CN103053588B - Insecticide/bactericide composition containing dinotefuran and prochloraz and application thereof - Google Patents
Insecticide/bactericide composition containing dinotefuran and prochloraz and application thereof Download PDFInfo
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- CN103053588B CN103053588B CN201110321793.3A CN201110321793A CN103053588B CN 103053588 B CN103053588 B CN 103053588B CN 201110321793 A CN201110321793 A CN 201110321793A CN 103053588 B CN103053588 B CN 103053588B
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Abstract
The invention discloses an insecticide/bactericide composition containing dinotefuran and prochloraz and application thereof. The insecticide/bactericide composition takes dinotefuran and prochloraz as main active ingredients, wherein the weight ratio of dinotefuran to prochloraz is (1-85):(0.5-70). The insecticide/bactericide composition has the beneficial effects that the insecticide/bactericide composition can have higher synergy and is especially suitable for controlling fungal diseases caused by crop pests, ascomycetes and fungi imperfecti; the dosage of the mixture is greatly reduced compared with that of the independent active compound, namely that the activity of the mixture is greater than that of the independent component; the drug dosage is reduced in practical application and then the drug cost is reduced; the insecticide/bactericide composition can control the fungal diseases caused by hemiptera, lepidoptera and coleoptera pests on the crops, ascomycetes and fungi imperfecti, and has obviously higher effects than single drugs; and besides, the composition is also especially suitable for treating seeds and protecting the seeds from the diseases after germination.
Description
Technical field
The invention belongs to pesticide field, be specifically related to a kind of composite insecticidal bactericidal composition containing MTI-446 and Prochloraz and uses thereof.
Background technology
MTI-446 (dinotefuran) is the third generation nicotinic insecticide of Mitsui chemical company exploitation.The chemical constitution of itself and existing nicotinic insecticide is far from each other, and chloro-pyridine base, chloro thiazolyl before its tetrahydrofuran base has replaced, containing halogen.Meanwhile, also different with nicotine at aspect of performance.So people are referred to as " furans nicotine " at present.MTI-446 chemical name: 1-methyl-2-nitro-3-(tetrahydrochysene-3-furfuryl) guanidine, structural formula is as follows:
A new generation's anabasine insecticide MTI-446 Main Function, in insect neurotransmission system, makes insect paralysis dead.This medicament insecticidal spectrum is wide, has remarkable interior suction osmosis, and has shown very high insecticidal activity at very low dosage.This medicament is fool proof to mammal, birds and aquatile, and crop, without poisoning, be can be used for to numerous crops such as paddy rice, fruit tree, vegetables.To rice grub brown planthopper, white-backed planthopper, small brown rice planthopper, rice leafhopper, rice spider rafter stinkbug, star stinkbug, green rice bug resemble, red must fleahopper, the negative mixed worm of rice, rice cylinder water snout moth's larva be efficient.Effective to striped rice borer, oryza chinensis class.Efficient to vegetables, fruit insect Phytophthira, aleyrodid class, a red-spotted lizard class, unaspis shield kuwana, the green stinkbug of Zhu, peach fruit borer, tangerine lyonetid, the thin moth of tea, striped flea-beetle, the beans fly of diving.The cured a red-spotted lizard in diagonal angle, diamond-back moth, two secret notes are chrysomelid, tea golden thistle horse, onion thrips, golden thistle horse, oranges and tangerines golden thistle horse, soybean pod gall-midge, tomato Liriomyza are effective.MTI-446 has very wide insecticidal spectrum, and fool proof again to crop, people and animals and environment, then is equipped with the using method of various uses, this agricultural chemicals large-tonnage agricultural chemicals that is expected to become international.
Prochloraz (prochloraz), chemical name: N-propyl group-N-[2-(2,4,6-Trichlorophenoxy) ethyl]-imidazoles-1-formamide, be the imidazoles bactericide of being developed by Bayer AG, its structural formula is as follows:
Prochloraz is efficient, wide spectrum, low toxicity type bactericide, has the multiple action such as interior suction conduction, prevention protection treatment, works by the biosynthesis of inhibition sterol, and the multiple diseases preventive effect causing for sac fungi and imperfect fungus is splendid.The disease that sac fungi, imperfect fungus are caused has special efficacy, can be used for preventing and treating gourd, fruit and vegetable citrus anthracnose, blossom-end rot, penicilliosis, green mould, banana anthracnose, leaf spot, mango anthracnose, leaf spot of peanut, the vegetables anthracnose such as capsicum, eggplant, muskmelon, tomato, Strawberry anthracnose; Bakanae disease of rice, rice blast; Sclerotinia rot of colza, leaf spot, mushroom brown spot, apple anthracnose, pear scab etc.Miscibilty is strong, can with various sterilization agent, Insecticides (tech) & Herbicides (tech) mixture.
Under the condition of long-term single drug, target increases gradually to the resistance of medicament, and agricultural chemicals single dose can decline gradually to the effect of control of insect, greatly shortens the service life of a good medicament.Inventor finds after deliberation, and the Synergistic of agricultural chemicals is composite to be expanding prevention spectrum and to improve preventive effect and extend the effective measures of medicament pot life, and not yet finds up to now the insecticidal and bactericidal composition patent about MTI-446 and Prochloraz.
Summary of the invention
The object of this invention is to provide a kind of high-efficiency low-toxicity composite insecticidal bactericidal composition containing MTI-446 and Prochloraz, this Pesticidal combination is the multifunctional insecticide bactericidal composition of the multiple fungal disease that causes of control Semiptera, coleoptera, lepidoptera pest or sac fungi and imperfect fungus.
Another object of the present invention is to provide this insecticidal and bactericidal composition and prevents and treats resistance Semiptera in preparation, coleoptera, application on the multiple fungal disease pesticide-germicide medicine that lepidoptera pest and sac fungi and imperfect fungus cause, particularly preparation control rice fulgorid, leafhopper, stinkbug, aleyrodid, aphid and citrus anthracnose, blossom-end rot, penicilliosis, green mould, banana anthracnose, leaf spot, mango anthracnose, leaf spot of peanut, capsicum, eggplant, muskmelon, the vegetables anthracnose such as tomato, Strawberry anthracnose, bakanae disease of rice, rice blast, sclerotinia rot of colza, leaf spot, mushroom brown spot, apple anthracnose, application on the pesticide-germicide medicine of pear scab.
The object of the invention is to be achieved through the following technical solutions:
Containing a high-efficiency low-toxicity composite insecticidal bactericidal composition for MTI-446 and Prochloraz, this insecticidal and bactericidal composition is taking MTI-446 and Prochloraz as main active ingredient, and wherein, the weight ratio of MTI-446 and Prochloraz is 1～85: 0.5～70.In this insecticidal and bactericidal composition, effective ingredient is present in composition with synergy effective dose.
The weight ratio of MTI-446 and Prochloraz preferably 0.5～50: 2～50 in this potentiating pesticidal bactericidal composition, more preferably 0.5～10: 4～30, most preferably 1: 20～60.
In the present composition, the two percentage by weight that accounts for composition of MTI-446 and Prochloraz is 2～80%.Be preferably 5～50%, most preferably 10～40%.
Insecticidal and bactericidal composition of the present invention taking MTI-446 and Prochloraz as main active ingredient and insecticides adjuvant and excipient be mixed with any one formulation allowing on agricultural chemicals, the preferred emulsion of described formulation, suspending agent, wetting powder, aqueous emulsion, microemulsion and water dispersion granule.
Auxiliary agent can adopt calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, the rare block compound of polyoxyethylene polyoxy third (as agriculture breast 33
#), one or more combinations in polyoxyethylene nonylphenol ether, excipient comprises cyclohexanone, dimethylbenzene, solvent naphtha, water, antifreezing agent (as propane diols), deionized water etc.Above auxiliary agent, excipient and other auxiliary material can alone or and use.
Pesticidal combination of the present invention has good control efficiency to the multiple fungal disease that easily multiple Semiptera, coleoptera, lepidoptera pest or sac fungi, the imperfect fungus of generation resistance cause such as rice fulgorid, leafhopper, aphid; And suppress insect or the drug-fast generation of fungi to unitary agent (MTI-446 and Prochloraz are arbitrary).
Insecticidal and bactericidal composition of the present invention is prevented and treated the application on resistance Semiptera, coleoptera, lepidoptera pest and fungi in preparation, especially preventing and treating leafhopper, stinkbug, aleyrodid, plant hopper and aphid and citrus anthracnose, blossom-end rot, penicilliosis, green mould, banana anthracnose, leaf spot, mango anthracnose, leaf spot of peanut, the vegetables anthracnose such as capsicum, eggplant, muskmelon, tomato, Strawberry anthracnose, bakanae disease of rice, rice blast, sclerotinia rot of colza, leaf spot, mushroom brown spot, apple anthracnose, the application in pear scab all has significant effect.Above-mentioned insecticidal and bactericidal composition can produce higher synergistic function, and the consumption of the independent reactive compound of amount ratio of this mixture reduces greatly, and the activity of mixture is greater than the activity of independent component." % " of the present invention is mass percent.
Compared with prior art beneficial effect of the present invention: (1) is compared with single dose, said composition antagonism Semiptera, coleoptera, lepidoptera pest is as rice fulgorid, leafhopper, aphid and fungal disease are as citrus anthracnose, blossom-end rot, penicilliosis, green mould, banana anthracnose, leaf spot, mango anthracnose, leaf spot of peanut, capsicum, eggplant, muskmelon, the vegetables anthracnose such as tomato, Strawberry anthracnose, bakanae disease of rice, rice blast, sclerotinia rot of colza, leaf spot, mushroom brown spot, apple anthracnose, the fungal diseases such as pear scab have obvious synergistic function, overcome and delayed pesticide resistance, expanding prevention spectrum, obviously improve control efficiency, (2) reduce control recruitment, drug cost, (3) alternative high-toxic pesticide, (4) have the effect of controlling worm and diseases prevention concurrently, (5) compare with Prochloraz single dose with MTI-446, produce and use cost reduction, (6) suppress Semiptera, coleoptera, the resistance enhancing of lepidoptera pest to agricultural chemicals, the drug-fast generation of Antifungi, its successful uses higher than its single dose.
Embodiment
Below in conjunction with embodiment, the invention will be further described:
The expection activity of two kinds of active agent combinations can calculate as follows (referring to colby, S.R.; Weed 15, page 20-22,1967)
If
The lethality of X=in the time that rate of application with m ppm uses reactive compound A, is expressed as the percentage of untreated control group.
The lethality of Y=in the time that rate of application with n ppm uses reactive compound B, is expressed as the percentage of untreated control group.
The lethality of E=in the time that rate of application with m and n ppm uses reactive compound A and B, is expressed as the percentage of untreated control group.
:
E＝X+Y-(XY/100)
If actual insect mortality exceedes calculated value, the lethality of bond has additive property, has syneryistic effect.
Embodiment:
Adopt rice stem infusion process to carry out indoor bioassay, selecting resistant rice plant hopper is target pest, and every processing repeats 3 times, and every concentration is processed 60, the results are shown in Table 1.
Table 1: the composite toxicity to Brown Planthopper of MTI-446-Prochloraz
Embodiment:
Employing is soaked leaf dip method and is carried out indoor synergy biologicall test, and selecting resistance wheat aphid is target pest, and every processing repeats 3 times, and every concentration is processed 60, the results are shown in Table 2:
Table 2: the composite toxicity to aphid of MTI-446-Prochloraz
Embodiment:
Employing is soaked leaf dip method and is carried out indoor synergy biologicall test, and selecting resistant rice stinkbug is target pest, and every processing repeats 3 times, and every concentration is processed 60, the results are shown in Table 3:
Table 3: the composite toxicity to rice stinkbug of MTI-446-Prochloraz
Embodiment
Taking rice blast pathogen as subjects, adopt colony diameter method to calculate the activity of the many germs of medicament, the results are shown in Table 4.
Table 4: the composite indoor bacteriostatic activity to rice blast of MTI-446-Prochloraz
By this Fungicidal insecticidal composition, for field control effectiveness test, liquid 30L is used on every mu of ground, further verifies the synergetic of said composition, the results are shown in Table 5.
Table 5: the composite field test results to Brown Planthopper, rice blast of MTI-446-Prochloraz
Indoor biometrics and field efficacy result show, MTI-446 Prochloraz composition antagonism brown plant-hopper, stinkbug, aphid and rice blast have good control efficiency, control efficiency is all better than the effect of single dose kind, so Prochloraz and MTI-446 have obvious synergistic function after composite.
Two kinds of reactive compounds can be processed into any one formulation of permission, and below with two kinds of preparations that active ingredient is processed into of specific embodiment explanation, but the preparation that these two kinds of active components can be processed is not limited only to following listed.
Embodiment 2:
Take 5g MTI-446,50g Prochloraz, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33
#2g, alkylphenol polyoxyethylene 1g, dimethylbenzene 13g, adds water to 100g.The method of above raw material being prepared routinely to aqueous emulsion drops into the mixing of mixing kettle high speed, and making main active ingredient weight percentage is 55% MTI-446-prochloraz aqueous emulsion.
Embodiment 3:
Take 2g MTI-446,30g Prochloraz, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33
#2g, alkylphenol polyoxyethylene 1g, cyclohexanone 10g, adds water to 100g.The method that above raw material is prepared to microemulsion routinely drops in mixing kettle mixes, and making main active ingredient weight percentage is 32% MTI-446-Prochloraz microemulsion.
Embodiment 4:
Take 1g MTI-446,10g Prochloraz, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33
#2g, alkylphenol polyoxyethylene 1g, cyclohexanone 10g, adds water to 100g.The method that above raw material is prepared to microemulsion routinely drops in mixing kettle mixes, and making main active ingredient weight percentage is 32% MTI-446-Prochloraz microemulsion.
Embodiment 5: take 50g MTI-446,20g Prochloraz, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, dimethylbenzene are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and making main active ingredient weight percentage is 70% MTI-446-Prochloraz missible oil.
Embodiment 6: take 2g MTI-446,40g Prochloraz, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, dimethylbenzene are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and making main active ingredient weight percentage is 42% MTI-446-Prochloraz missible oil.
Embodiment 7: take 0.2g MTI-446,50g Prochloraz, calcium dodecyl benzene sulfonate 9g, phenethyl phenol polyethenoxy ether 8g, dimethylbenzene are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and making main active ingredient weight percentage is 50.2% MTI-446-Prochloraz missible oil.
Embodiment 8: take 3g MTI-446,12g Prochloraz, sodium lignin sulfonate 2g, polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, water complements to 100g, and under the effect of sand mill, making main active ingredient weight percentage is 42% MTI-446-Prochloraz suspending agent.
Embodiment 9: take 5g MTI-446,30g Prochloraz, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, dimethylbenzene are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and making main active ingredient weight percentage is 35% MTI-446-Prochloraz missible oil.
Embodiment 10: take 20g MTI-446,5g Prochloraz, the 8g of wooden sodium sulfonate, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, diatomite 28g, it is 7% MTI-446-Prochloraz water dispersion granule that above raw material is made to main active ingredient weight percentage by water dispersible granular agent method.
Embodiment 11: take 30g MTI-446,12g Prochloraz, sodium lignin sulfonate 2g, polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, water complements to 100g, and under the effect of sand mill, making main active ingredient weight percentage is 42% MTI-446-Prochloraz suspending agent.
Embodiment 12: take 2g MTI-446,5g Prochloraz, the 8g of wooden sodium sulfonate, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, diatomite 28g, it is 7% MTI-446-Prochloraz water dispersion granule that above raw material is made to main active ingredient weight percentage by water dispersible granular agent method.
Embodiment 13: take 5g MTI-446,13g Prochloraz, lignin 10g, Negel 2g, add to 100g with diatomite, above raw material is mixed in micronizer, and making main active ingredient weight percentage is 20% MTI-446 and Prochloraz wetting powder.
Embodiment 14: take 2g MTI-446,18g Prochloraz, lignin 10g, Negel 2g, add to 100g with diatomite, above raw material is mixed in micronizer, and making main active ingredient weight percentage is 20% MTI-446 and Prochloraz wetting powder.
Embodiment 15: take 7g MTI-446,70g Prochloraz, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, dimethylbenzene are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and making main active ingredient weight percentage is 77% MTI-446-Prochloraz missible oil.
Claims (6)
1. containing a composite insecticidal bactericidal composition for MTI-446 and Prochloraz, it is characterized in that this insecticidal and bactericidal composition is taking MTI-446 and Prochloraz as active ingredient, wherein, the weight ratio of MTI-446 and Prochloraz is 0.5 ~ 10:4 ~ 30.
2. the potentiating pesticidal bactericidal composition containing MTI-446 and Prochloraz according to claim 1, is characterized in that the two weight percentage that accounts for composition of MTI-446 and Prochloraz is 2 ~ 80%.
3. the potentiating pesticidal bactericidal composition containing MTI-446 and Prochloraz according to claim 2, is characterized in that the two weight percentage that accounts for composition of MTI-446 and Prochloraz is 5 ~ 50%.
4. the potentiating pesticidal bactericidal composition containing MTI-446 and Prochloraz according to claim 3, is characterized in that the two weight percentage that accounts for composition of MTI-446 and Prochloraz is 10 ~ 40%.
5. the potentiating pesticidal bactericidal composition containing MTI-446 and Prochloraz according to claim 1, the formulation that it is characterized in that described insecticidal and bactericidal composition is missible oil, suspending agent, aqueous emulsion, wetting powder, microemulsion or water dispersion granule.
Potentiating pesticidal bactericidal composition containing MTI-446 and Prochloraz according to claim 1 anti-ly eliminate aphis in preparation, application on the pesticide-germicide medicine of aleyrodid, leafhopper, stinkbug, plant hopper and rice blast.
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| CN104365669A (en) * | 2014-10-30 | 2015-02-25 | 柳州市惠农化工有限公司 | Dinotefuran and copper calcium sulphate suspension emulsion and application thereof |
| CN108432789A (en) * | 2018-02-13 | 2018-08-24 | 平南县亿翔环保能源有限公司 | The pyroligneous-contained anti-drug to eliminate aphis |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2006015865A1 (en) * | 2004-08-12 | 2006-02-16 | Syngenta Participations Ag | Fungicidal compositions |
| CN101043813A (en) * | 2003-04-11 | 2007-09-26 | 哈茨山公司 | High concentration dinotefuran formulations containing methoprene |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101043813A (en) * | 2003-04-11 | 2007-09-26 | 哈茨山公司 | High concentration dinotefuran formulations containing methoprene |
| WO2006015865A1 (en) * | 2004-08-12 | 2006-02-16 | Syngenta Participations Ag | Fungicidal compositions |
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