CN106187514A - A kind of lignin particles fertilizer - Google Patents
A kind of lignin particles fertilizer Download PDFInfo
- Publication number
- CN106187514A CN106187514A CN201610572506.9A CN201610572506A CN106187514A CN 106187514 A CN106187514 A CN 106187514A CN 201610572506 A CN201610572506 A CN 201610572506A CN 106187514 A CN106187514 A CN 106187514A
- Authority
- CN
- China
- Prior art keywords
- fertilizer
- compost
- coarse granule
- fermentation
- standby
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F17/00—Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
- C05F17/50—Treatments combining two or more different biological or biochemical treatments, e.g. anaerobic and aerobic treatment or vermicomposting and aerobic treatment
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
Abstract
The invention discloses a kind of lignin particles fertilizer, be prepared by the raw materials in: oil foot 23 26, broad-leaved wood flour 32 34, Buckwheat shell 14 16, calcium lignosulfonate 57, Oleum Glycines 4.3 4.7, xylose powder 3.5 3.8, Pulvis Talci 34, MAP 8 10, compost coarse granule 25 26, sunflower straw 37 39, dodecyldimethylammonium hydroxide inner salt 1.6 1.8, POLYSORBATE 80 1.2 1.3, bentonite 18 20, water are appropriate;The fertilizer of the present invention is according to the slower characteristic of the biodegradation rate of lignin, in conjunction with straw biomass charcoal and broad-leaved wood flour, the addition of calcium lignosulfonate, achieve the nutrient slowly-released effect of fertilizer, by the slow degraded of fertilizer, both the form easily absorbed with plant releases macronutrient, turn avoid and use the excessive element pollution problem that common fertilizer occurs, all have in terms of fertilizer efficiency and environmental protection and preferably apply effect.
Description
Technical field
The present invention relates to technical field of fertilizers, particularly relate to a kind of lignin particles fertilizer.
Background technology
Along with the level of modernization of agricultural is more and more higher, fertilizer the most gradually replaces common chemical fertilizer, becomes in agricultural production
Important fertilizer, fertilizer has the multiple advantages such as nutrition complete, improvement soil, raising utilization rate of fertilizer.But it is presently commercially available
Fertilizer suffers from many defects, and one is easily to produce a large amount of greenhouse gases in preparation process, and is discharged into air without control
In, cause air pollution;Two is to meet the demand that soil pollution is repaired, and simple soil structure improved addictive cannot realize polluting
The raising of soil crop quality;Three is that nutrient supply is slow, though longer than common fertilizer efficiency, but be difficult to meet plant vigorous growth
Time demand to nutrient;Four is that fertilizer volume is big, transports and stores inconvenience;Five be for special soil environment such as soda acid, drought wet,
Soil that Partial Elements lacks and the nutrient demand of concrete crop without effectively for.
On the sieve of matured compost, coarse granule quality is soft, short texture, has stronger absorbability, in change of moisture content relatively
Remain to keep the gas diffusion of certain porosity, beneficially cover layer time big, contain simultaneously a large amount of microorganism such as methane-oxidizing bacteria,
Nitrobacterias etc., therefore, the discharge utilizing the upper coarse granule of matured compost sieve to reduce Composting Process greenhouse gases simply and is prone to
Realize.
Use dodecyldimethylammonium hydroxide inner salt and POLYSORBATE 80 that fertiliser granulates is modified, can obtain simultaneously there is alkyl
The fertiliser granulates of hydrophobic carbochain and respectively band positive and negative charge hydrophilic group structure, in the premise retaining heavy metal absorption property
Under, further increasing the absorbability to organic pollution, the preparation for fertilizer opens new approach.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of lignin particles fertilizer.
The present invention is achieved by the following technical solutions:
A kind of lignin particles fertilizer, is prepared by the raw materials in: oil foot 23-26, broad-leaved wood flour 32-34, Semen Fagopyri Esculenti
Shell 14-16, calcium lignosulfonate 5-7, Oleum Glycines 4.3-4.7, xylose powder 3.5-3.8, Pulvis Talci 3-4, MAP 8-10, compost
Coarse granule 25-26, sunflower straw 37-39, dodecyldimethylammonium hydroxide inner salt 1.6-1.8, POLYSORBATE 80 1.2-1.3, bentonite
18-20, water are appropriate.
Described compost coarse granule is through screening after compost maturity, as on the particle diameter of the offal treatment sieve more than 10mm
Coarse granule.
Specifically comprising the following steps that of the preparation method of described lignin particles fertilizer
(1) oil foot, broad-leaved wood flour, Buckwheat shell mixing are placed in fermentation vat and carry out compost fermentation, and by equal for compost coarse granule
The even compost surface that is laid in, keeps fermentation heap water content at 60-65%, adds calcium lignosulfonate, bean after fermenting 18-20 days
Oil, xylose powder, then carry out turning, is mixed homogeneously with lower floor fermentation material by upper strata coarse granule, continues to ferment 20-24 days, period
Carry out 2-3 turning again, obtain fermentation material standby;
(2) clean for sunflower straw drip washing post-drying is pulverized, be placed in high temperature furnace, under anaerobic with 15-20 DEG C every point
Speed be warming up to 600 DEG C, and at this temperature insulation 100-120 minute, take out after being cooled to room temperature biomass carbon is standby;
(3) bentonite is put in high temperature furnace, rise to 380-400 DEG C with the speed of 30 DEG C every point, come out of the stove after calcining 2 hours cold
But, levigate 80-100 mesh sieve the most excessively is standby;
(4) with 10 times of quality water mixings after step 2 gained biomass carbon and step 3 gained bentonite powder being mixed, and heat up
To 40-42 DEG C, it is being stirred continuously lower addition dodecyldimethylammonium hydroxide inner salt, is filtering after being incubated 3-4 hour and remove solution, natural
Add 10-12 times of quality water after Feng Ganing, add POLYSORBATE 80 after mix homogeneously, aqueous solution is heated to 46-48 DEG C, constantly
Stir and be incubated 90-120 minute, be filtered to remove solution afterwards, by mixture dry for standby at 60-65 DEG C;
(5) by step 1 gained fermentation material dry after pulverize, and with step 4 gained mixture, Pulvis Talci, MAP and its
Remaining leftover materials mixing granulation, obtains fertilizer of the present invention.
The invention have the advantage that
Preparation process use compost coarse granule cover in advance, the compost fermentation mode of later stage mixing, compost can not only be improved
Physical arrangement, improves composting production rotten degree, utilizes its open structure and stronger adsorptivity simultaneously, reduce earlier fermentation ammonia with
And the discharge of the gas such as later stage methane, decrease the nitrogen loss of fermentation while protecting environment, improve fertilizer fertility.
Preparation process utilize the dodecyldimethylammonium hydroxide inner salt of easily biological-degradable and POLYSORBATE 80 to charcoal-bentonite
Composite interstitial substance is modified, and can not only improve the cation exchange capacity (CEC) of soil, has outstanding organic pollution and a huge sum of money simultaneously
Belong to the dual absorbability of pollutant, improve the safety of soil plantation, add the surcharge of fertilizer.
The fertilizer of the present invention is according to the slower characteristic of the biodegradation rate of lignin, in conjunction with straw biomass charcoal with wealthy
Leaf wood flour, the addition of calcium lignosulfonate, it is achieved that the nutrient slowly-released effect of fertilizer, by the slow degraded of fertilizer, both to plant
The form that thing easily absorbs releases macronutrient, turn avoid and uses the excessive element pollution problem that common fertilizer occurs,
All have in terms of fertilizer efficiency and environmental protection and preferably apply effect.
Detailed description of the invention
A kind of lignin particles fertilizer, is made up of the raw material of following weight portion (kg): oil foot 23, broad-leaved wood flour 32, buckwheat
Wheat husk 14, calcium lignosulfonate 5, Oleum Glycines 4.3, xylose powder 3.5, Pulvis Talci 3, MAP 8, compost coarse granule 25, Helianthi
Straw 37, dodecyldimethylammonium hydroxide inner salt 1.6, POLYSORBATE 80 1.2, bentonite 18, water are appropriate.
Described compost coarse granule is through screening after compost maturity, as on the particle diameter of the offal treatment sieve more than 10mm
Coarse granule.
Specifically comprising the following steps that of the preparation method of described lignin particles fertilizer
(1) oil foot, broad-leaved wood flour, Buckwheat shell mixing are placed in fermentation vat and carry out compost fermentation, and by equal for compost coarse granule
The even compost surface that is laid in, keeps fermentation heap water content 60%, adds calcium lignosulfonate, Oleum Glycines, xylose after fermenting 18 days
Powder, then carries out turning, is mixed homogeneously with lower floor fermentation material by upper strata coarse granule, continues fermentation 20 days, and period carries out 2 times turning over again
Heap, obtains fermentation material standby;
(2) clean for sunflower straw drip washing post-drying is pulverized, be placed in high temperature furnace, under anaerobic with the speed of 15 DEG C every point
Degree be warming up to 600 DEG C, and at this temperature insulation 100 minutes, take out after being cooled to room temperature biomass carbon is standby;
(3) bentonite is put in high temperature furnace, rise to 380 DEG C with the speed of 30 DEG C every point, cooling of coming out of the stove after calcining 2 hours, mill
80 mesh sieves are crossed standby after thin;
(4) with 10 times of quality water mixings after step 2 gained biomass carbon and step 3 gained bentonite powder being mixed, and heat up
To 40 DEG C, it is being stirred continuously lower addition dodecyldimethylammonium hydroxide inner salt, is filtering after being incubated 3 hours and remove solution, natural air drying
After add 10 times of quality water, after mix homogeneously add POLYSORBATE 80, aqueous solution is heated to 46 DEG C, is stirred continuously and is incubated
90 minutes, it is filtered to remove solution afterwards, by mixture dry for standby at 60 DEG C;
(5) by step 1 gained fermentation material dry after pulverize, and with step 4 gained mixture, Pulvis Talci, MAP and its
Remaining leftover materials mixing granulation, obtains fertilizer of the present invention.
In order to further illustrate the using value of the present invention, inventor chooses one piece of experimental plot, is come by the plantation of Oryza sativa L.
Verifying the concrete effect of fertilizer of the present invention, wherein 10 mu of ground use fertilizer of the present invention as experimental group, and another 10 mu of ground use common
As a control group, control measures are identical for commercially available fertilizer, found that experimental group paddy growth is especially the most healthy and strong in the later stage, and per mu yield
Measuring relatively matched group and improve 8%, disease resistance improves simultaneously, and Oryza sativa L. common disease and pest incidence rate relatively matched group substantially reduces.
Claims (3)
1. a lignin particles fertilizer, it is characterised in that be prepared by the raw materials in: oil foot 23-26, leaf wood
Bits 32-34, Buckwheat shell 14-16, calcium lignosulfonate 5-7, Oleum Glycines 4.3-4.7, xylose powder 3.5-3.8, Pulvis Talci 3-4, phosphoric acid
One ammonium 8-10, compost coarse granule 25-26, sunflower straw 37-39, dodecyldimethylammonium hydroxide inner salt 1.6-1.8, POLYSORBATE 80
1.2-1.3, bentonite 18-20, water are appropriate.
2. it is through screening after compost maturity according to the compost coarse granule described in claims 1, as the particle diameter of offal treatment
More than coarse granule on the sieve of 10mm.
3. according to the lignin particles fertilizer described in claims 1, it is characterised in that the concrete steps of preparation method are such as
Under:
(1) oil foot, broad-leaved wood flour, Buckwheat shell mixing are placed in fermentation vat and carry out compost fermentation, and by equal for compost coarse granule
The even compost surface that is laid in, keeps fermentation heap water content at 60-65%, adds calcium lignosulfonate, bean after fermenting 18-20 days
Oil, xylose powder, then carry out turning, is mixed homogeneously with lower floor fermentation material by upper strata coarse granule, continues to ferment 20-24 days, period
Carry out 2-3 turning again, obtain fermentation material standby;
(2) clean for sunflower straw drip washing post-drying is pulverized, be placed in high temperature furnace, under anaerobic with 15-20 DEG C every point
Speed be warming up to 600 DEG C, and at this temperature insulation 100-120 minute, take out after being cooled to room temperature biomass carbon is standby;
(3) bentonite is put in high temperature furnace, rise to 380-400 DEG C with the speed of 30 DEG C every point, come out of the stove after calcining 2 hours cold
But, levigate 80-100 mesh sieve the most excessively is standby;
(4) with 10 times of quality water mixings after step 2 gained biomass carbon and step 3 gained bentonite powder being mixed, and heat up
To 40-42 DEG C, it is being stirred continuously lower addition dodecyldimethylammonium hydroxide inner salt, is filtering after being incubated 3-4 hour and remove solution, natural
Add 10-12 times of quality water after Feng Ganing, add POLYSORBATE 80 after mix homogeneously, aqueous solution is heated to 46-48 DEG C, constantly
Stir and be incubated 90-120 minute, be filtered to remove solution afterwards, by mixture dry for standby at 60-65 DEG C;
(5) by step 1 gained fermentation material dry after pulverize, and with step 4 gained mixture, Pulvis Talci, MAP and its
Remaining leftover materials mixing granulation, obtains fertilizer of the present invention.
Priority Applications (1)
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CN201610572506.9A CN106187514A (en) | 2016-07-20 | 2016-07-20 | A kind of lignin particles fertilizer |
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CN201610572506.9A CN106187514A (en) | 2016-07-20 | 2016-07-20 | A kind of lignin particles fertilizer |
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CN106187514A true CN106187514A (en) | 2016-12-07 |
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ID=57494199
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CN201610572506.9A Pending CN106187514A (en) | 2016-07-20 | 2016-07-20 | A kind of lignin particles fertilizer |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106883025A (en) * | 2017-03-13 | 2017-06-23 | 安徽省卫国农业科技有限公司 | A kind of biologic grain organic fertilizer |
CN107333636A (en) * | 2017-02-03 | 2017-11-10 | 安徽帝元现代农业投资发展有限公司 | A kind of straw biomass charcoal cultivation matrix with highly-breathable energy |
CN109984151A (en) * | 2017-12-30 | 2019-07-09 | 李爱伏 | A kind of processing method of the micro- fertilizer of calcium lignosulfonate base green bio pesticide |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107333636A (en) * | 2017-02-03 | 2017-11-10 | 安徽帝元现代农业投资发展有限公司 | A kind of straw biomass charcoal cultivation matrix with highly-breathable energy |
CN106883025A (en) * | 2017-03-13 | 2017-06-23 | 安徽省卫国农业科技有限公司 | A kind of biologic grain organic fertilizer |
CN109984151A (en) * | 2017-12-30 | 2019-07-09 | 李爱伏 | A kind of processing method of the micro- fertilizer of calcium lignosulfonate base green bio pesticide |
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Application publication date: 20161207 |