CN102918068B - 酰胺酯内给电子体和方法 - Google Patents

酰胺酯内给电子体和方法 Download PDF

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Publication number
CN102918068B
CN102918068B CN201180020873.3A CN201180020873A CN102918068B CN 102918068 B CN102918068 B CN 102918068B CN 201180020873 A CN201180020873 A CN 201180020873A CN 102918068 B CN102918068 B CN 102918068B
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CN
China
Prior art keywords
electron donor
procatalyst
carboxylic acid
amide ester
acid amide
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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CN201180020873.3A
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English (en)
Chinese (zh)
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CN102918068A (zh
Inventor
X.黄
陈林枫
C.C.威廉斯
T.W.梁
陶涛
高宽强
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WR Grace and Co Conn
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WR Grace and Co
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Publication of CN102918068A publication Critical patent/CN102918068A/zh
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Expired - Fee Related legal-status Critical Current
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651—Pretreating with non-metals or metal-free compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/04—Broad molecular weight distribution, i.e. Mw/Mn > 6
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/18—Bulk density

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
CN201180020873.3A 2010-02-26 2011-02-24 酰胺酯内给电子体和方法 Expired - Fee Related CN102918068B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US30854310P 2010-02-26 2010-02-26
US61/308,543 2010-02-26
PCT/US2011/026036 WO2011106500A1 (en) 2010-02-26 2011-02-24 Amide ester internal electron and process

Publications (2)

Publication Number Publication Date
CN102918068A CN102918068A (zh) 2013-02-06
CN102918068B true CN102918068B (zh) 2016-01-06

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Family Applications (1)

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CN201180020873.3A Expired - Fee Related CN102918068B (zh) 2010-02-26 2011-02-24 酰胺酯内给电子体和方法

Country Status (10)

Country Link
US (1) US8551903B2 (https=)
EP (1) EP2539379B1 (https=)
JP (1) JP5779193B2 (https=)
KR (1) KR101824747B1 (https=)
CN (1) CN102918068B (https=)
BR (1) BR112012021519B1 (https=)
MY (1) MY181149A (https=)
RU (1) RU2623223C2 (https=)
SG (1) SG183813A1 (https=)
WO (1) WO2011106500A1 (https=)

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EP2723780B1 (en) 2011-06-24 2017-04-26 Basell Poliolefine Italia S.r.l. Catalyst components for the polymerization of olefins
IN2014DN10763A (https=) * 2012-06-29 2015-09-04 Saudi Basic Ind Corp
BR112015017749B1 (pt) * 2013-01-31 2021-01-12 Saudi Basic Industries Corporation composição de catalisador para a polimerização de olefinas, seu processo para a preparação e seu uso, sistema de catalisador e processo de produção de uma poliolefina
US9790291B2 (en) * 2013-03-14 2017-10-17 Formosa Plastics Corporation, Usa Non-phthalate compounds as electron donors for polyolefin catalysts
EP3044239B9 (en) * 2013-09-09 2019-08-28 Basell Poliolefine Italia S.r.l. Catalyst components for the polymerization of olefins
BR112016013951B1 (pt) * 2013-12-20 2022-02-22 Sabic Global Technologies B.V. Processo para a preparação de um pró-catalisador para polimerização de uma olefina, uso de uma benzamida, composição de catalisador, pró-catalisador e processo para a preparação de poliolefinas compreendendo o mesmo
KR102365377B1 (ko) 2013-12-20 2022-02-21 사우디 베이식 인더스트리즈 코포레이션 올레핀 중합용 촉매 시스템
KR20160102018A (ko) 2013-12-20 2016-08-26 사우디 베이식 인더스트리즈 코포레이션 올레핀 중합용 전구 촉매
US10059656B2 (en) 2013-12-20 2018-08-28 Sabic Global Technologies B.V. Catalyst composition for polymerization of olefins
EP3083723B1 (en) 2013-12-20 2022-01-19 Saudi Basic Industries Corporation Catalyst system for polymerisation of an olefin
EP3083722B1 (en) 2013-12-20 2021-11-10 Saudi Basic Industries Corporation Catalyst system for polymerisation of an olefin
MX2016008039A (es) * 2013-12-20 2017-05-12 Saudi Basic Ind Corp Sistema catalizador para polimerizacion de una olefina.
EP3149054A1 (en) * 2014-06-02 2017-04-05 SABIC Global Technologies B.V. Procatalyst for polymerization of olefins comprising a monoester and an amidobenzoate internal donor
US9593184B2 (en) * 2014-10-28 2017-03-14 Formosa Plastics Corporation, Usa Oxalic acid diamides as modifiers for polyolefin catalysts
KR101872195B1 (ko) 2015-03-10 2018-06-28 바셀 폴리올레핀 이탈리아 에스.알.엘 올레핀 중합용 촉매 성분
WO2017079940A1 (zh) * 2015-11-12 2017-05-18 营口市向阳催化剂有限责任公司 含有磷酸酯类外给电子体的聚丙烯聚合用催化体系及其应用
US10836847B2 (en) 2015-12-02 2020-11-17 Sabic Global Technologies B.V. Procatalyst for polymerization of olefins
WO2017093132A1 (en) * 2015-12-02 2017-06-08 Sabic Global Technologies B.V. Process for preparing a procatalyst for polymerization of olefins
EA038377B1 (ru) * 2015-12-02 2021-08-18 Сабик Глоубл Текнолоджиз Б.В. Прокатализатор для полимеризации олефинов
EP3697755B1 (en) * 2017-10-20 2021-09-15 SABIC Global Technologies B.V. Novel synthesis method for the preparation of dibenzoate compounds, such as 4-[benzoyl(methyl)amino]pentane-2-yl dibenzoate
JP7130301B2 (ja) 2018-05-04 2022-09-05 エルジー・ケム・リミテッド オレフィン系共重合体及びその製造方法
JPWO2024204845A1 (https=) * 2023-03-30 2024-10-03
WO2024204847A1 (ja) * 2023-03-30 2024-10-03 三井化学株式会社 アミド化合物
WO2024204846A1 (ja) * 2023-03-31 2024-10-03 三井化学株式会社 カルバメート化合物
KR20250139411A (ko) * 2023-03-31 2025-09-23 미쓰이 가가쿠 가부시키가이샤 고체상 타이타늄 촉매 성분, 올레핀 중합용 촉매, 올레핀의 중합 방법

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CN1169845C (zh) * 2002-02-07 2004-10-06 中国石油化工股份有限公司 用于烯烃聚合的固体催化剂组分和含该催化剂组分的催化剂及其应用
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CN101104589A (zh) * 2006-07-13 2008-01-16 中国石油化工股份有限公司 用于制备烯烃聚合催化剂的氨酯化合物
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Also Published As

Publication number Publication date
JP5779193B2 (ja) 2015-09-16
EP2539379A1 (en) 2013-01-02
BR112012021519B1 (pt) 2019-12-17
EP2539379B1 (en) 2017-09-06
RU2012141060A (ru) 2014-04-10
BR112012021519A2 (pt) 2016-07-05
KR20130020771A (ko) 2013-02-28
US20120316299A1 (en) 2012-12-13
KR101824747B1 (ko) 2018-03-14
JP2013521341A (ja) 2013-06-10
RU2623223C2 (ru) 2017-06-23
US8551903B2 (en) 2013-10-08
CN102918068A (zh) 2013-02-06
WO2011106500A1 (en) 2011-09-01
SG183813A1 (en) 2012-10-30
MY181149A (en) 2020-12-19

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