CN102918068B - 酰胺酯内给电子体和方法 - Google Patents

酰胺酯内给电子体和方法 Download PDF

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Publication number
CN102918068B
CN102918068B CN201180020873.3A CN201180020873A CN102918068B CN 102918068 B CN102918068 B CN 102918068B CN 201180020873 A CN201180020873 A CN 201180020873A CN 102918068 B CN102918068 B CN 102918068B
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CN
China
Prior art keywords
electron donor
procatalyst
carboxylic acid
amide ester
acid amide
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Expired - Fee Related
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CN201180020873.3A
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English (en)
Chinese (zh)
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CN102918068A (zh
Inventor
X.黄
陈林枫
C.C.威廉斯
T.W.梁
陶涛
高宽强
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WR Grace and Co Conn
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WR Grace and Co
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651Pretreating with non-metals or metal-free compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652Pretreating with metals or metal-containing compounds
    • C08F4/654Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/04Broad molecular weight distribution, i.e. Mw/Mn > 6
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/18Bulk density

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
CN201180020873.3A 2010-02-26 2011-02-24 酰胺酯内给电子体和方法 Expired - Fee Related CN102918068B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US30854310P 2010-02-26 2010-02-26
US61/308,543 2010-02-26
PCT/US2011/026036 WO2011106500A1 (en) 2010-02-26 2011-02-24 Amide ester internal electron and process

Publications (2)

Publication Number Publication Date
CN102918068A CN102918068A (zh) 2013-02-06
CN102918068B true CN102918068B (zh) 2016-01-06

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CN201180020873.3A Expired - Fee Related CN102918068B (zh) 2010-02-26 2011-02-24 酰胺酯内给电子体和方法

Country Status (10)

Country Link
US (1) US8551903B2 (https=)
EP (1) EP2539379B1 (https=)
JP (1) JP5779193B2 (https=)
KR (1) KR101824747B1 (https=)
CN (1) CN102918068B (https=)
BR (1) BR112012021519B1 (https=)
MY (1) MY181149A (https=)
RU (1) RU2623223C2 (https=)
SG (1) SG183813A1 (https=)
WO (1) WO2011106500A1 (https=)

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CN103781805B (zh) 2011-06-24 2016-10-12 巴塞尔聚烯烃意大利有限责任公司 用于烯烃聚合的催化剂组分
EP2867264B1 (en) * 2012-06-29 2016-04-20 Saudi Basic Industries Corporation Catalyst composition for polymerization of olefins
US9587051B2 (en) * 2013-01-31 2017-03-07 Saudi Basic Industries Corporation Process for preparing a catalyst component for polymerization of olefins
US9790291B2 (en) * 2013-03-14 2017-10-17 Formosa Plastics Corporation, Usa Non-phthalate compounds as electron donors for polyolefin catalysts
BR112016003829B1 (pt) 2013-09-09 2020-10-06 Basell Poliolefine Italia S.R.L. Componente catalisador sólido, catalisador e processo para (co)polimerização de olefinas
MX2016008039A (es) * 2013-12-20 2017-05-12 Saudi Basic Ind Corp Sistema catalizador para polimerizacion de una olefina.
MX2016008041A (es) 2013-12-20 2017-03-03 Saudi Basic Ind Corp Sistema catalizador para polimerizacion de una olefina.
WO2015091984A1 (en) 2013-12-20 2015-06-25 Saudi Basic Industries Corporation Procatalyst for polymerization of olefins
EP3083722B1 (en) 2013-12-20 2021-11-10 Saudi Basic Industries Corporation Catalyst system for polymerisation of an olefin
CN105934449B (zh) * 2013-12-20 2018-07-10 沙特基础工业公司 用于烯烃聚合的催化剂组合物
US10059656B2 (en) 2013-12-20 2018-08-28 Sabic Global Technologies B.V. Catalyst composition for polymerization of olefins
CN105940023B (zh) 2013-12-20 2019-01-18 沙特基础工业公司 用于烯烃聚合的催化剂体系
CN106414520A (zh) * 2014-06-02 2017-02-15 Sabic环球技术有限责任公司 用于烯烃聚合的包含单酯和氨基苯甲酸酯内部供体的原催化剂
US9593184B2 (en) * 2014-10-28 2017-03-14 Formosa Plastics Corporation, Usa Oxalic acid diamides as modifiers for polyolefin catalysts
JP6388726B2 (ja) * 2015-03-10 2018-09-12 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ オレフイン重合用触媒成分
WO2017079940A1 (zh) * 2015-11-12 2017-05-18 营口市向阳催化剂有限责任公司 含有磷酸酯类外给电子体的聚丙烯聚合用催化体系及其应用
EA038377B1 (ru) * 2015-12-02 2021-08-18 Сабик Глоубл Текнолоджиз Б.В. Прокатализатор для полимеризации олефинов
WO2017093129A1 (en) * 2015-12-02 2017-06-08 Sabic Global Technologies B.V. Process for preparing a procatalyst for polymerization of olefins
US10836847B2 (en) 2015-12-02 2020-11-17 Sabic Global Technologies B.V. Procatalyst for polymerization of olefins
CN110678441B (zh) * 2017-10-20 2023-03-31 Sabic环球技术有限责任公司 用于制备二苯甲酸酯化合物如4-[苯甲酰(甲基)氨基]戊烷-2-基二苯甲酸酯的新合成方法
KR102117624B1 (ko) 2018-05-04 2020-06-02 주식회사 엘지화학 올레핀계 공중합체 및 이의 제조방법
JPWO2024204845A1 (https=) * 2023-03-30 2024-10-03
KR20250149735A (ko) * 2023-03-30 2025-10-16 미쓰이 가가쿠 가부시키가이샤 아마이드 화합물
EP4692050A1 (en) * 2023-03-31 2026-02-11 Mitsui Chemicals, Inc. Carbamate compound
EP4692134A1 (en) * 2023-03-31 2026-02-11 Mitsui Chemicals, Inc. Solid titanium catalyst component, catalyst for olefin polymerization, and method for polymerizing olefin

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Also Published As

Publication number Publication date
BR112012021519A2 (pt) 2016-07-05
MY181149A (en) 2020-12-19
US20120316299A1 (en) 2012-12-13
RU2623223C2 (ru) 2017-06-23
JP5779193B2 (ja) 2015-09-16
CN102918068A (zh) 2013-02-06
US8551903B2 (en) 2013-10-08
KR101824747B1 (ko) 2018-03-14
SG183813A1 (en) 2012-10-30
JP2013521341A (ja) 2013-06-10
BR112012021519B1 (pt) 2019-12-17
EP2539379B1 (en) 2017-09-06
KR20130020771A (ko) 2013-02-28
RU2012141060A (ru) 2014-04-10
EP2539379A1 (en) 2013-01-02
WO2011106500A1 (en) 2011-09-01

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