CN102965767B - 杂化碳纳米纤维及其制备方法 - Google Patents
杂化碳纳米纤维及其制备方法 Download PDFInfo
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- CN102965767B CN102965767B CN201210482907.7A CN201210482907A CN102965767B CN 102965767 B CN102965767 B CN 102965767B CN 201210482907 A CN201210482907 A CN 201210482907A CN 102965767 B CN102965767 B CN 102965767B
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- carbon nano
- nano fibers
- hybridizing carbon
- hybridizing
- electrospinning
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 93
- 239000002134 carbon nanofiber Substances 0.000 title claims abstract description 90
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 239000000835 fiber Substances 0.000 claims abstract description 31
- 229920002239 polyacrylonitrile Polymers 0.000 claims abstract description 19
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 18
- 239000012298 atmosphere Substances 0.000 claims abstract description 17
- 229910052796 boron Inorganic materials 0.000 claims abstract description 7
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 7
- 238000003763 carbonization Methods 0.000 claims abstract description 5
- 238000001523 electrospinning Methods 0.000 claims description 32
- 238000009413 insulation Methods 0.000 claims description 29
- 239000000203 mixture Substances 0.000 claims description 20
- 239000002243 precursor Substances 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 15
- 239000007788 liquid Substances 0.000 claims description 12
- 239000000919 ceramic Substances 0.000 claims description 8
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 6
- 239000003960 organic solvent Substances 0.000 claims description 5
- 239000012299 nitrogen atmosphere Substances 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 abstract description 4
- 238000007254 oxidation reaction Methods 0.000 abstract description 4
- 238000004321 preservation Methods 0.000 abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 24
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 15
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 8
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000012264 purified product Substances 0.000 description 6
- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 description 5
- 238000010189 synthetic method Methods 0.000 description 5
- FAQYAMRNWDIXMY-UHFFFAOYSA-N trichloroborane Chemical compound ClB(Cl)Cl FAQYAMRNWDIXMY-UHFFFAOYSA-N 0.000 description 5
- 238000001816 cooling Methods 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 229920000049 Carbon (fiber) Polymers 0.000 description 3
- 241000237502 Ostreidae Species 0.000 description 3
- 229910052786 argon Inorganic materials 0.000 description 3
- 239000007844 bleaching agent Substances 0.000 description 3
- 239000004917 carbon fiber Substances 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 238000000280 densification Methods 0.000 description 3
- MROCJMGDEKINLD-UHFFFAOYSA-N dichlorosilane Chemical compound Cl[SiH2]Cl MROCJMGDEKINLD-UHFFFAOYSA-N 0.000 description 3
- 238000011049 filling Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000001000 micrograph Methods 0.000 description 3
- 235000020636 oyster Nutrition 0.000 description 3
- 238000000859 sublimation Methods 0.000 description 3
- 230000008022 sublimation Effects 0.000 description 3
- 238000001757 thermogravimetry curve Methods 0.000 description 3
- VVJKKWFAADXIJK-UHFFFAOYSA-N Allylamine Chemical compound NCC=C VVJKKWFAADXIJK-UHFFFAOYSA-N 0.000 description 2
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000010041 electrostatic spinning Methods 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 238000002679 ablation Methods 0.000 description 1
- VENHQJAOODTGTK-UHFFFAOYSA-N azane;ethynylbenzene Chemical compound N.C#CC1=CC=CC=C1 VENHQJAOODTGTK-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 238000009616 inductively coupled plasma Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 239000011232 storage material Substances 0.000 description 1
- 238000002411 thermogravimetry Methods 0.000 description 1
- 238000012032 thrombin generation assay Methods 0.000 description 1
- 208000014903 transposition of the great arteries Diseases 0.000 description 1
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- Inorganic Fibers (AREA)
Abstract
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Families Citing this family (3)
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CN109797459B (zh) * | 2019-01-23 | 2021-04-02 | 中国人民解放军国防科技大学 | 一种SiBCN纳米陶瓷纤维的制备方法 |
CN113046862B (zh) * | 2021-03-09 | 2022-09-16 | 中国人民解放军国防科技大学 | 超细直径的bcn和bn陶瓷纤维的制备方法 |
CN115613013B (zh) * | 2022-10-31 | 2024-06-04 | 中国科学院化学研究所 | 一种复合绝缘层及其制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101884932A (zh) * | 2010-06-11 | 2010-11-17 | 哈尔滨工业大学深圳研究生院 | 氮掺杂碳纳米纤维氧还原催化剂及其制备方法和应用 |
CN101956252A (zh) * | 2010-09-19 | 2011-01-26 | 东华大学 | 一种硼改性聚丙烯腈原丝制备碳纤维的方法 |
CN102382623A (zh) * | 2011-08-02 | 2012-03-21 | 山东大学 | 一种碳基复合吸波材料的制备方法 |
CN102643101A (zh) * | 2012-04-18 | 2012-08-22 | 东华大学 | 一种c/sibnc复合材料的制备方法 |
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JP2837586B2 (ja) * | 1992-09-01 | 1998-12-16 | 三井鉱山株式会社 | シリカ含有炭素繊維、その製造方法およびそれを使用した繊維補強セメント系材料 |
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Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101884932A (zh) * | 2010-06-11 | 2010-11-17 | 哈尔滨工业大学深圳研究生院 | 氮掺杂碳纳米纤维氧还原催化剂及其制备方法和应用 |
CN101956252A (zh) * | 2010-09-19 | 2011-01-26 | 东华大学 | 一种硼改性聚丙烯腈原丝制备碳纤维的方法 |
CN102382623A (zh) * | 2011-08-02 | 2012-03-21 | 山东大学 | 一种碳基复合吸波材料的制备方法 |
CN102643101A (zh) * | 2012-04-18 | 2012-08-22 | 东华大学 | 一种c/sibnc复合材料的制备方法 |
Non-Patent Citations (3)
Title |
---|
JP特开平6-81219A 1994.03.22 |
史童男.钨、硼、氮掺杂改性纳米碳纤维及其氧还原活性的研究.《中国优秀硕士学位论文全文数据库 工程科技I辑》.2011,(第06期),第B16-157页. |
钨、硼、氮掺杂改性纳米碳纤维及其氧还原活性的研究;史童男;《中国优秀硕士学位论文全文数据库 工程科技I辑》;20110615(第06期);第B16-157页 * |
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