CN105948997A - Biomass organic fertilizer capable of increasing PH of acid soil - Google Patents
Biomass organic fertilizer capable of increasing PH of acid soil Download PDFInfo
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- CN105948997A CN105948997A CN201610324711.3A CN201610324711A CN105948997A CN 105948997 A CN105948997 A CN 105948997A CN 201610324711 A CN201610324711 A CN 201610324711A CN 105948997 A CN105948997 A CN 105948997A
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- organic fertilizer
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C3/00—Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor
Abstract
The invention discloses a biomass organic fertilizer capable of increasing PH of acid soil. The biomass organic fertilizer is prepared from raw materials in parts by weight as follows: 6-8 parts of seaweed meal, 2-3 parts of calcium sulfate, 2-3 parts of sodium lignin sulfonate, 28-32 parts of saw dust, 3-5 parts of monoammonium carbonate, 73-77 parts of crop straw, 15-16 parts of plant ash, 6-8 parts of attapulgite powder, 4-5 parts of lentinan, 3-4 parts of sodium nitrate, 53-57 parts of elodea nuttallii, 2-4 parts of a cellulase preparation, 3-4 parts of a protease preparation, 9-10 parts of Tamarindus indica Linn. and a proper amount of water. The biomass organic fertilizer adopts various alkaline raw materials and can reduce the content of exchangeable Al<3+> and H<+> of soil and increase the pH value of surface soil through adsorption of charcoal and activity of organic matters, so that the soil can be suitable for planting of plants, the fertility preservation potential of the soil can be improved with the aid of various nutrient materials, the fertility maintenance performance of the soil is improved, the soil is suitable for growth of plants, and the yield is increased.
Description
Technical field
The present invention relates to organic fertilizer technical field, particularly relate to a kind of biomass organic fertilizer improving acid ground PH.
Background technology
Along with the specialization of China's agricultural production, industrialization, the development of scale; agricultural is constantly upgraded for the requirement of fertilizer, soil fertility; and a large amount of uses of tradition inorganic fertilizer cause soil physico-chemical property to deteriorate; the yield of agricultural product, quality and resistance decline, and constrain the sustainable development of agricultural planting.Manure use is selected to improve planting conditions for problem above many agricultural plantings family, but the committed step in fertilizer preparation process is the decomposition to the cellulose substances that difficulty is decomposed, in the structure of straw, cellulose is the important composition composition of stalk cell wall, play support and the major function of fixing plant, it is difficult to, by biological decomposition, hinder release and the mineralising of cellular content.
For this, using enzyme that Plant fiber carries out degraded is a kind of preferably method, but free enzyme is not sufficiently stable under the conditions of high temperature, strong acid, highly basic, high ion concentration etc., easily inactivates and reduce its catalytic capability, cause the considerable restraint in application.
To this end, the method that the present inventor provides the immobilized enzyme of a kind of biomass carbon, to improve the stability of enzyme and anti-inhibition, and should not plant for acid ground, the feature yielded poorly, it is provided that a kind of biomass organic fertilizer improving acid ground PH, in order to promote the development of agricultural planting industry.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of biomass organic fertilizer improving acid ground PH.
The present invention is achieved by the following technical solutions:
A kind of biomass organic fertilizer improving acid ground PH, is prepared by the raw materials in: Sargassum powder 6-8, calcium sulfate 2-3, sodium lignin sulfonate 2-3, sawdust 28-32, carbonic acid one ammonium 3-5, agricultural crop straw 73-77, plant ash 15-16, attapulgite 6-8, lentinan 4-5, sodium nitrate 3-4, waterweed 53-57, cellulase preparation 2-4, protease preparation 3-4, tamarind fruit 9-10, water are appropriate.
Specifically comprising the following steps that of the preparation method of described biomass organic fertilizer
(1) filter after tamarind fruit squeezing juice, filtrate and calcium sulfate, sodium lignin sulfonate are mixed and heated to 74-76 DEG C, stir 20 minutes post-dryings, obtain powder standby;
(2) waterweed drying is placed in sealing high temperature furnace, it is warming up to 450 DEG C with the speed of 5-7 DEG C/minute, continues heating and thermal insulation 2-3 hour after reaching final temperature, take out after cooling, by gained charcoal grinding and sieving, take particle diameter standby at the granule of 0.15-0.25mm;
(3) charcoal and water are soaked 18-24 hour after 1:9 mixes in mass ratio, continue after centrifugal segregation supernatant to repeat to soak, to supernatant colourless after by gained charcoal dry for standby at 50-55 DEG C;
(4) by the potassium permanganate solution of step 3 gained charcoal with 0.2mol/L after 1:12 mixes in mass ratio, use frequency is 30-40kHz, power is that ultrasonic echography 90-120 minute of 15W is with mixing, heating be evaporated after in putting into high temperature furnace at 500-550 DEG C Non-oxygen pyrolytic 30-40 minute, the biological carbon materials having obtained Mn oxide immobilized, standby;
(5) in step 4 gained biological carbon materials, 5-6 times of quality water is added, add cellulase preparation and protease preparation, regulation liquid PH is 5.0-5.5, impregnate 7 hours after being slowly stirred at a room temperature 10-20 minute, filter and dry at 50-52 DEG C, obtain the charcoal composite that exogenous enzyme is fixing;
(6) by step 1 gained tamarind marc and agricultural crop straw, Sargassum powder, plant ash, the sawdust laggard row compost fermentation of mixing, after 20 days, compost temperature reduces, add attapulgite, lentinan and step 5 gained charcoal composite, continue fermentation 12-15 days;
(7) pulverize after step 6 gained fermentation material being dried under 45-50 DEG C of low temperature, and mix with carbonic acid one ammonium, sodium nitrate, step 1 gained powder and other leftover materials and be placed in comminutor granulation, obtain biomass fertilizers of the present invention.
The invention have the advantage that
The by-product attachments such as inorganic salt that waterweed gained charcoal surface after pyrolysis can produce during being pyrolyzed, vinegar liquid, tar, therefore use and mix the centrifugal eluting of immersion with water to remove impurity, both improve the absorption property of charcoal, the secondary pollution that impurity causes after entering soil can have been prevented again.
Mn oxide is immobilized on charcoal being greatly improved the adsorption effect of its heavy metal, strengthens the fertiliser granulates restraining forces to heavy metal pollution of soil, improve Soil Safety.
Cellulase and proteinase synergy effect is used to carry out degradable fermented to compost, the degraded of stalk cellulose is promoted by cellulase, destroy the framing structure of stalk cell wall, again by the crude protein on proteases for decomposing stalk cell wall, cell wall is formed passage and improves nitrogen content, final decomposing and fermenting material completely, significantly improves the nutrient content of fertiliser granulates.
The biomass fertilizer of the present invention uses multiple basic materials, coordinates absorption and the activity of organic matter of charcoal, can reduce soil exchangeable Al3+、H+Content, improves the pH value of topsoil soils, makes it suitable for the plantation of plant, then improves the fertile potentiality of soil storage under the auxiliary of multiple nutrient material, strengthens the fertilizer conservation performance of soil, and then the growth of suitable for crop, improve yield.
Detailed description of the invention
A kind of biomass organic fertilizer improving acid ground PH, is made up of the raw material of following weight portion (kg): Sargassum powder 6, calcium sulfate 2, sodium lignin sulfonate 2, sawdust 28, carbonic acid one ammonium 3, agricultural crop straw 73, plant ash 15, attapulgite 6, lentinan 4, sodium nitrate 3, waterweed 53, cellulase preparation 2, protease preparation 3, tamarind fruit 9, water appropriate.
Specifically comprising the following steps that of the preparation method of described biomass organic fertilizer
(1) filter after tamarind fruit squeezing juice, filtrate and calcium sulfate, sodium lignin sulfonate are mixed and heated to 74 DEG C, stir 20 minutes post-dryings, obtain powder standby;
(2) waterweed drying is placed in sealing high temperature furnace, is warming up to 450 DEG C with the speed of 5 DEG C/minute, continue heating and thermal insulation 2 hours after reaching final temperature, take out after cooling, by gained charcoal grinding and sieving, take particle diameter standby at the granule of 0.15mm;
(3) charcoal and water are soaked 18 hours after 1:9 mixes in mass ratio, continue after centrifugal segregation supernatant to repeat to soak, to supernatant colourless after by gained charcoal dry for standby at 50 DEG C;
(4) by the potassium permanganate solution of step 3 gained charcoal with 0.2mol/L after 1:12 mixes in mass ratio, use frequency is 30kHz, power is that the ultrasonic echography 90 minutes of 15W is with mixing, heating be evaporated after in putting into high temperature furnace at 500 DEG C Non-oxygen pyrolytic 30 minutes, the biological carbon materials having obtained Mn oxide immobilized, standby;
(5) in step 4 gained biological carbon materials, 5 times of quality water are added, adding cellulase preparation and protease preparation, regulation liquid PH is 5.0, impregnates 7 hours after being slowly stirred at a room temperature 10 minutes, filter and dry at 50 DEG C, obtain the charcoal composite that exogenous enzyme is fixing;
(6) by step 1 gained tamarind marc and agricultural crop straw, Sargassum powder, plant ash, the sawdust laggard row compost fermentation of mixing, after 20 days, compost temperature reduces, add attapulgite, lentinan and step 5 gained charcoal composite, continue fermentation 12 days;
(7) pulverize after step 6 gained fermentation material being dried under 45 DEG C of low temperature, and mix with carbonic acid one ammonium, sodium nitrate, step 1 gained powder and other leftover materials and be placed in comminutor granulation, obtain biomass fertilizers of the present invention.
The application of the invention biomass fertilizer, soil fertility obtains improvement by a relatively large margin, wherein available nitrogen, phosphorus, potassium and various trace elements content are all improved, the physicochemical property of soil also makes moderate progress simultaneously, it is in particular in that soil plough horizon pH value is stable at 6.5-7.0, the cultivation of suitable crops, dry and wet balance simultaneously, the content of organic matter increases, in soil, profitable strain quantity increases, in soil, organic carbon level and Cation Exchange Capacity in Soils are all improved, finally give the agricultural product of high yield and quality, can be seen that fertilizer of the present invention has high use value.
Claims (2)
1. the biomass organic fertilizer improving acid ground PH, it is characterized in that, be prepared by the raw materials in: Sargassum powder 6-8, calcium sulfate 2-3, sodium lignin sulfonate 2-3, sawdust 28-32, carbonic acid one ammonium 3-5, agricultural crop straw 73-77, plant ash 15-16, attapulgite 6-8, lentinan 4-5, sodium nitrate 3-4, waterweed 53-57, cellulase preparation 2-4, protease preparation 3-4, tamarind fruit 9-10, water are appropriate.
2. according to the biomass organic fertilizer of the raising acid ground PH described in claims 1, it is characterised in that specifically comprising the following steps that of preparation method
(1) filter after tamarind fruit squeezing juice, filtrate and calcium sulfate, sodium lignin sulfonate are mixed and heated to 74-76 DEG C, stir 20 minutes post-dryings, obtain powder standby;
(2) waterweed drying is placed in sealing high temperature furnace, it is warming up to 450 DEG C with the speed of 5-7 DEG C/minute, continues heating and thermal insulation 2-3 hour after reaching final temperature, take out after cooling, by gained charcoal grinding and sieving, take particle diameter standby at the granule of 0.15-0.25mm;
(3) charcoal and water are soaked 18-24 hour after 1:9 mixes in mass ratio, continue after centrifugal segregation supernatant to repeat to soak, to supernatant colourless after by gained charcoal dry for standby at 50-55 DEG C;
(4) by the potassium permanganate solution of step 3 gained charcoal with 0.2mol/L after 1:12 mixes in mass ratio, use frequency is 30-40kHz, power is that ultrasonic echography 90-120 minute of 15W is with mixing, heating be evaporated after in putting into high temperature furnace at 500-550 DEG C Non-oxygen pyrolytic 30-40 minute, the biological carbon materials having obtained Mn oxide immobilized, standby;
(5) in step 4 gained biological carbon materials, 5-6 times of quality water is added, add cellulase preparation and protease preparation, regulation liquid PH is 5.0-5.5, impregnate 7 hours after being slowly stirred at a room temperature 10-20 minute, filter and dry at 50-52 DEG C, obtain the charcoal composite that exogenous enzyme is fixing;
(6) by step 1 gained tamarind marc and agricultural crop straw, Sargassum powder, plant ash, the sawdust laggard row compost fermentation of mixing, after 20 days, compost temperature reduces, add attapulgite, lentinan and step 5 gained charcoal composite, continue fermentation 12-15 days;
(7) pulverize after step 6 gained fermentation material being dried under 45-50 DEG C of low temperature, and mix with carbonic acid one ammonium, sodium nitrate, step 1 gained powder and other leftover materials and be placed in comminutor granulation, obtain biomass fertilizers of the present invention.
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107382477A (en) * | 2017-07-31 | 2017-11-24 | 安徽华联肥业有限公司 | A kind of microbial immobilized organic fertilizer and preparation method thereof |
CN107805169A (en) * | 2017-12-04 | 2018-03-16 | 浙江聚贤盛邦农业科技有限公司 | A kind of alkaline biological organic enzyme fertilizer and preparation method thereof |
CN107879861A (en) * | 2017-12-13 | 2018-04-06 | 渠县金穗农业科技有限公司 | A kind of organic fertilizer and preparation method thereof |
CN108164358A (en) * | 2017-12-23 | 2018-06-15 | 郭舒洋 | A kind of preparation method of getting fat removing toxic substances type acid soil improving agent |
CN109575932A (en) * | 2019-01-23 | 2019-04-05 | 海南省农业科学院农业环境与土壤研究所 | A kind of acid soil improving agent and preparation method thereof |
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CN103951506A (en) * | 2014-04-24 | 2014-07-30 | 泰瑞生态科学(济宁)有限公司 | Water soluble fertilizer containing mushroom proteoglycan |
CN104587958A (en) * | 2015-01-23 | 2015-05-06 | 中国科学院生态环境研究中心 | Composite biological carbon material loading iron oxide as well as preparation method and application of composite biological carbon material |
CN105061086A (en) * | 2015-08-26 | 2015-11-18 | 迪斯科科技集团(宜昌)有限公司 | Acid soil conditioner containing biological carbon and preparing method thereof |
CN105295944A (en) * | 2015-11-24 | 2016-02-03 | 赵洪军 | Biological soil conditioner with acidic soil improvement function |
CN105347907A (en) * | 2015-10-19 | 2016-02-24 | 福建金土地生物科技有限公司 | Biochar-based fertilizer for restoration of heavy metal contamination of arable soil |
CN105462595A (en) * | 2015-12-21 | 2016-04-06 | 武汉飞喜乐农业科技有限公司 | Acid soil modifier and preparation method thereof |
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Patent Citations (6)
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CN103951506A (en) * | 2014-04-24 | 2014-07-30 | 泰瑞生态科学(济宁)有限公司 | Water soluble fertilizer containing mushroom proteoglycan |
CN104587958A (en) * | 2015-01-23 | 2015-05-06 | 中国科学院生态环境研究中心 | Composite biological carbon material loading iron oxide as well as preparation method and application of composite biological carbon material |
CN105061086A (en) * | 2015-08-26 | 2015-11-18 | 迪斯科科技集团(宜昌)有限公司 | Acid soil conditioner containing biological carbon and preparing method thereof |
CN105347907A (en) * | 2015-10-19 | 2016-02-24 | 福建金土地生物科技有限公司 | Biochar-based fertilizer for restoration of heavy metal contamination of arable soil |
CN105295944A (en) * | 2015-11-24 | 2016-02-03 | 赵洪军 | Biological soil conditioner with acidic soil improvement function |
CN105462595A (en) * | 2015-12-21 | 2016-04-06 | 武汉飞喜乐农业科技有限公司 | Acid soil modifier and preparation method thereof |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107382477A (en) * | 2017-07-31 | 2017-11-24 | 安徽华联肥业有限公司 | A kind of microbial immobilized organic fertilizer and preparation method thereof |
CN107805169A (en) * | 2017-12-04 | 2018-03-16 | 浙江聚贤盛邦农业科技有限公司 | A kind of alkaline biological organic enzyme fertilizer and preparation method thereof |
CN107879861A (en) * | 2017-12-13 | 2018-04-06 | 渠县金穗农业科技有限公司 | A kind of organic fertilizer and preparation method thereof |
CN108164358A (en) * | 2017-12-23 | 2018-06-15 | 郭舒洋 | A kind of preparation method of getting fat removing toxic substances type acid soil improving agent |
CN109575932A (en) * | 2019-01-23 | 2019-04-05 | 海南省农业科学院农业环境与土壤研究所 | A kind of acid soil improving agent and preparation method thereof |
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Application publication date: 20160921 |