BR112012021519B1 - proccesso, composição de procatalisador, composição catalítica e processo para produzir um polímero a base de olefina - Google Patents

proccesso, composição de procatalisador, composição catalítica e processo para produzir um polímero a base de olefina Download PDF

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Publication number
BR112012021519B1
BR112012021519B1 BR112012021519-1A BR112012021519A BR112012021519B1 BR 112012021519 B1 BR112012021519 B1 BR 112012021519B1 BR 112012021519 A BR112012021519 A BR 112012021519A BR 112012021519 B1 BR112012021519 B1 BR 112012021519B1
Authority
BR
Brazil
Prior art keywords
pro
group
electron donor
catalyst
amide ester
Prior art date
Application number
BR112012021519-1A
Other languages
English (en)
Portuguese (pt)
Other versions
BR112012021519A2 (pt
Inventor
Linfeng Chen
Clark C. Williams
Tak W. Leung
Tao Tao
Kuanqiang Gao
Xiaodong Huang
Original Assignee
W. R. Grace & Co-Conn
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by W. R. Grace & Co-Conn filed Critical W. R. Grace & Co-Conn
Publication of BR112012021519A2 publication Critical patent/BR112012021519A2/pt
Publication of BR112012021519B1 publication Critical patent/BR112012021519B1/pt

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651Pretreating with non-metals or metal-free compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652Pretreating with metals or metal-containing compounds
    • C08F4/654Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/04Broad molecular weight distribution, i.e. Mw/Mn > 6
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/18Bulk density

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
BR112012021519-1A 2010-02-26 2011-02-24 proccesso, composição de procatalisador, composição catalítica e processo para produzir um polímero a base de olefina BR112012021519B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US30854310P 2010-02-26 2010-02-26
US61/308,543 2010-02-26
PCT/US2011/026036 WO2011106500A1 (en) 2010-02-26 2011-02-24 Amide ester internal electron and process

Publications (2)

Publication Number Publication Date
BR112012021519A2 BR112012021519A2 (pt) 2016-07-05
BR112012021519B1 true BR112012021519B1 (pt) 2019-12-17

Family

ID=44209862

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112012021519-1A BR112012021519B1 (pt) 2010-02-26 2011-02-24 proccesso, composição de procatalisador, composição catalítica e processo para produzir um polímero a base de olefina

Country Status (10)

Country Link
US (1) US8551903B2 (https=)
EP (1) EP2539379B1 (https=)
JP (1) JP5779193B2 (https=)
KR (1) KR101824747B1 (https=)
CN (1) CN102918068B (https=)
BR (1) BR112012021519B1 (https=)
MY (1) MY181149A (https=)
RU (1) RU2623223C2 (https=)
SG (1) SG183813A1 (https=)
WO (1) WO2011106500A1 (https=)

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Publication number Priority date Publication date Assignee Title
EP2723780B1 (en) 2011-06-24 2017-04-26 Basell Poliolefine Italia S.r.l. Catalyst components for the polymerization of olefins
IN2014DN10763A (https=) * 2012-06-29 2015-09-04 Saudi Basic Ind Corp
BR112015017749B1 (pt) * 2013-01-31 2021-01-12 Saudi Basic Industries Corporation composição de catalisador para a polimerização de olefinas, seu processo para a preparação e seu uso, sistema de catalisador e processo de produção de uma poliolefina
US9790291B2 (en) * 2013-03-14 2017-10-17 Formosa Plastics Corporation, Usa Non-phthalate compounds as electron donors for polyolefin catalysts
EP3044239B9 (en) * 2013-09-09 2019-08-28 Basell Poliolefine Italia S.r.l. Catalyst components for the polymerization of olefins
BR112016013951B1 (pt) * 2013-12-20 2022-02-22 Sabic Global Technologies B.V. Processo para a preparação de um pró-catalisador para polimerização de uma olefina, uso de uma benzamida, composição de catalisador, pró-catalisador e processo para a preparação de poliolefinas compreendendo o mesmo
KR102365377B1 (ko) 2013-12-20 2022-02-21 사우디 베이식 인더스트리즈 코포레이션 올레핀 중합용 촉매 시스템
KR20160102018A (ko) 2013-12-20 2016-08-26 사우디 베이식 인더스트리즈 코포레이션 올레핀 중합용 전구 촉매
US10059656B2 (en) 2013-12-20 2018-08-28 Sabic Global Technologies B.V. Catalyst composition for polymerization of olefins
EP3083723B1 (en) 2013-12-20 2022-01-19 Saudi Basic Industries Corporation Catalyst system for polymerisation of an olefin
EP3083722B1 (en) 2013-12-20 2021-11-10 Saudi Basic Industries Corporation Catalyst system for polymerisation of an olefin
MX2016008039A (es) * 2013-12-20 2017-05-12 Saudi Basic Ind Corp Sistema catalizador para polimerizacion de una olefina.
EP3149054A1 (en) * 2014-06-02 2017-04-05 SABIC Global Technologies B.V. Procatalyst for polymerization of olefins comprising a monoester and an amidobenzoate internal donor
US9593184B2 (en) * 2014-10-28 2017-03-14 Formosa Plastics Corporation, Usa Oxalic acid diamides as modifiers for polyolefin catalysts
KR101872195B1 (ko) 2015-03-10 2018-06-28 바셀 폴리올레핀 이탈리아 에스.알.엘 올레핀 중합용 촉매 성분
WO2017079940A1 (zh) * 2015-11-12 2017-05-18 营口市向阳催化剂有限责任公司 含有磷酸酯类外给电子体的聚丙烯聚合用催化体系及其应用
US10836847B2 (en) 2015-12-02 2020-11-17 Sabic Global Technologies B.V. Procatalyst for polymerization of olefins
WO2017093132A1 (en) * 2015-12-02 2017-06-08 Sabic Global Technologies B.V. Process for preparing a procatalyst for polymerization of olefins
EA038377B1 (ru) * 2015-12-02 2021-08-18 Сабик Глоубл Текнолоджиз Б.В. Прокатализатор для полимеризации олефинов
EP3697755B1 (en) * 2017-10-20 2021-09-15 SABIC Global Technologies B.V. Novel synthesis method for the preparation of dibenzoate compounds, such as 4-[benzoyl(methyl)amino]pentane-2-yl dibenzoate
JP7130301B2 (ja) 2018-05-04 2022-09-05 エルジー・ケム・リミテッド オレフィン系共重合体及びその製造方法
JPWO2024204845A1 (https=) * 2023-03-30 2024-10-03
WO2024204847A1 (ja) * 2023-03-30 2024-10-03 三井化学株式会社 アミド化合物
WO2024204846A1 (ja) * 2023-03-31 2024-10-03 三井化学株式会社 カルバメート化合物
KR20250139411A (ko) * 2023-03-31 2025-09-23 미쓰이 가가쿠 가부시키가이샤 고체상 타이타늄 촉매 성분, 올레핀 중합용 촉매, 올레핀의 중합 방법

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CA1141093A (en) * 1979-05-17 1983-02-08 Brian L. Goodall Olefin polymerization catalyst compositions and a process for the polymerization of olefins employing such compositions
JPS5665008A (en) * 1979-10-31 1981-06-02 Denki Kagaku Kogyo Kk Catalyst component for olefin polymerization
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US6825146B2 (en) 2001-05-29 2004-11-30 Union Carbide Chemicals & Plastics Technology Corporation Olefin polymerization catalyst compositions and method of preparation
CN100441561C (zh) 2002-02-07 2008-12-10 中国石油化工股份有限公司 用于制备烯烃聚合催化剂的多酯化合物
CN1169845C (zh) * 2002-02-07 2004-10-06 中国石油化工股份有限公司 用于烯烃聚合的固体催化剂组分和含该催化剂组分的催化剂及其应用
CN1213080C (zh) * 2003-04-21 2005-08-03 中国石油化工股份有限公司 用于烯烃聚合反应的催化剂组分及其催化剂
US7351778B2 (en) 2004-04-30 2008-04-01 China Petroleum & Chemical Corporation Catalyst component for olefin polymerization and catalyst comprising the same
US8288606B2 (en) * 2005-03-08 2012-10-16 Ineos Usa Llc Propylene polymer catalyst donor component
CN101104589A (zh) * 2006-07-13 2008-01-16 中国石油化工股份有限公司 用于制备烯烃聚合催化剂的氨酯化合物
CN101104656B (zh) * 2006-07-13 2010-11-10 中国石油化工股份有限公司 用于烯烃聚合反应的催化剂组分及其催化剂
WO2011106494A1 (en) 2010-02-26 2011-09-01 Dow Global Technologies Llc Procatalyst composition with substituted amide ester internal electron donor
MY159696A (en) 2010-02-26 2017-01-13 W R Grace & Co -Conn Halogenated amide ester and internal electron donor with same

Also Published As

Publication number Publication date
JP5779193B2 (ja) 2015-09-16
EP2539379A1 (en) 2013-01-02
EP2539379B1 (en) 2017-09-06
RU2012141060A (ru) 2014-04-10
BR112012021519A2 (pt) 2016-07-05
KR20130020771A (ko) 2013-02-28
CN102918068B (zh) 2016-01-06
US20120316299A1 (en) 2012-12-13
KR101824747B1 (ko) 2018-03-14
JP2013521341A (ja) 2013-06-10
RU2623223C2 (ru) 2017-06-23
US8551903B2 (en) 2013-10-08
CN102918068A (zh) 2013-02-06
WO2011106500A1 (en) 2011-09-01
SG183813A1 (en) 2012-10-30
MY181149A (en) 2020-12-19

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Legal Events

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B25C Requirement related to requested transfer of rights

Owner name: DOW GLOBAL TECHNOLOGIES LLC (US)

B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B25A Requested transfer of rights approved

Owner name: W. R. GRACE AND CO. - CONN (US)

B06T Formal requirements before examination [chapter 6.20 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 24/02/2011, OBSERVADAS AS CONDICOES LEGAIS.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE A 15A ANUIDADE.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2868 DE 23-12-2025 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.