CN104365634A - Fungicide composition containing amisulborum and mancozeb and application - Google Patents

Fungicide composition containing amisulborum and mancozeb and application Download PDF

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CN104365634A
CN104365634A CN201410612355.6A CN201410612355A CN104365634A CN 104365634 A CN104365634 A CN 104365634A CN 201410612355 A CN201410612355 A CN 201410612355A CN 104365634 A CN104365634 A CN 104365634A
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mancozeb
amisulbrom
bactericidal composition
agent
dispersant
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崔淑华
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Abstract

The invention relates to the technical field of pesticide compounding, in particular relates to a fungicide composition containing amisulborum and mancozeb and also relates to application of the fungicide composition. Active components of the fungicide composition comprise amisulborum and mancozeb; the mass ratio of amisulborum to mancozeb ranges from 5:1 to 1:20; the mass percentage of amisulborum and mancozeb in the composition is 1-80 percent, and the balance comprises pesticidally available and acceptable auxiliary components. The fungicide composition disclosed by the invention is wettable powder, a suspending agent or a water dispersing agent and can be used for effectively preventing and treating diseases such as downy mildew and pestilence of vegetables, grapes, litchi and melons.

Description

A kind of bactericidal composition and application containing amisulbrom and mancozeb
Technical field
The present invention relates to technical field of pesticide combination, be specifically related to a kind of bactericidal composition containing amisulbrom and mancozeb, also relate to the application of this bactericidal composition.
Background technology
Downy mildew and epidemic disease are the Common Diseases in the proportion of crop planting processes such as vegetable and fruit, Pseudoperonospora cubensis and the destructiveness of phytophthora root rot bacterium to host plant strong, harmfulness is large, after crop is infected, often significantly the underproduction is even had no harvest, have a strong impact on vegetables and fruit quality and household economy benefit, developed its relevant control product and there is the great market space.According to the literature, due to single agricultural chemicals and other unscientific application methods, downy mildew and epidemic disease has been caused to create pesticide resistance to a lot of common pesticides, after resistance produces, the increase of formulation rate and spraying times causes again peasant burden to increase the weight of and increasing environmental pollution, therefore, one of the mixture common methods becoming control of agricultural pest of different pesticide species.
Amisulbrom (Amisulborum) is the new type bactericide of Japanese Nissan chemical company initiative, chemical name is 3-(the fluoro-2 methyl indole of the bromo-6-of 3--1-base sulphonyl)-N, N-dimethyl-1,2,4-triazole-1-sulfonamide, belongs to triazolylsulfonamide series bactericidal agent.This bactericide mode of action is novel unique, to epidemic disease, mould and Pseudoperonospora cubensis spore activity of dissociating is very high, carry out control by indirectly suppressing free spore-germination to epidemic disease and downy mildew germ to prevent, there is very strong prevention, treatment, osmotically active, and have good lasting effect and rain wash resistance, good control efficiency can be reached under low usage amount.Nearest research finds, after bacteria infection, spray amisulbrom, and the blade that can make to fall ill can not be formed and perfect spore, thus suppresses other positions to be caused a disease, and avoids crop superinfection germ.Now be mainly used in preventing and treating grape, cucumber downy mildew, potato and tomato blight etc.Its chemical structural formula is:
Mancozeb (Mancozeb) is a kind of excellent protective fungicide, belongs to low-toxin farm chemicals.Have that fungicidal spectrum is wide, bactericidal mechanism is many, not easily produce resistance, control efficiency is obviously better than other features with series bactericidal agent, and therefore consumption one is large tonnage product in the world.Current domestic most composite bactericide is all formulated with mancozeb processing, and manganese, zinc microelement have significantly short strong, production-increasing function to crop.Be mainly used in preventing and treating the Phytophthora of Phycomycetes, the Cercospora of Fungi Imperfecti, the multiple diseases that Ascochyta etc. cause, effective to multiple diseases such as the anthracnose on fruit tree, vegetables, early blight, as sigatoka, alternaria leaf spot of apple, ring spot, anthracnose, pear scab, the downy mildew of grape, gray mold, anthracnose, anthrachose of grape, melon anthracnose, downy mildew, zonate spot and brown spot, the multiple diseases such as epidemic disease, graywall, anthracnose, spot disease of potato.Show that mancozeb controls disease by more than ten years Field information effective, steady quality is reliable.
Although amisulbrom has higher bactericidal activity to epidemic disease and downy mildew germ, if be used alone for a long time, easily make plant germ develop immunity to drugs to it, then produce the problems such as dosage increasing, preventive effect reduction, lasting period shortening.Being carried out by the medicament of the different mechanism of action rationally composite, is delay disease to develop immunity to drugs very effective common method, and can according to the effect in production application, judge this composite be synergistic effect or antagonism.The formula that two kinds of agriculture chemical compounding compatibilities are good, can significantly improve preventive effect, greatly reduce the dosage of agricultural chemicals, can also expand fungicidal spectrum, improves germicidal efficiency.
In the present composition, two kinds of active component mechanisms of action are different, and the present inventor, through lot of experiments recipe determination, proposes a kind of Compositional type bactericidal composition, namely with two yuan of combination sterilization compositions that amisulbrom and mancozeb carry out for active ingredient.The experiment of actual indoor virulence and field efficacy experiment show, by amisulbrom and mancozeb composite in certain proportion, there is good synergy and act synergistically, substantially increase germicidal efficiency.Meanwhile, well can delay the generation of Disease Resistance, reduce drug cost, improve actual preventive effect, can be used for preventing and treating vegetables, fruit tree, the downy mildew of the crop such as melon and epidemic disease.Composite about amisulbrom and mancozeb, there is not yet relevant report at home and abroad at present.
Summary of the invention
The object of the invention is to propose that one has synergistic function, use cost is low, to veterinary antibiotics and the crop downy mildew such as melon and the good bactericidal composition of epidemic disease preventive effect.
For realizing above object, the technical solution adopted in the present invention is: a kind of bactericidal composition and application containing amisulbrom and mancozeb, comprises following content:
The active ingredient of this bactericidal composition is amisulbrom and mancozeb binary built, and all the other are auxiliary element.
In described bactericidal composition, amisulbrom and the mass fraction of mancozeb are than being 80:1 ~ 1:80, and when the mass ratio of amisulbrom and mancozeb is 5:1 ~ 1:20, synergistic effect is optimum.
Its formulation of described bactericidal composition is any one in wetting powder, suspending agent, water dispersible granules.
When bactericidal composition is wetting powder, the percentage by weight of each component is: amisulbrom 1% ~ 80%, mancozeb 1% ~ 80%, dispersant 1% ~ 20%, wetting agent 1% ~ 10%, filler 1% ~ 70%, by above-mentioned weight proportion, amisulbrom is mixed with mancozeb and dispersant, wetting agent and filler, uniform stirring in stirred tank, mix again after airslide disintegrating mill is pulverized, obtain wetting powder bactericidal composition.
When bactericidal composition is suspending agent, the percentage by weight of each component is: amisulbrom 1% ~ 80%, mancozeb 1% ~ 80%, dispersant 5% ~ 20%, antifreezing agent 1% ~ 5%, thickener 0.1% ~ 2%, defoamer 0.1% ~ 0.8%, surplus is water, the concrete production stage of this suspending agent is: first mixed by above-mentioned proportioning by auxiliary agent, mix through high speed shear, add amisulbrom and mancozeb, abrading-ball 2 ~ 3 hours in ball crusher, make a diameter all at below 5mm, obtain the bactericidal composition of aqueous suspension formulations.
When bactericidal composition is water dispersible granules, the mass percent of component is: amisulbrom 1% ~ 80%, mancozeb 1% ~ 80%, dispersant 3% ~ 20%, wetting agent 3% ~ 10%, disintegrant 1% ~ 5%, filler 1% ~ 70%, the concrete production stage of this water dispersible granules is: amisulbrom, mancozeb and dispersant, wetting agent, disintegrant and filler are mixed, pulverize with micro jet, through mediating, then add in fluidized-bed granulation dryer and carry out granulation, drying, screening, obtain the bactericidal composition of water dispersant.
Described dispersant is: one or more in polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, fatty acid glyceride APEO.
Described wetting agent is: one or more in lauryl sodium sulfate, calcium dodecyl benzene sulfonate, Nekal BX, wetting and penetrating agent F, alkylnaphthalene sulfonate, polyoxyethylene tri-styryl phosphenylic acid salt, spaonin powder, silkworm excrement, soapberry powder.
Described disintegrant is: one or more in bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, sodium bicarbonate.
Described filler is: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate.
Described thickener is: one or more in xanthans, CMC, hydroxyethylcellulose, methylcellulose, Magnesiumaluminumsilicate, polyvinyl alcohol.
Described antifreezing agent is: one or more in ethylene glycol, propane diols, glycerine, polyethylene glycol.
Described defoamer is: silicone oil, silicone compound, C 10-20saturated fat acid compounds, C 8-10one or more in aliphatic alcohols compound.
The composite bactericide that the present invention is active ingredient with amisulbrom and mancozeb has obvious synergistic effect, the drug-fast generation of germ can be delayed, and reduce pesticide producing cost and peasant's use cost, effectively can control the disease such as downy mildew, epidemic disease on veterinary antibiotics, the crop such as melon.
Beneficial effect of the present invention is:
Bactericidal composition provided by the invention, in certain ratio range, obvious synergistic effect is shown to cucumber downy mildew, capsicum epidemic disease, the control efficiency of composition is significantly improved than single dose, reduce the using dosage of agricultural chemicals, reduce drug cost, decrease the adverse effect of agricultural chemicals to ecotope.
Two kinds of active ingredient mechanism of action of bactericidal composition provided by the invention are different, can overcome the single shortcoming making with medicament easily produce resistance for a long time, can extend the service life of medicament, significant to the comprehensive regulation of disease.
Composition pesticide of the present invention is to crop safety.
Embodiment
Below in conjunction with specific embodiment, the present invention is further described, so that those skilled in the art more understands the present invention, but does not therefore limit the present invention.
The method that the present invention adopts indoor bioassay and field trial to combine.If no special instructions, the ratio (comprising percentage) below mentioned is all mass ratio.It should be pointed out that all any amendments done within the spirit and principles in the present invention, equivalent replacement and improvement etc., all should be included within protection scope of the present invention.
Test example
After the pestsides synthesis of different cultivars, usually show three kinds of type of action, i.e. summation action, synergistic effect and antagonism, but be specially which kind of effect, unpredictable.Bactericidal composition that the present invention tells for active ingredient, adopts biologicall test example to be illustrated with amisulbrom and mancozeb.
Test example 1: amisulbrom and the composite toxicity test to cucumber downy mildew of mancozeb
Subjects: bacterium of downy mildew of cucumber
Test target: the cucumber of never executing amisulbrom and mancozeb and medicament of the same type from Shouguang, Shandong gathers potted plantly and is separated, for examination cucumber variety: Chang Chun Mi Ci.
Test method:
First use the former medicine of acetone solution, appropriate two former medicines are made into several different ratio by the result according to preliminary experiment, then it is stand-by with acetone, each process to be diluted to several concentration gradients respectively.
By susceptible cucumber variety Chang Chun Mi Ci cultivation in pot for growing seedlings, be placed in greenhouse and cultivate, plant to be planted grows to three to four leaf after dates, gathers the blade of identical leaf age, for cultivation and the mensuration of cucumber downy mildew germ.
Cucumber downy mildew germ adopt plants method 20 DEG C, cultivate under the condition of 12h alternation of light and darkness, every 30d turns culture 1 time.With the conidium on sterile water wash-out incidence of leaf during inoculation, being mixed with spore concentration is 1 × 10 6the spore suspension of individual/mL.
Leaf dish moisturizing method is adopted to carry out toxicity test.First the blade of collection is prepared into the leaf dish that diameter is 1.5cm, random mixing, be placed in the series concentration liquid configured respectively and soak 1h, each concentration 50 leaf dishes, test with the process of not adding medicine as blank, after immersion terminates, leaf faces up and puts on the blotting paper that identical liquor strength is wetting, liquid on leaf dish is blotted, the spore suspension prepared is inoculated in leaf dish central authorities, after room temperature places 5min, be placed in 20 DEG C, cultivate under the condition of 12h alternation of light and darkness, the onset area on leaf dish is measured after 10d, calculate disease index and control efficiency.
The percentage accounting for leaf disc area according to lesion area divides disease level
0 grade: anosis;
1 grade: sorus area accounts for less than 5% of whole leaf area;
3 grades: sorus area accounts for below the 6%-10% of whole leaf area;
5 grades: sorus area accounts for below the 11%-20% of whole leaf area;
7 grades: sorus area accounts for below the 21%-50% of whole leaf area;
9 grades: sorus area accounts for more than 50% of whole leaf area.
Drug effect computational methods:
Control efficiency is converted into probability value (y), and drug concentration (mg/L) converts logarithm value (x) to, calculates virulence equation and concentration EC in suppressing with method of least squares 50.
Carry out the toxicity test of mixture according to mixed ratio by single dose toxicity test method.
Co-toxicity coefficient (CTC) is calculated, co-toxicity coefficient CTC computing formula following (take amisulbrom as standard agent, its toxicity index is 100) according to the abundant method of Sun Yun:
TI × P mancozeb of TI × P amisulbrom+mancozeb of theoretical toxicity index (the TTI)=amisulbrom of M
In formula:
M is the mixture of amisulbrom and mancozeb different ratio
P amisulbrom is the ratio of amisulbrom shared by mixture
P mancozeb is the ratio ratio of mancozeb shared by mixture.
If co-toxicity coefficient CTC≤80, then composition shows as antagonism; If 80 < CTC < 120, then composition shows as summation action; If CTC >=120, then composition shows as synergistic effect.
Amisulbrom and the toxicity test of mancozeb to cucumber downy mildew of different quality mark ratio the results are shown in Table 1:
Table 1 amisulbrom and mancozeb are to the toxicity test result of cucumber downy mildew
Treatment agent and mass ratio EC 50Value (mg/L) ATI TTI Co-toxicity coefficient CTC
Amisulbrom (A) 0.215 100 / /
Mancozeb (B) 11.22 1.92 / /
A:B is 20:1 0.180 119.4 95.3 125.3
A:B is 10:1 0.171 125.7 91.1 138.0
A:B is 5:1 0.167 128.7 83.7 153.9
A:B is 3:1 0.168 128.0 75.5 169.5
A:B is 2:1 0.172 125.0 67.3 185.7
A:B is 1:1 0.203 105.9 51.0 207.8
A:B is 1:2 0.265 81.1 34.6 234.4
A:B is 1:3 0.406 53.0 26.4 200.3
A:B is 1:5 0.632 34.0 18.3 186.2
A:B is 1:10 1.278 16.8 10.8 155.2
A:B is 1:20 2.247 9.6 6.6 145.2
As can be seen from the table, with amisulbrom and mancozeb for active ingredient carries out composite control cucumber downy mildew, when mass ratio is between 20:1 ~ 1:20, co-toxicity coefficient, more than 125.3, has synergistic effect; When mass ratio is between 5:1 ~ 1:20, co-toxicity coefficient is all higher than 145.2, and synergistic effect is obvious.Suggestion carries out further field control effectiveness test to the mixture preparation of suitable proportion about 5:1 ~ 1:20 scope, to evaluate its field practical application effect.
Test example 2: the field control effectiveness test of control cucumber downy mildew
Test method
Test on Shandong Pingdu City cucumber ground, test dispenser twice altogether, check plot spray equivalent clear water.When making up a prescription, after first medicament fully being dissolved with a small amount of water, then add suitable quantity of water carry out complete stool spraying process, even spraying.All adopt power driven sprayer during spray medicine, operating pressure is 0.3 ~ 0.4MPa, shower nozzle aperture 1.3mm.Community spouting liquid is 30 ~ 40kg/667m 2, continuous dispenser twice, 7 days intervals, sprays application to crop complete stool uniformly by liquid.
Investigation method
The cucumber booth selecting occurring degree medium is that experimental field soil fertility is medium, and irrigation and drainage are convenient.Each community double diagonal line investigates 5 points, and often some investigation 3 strain cucumber, record occurring degree by staging.
Grade scale is as follows:
0 grade: anosis;
1 grade: sorus area accounts for less than 5% of whole leaf area;
3 grades: sorus area accounts for below the 6%-10% of whole leaf area;
5 grades: sorus area accounts for below the 11%-20% of whole leaf area;
7 grades: sorus area accounts for below the 21%-50% of whole leaf area;
9 grades: sorus area accounts for more than 50% of whole leaf area.
Test is investigated 4 times altogether, and before medicine, radix investigation, investigates after 7 days, the 2nd time medicine after the 1st medicine for 7 days and 14 days.
Drug effect computational methods
Poisoning is investigated: whether after dispenser, continuous 7d estimates medicament has poisoning to crop.
Result of the test and analysis
Each group of experimental pharmacy process to the control efficiency of cucumber downy mildew in table 2
The effect of cucumber downy mildew prevented and treated by table 2 respectively process
As can be seen from Table 2, amisulbrom and mancozeb bactericidal composition, with the ratio of 1:3, are tested by different amounts, and complex preparation dosage is lower than single dose dosage, after dispenser, it is all better than contrasting medicament to the preventive effect of cucumber downy mildew, and bactericidal effect increases progressively with the increase of dosage.According to field range estimation, within the scope of test dose, plant growth is normal, and the poisoning phenomenon to cucumber does not all appear in each treatment agent, illustrates that it is safe to cucumber.Prevent at the initial stage of a disease or in advance, preventive effect effect is by even more ideal.Advise that the bactericide different from the mechanism of action is used in combination to delay the drug-fast generation of germ.
Test example 3: the field control effectiveness test of control capsicum epidemic disease
Test method
Test is located at pepper planting district of Hunan Province, and capsicum epidemic disease occurs seriously over the years.Field soil is fertile, and other conditions are moderate.Test dispenser twice altogether, check plot spray equivalent clear water.Continuous dispenser twice, 7 days intervals, sprays application to crop complete stool uniformly by liquid.
Investigation method
Each community random searching 5 point, often some investigation 3 strains, record occurring degree by staging, record diseased plant number, dead strain number or obviously withered plant number.
Stage division (by symptom type classification):
0 grade: healthy without disease;
1 grade: overground part only leaf, fruit has scab;
3 grades: terrestrial stem, branch have brown rot spot;
5 grades: basal part of stem has brown rot spot;
7 grades: terrestrial stem, branch and stem rot all have brown rot spot, and part branch is withered;
9 grades: complete stool is withered.
Test is investigated 4 times altogether, and before medicine, radix investigation, investigates after 7 days, the 2nd time medicine after the 1st medicine for 7 days and 14 days.
Drug effect computational methods
Poisoning is investigated: whether after dispenser, continuous 7d estimates medicament has poisoning to crop.
Result of the test and analysis
Each group of experimental pharmacy process to the control efficiency of capsicum epidemic disease in table 3
The effect of capsicum epidemic disease prevented and treated by table 3 respectively process
As known from Table 3, amisulbrom and mancozeb bactericidal composition are with the ratio of 1:3, test by different amounts, complex preparation dosage is lower than single dose dosage, after dispenser, it is to the effect of the control efficiency of capsicum epidemic disease apparently higher than amisulbrom and mancozeb single dose, and the lasting period is also better, is the desirable medicament preventing and treating epidemic disease, and to capsicum safety, the drug-fast generation of germ effectively can be delayed.
Example of formulations 1: amisulbrom mancozeb wettable powder A
Amisulbrom 20%, mancozeb 20%, sodium lignin sulfonate 6%, lauryl sodium sulfate 2%, white carbon 2%, kaolin supply 100%, above-mentioned each component is mixed in proportion, uniform stirring in stirred tank, namely obtains 40% amisulbrom mancozeb wettable powder A after airslide disintegrating mill is pulverized.
Example of formulations 2: amisulbrom mancozeb wettable powder B
Amisulbrom 10%, mancozeb 40%, polycarboxylate 6%, lauryl sodium sulfate 6%, kaolin supply 100%, above-mentioned each component is mixed in proportion, uniform stirring in stirred tank, namely obtains 50% amisulbrom mancozeb wettable powder B after airslide disintegrating mill is pulverized.
Example of formulations 3: amisulbrom mancozeb wettable powder C
Amisulbrom 15%, mancozeb 60%, lauryl sodium sulfate 2%, sodium lignin sulfonate 5%, naphthalene sulfonate 3%, kaolin supply 100%, above-mentioned each component is mixed in proportion, uniform stirring in stirred tank, namely obtains 75% amisulbrom mancozeb wettable powder C after airslide disintegrating mill is pulverized.
Example of formulations 4: amisulbrom mancozeb suspending agent A
15% lignosulfonates, 5% propane diols, 2% xanthans, 0.6% silicone oil and 57.4% water are mixed, after high speed shear mixes, add 10% amisulbrom and 10% mancozeb, abrading-ball 2 ~ 3 hours in ball crusher, make a diameter all at below 5mm, the aqueous suspension formulations A of obtained 20% amisulbrom and mancozeb bactericidal composition.
Example of formulations 5: amisulbrom mancozeb suspending agent B
10% alkylphenol polyoxyethylene, 4% propane diols, 1% xanthans, 0.5% silicone oil and 44.5% water are mixed, after high speed shear mixes, add 10% amisulbrom and 30% mancozeb, abrading-ball 2 ~ 3 hours in ball crusher, make a diameter all at below 5mm, the aqueous suspension formulations B of obtained 40% amisulbrom and mancozeb bactericidal composition.
Example of formulations 6: amisulbrom mancozeb water dispersible granule
5% amisulbrom, 15% mancozeb, 13% lignosulfonates, 4% lauryl sodium sulfate, 3% ammonium sulfate, 60% diatomite mixes, pulverize with micro jet, through mediating, then add in fluidized-bed granulation dryer and carry out through sample analysis after granulation, drying, screening, the water dispersible granules of obtained 20% amisulbrom and mancozeb bactericidal composition.
In sum, of the present invention with amisulbrom and mancozeb for the composite bactericidal composition preparation of active ingredient, have good control efficiency to cucumber downy mildew and capsicum epidemic disease, and to crop safety.Complex preparation not only increases preventive effect, and has delayed germ to the drug-fast generation of medicament, and reduce peasant drug cost, so this compounded combination tool in production practices is of great significance.

Claims (3)

1. contain a bactericidal composition for amisulbrom and mancozeb, it is characterized in that, the active ingredient of this bactericidal composition is amisulbrom and mancozeb binary built, and all the other are auxiliary element;
Its formulation of described bactericidal composition is any one in wetting powder, suspending agent, water dispersible granules;
When bactericidal composition is wetting powder, the percentage by weight of each component is: amisulbrom 1% ~ 80%, mancozeb 1% ~ 80%, dispersant 1% ~ 20%, wetting agent 1% ~ 10%, filler 1% ~ 70%, by above-mentioned weight proportion, amisulbrom is mixed with mancozeb and dispersant, wetting agent and filler, uniform stirring in stirred tank, mix again after airslide disintegrating mill is pulverized, obtain wetting powder bactericidal composition;
When bactericidal composition is suspending agent, the percentage by weight of each component is: amisulbrom 1% ~ 80%, mancozeb 1% ~ 80%, dispersant 5% ~ 20%, antifreezing agent 1% ~ 5%, thickener 0.1% ~ 2%, defoamer 0.1% ~ 0.8%, surplus is water, the concrete production stage of this suspending agent is: first mixed by above-mentioned proportioning by auxiliary agent, mix through high speed shear, add amisulbrom and mancozeb, abrading-ball 2 ~ 3 hours in ball crusher, make a diameter all at below 5mm, obtain the bactericidal composition of aqueous suspension formulations;
When bactericidal composition is water dispersible granules, the mass percent of component is: amisulbrom 1% ~ 80%, mancozeb 1% ~ 80%, dispersant 3% ~ 20%, wetting agent 3% ~ 10%, disintegrant 1% ~ 5%, filler 1% ~ 70%, the concrete production stage of this water dispersible granules is: amisulbrom, mancozeb and dispersant, wetting agent, disintegrant and filler are mixed, pulverize with micro jet, through mediating, then add in fluidized-bed granulation dryer and carry out granulation, drying, screening, obtain the bactericidal composition of water dispersant;
Wherein, the mass ratio of amisulbrom and mancozeb is 5:1 ~ 1:20.
2. bactericidal composition preparation according to claim 1, is characterized in that:
Described dispersant is: one or more in polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, fatty acid glyceride APEO;
Described wetting agent is: one or more in lauryl sodium sulfate, calcium dodecyl benzene sulfonate, Nekal BX, wetting and penetrating agent F, alkylnaphthalene sulfonate, polyoxyethylene tri-styryl phosphenylic acid salt, spaonin powder, silkworm excrement, soapberry powder;
Described disintegrant is: one or more in bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, sodium bicarbonate;
Described filler is: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate;
Described thickener is: one or more in xanthans, CMC, hydroxyethylcellulose, methylcellulose, Magnesiumaluminumsilicate, polyvinyl alcohol;
Described antifreezing agent is: one or more in ethylene glycol, propane diols, glycerine, polyethylene glycol;
Described defoamer is: silicone oil, silicone compound, C 10-20saturated fat acid compounds, C 8-10one or more in aliphatic alcohols compound.
3. the application of bactericidal composition according to claim 1 in control vegetables, grape, lichee, downy mildew, the epidemic disease such as melon.
CN201410612355.6A 2014-11-04 2014-11-04 Fungicide composition containing amisulborum and mancozeb and application Pending CN104365634A (en)

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CN107372553A (en) * 2016-02-19 2017-11-24 陕西上格之路生物科学有限公司 A kind of bactericidal composition containing amisulbrom
CN108541710A (en) * 2018-03-30 2018-09-18 北京科发伟业农药技术中心 The composition of containing chlorantraniliprole and amisulbrom

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Publication number Priority date Publication date Assignee Title
CN107372553A (en) * 2016-02-19 2017-11-24 陕西上格之路生物科学有限公司 A kind of bactericidal composition containing amisulbrom
CN108541710A (en) * 2018-03-30 2018-09-18 北京科发伟业农药技术中心 The composition of containing chlorantraniliprole and amisulbrom

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