CN103004823A - Bactericide composition containing pyraclostrobin and bromothalonil - Google Patents
Bactericide composition containing pyraclostrobin and bromothalonil Download PDFInfo
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- CN103004823A CN103004823A CN201310019646XA CN201310019646A CN103004823A CN 103004823 A CN103004823 A CN 103004823A CN 201310019646X A CN201310019646X A CN 201310019646XA CN 201310019646 A CN201310019646 A CN 201310019646A CN 103004823 A CN103004823 A CN 103004823A
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- bromothalonil
- pyraclostrobin
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Abstract
The invention relates to the field of pesticides and bactericides, and particularly discloses a bactericide composition containing pyraclostrobin and bromothalonil. Effective ingredients of the bactericide composition are the pyraclostrobin and the bromothalonil respectively, and the weight ratio of the pyraclostrobin to the bromothalonil is 1:79-79:1. The bactericide composition containing the pyraclostrobin and the bromothalonil has the advantages that problems that control effects of pyraclostrobin and bromothalonil to diseases such as downy mildew, anthracnose and the like of crops are simple, persistence periods of the pyraclostrobin and the bromothalonil are short and the like are solved; insecticide resistance is delayed, the persistence period of the bactericide composition is prolonged, and the bactericide composition is low in cost; and the bactericide composition can be manufactured into different formulations, realizes an excellent control effect for various diseases such as scab, the anthracnose, powdery mildew, the downy mildew, leaf spots, brown rot, white rot, botrytis and the like of various fruit trees and vegetables, and is particularly good in control effect for cucumber downy mildew, cucumber powdery mildew, apple anthracnose, watermelon anthracnose and the like.
Description
(1) technical field
The present invention relates to the agriculture chemicals fungicide field, particularly a kind of combination sterilization composition that contains pyraclostrobin and bromothalonil.
(2) background technology
(English common name: Pyraclostrobin) have another name called Kai Run, belong to methoxy acrylic bactericide, chemical name is N-2-1-(4-chlorobenzene)-1H-pyrazole-3-yl oxygen methylbenzene-N-methoxy methyl carbamate to pyraclostrobin, molecular formula: C
19H
18ClN
3O
4, molecular weight: 387.82, structural formula is:
Although pyraclostrobin can be prevented and treated the plant disease that is caused by fungal pathogens such as ascus guiding principle, Basidiomycetes, Fungi Imperfecti and Oomycetes, but the action site of pyraclostrobin is single, if long-term single use, unavoidably can produce resistance, and this reagent cost is high, and difficulty is larger in plant protection is promoted.
(English common name: Bromothalonil) have another name called charcoal Trane, Tektamer, tektamer, chemical name is 1,2 '-two bromo-2 to bromothalonil, 4-dicyanobutane, molecular formula: C
6H
6Br
2N
2, molecular weight: 265.94, structural formula is:
Bromothalonil is the bactericide of a kind of wide spectrum, efficient, low toxicity, can suppress and root out the growth of fungi, bacterium, algae, and corps diseases is had preferably control efficiency.But long-term use is more single to the effect of crop disease control, but the lasting period is short, and control efficiency is undesirable.
(3) summary of the invention
The present invention provides the combination sterilization composition that contains pyraclostrobin and bromothalonil that a kind of preventive and therapeutic effect is various, delay pesticide resistance, prolong the lasting period, reduce production costs in order to remedy the deficiencies in the prior art.
The present invention is achieved through the following technical solutions:
A kind of combination sterilization composition that contains pyraclostrobin and bromothalonil, its active ingredient consists of pyraclostrobin and bromothalonil, and the weight ratio of described pyraclostrobin and bromothalonil is 1: 79～79: 1.
This contains the combination sterilization composition of pyraclostrobin and bromothalonil, and the weight ratio that its preferred scheme is pyraclostrobin and bromothalonil is 1: 50～50: 1.
This contains the combination sterilization composition of pyraclostrobin and bromothalonil, and its active ingredient pyraclostrobin and bromothalonil account for 5%～80% of combination sterilization composition gross weight, and all the other are auxiliary element.Described auxiliary element can be solvent, emulsifier, dispersant, wetting agent, stabilizing agent, antifreezing agent, thickener, defoamer, filler or adhesive, reaching other is of value to active ingredient stable material of bringing into play with drug effect in preparation, can be wherein one or more.This auxiliary element is conducive to combination sterilization composition is made the formulation that is fit to the upper use of agricultural, and preferred formulation is missible oil, wetting powder, water dispersible granules or aqueous suspension agent.
Described solvent is one or more in DMF, dimethylbenzene, toluene, cyclohexanone, dimethyl sulfoxide (DMSO), cyclohexanol, isopropyl alcohol, methyl alcohol, ethanol, the ethyl acetate.
Described emulsifier is one or more in OPEO, polyoxyethylene nonylphenol ether, Bian Ji phenol polyethenoxy ether, styryl phenol polyethenoxy ether, phenethyl phenol polyoxyethylene poly-oxygen propylene aether, castor oil polyoxyethylene ether, the alkyl benzene calcium sulfonate.
Described dispersant is one or more in sodium lignin sulfonate, calcium lignosulfonate, methyl naphthalene sulfonic acid salt formaldehyde condensation products sulphate, Negel, the naphthalene sulfonic acid-formaldehyde condensation product.
Described wetting agent is one or more that pull open in powder, lauryl sodium sulfate, the glycerine.
Described stabilizing agent is one or more in epoxychloropropane, tributyl phosphate, BHT, the butylated hydroxy anisole.
Described antifreezing agent is one or more in ethylene glycol, isopropyl alcohol, urea, the glycerine.
Described thickener is one or more in xanthans, aluminium-magnesium silicate, bentonite, PAA, the gum Arabic.
The preferred silicon defoamer of described defoamer.
Described filler is one or more in white carbon, precipitated calcium carbonate, potter's clay, ammonium sulfate, kaolin, the diatomite.
Described adhesive is one or more in starch, xanthans, the sodium alginate.
The beneficial effect that the present invention contains the combination sterilization composition of pyraclostrobin and bromothalonil is: solved pyraclostrobin, bromothalonil is to crops downy mildew, the disease control effects such as anthracnose are single, but the problems such as the lasting period is short, it is various to have preventive and therapeutic effect, delay pesticide resistance, prolong the characteristics of lasting period, and cost is lower, can be prepared into different formulations, pyraclostrobin and bromothalonil compounded use, can play the effect of Synergistic and expansion fungicidal spectrum, scab to multiple fruit tree and vegetables, anthracnose, powdery mildew, downy mildew, leaf spot, brown rot, white rot, gray mold, the multiple diseases such as downy mildew all play good preventive and therapeutic effect, especially cucumber downy mildew, powdery mildew of cucumber, apple anthracnose, the control of the diseases such as watermelon anthrax.
(4) embodiment
The invention will be further described below in conjunction with embodiment, but the present invention is not limited thereto, and the formulation preparation method among the embodiment is conventional preparation method, no longer describes in detail.
(I) preparation of missible oil:
Active ingredient, solvent, emulsifier are mixed, make it become even oil phase, namely get missible oil.
Embodiment 1:20% pyraclostrobin bromothalonil missible oil comprises the following component of following weight:
Pyraclostrobin 10 kilograms of (rolling over hundred weights), bromothalonil 10 kilograms of (rolling over hundred weights), 10 kilograms of DMFs, 4.5 kilograms of calcium dodecyl benzene sulfonates, 5.5 kilograms of triphenyl vinyl phenol APEOs, 2 kilograms of tributyl phosphates, toluene complement to double centner.
Embodiment 2:70% pyraclostrobin bromothalonil missible oil comprises the following component of following weight:
Pyraclostrobin 3 kilograms of (rolling over hundred weights), bromothalonil 67 kilograms of (rolling over hundred weights), 8 kilograms of calcium dodecyl benzene sulfonates, 5.2 kilograms of triphenyl vinyl phenol APEOs, 2 kilograms of tributyl phosphates, 1 kilogram of butylated hydroxy anisole, cyclohexanol complement to double centner.
Embodiment 3:30% pyraclostrobin bromothalonil missible oil comprises the following component of following weight:
Pyraclostrobin 5 kilograms of (rolling over hundred weights), bromothalonil 25 kilograms of (rolling over hundred weights), 15 kilograms of DMFs, 6 kilograms of OPEOs, 2 kilograms of epoxychloropropane, dimethylbenzene complement to double centner.
(II) preparation of wetting powder:
Active component, auxiliary agent and filler etc. are fully mixed in the ratio of prescription, behind ultra-fine pulverizer disintegrating, namely get wetting powder.
Embodiment 4:5% pyraclostrobin bromothalonil wetting powder comprises the following component of following weight:
Pyraclostrobin 2.5 kilograms of (rolling over hundred weights), bromothalonil 2.5 kilograms of (rolling over hundred weights), 4 kilograms of sodium lignin sulfonates, 2 kilograms of calcium lignosulfonates, 3 kilograms of lauryl sodium sulfate, 12 kilograms of white carbons, kaolin complement to double centner.
Embodiment 5:51% pyraclostrobin bromothalonil wetting powder comprises the following component of following weight:
Pyraclostrobin 1 kilogram of (rolling over hundred weights), bromothalonil 50 kilograms of (rolling over hundred weights), 3 kilograms of sodium lignin sulfonates, 2 kilograms of lauryl sodium sulfate, 12 kilograms of white carbons, kaolin complement to double centner.
Embodiment 6:80% pyraclostrobin bromothalonil wetting powder comprises the following component of following weight:
Pyraclostrobin 79 kilograms of (rolling over hundred weights), bromothalonil 1 kilogram of (rolling over hundred weights), 6 kilograms of calcium lignosulfonates, pull open 4 kilograms in powder, 5 kilograms of white carbons, kaolin and complement to double centner.
(III) preparation of water dispersible granules:
Active ingredient pyraclostrobin and bromothalonil, auxiliary agent, filler are mixed in proportion, through air-flow crushing, then add an amount of water, namely get water dispersible granules through kneading, granulation, drying, screening.
Embodiment 7:60% pyraclostrobin bromothalonil water dispersible granules comprises the following component of following weight:
Pyraclostrobin 45 kilograms of (rolling over hundred weights), bromothalonil 15 kilograms of (rolling over hundred weights), 2 kilograms of naphthalene sulfonic acid-formaldehyde condensation products, 2 kilograms of sodium lignin sulfonates, 3 kilograms of lauryl sodium sulfate, pull open 2 kilograms in powder, 20 kilograms in ammonium sulfate, kaolin and complement to double centner.
Embodiment 8:51% pyraclostrobin bromothalonil water dispersible granules comprises the following component of following weight:
Pyraclostrobin 50 kilograms of (rolling over hundred weights), bromothalonil 1 kilogram of (rolling over hundred weights), 1 kilogram of naphthalene sulfonic acid-formaldehyde condensation product, 2 kilograms of sodium lignin sulfonates, 2 kilograms of lauryl sodium sulfate, 10 kilograms of white carbons, 11 kilograms in urea, 4 kilograms of glycerine, diatomite complement to double centner.
Embodiment 9:80% pyraclostrobin bromothalonil water dispersible granules comprises the following component of following weight:
Pyraclostrobin 1 kilogram of (rolling over hundred weights), bromothalonil 79 kilograms of (rolling over hundred weights), 3 kilograms of naphthalene sulfonic acid-formaldehyde condensation products, 3 kilograms of sodium lignin sulfonates, 4 kilograms of lauryl sodium sulfate, 5 kilograms of Negels, ammonium sulfate complement to double centner.
(IV) preparation of aqueous suspension agent:
Take water as medium, active ingredient, dispersant, wetting agent, emulsifier, antifreezing agent etc. are added in the sand milling still, carry out sand milling and namely get aqueous suspension agent.
Embodiment 10:40% pyraclostrobin bromothalonil aqueous suspension agent comprises the following component of following weight:
Pyraclostrobin 2 kilograms of (rolling over hundred weights), bromothalonil 38 kilograms of (rolling over hundred weights), 2.5 kilograms of naphthalene sulfonic acid-formaldehyde condensation products, 2 kilograms of lauryl sodium sulfate, 2 kilograms of castor oil polyoxyethylene ethers, 2.5 kilograms of phenethyl phenol polyoxyethylene poly-oxygen propylene aethers, 1 kilogram of white carbon, 0.2 kilogram of xanthans, 0.15 kilogram of aluminium-magnesium silicate, 5 kilograms of ethylene glycol, water complement to double centner.
The present invention is by a large amount of screening tests, use the abundant method of Sun Yun pyraclostrobin and bromothalonil composition to be carried out the synergistic effect analysis of different proportionings, discovery is in certain ratio range, pyraclostrobin and bromothalonil combination, antagonism downy mildew, anthracnose, powdery mildew have obvious synergistic function, and be not only the simple superposition of two kinds of medicaments, specifically be illustrated with following biologicall test test example.
Test example is 1.: pyraclostrobin and bromothalonil compounded are to the effect of cucumber downy mildew:
Pot-culture method is adopted in test, measures pyraclostrobin, bromothalonil and its composition to the control efficiency of cucumber downy mildew.
Choose three to four consistent leaf phase cucumber seedlings of growing way, every kind of test medicine selects 5 basins for the examination cucumber seedling, sprays the about 5mL of every basin under 50PSI pressure with the Potter spray tower.Every kind of test medicine arranges 5 concentration gradients.24h connects bacterium after the chemicals treatment, the sick leaf of the cucumber downy mildew that picks up from the field is evenly shaken off conidium inoculate above cucumber seedling, then cucumber seedling is put into the greenhouse and cultivates.Behind the 7d, according to the morbidity standard complete stool investigation disease index of cucumber downy mildew, and calculate control efficiency, then calculate concentration EC in the inhibition with method of least squares
50, calculate co-toxicity coefficient (CTC) according to the abundant method of Sun Yun again.
When CTC≤80, then the composition performance is for antagonism, and when 80＜CTC＜120, then the composition performance is for summation action, and when CTC 〉=120, then the composition performance is synergistic effect.
Actual measurement toxicity index (ATI)=(standard medicament EC
50/ reagent agent EC
50) * 100;
The percentage composition of bromothalonil in the percentage composition of pyraclostrobin+bromothalonil medicament toxicity index * mixture in theoretical toxicity index (TTI)=pyraclostrobin medicament toxicity index * mixture;
Co-toxicity coefficient (CTC)=[mixture actual measurement toxicity index (the ATI)/theoretical toxicity index (TTI) of mixture] * 100;
Table 1 different disposal is to the Toxicity Determination result of bacterium of downy mildew of cucumber
As shown in Table 1, pyraclostrobin and bromothalonil have obvious synergistic effect between proportioning 1: 50～50: 1, and especially between 1: 25～25: 1, synergistic effect is more obvious, and co-toxicity coefficient is more than 220.
Test example is 2.: pyraclostrobin and bromothalonil compounded are to the effect of downy mildew of garpe:
In the toxic dielectric method of indoor employing, measure combination sterilization composition 60% water dispersible granules of the present invention and 25% pyraclostrobin missible oil, 25% bromothalonil missible oil to the fungistatic effect of downy mildew of garpe.
Test method: in the PDA medium, add respectively quantitative above-mentioned three kinds of medicaments (establishing not dosing blank), inoculation downy mildew of garpe fungi strain after the cooling, cultivate 24 ℃ of unglazed photographs under the condition after the inoculation, after cultivating 120 hours, carry out result's investigation.Test result is as follows:
Table 2 different disposal is to the indoor Antibacterial Activity result of Plasmopara viticola
As shown in Table 2, the present invention's combination sterilization composition of containing pyraclostrobin and bromothalonil is significantly higher than the activity of two kinds of single doses to the bacteriostatic activity of downy mildew of garpe.
Claims (10)
1. combination sterilization composition that contains pyraclostrobin and bromothalonil, it is characterized in that: its active ingredient consists of pyraclostrobin and bromothalonil, and the weight ratio of described pyraclostrobin and bromothalonil is 1: 79～79: 1.
2. a kind of combination sterilization composition that contains pyraclostrobin and bromothalonil according to claim 1, it is characterized in that: the weight ratio of described pyraclostrobin and bromothalonil is 1: 50～50: 1.
3. a kind of combination sterilization composition that contains pyraclostrobin and bromothalonil according to claim 1 and 2, it is characterized in that: described active ingredient pyraclostrobin and bromothalonil account for 5%～80% of combination sterilization composition gross weight, and all the other are auxiliary element.
4. a kind of combination sterilization composition that contains pyraclostrobin and bromothalonil according to claim 3, it is characterized in that: described auxiliary element is one or more in solvent, emulsifier, dispersant, wetting agent, stabilizing agent, antifreezing agent, thickener, defoamer, filler, the adhesive.
5. a kind of combination sterilization composition that contains pyraclostrobin and bromothalonil according to claim 4, it is characterized in that: described solvent is one or more in DMF, dimethylbenzene, toluene, cyclohexanone, dimethyl sulfoxide (DMSO), cyclohexanol, isopropyl alcohol, methyl alcohol, ethanol, the ethyl acetate.
6. a kind of combination sterilization composition that contains pyraclostrobin and bromothalonil according to claim 4, it is characterized in that: described emulsifier is one or more in OPEO, polyoxyethylene nonylphenol ether, Bian Ji phenol polyethenoxy ether, styryl phenol polyethenoxy ether, phenethyl phenol polyoxyethylene poly-oxygen propylene aether, castor oil polyoxyethylene ether, the alkyl benzene calcium sulfonate.
7. a kind of combination sterilization composition that contains pyraclostrobin and bromothalonil according to claim 4, it is characterized in that: described dispersant is one or more in sodium lignin sulfonate, calcium lignosulfonate, methyl naphthalene sulfonic acid salt formaldehyde condensation products sulphate, Negel, the naphthalene sulfonic acid-formaldehyde condensation product; Described wetting agent is one or more that pull open in powder, lauryl sodium sulfate, the glycerine.
8. a kind of combination sterilization composition that contains pyraclostrobin and bromothalonil according to claim 4, it is characterized in that: described stabilizing agent is one or more in epoxychloropropane, tributyl phosphate, BHT, the butylated hydroxy anisole; Described antifreezing agent is one or more in ethylene glycol, isopropyl alcohol, urea, the glycerine.
9. a kind of combination sterilization composition that contains pyraclostrobin and bromothalonil according to claim 4, it is characterized in that: described thickener is one or more in xanthans, aluminium-magnesium silicate, bentonite, PAA, the gum Arabic; Described filler is one or more in white carbon, precipitated calcium carbonate, potter's clay, ammonium sulfate, kaolin, the diatomite; Described adhesive is one or more in starch, xanthans, the sodium alginate.
10. a kind of combination sterilization composition that contains pyraclostrobin and bromothalonil according to claim 3, it is characterized in that: the formulation of this combination sterilization composition is missible oil, wetting powder, water dispersible granules or aqueous suspension agent.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104970032A (en) * | 2015-07-09 | 2015-10-14 | 广西兄弟农药厂(普通合伙) | Pesticide microemulsion containing bromothalonil and pyraclostrobin |
| CN105360152A (en) * | 2015-12-02 | 2016-03-02 | 安徽省农业科学院植物保护与农产品质量安全研究所 | Bactericidal composition containing pyraclostrobin and hydantoin |
| CN105360146A (en) * | 2015-12-02 | 2016-03-02 | 安徽省农业科学院植物保护与农产品质量安全研究所 | Bactericidal composition containing pyraclostrobin and procymidone |
| CN106665646A (en) * | 2016-12-23 | 2017-05-17 | 江苏农林职业技术学院 | Disease-control fungicide for cornus florida and application method of disease-control fungicide |
| CN113396924A (en) * | 2021-06-21 | 2021-09-17 | 广西壮族自治区亚热带作物研究所（广西亚热带农产品加工研究所） | Bactericidal composition for preventing and treating macadamia nut anthracnose |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101690490A (en) * | 2009-10-14 | 2010-04-07 | 成都皇牌作物科学有限公司 | Bactericidal composition compounded by bromothalonil and methoxy acrylic acid esters |
-
2013
- 2013-01-21 CN CN201310019646XA patent/CN103004823A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101690490A (en) * | 2009-10-14 | 2010-04-07 | 成都皇牌作物科学有限公司 | Bactericidal composition compounded by bromothalonil and methoxy acrylic acid esters |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104970032A (en) * | 2015-07-09 | 2015-10-14 | 广西兄弟农药厂(普通合伙) | Pesticide microemulsion containing bromothalonil and pyraclostrobin |
| CN105360152A (en) * | 2015-12-02 | 2016-03-02 | 安徽省农业科学院植物保护与农产品质量安全研究所 | Bactericidal composition containing pyraclostrobin and hydantoin |
| CN105360146A (en) * | 2015-12-02 | 2016-03-02 | 安徽省农业科学院植物保护与农产品质量安全研究所 | Bactericidal composition containing pyraclostrobin and procymidone |
| CN106665646A (en) * | 2016-12-23 | 2017-05-17 | 江苏农林职业技术学院 | Disease-control fungicide for cornus florida and application method of disease-control fungicide |
| CN113396924A (en) * | 2021-06-21 | 2021-09-17 | 广西壮族自治区亚热带作物研究所（广西亚热带农产品加工研究所） | Bactericidal composition for preventing and treating macadamia nut anthracnose |
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