CN107189604A - A kind of environment-friendly type building construction finishing paint and preparation method thereof - Google Patents

A kind of environment-friendly type building construction finishing paint and preparation method thereof Download PDF

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Publication number
CN107189604A
CN107189604A CN201710566518.5A CN201710566518A CN107189604A CN 107189604 A CN107189604 A CN 107189604A CN 201710566518 A CN201710566518 A CN 201710566518A CN 107189604 A CN107189604 A CN 107189604A
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Prior art keywords
parts
environment
building construction
friendly building
finishing coating
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CN201710566518.5A
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Chinese (zh)
Inventor
李丹丹
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Hefei Environmental Protection Technology Co Ltd Fanteng
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Hefei Environmental Protection Technology Co Ltd Fanteng
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Priority to CN201710566518.5A priority Critical patent/CN107189604A/en
Publication of CN107189604A publication Critical patent/CN107189604A/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04—Homopolymers or copolymers of monomers containing silicon
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of environment-friendly type building construction finishing paint, belong to technical field of coatings, include the raw material of following parts by weight：35 parts of 30 40 parts of silicone acrylic emulsion, 10 14 parts of waterglass, 58 parts of cocounut oil, 10 12 parts of palm oil, 15 17 parts of aerosil, 46 parts of vermiculite power, 57 parts of titanium dioxide, 46 parts of calcium carbonate, 13 15 parts of brominated epoxy resin, resorcinol double (diphenyl phosphoesters), 13 parts of carboxymethyl cellulose, 9 13 parts of ethylene glycol, 24 parts of water reducer, 12 parts of defoamer, 0.5 1 parts of light stabilizer, 12 parts of coalescents, 26 30 parts of water；The invention also discloses a kind of preparation method of environment-friendly type building construction finishing paint；Environmental pollution of the present invention is small, and adhesive ability is strong, with preferably fire retardancy.

Description

Environment-friendly building construction and decoration coating and preparation method thereof
Technical Field
The invention relates to the technical field of coatings, and particularly relates to an environment-friendly building construction and decoration coating and a preparation method thereof.
Background
The coating is traditionally named as paint in China. The coating is a continuous film which is coated on the surface of an object to be protected or decorated and can form firm adhesion with the object to be coated, and is a viscous liquid which is prepared by taking resin, oil or emulsion as a main material, adding or not adding pigments and fillers, adding corresponding auxiliaries and using an organic solvent or water.
The book of coating technology which is relatively authoritative in the Chinese coating world is defined as follows: the paint is a material which can be coated on the surface of an object by different construction processes to form a continuous solid film with firm adhesion and certain strength. The film thus formed is generally called a coating film, also called a paint film or a coating.
At present, the decorative paint used in building construction and decoration, whether water-based paint or oil-based paint, has the defects of low bonding force with a cement base layer, poor durability, easy cracking, peeling and falling off; high price and the like. Especially, the defects are more obvious when the paint is applied to spraying of the fair-faced concrete base layer, and decoration disputes also occur occasionally.
In the patent document with publication number CN104628328A, an environment-friendly building construction finishing coating and a preparation method thereof are disclosed, which comprises the following components (parts by weight): 30-40% of white cement, 20-35% of quartz powder, 5-10% of starch viscose, 3-4% of silicate, 0.2-1.0% of defoaming agent, 2-3.5% of pigment and 3-5% of polyurethane; the components are stirred and mixed evenly according to the proportion, and the dry powder is packaged. During construction, water is added into the dry powder coating, and the dry powder coating is uniformly stirred and sprayed. The invention can be firmly bonded with a cement base surface, and the coating does not crack, is not easy to fall off, is waterproof, anticorrosive, alkali-resistant, brushing-resistant, fireproof, nontoxic, tasteless and strong in decoration; but the fire resistance and high temperature resistance of the invention can be further improved.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provides the environment-friendly building construction and decoration coating and the preparation method thereof, and the coating is simple to prepare, environment-friendly, less in pollution, strong in adhesive capacity and better in flame retardant capacity.
The invention provides an environment-friendly building construction and decoration coating which comprises the following raw materials in parts by weight:
30-40 parts of silicone-acrylate emulsion, 10-14 parts of water glass, 5-8 parts of coconut oil, 10-12 parts of palm oil, 15-17 parts of fumed silica, 4-6 parts of vermiculite powder, 5-7 parts of titanium dioxide, 4-6 parts of calcium carbonate, 13-15 parts of brominated epoxy resin, 3-5 parts of resorcinol bis (diphenyl phosphate), 1-3 parts of carboxymethyl cellulose, 9-13 parts of ethylene glycol, 2-4 parts of a water reducing agent, 1-2 parts of a defoaming agent, 0.5-1 part of a light stabilizer, 1-2 parts of a film forming aid and 26-30 parts of water.
Preferably, the mesh number of the vermiculite powder and the titanium dioxide is 300 meshes, and the calcium carbonate is light calcium carbonate with the mesh number of 600 meshes.
Preferably, the water reducing agent is one or a mixture of two or more of a naphthalene sulfonate formaldehyde condensate, a melamine sulfonate formaldehyde condensate, an aminosulfonate and an aliphatic hydroxysulfonate condensate.
Preferably, the defoaming agent is one or a mixture of two or more of silicone emulsion, higher alcohol fatty acid ester complex, polyoxyethylene polyoxypropylene pentaerythritol ether, polyoxyethylene polyoxypropylene amine ether, polyoxypropylene glycerol ether, polyoxypropylene polyoxyethylene glycerol ether and polydimethylsiloxane.
Preferably, the light stabilizer is a mixture of a light-shielding agent and an ultraviolet absorber, the weight ratio of the light-shielding agent to the ultraviolet absorber is 1:2, and the light-shielding agent is one or a mixture of more than two of carbon black, titanium oxide, phthalocyanine blue and phthalocyanine green.
Preferably, the coalescent is an alcohol ester twelve.
The invention also provides a preparation method of the environment-friendly building construction finishing coating, which comprises the following steps:
(1) weighing the raw materials in parts by weight;
(2) adding water glass, coconut oil, palm oil, brominated epoxy resin, resorcinol bis (diphenyl phosphate), carboxymethyl cellulose and water into a stirrer, stirring for 8-10min, standing for 2-4min, adding a silicone-acrylic emulsion, ethylene glycol, a water reducing agent, a defoaming agent, a light stabilizer and a film-forming aid, stirring for 20-30min, adding fumed silica, vermiculite powder, titanium dioxide and calcium carbonate, and stirring uniformly.
Wherein,
the stirring speed of the stirrer in the step (2) is 400-500 r/min.
The environment-friendly building construction and decoration coating and the preparation method thereof have the advantages of simple preparation, little environment pollution, strong adhesion capability and better flame retardant capability, and the specific beneficial effects are as follows:
(1) the silicone-acrylic emulsion is an environment-friendly building emulsion with high weather resistance, high water resistance and pollution resistance, and has strong water glass bonding force, higher strength, good acid resistance and good heat resistance; the addition of the coconut oil and the palm oil can make the smell of the coating fresh and elegant, improve the weather resistance of the coating and simultaneously have good air purification effect;
(2) the brominated epoxy resin and the resorcinol bis (diphenyl phosphate) have good flame retardant capability and are very environment-friendly; the carboxymethyl cellulose has the functions of thickening, film forming, adhesion, water retention, colloid protection, emulsification, suspension and the like; the addition of ethylene glycol has an antifreezing effect;
(3) the water reducing agent, the defoaming agent, the light stabilizer and the film forming additive can improve the physical property and the processing stability of the coating and prolong the service life of the coating; the fumed silica can improve the high temperature resistance, and the vermiculite powder and the calcium carbonate can improve the wear resistance and the physical strength of the coating;
(4) the physical property, the heat preservation and insulation capability and the high temperature resistance of the coating can be effectively ensured by mixing the raw materials in corresponding proportion; the preparation method can effectively and fully mix the raw materials.
Detailed Description
The present invention will be described in further detail with reference to specific examples.
Example 1
The environment-friendly building construction finishing coating comprises the following raw materials in parts by weight:
30 parts of silicone-acrylate emulsion, 10 parts of water glass, 5 parts of coconut oil, 10 parts of palm oil, 15 parts of fumed silica, 4 parts of vermiculite powder, 5 parts of titanium dioxide, 4 parts of calcium carbonate, 13 parts of brominated epoxy resin, 3 parts of resorcinol bis (diphenyl phosphate), 1 part of carboxymethyl cellulose, 9 parts of ethylene glycol, 2 parts of water reducing agent, 1 part of defoaming agent, 0.5 part of light stabilizer, 1 part of film forming aid and 26 parts of water.
In this example, the mesh number of the vermiculite powder and the titanium dioxide is 300 meshes, and the calcium carbonate is light calcium carbonate with the mesh number of 600 meshes.
In this embodiment, the water reducing agent is a mixture of a naphthalene sulfonate formaldehyde condensate, a melamine sulfonate formaldehyde condensate, an aminosulfonate, and an aliphatic hydroxysulfonate condensate.
In this embodiment, the defoaming agent is a mixture of silicone emulsion, a higher alcohol fatty acid ester complex, polyoxyethylene polyoxypropylene pentaerythritol ether, polyoxyethylene polyoxypropylene amine ether, polyoxypropylene glycerol ether, polyoxypropylene polyoxyethylene glycerol ether, and polydimethylsiloxane.
In this example, the light stabilizer is a mixture of a light shielding agent and an ultraviolet absorber, the weight ratio of the light shielding agent to the ultraviolet absorber is 1:2, and the light shielding agent is a mixture of carbon black, titanium oxide, phthalocyanine blue, and phthalocyanine green.
In this example, the coalescent was alcohol ester twelve.
The embodiment also provides a preparation method of the environment-friendly building construction and decoration coating, which comprises the following steps:
(1) weighing the raw materials in parts by weight;
(2) adding water glass, coconut oil, palm oil, brominated epoxy resin, resorcinol bis (diphenyl phosphate), carboxymethyl cellulose and water into a stirrer, stirring for 8min, standing for 2min, adding a silicone-acrylic emulsion, ethylene glycol, a water reducing agent, a defoaming agent, a light stabilizer and a film forming auxiliary agent, stirring for 20min, adding fumed silica, vermiculite powder, titanium dioxide and calcium carbonate, and stirring uniformly.
Wherein,
in the step (2), the stirring speed of the stirrer is 400 r/min.
Example 2
The environment-friendly building construction finishing coating comprises the following raw materials in parts by weight:
35 parts of silicone-acrylate emulsion, 12 parts of water glass, 7 parts of coconut oil, 11 parts of palm oil, 16 parts of fumed silica, 5 parts of vermiculite powder, 6 parts of titanium dioxide, 5 parts of calcium carbonate, 14 parts of brominated epoxy resin, 4 parts of resorcinol bis (diphenyl phosphate), 2 parts of carboxymethyl cellulose, 11 parts of ethylene glycol, 3 parts of a water reducing agent, 1.5 parts of a defoaming agent, 0.8 part of a light stabilizer, 1.5 parts of a film forming aid and 28 parts of water.
In this example, the mesh number of the vermiculite powder and the titanium dioxide is 300 meshes, and the calcium carbonate is light calcium carbonate with the mesh number of 600 meshes.
In this embodiment, the water reducing agent is a mixture of a naphthalene sulfonate formaldehyde condensate, a melamine sulfonate formaldehyde condensate, an aminosulfonate, and an aliphatic hydroxysulfonate condensate.
In this embodiment, the defoaming agent is a mixture of silicone emulsion, a higher alcohol fatty acid ester complex, polyoxyethylene polyoxypropylene pentaerythritol ether, polyoxyethylene polyoxypropylene amine ether, polyoxypropylene glycerol ether, polyoxypropylene polyoxyethylene glycerol ether, and polydimethylsiloxane.
In this example, the light stabilizer is a mixture of a light shielding agent and an ultraviolet absorber, the weight ratio of the light shielding agent to the ultraviolet absorber is 1:2, and the light shielding agent is a mixture of carbon black, titanium oxide, phthalocyanine blue, and phthalocyanine green.
In this example, the coalescent was alcohol ester twelve.
The embodiment also provides a preparation method of the environment-friendly building construction and decoration coating, which comprises the following steps:
(1) weighing the raw materials in parts by weight;
(2) adding water glass, coconut oil, palm oil, brominated epoxy resin, resorcinol bis (diphenyl phosphate), carboxymethyl cellulose and water into a stirrer, stirring for 9min, standing for 3min, adding a silicone-acrylic emulsion, ethylene glycol, a water reducing agent, a defoaming agent, a light stabilizer and a film forming auxiliary agent, stirring for 25min, adding fumed silica, vermiculite powder, titanium dioxide and calcium carbonate, and stirring uniformly.
Wherein,
the stirring speed of the stirrer in the step (2) is 450 r/min.
Example 3
The environment-friendly building construction finishing coating comprises the following raw materials in parts by weight:
40 parts of silicone-acrylate emulsion, 14 parts of water glass, 8 parts of coconut oil, 12 parts of palm oil, 17 parts of fumed silica, 6 parts of vermiculite powder, 7 parts of titanium dioxide, 6 parts of calcium carbonate, 15 parts of brominated epoxy resin, 5 parts of resorcinol bis (diphenyl phosphate), 3 parts of carboxymethyl cellulose, 13 parts of ethylene glycol, 4 parts of water reducing agent, 2 parts of defoaming agent, 1 part of light stabilizer, 2 parts of film forming aid and 30 parts of water.
In this example, the mesh number of the vermiculite powder and the titanium dioxide is 300 meshes, and the calcium carbonate is light calcium carbonate with the mesh number of 600 meshes.
In this embodiment, the water reducing agent is a mixture of a naphthalene sulfonate formaldehyde condensate, a melamine sulfonate formaldehyde condensate, an aminosulfonate, and an aliphatic hydroxysulfonate condensate.
In this embodiment, the defoaming agent is a mixture of silicone emulsion, a higher alcohol fatty acid ester complex, polyoxyethylene polyoxypropylene pentaerythritol ether, polyoxyethylene polyoxypropylene amine ether, polyoxypropylene glycerol ether, polyoxypropylene polyoxyethylene glycerol ether, and polydimethylsiloxane.
In this example, the light stabilizer is a mixture of a light shielding agent and an ultraviolet absorber, the weight ratio of the light shielding agent to the ultraviolet absorber is 1:2, and the light shielding agent is a mixture of carbon black, titanium oxide, phthalocyanine blue, and phthalocyanine green.
In this example, the coalescent was alcohol ester twelve.
The embodiment also provides a preparation method of the environment-friendly building construction and decoration coating, which comprises the following steps:
(1) weighing the raw materials in parts by weight;
(2) adding water glass, coconut oil, palm oil, brominated epoxy resin, resorcinol bis (diphenyl phosphate), carboxymethyl cellulose and water into a stirrer, stirring for 10min, standing for 4min, adding a silicone-acrylic emulsion, ethylene glycol, a water reducing agent, a defoaming agent, a light stabilizer and a film forming auxiliary agent, stirring for 30min, adding fumed silica, vermiculite powder, titanium dioxide and calcium carbonate, and stirring uniformly.
Wherein,
in the step (2), the stirring speed of the stirrer is 500 r/min.
The above description is only a preferred embodiment of the present invention, and the protection scope of the present invention is not limited to the above embodiments, and all technical solutions belonging to the idea of the present invention belong to the protection scope of the present invention. It should be noted that modifications and embellishments within the scope of the invention may occur to those skilled in the art without departing from the principle of the invention, and are considered to be within the scope of the invention.

Claims (8)

1. An environment-friendly building construction finishing coating is characterized in that: the feed comprises the following raw materials in parts by weight:
30-40 parts of silicone-acrylate emulsion, 10-14 parts of water glass, 5-8 parts of coconut oil, 10-12 parts of palm oil, 15-17 parts of fumed silica, 4-6 parts of vermiculite powder, 5-7 parts of titanium dioxide, 4-6 parts of calcium carbonate, 13-15 parts of brominated epoxy resin, 3-5 parts of resorcinol bis (diphenyl phosphate), 1-3 parts of carboxymethyl cellulose, 9-13 parts of ethylene glycol, 2-4 parts of a water reducing agent, 1-2 parts of a defoaming agent, 0.5-1 part of a light stabilizer, 1-2 parts of a film forming aid and 26-30 parts of water.
2. The environment-friendly building construction finishing coating as claimed in claim 1, wherein: the mesh number of the vermiculite powder and the titanium dioxide is 300 meshes, and the calcium carbonate is light calcium carbonate with the mesh number of 600 meshes.
3. The environment-friendly building construction finishing coating as claimed in claim 1, wherein: the water reducing agent is one or a mixture of more than two of naphthalene sulfonate formaldehyde condensate, melamine sulfonate formaldehyde condensate, sulfamate and aliphatic hydroxyl sulfonate condensate.
4. The environment-friendly building construction finishing coating as claimed in claim 1, wherein: the defoaming agent is one or a mixture of more than two of emulsified silicone oil, a higher alcohol fatty acid ester compound, polyoxyethylene polyoxypropylene pentaerythritol ether, polyoxyethylene polyoxypropylene amine ether, polyoxypropylene glycerol ether, polyoxypropylene polyoxyethylene glycerol ether and polydimethylsiloxane.
5. The environment-friendly building construction finishing coating as claimed in claim 1, wherein: the light stabilizer is a mixture of a light-shielding agent and an ultraviolet absorbent, the weight ratio of the light-shielding agent to the ultraviolet absorbent is 1:2, and the light-shielding agent is one or a mixture of more than two of carbon black, titanium oxide, phthalocyanine blue and phthalocyanine green.
6. The environment-friendly building construction finishing coating as claimed in claim 1, wherein: the film-forming additive is alcohol ester twelve.
7. The method for preparing environment-friendly building construction and finishing coating according to any one of claims 1 to 6, characterized in that: the method comprises the following steps:
(1) weighing the raw materials in parts by weight;
(2) adding water glass, coconut oil, palm oil, brominated epoxy resin, resorcinol bis (diphenyl phosphate), carboxymethyl cellulose and water into a stirrer, stirring for 8-10min, standing for 2-4min, adding a silicone-acrylic emulsion, ethylene glycol, a water reducing agent, a defoaming agent, a light stabilizer and a film-forming aid, stirring for 20-30min, adding fumed silica, vermiculite powder, titanium dioxide and calcium carbonate, and stirring uniformly.
8. The method for preparing environment-friendly building construction and finishing coating as claimed in claim 7, wherein: the stirring speed of the stirrer in the step (2) is 400-500 r/min.
CN201710566518.5A 2017-07-12 2017-07-12 A kind of environment-friendly type building construction finishing paint and preparation method thereof Withdrawn CN107189604A (en)

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CN107760137A (en) * 2017-11-21 2018-03-06 江苏艾科赛特新材料有限公司 It is a kind of to improve long-term water-fast and weather resistance roofing waterproof paint
CN108299877A (en) * 2017-09-28 2018-07-20 马鞍山松鹤信息科技有限公司 A kind of finishing special environment protection coating and its preparation process
CN111019479A (en) * 2019-12-20 2020-04-17 佛山科学技术学院 Coating and preparation method thereof
CN111961376A (en) * 2020-08-26 2020-11-20 南京工程学院 Manufacturing process of weather-resistant environment-friendly water-based paint

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108299877A (en) * 2017-09-28 2018-07-20 马鞍山松鹤信息科技有限公司 A kind of finishing special environment protection coating and its preparation process
CN107760137A (en) * 2017-11-21 2018-03-06 江苏艾科赛特新材料有限公司 It is a kind of to improve long-term water-fast and weather resistance roofing waterproof paint
CN107760137B (en) * 2017-11-21 2020-07-24 江苏艾科赛特新材料有限公司 Roof waterproof paint with improved long-term water resistance and weather resistance
CN111019479A (en) * 2019-12-20 2020-04-17 佛山科学技术学院 Coating and preparation method thereof
CN111961376A (en) * 2020-08-26 2020-11-20 南京工程学院 Manufacturing process of weather-resistant environment-friendly water-based paint

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Application publication date: 20170922