酸盐水泥35%、重钙粉15%、粉煤灰4%、氢氧化钙5%、淀粉醚2%、甲酸钙1%、彩色石英砂12%。 [0011] Example 3: The present invention is consisting of, in weight percent are: redispersible polymer powder 15%, 2% silicone hydrophobic agent, 1% methyl cellulose ethers, defoamers and bleed agent 1%, 2% lignocellulose, thixotropic lubricants 5%, 35% Portland cement, 15% of heavy calcium, 4% ash, 5% calcium hydroxide, 2% starch ethers, calcium 1 %, 12% colored quartz sand.

[0012] 生产方法同实施例1。 [0012] The method of producing the same as in Example 1.

[0013] 实施例4 :本发明由下列物质组成,按重量百分比分别为:可再分散乳胶粉25%、有机硅憎水剂1%、甲基纤维素醚2%、消泡剂和引气剂2%、木质纤维素1%、触变润滑剂1%、硅酸盐水泥25%、重钙粉25%、粉煤灰6%、氢氧化钙2%、淀粉醚5%、甲酸钙2%、彩色石英砂3%。 [0013] Example 4: The present invention is consisting of, in weight percent are: redispersible polymer powder 25% silicone hydrophobic agent 1%, 2% methyl cellulose ethers, defoamers and bleed agent 2%, 1% lignocellulose, thixotropic lubricant 1%, 25% Portland cement, 25% of heavy calcium, 6% ash, calcium hydroxide 2%, 5% starch ethers, calcium 2 %, 3% quartz sand color.

[0014] 生产方法同实施例1。 [0014] The method of producing the same as in Example 1. CN 102320797 A [0015] 实施例5 :本发明由下列物质组成,按重量百分比分别为:可再分散乳胶粉18%、有机硅憎水剂1. 5%、甲基纤维素醚1. 5%、消泡剂和引气剂1. 5%、木质纤维素1. 5%、触变润滑剂2%、硅酸盐水泥25%、重钙粉16%、粉煤灰5%、氢氧化钙3%、淀粉醚3%、甲酸钙1%、彩色石英砂21%。 CN 102320797 A [0015] Example 5: The present invention is consisting of, in weight percent are: redispersible powder can be 18%, silicone hydrophobic agent, 1.5%, 1.5% methyl cellulose ether , an antifoaming agent, and entraining agent 1.5%, 1.5% wood cellulose, thixotropic lubricants 2%, 25% portland cement, 16% of heavy calcium, 5% ash, calcium hydroxide 3%, 3% starch ethers, 1% calcium formate, 21% quartz sand color.

[0016] 生产方法同实施例1。 [0016] The method of producing the same as in Example 1.

[0017] 实施例6 :本发明由下列物质组成,按重量百分比分别为:可再分散乳胶粉15%、有机硅憎水剂1%、甲基纤维素醚1%、消泡剂和引气剂1%、木质纤维素1%、触变润滑剂1%、硅酸盐水泥沈%、重钙粉15%、粉煤灰4%、氢氧化钙2%、淀粉醚2%、甲酸钙1%、彩色石英砂30%。 [0017] Example 6: The present invention is consisting of, in weight percent are: redispersible polymer powder 15% 1% silicone hydrophobic agent, 1% methyl cellulose ethers, defoamers and bleed agent 1%, lignocellulose 1%, 1% of thixotropic lubricants, Shen% Portland cement, 15% of heavy calcium, 4% ash, calcium hydroxide 2%, 2% starch ethers, calcium 1 %, 30% colored quartz sand.

[0018] 生产方法同实施例1。 [0018] The method of producing the same as in Example 1.

[0019] 以上实施例所用可再分散乳胶粉,可采用可再分散乳胶粉5044N、5010N、8031H、 8034H、7055N、5011L等系列,根据胶粉不同的特性按比例添加,合计添加量为所用数量。 [0019] The above embodiments may be used in re-dispersible polymer powders redispersible powders employed 5044N, 5010N, 8031H, 8034H, 7055N, 5011L series, was added in proportion to the different characteristics of the powder, the addition amount of the total amount used . 有机硅憎水剂可采用德国SILRES系列BS3003、BS45、BS1001等。 Silicone hydrophobic agent can be series Germany SILRES BS3003, BS45, BS1001 and the like. 甲基纤维素醚可采用美国郝克力士甲基纤维素醚⑶LMINAL®系列C8681、C9101等。 Methyl cellulose ethers employed US Hauck Hercules methyl cellulose ether ⑶LMINAL® series C8681, C9101 and so on. 消泡剂和引气剂数量各半,可采用美国郝克力士SILIPUR消泡剂、SILPON引气剂。 Defoamers and half the number of air-entraining agent, employed US Hauck SILIPUR Hercules defoamer, SILPON air-entraining agent. 木质纤维素采用德国JRS公司ARB0CEL® 木质纤维素PWC5002ZC500。 Lignocellulosic Germany JRS companies ARB0CEL® lignocellulosic PWC5002ZC500. 触变润滑剂采用海名斯触变润滑剂。 Elementis thixotropic lubricant employed thixotropic lubricants. 石英砂可跟据造型不同添加不同目数的砂子配比,添加量根据其它添加剂用量不同平衡到100%。 Quartz sand may be added according to different shapes sand ratio of the number of different purposes, the addition amount of other additives used in an amount different balance to 100%.

[0020] 另外,根据用户对色彩的需求,在本发明所用物质配比之外,添加适量的氧化铁颜料,作为无机矿物颜料不受紫外线及外界环境的影响以调成不同的色彩,保障了色彩效果和色彩寿命的长期持久性。 [0020] Further, according to user demand for color, ratio than material used in this invention, an appropriate amount of iron oxide pigment, an inorganic mineral pigment is not affected by the external environment and ultraviolet radiation into a different color to protect the long-term persistence of color effects and color life.

Claims (2)

  1. 1. 一种可呼吸高阻燃外墙饰面材料,其特征在于:由下列物质组成,按重量百分比分别为:可再分散乳胶粉15-25%、有机硅憎水剂1-2%、甲基纤维素醚1-2%、消泡剂和引气剂1-2%、木质纤维素1-2%、触变润滑剂1-5%、硅酸盐水泥25-35%、重钙粉15_25%、粉煤灰4_6%、 氢氧化钙2-5%、淀粉醚2-5%、甲酸钙1-2%、彩色石英砂3-30%。 A breathable material is highly flame-retardant external finishes, characterized by: consisting, in weight percent are: redispersible powder 15-25% 1-2% silicone hydrophobic agent, 1-2% methyl cellulose ethers, defoamers and entraining agent 1-2%, 1-2%, lignocellulose, thixotropic lubricant 1-5%, 25-35% Portland cement, TSP 15_25% powder, fly ash 4_6%, 2-5% calcium hydroxide, starch ethers 2-5%, 1-2% calcium formate, color silica sand 3-30%.
  2. 2.根据权利要求1所述的可呼吸高阻燃外墙饰面材料,其特征在于:由下列物质组成, 按重量百分比分别为:可再分散乳胶粉20%、有机硅憎水剂1-2%、甲基纤维素醚1-2%、消泡剂和引气剂1_2%、木质纤维素1-2%、触变润滑剂3-4%、硅酸盐水泥30%、重钙粉20%、粉煤灰5%、氢氧化钙3-4%、淀粉醚3-4%、甲酸钙1%、彩色石英砂5-10%。 The external walls of breathable highly flame-retardant material according to claim 1, wherein: consisting of, in weight percent are: redispersible polymer powder 20% silicone hydrophobic agent 1- 2%, 1-2% methyl cellulose ethers, defoamers and entraining agent 1_2%, lignocellulose 1-2%, 3-4% thixotropic lubricants, 30% Portland cement, heavy calcium 20%, 5% ash, 3-4% calcium hydroxide, 3-4% starch ethers, 1% calcium formate, color silica sand 5-10%.
CN 201110259980 2011-09-05 2011-09-05 Respirable high-flame-retardance outer-wall facing material CN102320797B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103058591A (en) * 2012-12-26 2013-04-24 上海天补建筑科技有限公司 Protective coloring material used for concrete surfaces and preparation method thereof
CN103102122A (en) * 2012-12-17 2013-05-15 重庆市百世得建材有限公司 Mortar for external wall refurbishment and preparation method of mortar
CN104016633A (en) * 2014-05-29 2014-09-03 安徽梦谷纤维材料科技有限公司 Exterior wall color surface decoration mortar and preparation method thereof
CN105016688A (en) * 2015-08-03 2015-11-04 山东枫煜节能材料制造有限公司 Wall decoration inorganic finishing material
CN105084819A (en) * 2015-08-10 2015-11-25 北京索利特新型建筑材料有限公司 Phenolic foam board interface agent and preparation method thereof

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CN101935193A (en) * 2010-09-08 2011-01-05 赵明 Colored mortar for imitation tiles

Patent Citations (1)

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CN101935193A (en) * 2010-09-08 2011-01-05 赵明 Colored mortar for imitation tiles

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103102122A (en) * 2012-12-17 2013-05-15 重庆市百世得建材有限公司 Mortar for external wall refurbishment and preparation method of mortar
CN103058591A (en) * 2012-12-26 2013-04-24 上海天补建筑科技有限公司 Protective coloring material used for concrete surfaces and preparation method thereof
CN103058591B (en) 2012-12-26 2014-09-24 上海天补建筑科技有限公司 Protective coloring material used for concrete surfaces and preparation method thereof
CN104016633A (en) * 2014-05-29 2014-09-03 安徽梦谷纤维材料科技有限公司 Exterior wall color surface decoration mortar and preparation method thereof
CN104016633B (en) * 2014-05-29 2016-04-20 安徽梦谷纤维材料科技有限公司 One kind of color facades and plasters prepared
CN105016688A (en) * 2015-08-03 2015-11-04 山东枫煜节能材料制造有限公司 Wall decoration inorganic finishing material
CN105084819A (en) * 2015-08-10 2015-11-25 北京索利特新型建筑材料有限公司 Phenolic foam board interface agent and preparation method thereof

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