CN103053588A - Insecticide/bactericide composition containing dinotefuran and prochloraz and application thereof - Google Patents
Insecticide/bactericide composition containing dinotefuran and prochloraz and application thereof Download PDFInfo
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- CN103053588A CN103053588A CN2011103217933A CN201110321793A CN103053588A CN 103053588 A CN103053588 A CN 103053588A CN 2011103217933 A CN2011103217933 A CN 2011103217933A CN 201110321793 A CN201110321793 A CN 201110321793A CN 103053588 A CN103053588 A CN 103053588A
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- prochloraz
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Abstract
The invention discloses an insecticide/bactericide composition containing dinotefuran and prochloraz and application thereof. The insecticide/bactericide composition takes dinotefuran and prochloraz as main active ingredients, wherein the weight ratio of dinotefuran to prochloraz is (1-85):(0.5-70). The insecticide/bactericide composition has the beneficial effects that the insecticide/bactericide composition can have higher synergy and is especially suitable for controlling fungal diseases caused by crop pests, ascomycetes and fungi imperfecti; the dosage of the mixture is greatly reduced compared with that of the independent active compound, namely that the activity of the mixture is greater than that of the independent component; the drug dosage is reduced in practical application and then the drug cost is reduced; the insecticide/bactericide composition can control the fungal diseases caused by hemiptera, lepidoptera and coleoptera pests on the crops, ascomycetes and fungi imperfecti, and has obviously higher effects than single drugs; and besides, the composition is also especially suitable for treating seeds and protecting the seeds from the diseases after germination.
Description
Technical field
The invention belongs to pesticide field, be specifically related to a kind of composite insecticidal bactericidal composition that contains MTI-446 and Prochloraz and uses thereof.
Background technology
MTI-446 (dinotefuran) is the third generation nicotinic insecticide of Mitsui chemical company exploitation.The chemical constitution of itself and existing nicotinic insecticide is far from each other, and chloro-pyridine base, chloro thiazolyl before its tetrahydrofuran base has replaced do not contain the halogen family element.Simultaneously, also different with nicotine at aspect of performance.So people are referred to as " furans nicotine " at present.The MTI-446 chemical name: 1-methyl-2-nitro-3-(tetrahydrochysene-3-furfuryl) guanidine, structural formula is as follows:
A new generation's anabasine insecticide MTI-446 Main Function makes the insect paralysis dead in insect neurotransmission system.This medicament insecticidal spectrum is wide, has remarkable interior sorptivety and thoroughly acts on, and namely shown very high insecticidal activity at very low dosage.This medicament is fool proof to mammal, birds and aquatile, and crop without poisoning, be can be used for numerous crops such as paddy rice, fruit tree, vegetables.To rice grub brown planthopper, white-backed planthopper, small brown rice planthopper, rice leafhopper, rice spider rafter stinkbug, star stinkbug, green rice bug resemble, red must fleahopper, the negative mixed worm of rice, rice cylinder water snout moth's larva be efficient.Effective to striped rice borer, oryza chinensis class.Efficient to vegetables, fruit insect Phytophthira, aleyrodid class, a red-spotted lizard class, unaspis shield kuwana, the green stinkbug of Zhu, peach fruit borer, tangerine lyonetid, the thin moth of tea, striped flea-beetle, the beans fly of diving.The cured a red-spotted lizard in diagonal angle, diamond-back moth, two secret notes are chrysomelid, tea golden thistle horse, onion thrips, golden thistle horse, oranges and tangerines golden thistle horse, soybean pod gall-midge, tomato Liriomyza are effective.MTI-446 has very wide insecticidal spectrum, and fool proof again to crop, people and animals and environment, is equipped with the using method of various uses again, this agricultural chemicals large-tonnage agricultural chemicals that is expected to become international.
Prochloraz (prochloraz), chemical name: N-propyl group-N-[2-(2,4,6-Trichlorophenoxy) ethyl]-imidazoles-1-formamide, be that its structural formula is as follows by the imidazoles bactericide of Bayer AG's exploitation:
Prochloraz is efficient, wide spectrum, low toxicity type bactericide, has the multiple actions such as interior suction conduction, prevention protection treatment, works by the biosynthesis of inhibition sterol, and is splendid for the multiple diseases preventive effect that sac fungi and imperfect fungus cause.The disease that sac fungi, imperfect fungus are caused has special efficacy, can be used for preventing and treating gourd, fruit and vegetable citrus anthracnose, blossom-end rot, penicilliosis, green mould, banana anthracnose, leaf spot, mango anthracnose, leaf spot of peanut, the vegetables anthracnose such as capsicum, eggplant, muskmelon, tomato, Strawberry anthracnose; Bakanae disease of rice, rice blast; Sclerotinia rot of colza, leaf spot, mushroom brown spot, apple anthracnose, pear scab etc.Miscibilty is strong, can be mixed with various sterilization agent, Insecticides (tech) ﹠ Herbicides (tech).
Under the condition of long-term single drug, target increases gradually to the resistance of medicament, and the agricultural chemicals single dose can descend gradually to the effect of control of insect, greatly shortens the service life of a good medicament.The inventor finds that after deliberation the Synergistic of agricultural chemicals is composite to be that expanding prevention spectrum and raising preventive effect prolong the effective measures of medicament pot life, and not yet finds up to now the insecticidal and bactericidal composition patent of relevant MTI-446 and Prochloraz.
Summary of the invention
The purpose of this invention is to provide a kind of high-efficiency low-toxicity composite insecticidal bactericidal composition that contains MTI-446 and Prochloraz, this Pesticidal combination is the multifunctional insecticide bactericidal composition of the multiple fungal disease that causes of control Semiptera, coleoptera, lepidoptera pest or sac fungi and imperfect fungus.
Another object of the present invention provides this insecticidal and bactericidal composition and prevents and treats the resistance Semiptera in preparation, coleoptera, application on the multiple fungal disease pesticide-germicide medicine that lepidoptera pest and sac fungi and imperfect fungus cause, particularly preparation control rice fulgorid, leafhopper, stinkbug, aleyrodid, aphid and citrus anthracnose, blossom-end rot, penicilliosis, green mould, banana anthracnose, leaf spot, mango anthracnose, leaf spot of peanut, capsicum, eggplant, muskmelon, the vegetables anthracnose such as tomato, Strawberry anthracnose, bakanae disease of rice, rice blast, sclerotinia rot of colza, leaf spot, the mushroom brown spot, apple anthracnose, the application on the pesticide-germicide medicine of pear scab.
The objective of the invention is to be achieved through the following technical solutions:
A kind of high-efficiency low-toxicity composite insecticidal bactericidal composition that contains MTI-446 and Prochloraz, this insecticidal and bactericidal composition is take MTI-446 and Prochloraz as main active ingredient, and wherein, the weight ratio of MTI-446 and Prochloraz is 1～85: 0.5～70.Effective ingredient is present in the composition with the synergy effective dose in this insecticidal and bactericidal composition.
The weight ratio preferred 0.5～50: 2～50 of MTI-446 and Prochloraz in this potentiating pesticidal bactericidal composition, more preferably 0.5～10: 4～30, most preferably 1: 20～60.
In the present composition, the two percentage by weight that accounts for composition of MTI-446 and Prochloraz is 2～80%.Be preferably 5～50%, most preferably 10～40%.
Insecticidal and bactericidal composition of the present invention take MTI-446 and Prochloraz as main active ingredient and insecticides adjuvant and excipient be mixed with any one formulation that allows on the agricultural chemicals, the preferred emulsion of described formulation, suspending agent, wetting powder, aqueous emulsion, microemulsion and water dispersion granule.
Auxiliary agent can adopt calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, polyoxyethylene polyoxy third rare block compound (such as farming breast 33
#), the one or more combinations in the polyoxyethylene nonylphenol ether, excipient comprises cyclohexanone, dimethylbenzene, solvent naphtha, water, antifreezing agent (such as propane diols), deionized water etc.Above auxiliary agent, excipient and other auxiliary material can alone or and usefulness.
Pesticidal combination of the present invention has good control efficiency to the multiple fungal disease that easy multiple Semiptera, coleoptera, lepidoptera pest or sac fungi, the imperfect fungus that produces resistance such as rice fulgorid, leafhopper, aphid causes; And suppress insect or fungi to unitary agent (MTI-446 and Prochloraz bes's arbitrary) drug-fast generation.
Insecticidal and bactericidal composition of the present invention is prevented and treated application on resistance Semiptera, coleoptera, lepidoptera pest and the fungi in preparation, especially preventing and treating leafhopper, stinkbug, aleyrodid, plant hopper and aphid and citrus anthracnose, blossom-end rot, penicilliosis, green mould, banana anthracnose, leaf spot, mango anthracnose, leaf spot of peanut, the vegetables anthracnose such as capsicum, eggplant, muskmelon, tomato, Strawberry anthracnose, bakanae disease of rice, rice blast, sclerotinia rot of colza, leaf spot, the mushroom brown spot, apple anthracnose, the application on the pear scab all has significant effect.Above-mentioned insecticidal and bactericidal composition can produce higher synergistic function, and the consumption of the independent reactive compound of amount ratio of this mixture reduces greatly, and namely the activity of mixture is greater than the independent activity of component." % " of the present invention is mass percent.
Beneficial effect of the present invention compared with prior art: (1) is compared with single dose, said composition antagonism Semiptera, coleoptera, lepidoptera pest such as rice fulgorid, leafhopper, aphid and fungal disease such as citrus anthracnose, blossom-end rot, penicilliosis, green mould, banana anthracnose, leaf spot, mango anthracnose, leaf spot of peanut, capsicum, eggplant, muskmelon, the vegetables anthracnose such as tomato, Strawberry anthracnose, bakanae disease of rice, rice blast, sclerotinia rot of colza, leaf spot, the mushroom brown spot, apple anthracnose, the fungal diseases such as pear scab have obvious synergistic function, overcome and have delayed pesticide resistance, the expanding prevention spectrum has obviously improved control efficiency; (2) reduce control recruitment, drug cost; (3) alternative high-toxic pesticide; (4) have the effect of controlling worm and diseases prevention concurrently; (5) compare with the Prochloraz single dose with MTI-446, produce and the use cost reduction; (6) inhibition Semiptera, coleoptera, lepidoptera pest strengthen the resistance of agricultural chemicals, the drug-fast generation of Antifungi, and its successful is higher than its single dose to be used.
Embodiment
The invention will be further described below in conjunction with embodiment:
The expection activity of two kinds of active agent combinations can calculate as follows (referring to colby, S.R.; Weed 15, page 20-22,1967)
If
The lethality of X=when using reactive compound A with the rate of application of m ppm is expressed as the percentage of untreated control group.
The lethality of Y=when using reactive compound B with the rate of application of n ppm is expressed as the percentage of untreated control group.
The lethality of E=when using reactive compound A and B with the rate of application of m and n ppm is expressed as the percentage of untreated control group.
Then:
E＝X+Y-(XY/100)
If actual insect mortality surpasses calculated value, then the lethality of bond has additive property, namely has syneryistic effect.
Embodiment:
Adopt rice stem infusion process to carry out indoor bioassay, selecting the resistant rice plant hopper is target pest, and every processing repeats 3 times, and every concentration is processed 60, the results are shown in Table 1.
Table 1: the composite toxicity to Brown Planthopper of MTI-446-Prochloraz
Embodiment:
Employing is soaked the leaf dip method and is carried out indoor synergy biologicall test, and selecting the resistance wheat aphid is target pest, and every processing repeats 3 times, and every concentration is processed 60, the results are shown in Table 2:
Table 2: the composite toxicity to aphid of MTI-446-Prochloraz
Embodiment:
Employing is soaked the leaf dip method and is carried out indoor synergy biologicall test, and selecting the resistant rice stinkbug is target pest, and every processing repeats 3 times, and every concentration is processed 60, the results are shown in Table 3:
Table 3: the composite toxicity to the rice stinkbug of MTI-446-Prochloraz
Embodiment
Take rice blast pathogen as subjects, adopt the colony diameter method to calculate the activity of the many germs of medicament, the results are shown in Table 4.
Table 4: the composite indoor bacteriostatic activity to rice blast of MTI-446-Prochloraz
This Fungicidal insecticidal composition is used for field control effectiveness test, and liquid 30L is used on every mu of ground, further verifies the synergetic of said composition, the results are shown in Table 5.
Table 5: the composite field test results to Brown Planthopper, rice blast of MTI-446-Prochloraz
Indoor biometrics and field efficacy result show, MTI-446 Prochloraz composition antagonism brown plant-hopper, stinkbug, aphid and rice blast have good control efficiency, control efficiency all is better than the effect of single dose kind, so Prochloraz and MTI-446 have obvious synergistic function after composite.
Two kinds of reactive compounds can be processed into any one formulation of permission, and the below is with two kinds of preparations that active ingredient is processed into of specific embodiment explanation, but the preparation that these two kinds of active components can be processed is not limited only to following listed.
Embodiment 2:
Take by weighing 5g MTI-446,50g Prochloraz, phenethyl phenol polyethenoxy ether phosphate 3g, farming breast 33
#2g, alkylphenol polyoxyethylene 1g, dimethylbenzene 13g adds water to 100g.The method of above raw material being prepared routinely aqueous emulsion drops into the mixing of mixing kettle high speed, and making main active ingredient weight percentage is 55% MTI-446-prochloraz aqueous emulsion.
Embodiment 3:
Take by weighing 2g MTI-446,30g Prochloraz, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, farming breast 33
#2g, alkylphenol polyoxyethylene 1g, cyclohexanone 10g adds water to 100g.The method that above raw material is prepared microemulsion routinely drops in the mixing kettle mixes, and making main active ingredient weight percentage is 32% MTI-446-Prochloraz microemulsion.
Embodiment 4:
Take by weighing 1g MTI-446,10g Prochloraz, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, farming breast 33
#2g, alkylphenol polyoxyethylene 1g, cyclohexanone 10g adds water to 100g.The method that above raw material is prepared microemulsion routinely drops in the mixing kettle mixes, and making main active ingredient weight percentage is 32% MTI-446-Prochloraz microemulsion.
Embodiment 5: take by weighing 50g MTI-446,20g Prochloraz, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, dimethylbenzene are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and making main active ingredient weight percentage is 70% MTI-446-Prochloraz missible oil.
Embodiment 6: take by weighing 2g MTI-446,40g Prochloraz, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, dimethylbenzene are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and making main active ingredient weight percentage is 42% MTI-446-Prochloraz missible oil.
Embodiment 7: take by weighing 0.2g MTI-446,50g Prochloraz, calcium dodecyl benzene sulfonate 9g, phenethyl phenol polyethenoxy ether 8g, dimethylbenzene are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and making main active ingredient weight percentage is 50.2% MTI-446-Prochloraz missible oil.
Embodiment 8: take by weighing 3g MTI-446,12g Prochloraz, sodium lignin sulfonate 2g, polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, water complements to 100g, and making main active ingredient weight percentage under the effect of sand mill is 42% MTI-446-Prochloraz suspending agent.
Embodiment 9: take by weighing 5g MTI-446,30g Prochloraz, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, dimethylbenzene are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and making main active ingredient weight percentage is 35% MTI-446-Prochloraz missible oil.
Embodiment 10: take by weighing 20g MTI-446,5g Prochloraz, the 8g of wooden sodium sulfonate, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, diatomite 28g, it is 7% MTI-446-Prochloraz water dispersion granule that above raw material is made main active ingredient weight percentage by the water dispersible granular agent method.
Embodiment 11: take by weighing 30g MTI-446,12g Prochloraz, sodium lignin sulfonate 2g, polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, water complements to 100g, and making main active ingredient weight percentage under the effect of sand mill is 42% MTI-446-Prochloraz suspending agent.
Embodiment 12: take by weighing 2g MTI-446,5g Prochloraz, the 8g of wooden sodium sulfonate, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, diatomite 28g, it is 7% MTI-446-Prochloraz water dispersion granule that above raw material is made main active ingredient weight percentage by the water dispersible granular agent method.
Embodiment 13: take by weighing 5g MTI-446,13g Prochloraz, lignin 10g, Negel 2g, add to 100g with diatomite, above raw material is mixed in micronizer, and making main active ingredient weight percentage is 20% MTI-446 and Prochloraz wetting powder.
Embodiment 14: take by weighing 2g MTI-446,18g Prochloraz, lignin 10g, Negel 2g, add to 100g with diatomite, above raw material is mixed in micronizer, and making main active ingredient weight percentage is 20% MTI-446 and Prochloraz wetting powder.
Embodiment 15: take by weighing 7g MTI-446,70g Prochloraz, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, dimethylbenzene are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and making main active ingredient weight percentage is 77% MTI-446-Prochloraz missible oil.
Claims (10)
1. composite insecticidal bactericidal composition that contains MTI-446 and Prochloraz is characterized in that this insecticidal and bactericidal composition take MTI-446 and Prochloraz as main active ingredient, and wherein, the weight ratio of MTI-446 and Prochloraz is 1～85: 0.5～70.
2. insecticidal and bactericidal composition according to claim 1, the weight ratio that it is characterized in that described MTI-446 and Prochloraz is 0.5～50: 2～50.
3. Pesticidal combination according to claim 2, the weight ratio that it is characterized in that described MTI-446 and Prochloraz is 0.5～10: 4～30.
4. the potentiating pesticidal bactericidal composition that contains MTI-446 and Prochloraz according to claim 1 is characterized in that the two weight percentage that accounts for composition of MTI-446 and Prochloraz is 2～80%.
5. the potentiating pesticidal bactericidal composition that contains MTI-446 and Prochloraz according to claim 4 is characterized in that the two weight percentage that accounts for composition of MTI-446 and Prochloraz is 5～50%.
6. the potentiating pesticidal bactericidal composition that contains MTI-446 and Prochloraz according to claim 5 is characterized in that the two weight percentage that accounts for composition of MTI-446 and Prochloraz is 10～40%.
7. the potentiating pesticidal bactericidal composition that contains MTI-446 and Prochloraz according to claim 1 is characterized in that it take MTI-446 and Prochloraz as main active ingredient and insecticides adjuvant, excipients are mixed with any one formulation that allows on the agricultural chemicals.
8. the potentiating pesticidal bactericidal composition that contains MTI-446 and Prochloraz according to claim 7 is characterized in that described formulation is missible oil, suspending agent, aqueous emulsion, wetting powder, microemulsion or water dispersion granule.
9. the potentiating pesticidal bactericidal composition that contains MTI-446 and Prochloraz claimed in claim 1 is prevented and treated the application on the pesticide-germicide medicine of the fungal disease that resistance Semiptera evil, Lepidoptera, coleopteran pest or sac fungi, imperfect fungus cause in preparation.
The potentiating pesticidal bactericidal composition that contains MTI-446 and Prochloraz according to claim 9 anti-ly eliminate aphis in preparation, aleyrodid, leafhopper, stinkbug, plant hopper and citrus anthracnose, blossom-end rot, penicilliosis, green mould, banana anthracnose, leaf spot, mango anthracnose, leaf spot of peanut, the vegetables anthracnose such as capsicum, eggplant, muskmelon, tomato, Strawberry anthracnose, bakanae disease of rice, rice blast, sclerotinia rot of colza, leaf spot, the mushroom brown spot, apple anthracnose, the application on the pesticide-germicide medicine of pear scab.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104365669A (en) * | 2014-10-30 | 2015-02-25 | 柳州市惠农化工有限公司 | Dinotefuran and copper calcium sulphate suspension emulsion and application thereof |
| CN108432789A (en) * | 2018-02-13 | 2018-08-24 | 平南县亿翔环保能源有限公司 | The pyroligneous-contained anti-drug to eliminate aphis |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006015865A1 (en) * | 2004-08-12 | 2006-02-16 | Syngenta Participations Ag | Fungicidal compositions |
| CN101043813A (en) * | 2003-04-11 | 2007-09-26 | 哈茨山公司 | High concentration dinotefuran formulations containing methoprene |
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2011
- 2011-10-20 CN CN201110321793.3A patent/CN103053588B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101043813A (en) * | 2003-04-11 | 2007-09-26 | 哈茨山公司 | High concentration dinotefuran formulations containing methoprene |
| WO2006015865A1 (en) * | 2004-08-12 | 2006-02-16 | Syngenta Participations Ag | Fungicidal compositions |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104365669A (en) * | 2014-10-30 | 2015-02-25 | 柳州市惠农化工有限公司 | Dinotefuran and copper calcium sulphate suspension emulsion and application thereof |
| CN108432789A (en) * | 2018-02-13 | 2018-08-24 | 平南县亿翔环保能源有限公司 | The pyroligneous-contained anti-drug to eliminate aphis |
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