CN102992889B - Modified water-soluble nanoscale silica sol-containing mulberry fertilizer and preparation method thereof - Google Patents

Modified water-soluble nanoscale silica sol-containing mulberry fertilizer and preparation method thereof Download PDF

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CN102992889B
CN102992889B CN201210452364.4A CN201210452364A CN102992889B CN 102992889 B CN102992889 B CN 102992889B CN 201210452364 A CN201210452364 A CN 201210452364A CN 102992889 B CN102992889 B CN 102992889B
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fertilizer
colloidal sol
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CN102992889A (en
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赵启华
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Qidong Qixiu Vegetable & Fruit professional cooperatives
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FEIXI JINNIU SILKWORM AND MULBERRY SPECIALIZED FARMER COOPERATIVES
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Abstract

The invention discloses a modified water-soluble nanoscale silica sol-containing mulberry fertilizer and a preparation method thereof. The fertilizer is prepared the following raw materials in parts by weight: 28-32 parts of mushroom wastes, 20-25 parts of grass carbon, 18-22 parts of cake bran, 2-4 parts of zinc sulfate, 0.3-0.6 parts of boric acid, 0.7-0.9 parts of ammonium bicarbonate, 1.3-1.5 parts of magnesium sulfate, 2-4 parts of humic acid, 1-2 parts of trace element fertilizer, 3-5 parts of modified water-soluble nanoscale silica sol, 5-7 parts of light calcium carbonate, 2-4 parts of wollastonite in powder, 1-3 parts of fatty alcohol-polyoxyethylene ether sulfate, 0.8-1.2 parts of calcium lignosulfonate, 2-3 parts of chitosan acetic acid solution, 1-3 parts of pyroligneous liquor, 4-6 parts of cinnamon oil, 1-3 parts of wintergreen oil and 0.9-1.1 parts of carboxymethyl cellulose. The fertilizer takes the mushroom wastes, the grass carbon and the cake bran as main raw materials, mulberries have developed root systems, grow vigorously, are easy to plant, are easy to manage and have long economic lives, and the water and soil loss are reduced; and moreover, the modified water-soluble nanoscale silica sol, the light calcium carbonate and the wollastonite in powder are added into the raw materials as packing materials, an adsorption structure is increased, meanwhile, caking is prevented, and the dispersing performance of the fertilizer is increased.

Description

A kind of Mulberry fertilizer that contains modified soluble nano silicone colloidal sol and preparation method thereof
Technical field
The present invention relates to the required fertilizer of a plant growth, be specifically related to a kind of Mulberry fertilizer that contains modified soluble nano silicone colloidal sol and preparation method thereof.
Background technology
Silkworm and mulberry are traditional rural industries of China, are divided into two large classes, the one, plant mulberry, and the 2nd, breed silkworms.The mulberry leaf that mulberry tree produces number and quality, the quality and quantity that directly impact is bred silkworms.In traditional managing of mulberry field, do not apply fertilizer or execute farm manure and a small amount of simple substance fertilizer, the mulberry leaf of mulberry tree output are in output and all can not meet qualitatively the needs of supporting mulberry, become one of important factor of restriction sericulture there development.Research shows, nitrogen is too much, and mulberry leaf are soft, are generally bad mulberry; When phosphorus, potassium deficiency, this tendency is more obvious; Once phosphorus lacks, the nitrogen component in mulberry leaf and sugar degree are obviously influenced, especially make free smart nitronic acid abnormal accumulation, after silkworm is edible, there will be death; If potassium lacks, photosynthesis is suppressed, the resistivity of disease is weakened, but the excessive balance that easily causes Mg/K in mulberry leaf easily causes magnesium deficiency symptom, therefore, will supplement in right amount the content of nitrogen, phosphorus, potassium, improves the quality and quantity of mulberry leaf.
Summary of the invention
The object of the present invention is to provide a kind of Mulberry fertilizer that contains modified soluble nano silicone colloidal sol and preparation method thereof, it is main raw material that fertilizer of the present invention be take mushroom class waste, the peat composed of rotten mosses and grouts, mulberry tree well developed root system, grow vigorous, easily plant, manageability and the economical life long, reduced soil erosion, improved improvement of the ecological environment quality, in raw material of the present invention, modified soluble nano silicone colloidal sol, light calcium carbonate and wollastonite powder have been added as stopping composition simultaneously, increased adsorption structure, anti-caking, increases its dispersiveness simultaneously; The effective release, the crop that are conducive to fertilizer efficiency fully absorb.
The present invention adopts following technical scheme to achieve these goals:
The Mulberry fertilizer that contains modified soluble nano silicone colloidal sol, the weight part of its constitutive material is: mushroom class waste 28-32, peat composed of rotten mosses 20-25, grouts 18-22, zinc sulfate 2-4, boric acid 0.3-0.6, bicarbonate of ammonia 0.7-0.9, sal epsom 1.3-1.5, humic acid 2-4, trace element fertilizer 1-2, modified soluble nano silicone colloidal sol 3-5, light calcium carbonate 5-7, wollastonite powder 2-4, fatty alcohol polyoxyethylene ether sulfate 1-3, calcium lignin sulphonate 0.8-1.2, chitosan-acetic acid solution 2-3, wood vinegar 1-3, Oleum Cinnamomi 4-6, wintergreen oil 1-3 and carboxymethyl cellulose 0.9-1.1.
The Mulberry fertilizer that contains modified soluble nano silicone colloidal sol, the weight part of its constitutive material is: mushroom class waste 28-32, peat composed of rotten mosses 20-25, grouts 18-22, zinc sulfate 2-4, boric acid 0.3-0.6, bicarbonate of ammonia 0.7-0.9, sal epsom 1.3-1.5, humic acid 2-4, trace element fertilizer 1-2, modified soluble nano silicone colloidal sol 3-5, light calcium carbonate 5-7, wollastonite powder 2-4, fatty alcohol polyoxyethylene ether sulfate 1-3, calcium lignin sulphonate 0.8-1.2, chitosan-acetic acid solution 2-3, wood vinegar 1-3, Oleum Cinnamomi 4-6, wintergreen oil 1-3 and carboxymethyl cellulose 0.9-1.1.
The preparation method of the Mulberry fertilizer that contains modified soluble nano silicone colloidal sol, comprises the following steps:
(1) by the weight part of constitutive material, take each raw material, mushroom class waste, the peat composed of rotten mosses, grouts, modified soluble nano silicone colloidal sol, light calcium carbonate and wollastonite powder are added in stirrer, it is fully mixed;
(2) in step (1), by the weight part of constitutive material, add zinc sulfate, boric acid, bicarbonate of ammonia, sal epsom, humic acid, trace element fertilizer, fatty alcohol polyoxyethylene ether sulfate, calcium lignin sulphonate and chitosan-acetic acid solution, mix, regulate the water content 37-45% of compound, with wood vinegar, regulate PH to 5.7-6.4;
(3) compound in step (2) is carried out to just fermentation, fermentation 3-5 days, leavening temperature is controlled at 55-65 ℃;
(4) whipping step (3) solution, then carries out Secondary Fermentation, fermentation 9-11 days, and leavening temperature is controlled at 63-68 ℃;
(5) by the weight part of constitutive material, Oleum Cinnamomi, wintergreen oil and carboxymethyl cellulose are mixed, then carry out the fermented product coating of step (4) and process, last granulation obtains Mulberry fertilizer.
The preparation method of described modified soluble nano silicone colloidal sol, for to add 4-5% nano-carbon powder, 3-5% ferric oxide in water-soluble nano grade silica sol, is mixed and heated to 70-80 ℃, cooling obtaining after 30-40 minute.
Beneficial effect of the present invention:
It is main raw material that fertilizer of the present invention be take mushroom class waste, the peat composed of rotten mosses and grouts, mulberry tree well developed root system, grow vigorous, easily plant, manageability and the economical life long, reduced soil erosion, improved improvement of the ecological environment quality, in raw material of the present invention, modified soluble nano silicone colloidal sol, light calcium carbonate and wollastonite powder have been added as stopping composition simultaneously, increased adsorption structure, anti-caking, increases its dispersiveness simultaneously; The effective release, the crop that are conducive to fertilizer efficiency fully absorb.
Embodiment
Embodiment 1: the Mulberry fertilizer that contains modified soluble nano silicone colloidal sol, the weight part of its constitutive material is: mushroom class waste 28-32, peat composed of rotten mosses 20-25, grouts 18-22, zinc sulfate 2-4, boric acid 0.3-0.6, bicarbonate of ammonia 0.7-0.9, sal epsom 1.3-1.5, humic acid 2-4, trace element fertilizer 1-2, modified soluble nano silicone colloidal sol 3-5, light calcium carbonate 5-7, wollastonite powder 2-4, fatty alcohol polyoxyethylene ether sulfate 1-3, calcium lignin sulphonate 0.8-1.2, chitosan-acetic acid solution 2-3, wood vinegar 1-3, Oleum Cinnamomi 4-6, wintergreen oil 1-3 and carboxymethyl cellulose 0.9-1.1.
The preparation method of the Mulberry fertilizer that contains modified soluble nano silicone colloidal sol, comprises the following steps:
(1) by the weight part of constitutive material, take each raw material, mushroom class waste, the peat composed of rotten mosses, grouts, modified soluble nano silicone colloidal sol, light calcium carbonate and wollastonite powder are added in stirrer, it is fully mixed;
(2) in step (1), by the weight part of constitutive material, add zinc sulfate, boric acid, bicarbonate of ammonia, sal epsom, humic acid, trace element fertilizer, fatty alcohol polyoxyethylene ether sulfate, calcium lignin sulphonate and chitosan-acetic acid solution, mix, regulate the water content 37-45% of compound, with wood vinegar, regulate PH to 5.7-6.4;
(3) compound in step (2) is carried out to just fermentation, fermentation 3-5 days, leavening temperature is controlled at 55-65 ℃;
(4) whipping step (3) solution, then carries out Secondary Fermentation, fermentation 9-11 days, and leavening temperature is controlled at 63-68 ℃;
(5) by the weight part of constitutive material, Oleum Cinnamomi, wintergreen oil and carboxymethyl cellulose are mixed, then carry out the fermented product coating of step (4) and process, last granulation obtains Mulberry fertilizer.
The preparation method of described modified soluble nano silicone colloidal sol, for to add 4-5% nano-carbon powder, 3-5% ferric oxide in water-soluble nano grade silica sol, is mixed and heated to 70-80 ℃, cooling obtaining after 30-40 minute.
Use the fertilizer efficiency of the above-mentioned Mulberry fertilizer making to use result:
Figure BDA0000239424571

Claims (3)

1. a Mulberry fertilizer that contains modified soluble nano silicone colloidal sol, the weight part that it is characterized in that its constitutive material is: mushroom class waste 28-32, peat composed of rotten mosses 20-25, grouts 18-22, zinc sulfate 2-4, boric acid 0.3-0.6, bicarbonate of ammonia 0.7-0.9, sal epsom 1.3-1.5, humic acid 2-4, trace element fertilizer 1-2, modified soluble nano silicone colloidal sol 3-5, light calcium carbonate 5-7, wollastonite powder 2-4, fatty alcohol polyoxyethylene ether sulfate 1-3, calcium lignin sulphonate 0.8-1.2, chitosan-acetic acid solution 2-3, wood vinegar 1-3, Oleum Cinnamomi 4-6, wintergreen oil 1-3 and carboxymethyl cellulose 0.9-1.1, the preparation method of described modified soluble nano silicone colloidal sol, for to add 4-5% nano-carbon powder, 3-5% ferric oxide in water-soluble nano grade silica sol, is mixed and heated to 70-80 ℃, cooling obtaining after 30-40 minute.
2. the Mulberry fertilizer that contains modified soluble nano silicone colloidal sol according to claim 1, the weight part that it is characterized in that its constitutive material is: mushroom class waste 28-32, peat composed of rotten mosses 20-25, grouts 18-22, zinc sulfate 2-4, boric acid 0.3-0.6, bicarbonate of ammonia 0.7-0.9, sal epsom 1.3-1.5, humic acid 2-4, trace element fertilizer 1-2, modified soluble nano silicone colloidal sol 3-5, light calcium carbonate 5-7, wollastonite powder 2-4, fatty alcohol polyoxyethylene ether sulfate 1-3, calcium lignin sulphonate 0.8-1.2, chitosan-acetic acid solution 2-3, wood vinegar 1-3, Oleum Cinnamomi 4-6, wintergreen oil 1-3 and carboxymethyl cellulose 0.9-1.1.
3. a preparation method for the Mulberry fertilizer that contains modified soluble nano silicone colloidal sol as claimed in claim 1, is characterized in that comprising the following steps:
(1) by the weight part of constitutive material, take each raw material, mushroom class waste, the peat composed of rotten mosses, grouts, modified soluble nano silicone colloidal sol, light calcium carbonate and wollastonite powder are added in stirrer, it is fully mixed;
(2) in step (1), by the weight part of constitutive material, add zinc sulfate, boric acid, bicarbonate of ammonia, sal epsom, humic acid, trace element fertilizer, fatty alcohol polyoxyethylene ether sulfate, calcium lignin sulphonate and chitosan-acetic acid solution, mix, regulate the water content 37-45% of compound, with wood vinegar, regulate pH to 5.7-6.4;
(3) compound in step (2) is carried out to just fermentation, fermentation 3-5 days, leavening temperature is controlled at 55-65 ℃;
(4) whipping step (3) solution, then carries out Secondary Fermentation, fermentation 9-11 days, and leavening temperature is controlled at 63-68 ℃;
(5) by the weight part of constitutive material, Oleum Cinnamomi, wintergreen oil and carboxymethyl cellulose are mixed, then carry out the fermented product coating of step (4) and process, last granulation obtains Mulberry fertilizer.
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CN103755451A (en) * 2013-12-20 2014-04-30 当涂县科辉商贸有限公司 Microbial organic compound fertilizer and preparation method thereof
CN104098387A (en) * 2014-06-12 2014-10-15 阜阳市颍泉区涌泉种植专业合作社 Green and environment-friendly coated compound fertilizer and preparation method thereof
CN104072321B (en) * 2014-07-11 2016-08-17 河北民族师范学院 A kind of soil conditioner and preparation method thereof
CN104823655A (en) * 2015-04-22 2015-08-12 广德县菁菁果业专业合作社 Cultivation method of mulberries
CN106187514A (en) * 2016-07-20 2016-12-07 安徽三星化工有限责任公司 A kind of lignin particles fertilizer
CN108675897B (en) * 2018-07-05 2021-09-17 沈阳美华农业有限公司 Nano carbon sol, preparation method thereof and organic-inorganic mixed fertilizer

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GB741378A (en) * 1952-03-17 1955-11-30 Hans Adalbert Schweigart Compositions enhancing plant growth, and processes for their production
JPS60231479A (en) * 1984-04-28 1985-11-18 住金化工株式会社 Large grain ammonium sulfate and treatment
JP2849466B2 (en) * 1990-11-05 1999-01-20 旭化成工業株式会社 Granular coated agricultural material
CN1033507C (en) * 1993-01-07 1996-12-11 南京农业大学 Fertilizer applying onto leaves and its preparation method
CN1098081A (en) * 1993-07-25 1995-02-01 徐周良 Potentiated compound fertilizer for mulberry
CN1147492A (en) * 1995-10-09 1997-04-16 四川省农业科学院蚕桑研究所 Special organic composite fertilizer for mulberry
CN1351980A (en) * 2000-11-13 2002-06-05 张德昌 High efficiency organic compound fertilizer
CN101343201A (en) * 2008-06-27 2009-01-14 贺州学院 Foliage fertilizer for white mulberry and preparation thereof
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Patentee after: Qidong Qixiu Vegetable & Fruit professional cooperatives

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Patentee before: Feixi Jinniu Silkworm and Mulberry Specialized Farmer Cooperatives

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