Summary of the invention
The present invention is exactly for the problems referred to above, provide a kind of nutritive element to supplement fully, the undamaged ricin that utilizes of soil is produced to biological organic fertilizer, compound organic and inorganic fertilizer that amino acid multi-element chelate thing is produced, and a kind of nontoxic, harmless, the ricin that utilizes free from environmental pollution and that cost is low is produced the biological organic fertilizer of amino acid multi-element chelate thing production, the preparation method of compound organic and inorganic fertilizer.
For achieving the above object, the present invention adopts following technical scheme, the present invention is a kind of utilizes ricin to produce the biological organic fertilizer (micro-fertilizer in amino acid) that amino acid multi-element chelate thing is produced, comprise ricin, sulfuric acid, inorganic in micro-fertilizer, liquefied ammonia.
As a kind of preferred version, the present invention also comprises soy protein wastewater, described ricin, sulfuric acid, inorganic in micro-fertilizer, liquefied ammonia, soy protein wastewater portion rate be: ricin 22~40, sulfuric acid 18~22, micro-fertile 10~20 in inorganic, liquefied ammonia 4~8, soy protein wastewater 10~46.
Another kind utilizes ricin to produce the biological organic fertilizer that amino acid multi-element chelate thing is produced, comprise castor-oil plant scleroproein, organic waste, inorganic in micro-fertilizer, chelating amino acids liquid, attapulgite, PPF growth-promoting fungi.
As a kind of preferred version, castor-oil plant scleroproein of the present invention, organic waste, inorganic in micro-fertilizer, chelating amino acids liquid, attapulgite, PPF growth-promoting fungi portion rate be: castor-oil plant scleroproein 40~60, organic waste 5~25, in inorganic micro-fertile 10, chelating amino acids liquid 10~20 (solids accounts for 50%), attapulgite 5~10, PPF growth-promoting fungi 0.0003.
Utilize ricin to produce the biological organic-inorganic compound fertilizer that amino acid multi-element chelate thing is produced, comprise castor-oil plant fibrillarin powder, organic waste, chelating amino acids liquid, attapulgite, urea, monoammonium phosphate, Repone K, PPF growth-promoting fungi, inorganic in micro-fertilizer.
As a kind of preferred version, castor-oil plant fibrillarin powder of the present invention, organic waste, chelating amino acids liquid, attapulgite, urea, monoammonium phosphate, Repone K, PPF growth-promoting fungi, inorganic in micro-fertile portion rate be: castor-oil plant fibrillarin powder 20~30, organic waste 8~18, chelating amino acids liquid 10, attapulgite 10, urea 18.9, monoammonium phosphate 8.9, Repone K 15, PPF growth-promoting fungi 0.0003, inorganic in micro-fertile 5.
As another kind of preferred version, the present invention also comprises powdery siliceous fertilizer, castor-oil plant fibrillarin powder, organic waste, chelating amino acids liquid, attapulgite, urea, monoammonium phosphate, Repone K, PPF growth-promoting fungi, inorganic in micro-fertilizer, powdery siliceous fertilizer portion rate be: castor-oil plant fibrillarin powder 30, organic waste 12.6, chelating amino acids liquid 10, attapulgite 10, urea 10.9, monoammonium phosphate 6.7, Repone K 6.7, PPF growth-promoting fungi 0.0003, micro-fertile 8.1, powdery siliceous fertilizer 10 in inorganic.
Utilize ricin to produce the biological organic fertilizer of amino acid multi-element chelate thing production, the preparation method of compound organic and inorganic fertilizer, comprise the following steps:
1) castor bean meal is pulverized, is sieved, and prepares fiber powder on sieve, under sieve, prepares protein powder;
2) fiber powder after pulverizing, screening, arrangement, proportioning with N, P, K batch mixing after granulation; Protein powder through hydrolysis, in close, integrate, preserve after granulation;
3) after granulation through drying, cooling, make biological organic fertilizer, biological organic-inorganic compound fertilizer after sieving, wrap up PPF growth-promoting fungi.
As a kind of preferred version, the fiber powder of preparing of the present invention with the method for preparing protein powder is: leach castor bean meal material, through 40 order circle roller screen screens, wherein screen overflow is after pulverizer is pulverized, do bio-fertilizer mixed substrates material, screen underflow is crushed to 60 orders through pulverizer by robust fibre under 40 mesh sieves, then after 80 order rotating screen screens, wherein screen overflow does biological organic fertilizer mixed substrates material, obtains castor protein powder product under sieve;
Described hydrolyzable moiety is hydrolyzed by sulfuric acid, hydrochloric acid; In described, close by liquefied ammonia, ammonium hydrogencarbonate and close in being undertaken; Described integration is integrated by middle trace element;
The method of described granulation, oven dry is: control inlet temperature at 250 DEG C~350 DEG C, 95 DEG C~110 DEG C of temperature outs; The powder that the classified sieve of material after oven dry is less than particle diameter 2.5mm returns to tablets press after pulverizer is pulverized, and particle diameter 2.5mm~4.75mm enters cooler.
As another kind of preferred version, arrangement step of the present invention comprises: will discard municipal sludge extruding, turn over throwing, dry-matter feces of livestock and poultry is pulverized, sieved;
Described mixing, proportioning step comprise: will discard organic matter, amino acid supernatant liquor, castor-oil plant fiber powder, farm manure, mineral substance tackiness agent, nitrogen, phosphorus, potassium and mix with water, moisture weight accounts for 45% of mixture weight.
Beneficial effect of the present invention:
The present invention utilizes the castor bean meal after leaching, and the ricin of producing after pulverizing, sieving is basic raw material, for the production of amino acid multi-element chelate thing and fibrillarin powder, and sets it as the substrate material of producing fertilizer, compound organic and inorganic fertilizer.
Castor bean meal itself has ricinine, 2 kinds of toxin of allergen, and ricinine is more stable to heat.When in castor seeds processing Viscotrol C process, to fry through steaming, when extruding, temperature can reach 110 degree~250 degree pyroprocesses.Contained ricinine content of toxins 0.22% in Semen Ricini cake is leached in squeezing, and it is stronger to youngling toxicity, and allergen toxicity is at 100 degree timeinvariances, so content can have prevention and restraining effect to diseases and pests of agronomic crop up to 3.8%, two kind of toxin.Amino acid bio-organic fertilizer can improve crop quality, has quick-acting, long-acting, synergism, and can improve Soil structure, and nontoxic, harmless, free from environmental pollution.
The present invention is taking organic fertilizer as carrier, adds trace element and biological bacteria in chelating amino acids liquid, makes it organic and is combined with inorganic phase, and macroelement combines with middle trace element, and bio-fertilizer combines with fertilizer, supplements plant nutrition comprehensively.Amino acid bio compound organic and inorganic fertilizer contains multiple beneficial microorganism, the Substance Transformation that crop can not be able to be absorbed be can utilization absorbed by crops nutritive substance.
The impact of the gases such as ammonia, sulfurous gas or hydrogen two sulphur on environment generation that preparation method of the present invention has avoided existing method for preparing fertilizer fermentation step to cause; And kept away the expenditure of existing zymotechnique occupation of land, building cost, turnover throwing machine expense, significantly reduce product cost.
Embodiment
As shown in the figure, the present invention adopts following technical scheme, and the present invention is a kind of utilizes ricin to produce the biological organic fertilizer that amino acid multi-element chelate thing is produced, comprise ricin, sulfuric acid, inorganic in micro-fertilizer, liquefied ammonia.
The present invention also comprises soy protein wastewater, described ricin, sulfuric acid, inorganic in micro-fertilizer, liquefied ammonia, soy protein wastewater portion rate be: ricin 22~40, sulfuric acid 18~22, micro-fertile 10~20 in inorganic, liquefied ammonia 4~8, soy protein wastewater 10~46.
Another kind utilizes ricin to produce the biological organic fertilizer that amino acid multi-element chelate thing is produced, comprise castor-oil plant scleroproein, organic waste, inorganic in micro-fertilizer, chelating amino acids liquid, attapulgite, PPF growth-promoting fungi.
Described castor-oil plant scleroproein, organic waste, inorganic in micro-fertilizer, chelating amino acids liquid, attapulgite, PPF growth-promoting fungi portion rate be: castor-oil plant scleroproein 40~60, organic waste 5~25, in inorganic micro-fertile 10, chelating amino acids liquid 10~20 (solids accounts for 50%), attapulgite 5~10, PPF growth-promoting fungi 0.0003.
Utilize ricin to produce the biological organic-inorganic compound fertilizer that amino acid multi-element chelate thing is produced, comprise castor-oil plant fibrillarin powder, organic waste, chelating amino acids liquid, attapulgite, urea, monoammonium phosphate, Repone K, PPF growth-promoting fungi, inorganic in micro-fertilizer.
Described castor-oil plant fibrillarin powder, organic waste, chelating amino acids liquid, attapulgite, urea, monoammonium phosphate, Repone K, PPF growth-promoting fungi, inorganic in micro-fertile portion rate be: castor-oil plant fibrillarin powder 20~30, organic waste 8~18, chelating amino acids liquid 10, attapulgite 10, urea 18.9, monoammonium phosphate 8.9, Repone K 15, PPF growth-promoting fungi 0.0003, inorganic in micro-fertile 5.
The present invention also comprises powdery siliceous fertilizer, castor-oil plant fibrillarin powder, organic waste, chelating amino acids liquid, attapulgite, urea, monoammonium phosphate, Repone K, PPF growth-promoting fungi, inorganic in micro-fertilizer, powdery siliceous fertilizer portion rate be: castor-oil plant fibrillarin powder 30, organic waste 12.6, chelating amino acids liquid 10, attapulgite 10, urea 10.9, monoammonium phosphate 6.7, Repone K 6.7, PPF growth-promoting fungi 0.0003, micro-fertile 8.1, powdery siliceous fertilizer 10 in inorganic.
Utilize ricin to produce the biological organic fertilizer of amino acid multi-element chelate thing production, the preparation method of compound organic and inorganic fertilizer, comprise the following steps:
1) castor bean meal is pulverized, is sieved, and prepares fiber powder on sieve, under sieve, prepares protein powder;
2) fiber powder after pulverizing, screening, arrangement, proportioning with N, P, K batch mixing after granulation; Protein powder through hydrolysis, in close, integrate, preserve after granulation;
3) after granulation through drying, cooling, sieve, wrap up biological organic fertilizer, the biological organic-inorganic compound fertilizer after PPF growth-promoting fungi, made.
The described fiber powder of preparing with the method for preparing protein powder is: leach castor bean meal (moisture 8%~14%) material, through 40 order circle roller screen screens, wherein screen overflow (protein content 8%) is after pulverizer is pulverized, do bio-fertilizer mixed substrates material, screen underflow is crushed to 60 orders through pulverizer by robust fibre under 40 mesh sieves, again after 80 order rotating screen screens, wherein screen overflow does biological organic fertilizer mixed substrates material, under sieve, obtain castor protein powder product, its protein content is 38%;
Described hydrolyzable moiety is hydrolyzed by sulfuric acid, hydrochloric acid; In described, close by liquefied ammonia, ammonium hydrogencarbonate and close in being undertaken; Described integration is integrated by middle trace element;
The method of described granulation, oven dry is: arrangement, mixing, proportioning material are sent into roller pelletizer after mixing, simultaneously by PPF growth-promoting fungi and amino acid trace element chelated liquid spraying, parcel, granulation balling-up.Send into oven dry, screening operation by transfer roller again, control inlet temperature at 250 DEG C~350 DEG C, 95 DEG C~110 DEG C of temperature outs; The powder that the classified sieve of material (secondary drying) after oven dry is less than particle diameter 2.5mm returns to tablets press after pulverizer is pulverized; particle diameter 2.5mm~4.75mm enters cooler; drop to below 50 degree through the cooling temperature of charge that makes; enter packing machine parcel PPF and (utilize spraying technique for packing; fertilizer surface coatings functional living being bacterium, to improve the decomposition of the soil organism) be the packing of product after growth-promoting fungi.Dry granulation workshop section, adopt surface coatings technology, by PPF growth-promoting fungi film, on fertiliser granulates surface, proportional quantity is 3 ‰, and the temperature of charge after Drying and cooling is down to 50 DEG C when following, enters after packing machine parcel PPF growth-promoting fungi, carries out finished product packing.Material carrier feces of livestock and poultry contains the harmful bacteria such as intestinal bacteria, roundworm egg, is a granulated into after work in-process, all inactivation (80 DEG C of standard deactivation temperature) through secondary drying (110 DEG C~250 DEG C).
Described arrangement step comprises: will discard municipal sludge extruding, turn over throwing, dry-matter feces of livestock and poultry is pulverized, sieved;
Described mixing, proportioning step comprise: will discard organic matter, amino acid supernatant liquor, castor-oil plant fiber powder, farm manure, mineral substance tackiness agent, nitrogen, phosphorus, potassium and mix with water, moisture weight accounts for 45% of mixture weight.The material that contains farmers''s feces of livestock and poultry addition in batch mixing proportioning is 10% left and right, and puddles evenly, and after secondary drying maturation process, plant growth is not produced to " burning seedling " phenomenon.It is substrate material that the present invention adopts ricin, and its nutrient content is high, and fertilising consumption is few, and spontaneous fermentation heat keeps identical with ground temperature.Every mu of rate of fertilizer application of product of the present invention is 100 kilograms of left and right, existing fertilizer because of its nutrient content low, every mu of rate of fertilizer application is more than 1000 kilogram of left and right, will produce " burning seedling " problem if do not carry out fermentation maturity.
The method that the present invention utilizes castor protein powder to produce amino acid multi-element chelate thing is:
Ricin powder material is added to enamel reaction still, add the inorganic salt of 25% sulfuric acid and middle trace element (calcium, magnesium, silicon) simultaneously, be heated to 95 degree~105 degree, be hydrolyzed 4 hours, after hydrolysis, pass into liquefied ammonia or light magnesium oxide neutralization, potential of hydrogen (PH) is 5~6, and it is for subsequent use that reaction finishes that chelating liquid pump is got to storage tank.
The method that the present invention utilizes the upper fiber powder (protein content 8%) of castor-oil plant sieve to produce fertilizer mixed substrates material:
Ricin is producing in process, on the sieve producing, fiber and albumen powder account for the more than 60% of total amount, this partial material contains crude protein more than 8%, crude fat is more than 1.5%, nitrogen (N) 4.0%, phosphorus (P) 1.2%, potassium (K) 0.5%, robust fibre is more than 30%.Used time inserts the organic wastes such as feces of livestock and poultry, municipal sludge, soybean protein slag, make moisture reach 40%~45%, moisture source adopts castor protein powder to produce the processing wastewater (being chelating supernatant liquor) of amino acid multi-element chelate thing, when batch mixing, add nitrogen, phosphorus, potassium stirring and evenly mixing, deliver to granulation and dry workshop section.
Be below formulation ratio embodiment of the present invention.
1, micro-fertilizer in amino acid
Title specification |
Proportioning 1 |
Proportioning 2 |
Proportioning 3 |
Ricin |
220kg |
300kg |
400kg |
Sulfuric acid (95%) |
180kg |
200kg |
220kg |
Micro-fertilizer in inorganic |
100kg |
150kg |
200kg |
Liquefied ammonia |
40kg |
60kg |
80kg |
Soy protein wastewater |
460kg |
290kg |
100kg |
Quality index: amino acid/11 0%, trace element 2%, nitrogen (N) 4.5%.
2, biological organic fertilizer
Quality index:
Living bacteria count >=1.0 × 10cfu/g (state quota is 0.2 × 10cfu/g);
Organic content >=30% (GB is >=20%);
PH value 6-8, miscellaneous bacteria is counted < 15%, drinking water amount≤6%.
3, amino acid multi-element biological compound organic and inorganic fertilizer (formula 1).
Title specification |
Proportioning 1 |
Proportioning 2 |
Proportioning 3 |
Castor-oil plant fibrillarin powder |
300kg |
250kg |
200kg |
Organic waste (30%) |
80kg |
130kg |
180kg |
Chelating amino acids liquid (50%) |
100kg |
100kg |
100kg |
On Attapulgite |
100kg |
100kg |
100kg |
Urea |
185kg |
185kg |
185kg |
Monoammonium phosphate |
89kg |
89kg |
89kg |
Repone K |
150kg |
150kg |
150kg |
PPF function yeast |
3‰ |
3‰ |
3‰ |
Micro-fertilizer in inorganic |
50kg |
50kg |
50kg |
Quality index: N10%, P
2o
55%, K
2o10%, total nutrient 25%, organic matter 20%, trace element 0.2%, biological bacteria 0.2 hundred million/g.
4, amino acid multi-element biological compound organic and inorganic fertilizer (formula 2).
Title and specification |
Proportioning |
Castor-oil plant fibrillarin powder |
300kg |
Organic waste (30%) |
126kg |
Urea |
109kg |
Monoammonium phosphate |
67kg |
Repone K |
67kg |
Micro-fertilizer in inorganic |
81kg |
Chelating amino acids liquid |
100kg (Gu 50%) |
Powdery siliceous fertilizer |
100kg |
On Attapulgite |
100kg |
PPF function yeast |
3‰ |
Quality index: N7%, P3%, K5%, total nutrient 15%, organic matter 20%, SiO
22.5%, Mg1%.
The impact on Chinese sorghum growth according to different proportional quantities the bio-fertilizer that adds PPF growth-promoting fungi taking high reactivity castor protein powder as carrier, checking Jilin is to the production effect of the high-quality and efficient bio-feritlizer of extra large oil prodution industry company limited exploitation, for batch process provides theoretical foundation.
Booth castor-oil plant bio-fertilizer is executed kind of a test: verify the impact of different fertilizers on Chinese sorghum growth.
Test objective:
The impact of fertilizer taking amino acid multi-element biological fertilizer and amino acid multi-element biological compound organic and inorganic fertilizer as carrier on Chinese sorghum growth, checking Jilin is to the mass effect of the high-quality and efficient castor-oil plant bio-fertilizer of extra large oil prodution industry company limited exploitation, for batch process provides theoretical foundation.
Test materials and apparatus:
(1) test materials: micro-fertilizer (proportioning one) in sorghum seeds (Ao assorted No. two), amino acid, biological organic fertilizer (proportioning one), amino acid multi-element biological compound organic and inorganic fertilizer (formula one proportioning one), inorganic composite fertilizer (nitrogen: phosphorus: potassium=15: 15: 15, total content 45%).
(2) test tools made: watering can, ruler, balance (maximum range 2kg), ground-thermometer, dustpan, label, label, sieve (2mm), spade, rake, minute book.
Testing program
4 processing are established in this test altogether, 1 contrast, and CK is blank test.
Testing sequence
(1) system bed: 1. this experimental plot is long is 12m, wide 4m, and the total area is 48m
2.Wherein 30cm is respectively left in thing both sides, and residue experimental plot is equally divided into five furrow, and every furrow area is 7.2m
2(long 1.8m, wide 4m), furrow and furrow interval 10cm.2. by five furrow numberings, be followed successively by from the east to the west No. 1, No. 2, No. 3, No. 4, No. 5.3. soil in five furrow is dug to 25cm, mix, then folk song is done, smashes, mixed and sieve, shift out 1/3 of whole soil, residue soil is laid in five furrow.
(2) apply fertilizer to the subsoil: puddle evenly with 80% and each processing of shifting out soil, be laid in each furrow, make every furrow fertility even.
(3) seed selection: the sorghum seeds of artificial selection high-quality with planting, is guaranteed seedling rate as test.
(4) water: five furrow are evenly irrigated with watering can, in each furrow, water consumption wants consistent.
(5) sowing: after each furrow irrigate two hours, seed is seeded in furrow uniformly, ensures each test furrow consistent in density (kind of a 1.5kg for each furrow) when sowing.
(6) cover: go out 20% of soil with the time shift of system bed and take the circumstances into consideration to cover (the about 1cm of thickness) on seed.
(7) field management: after emerging, adopt precision management, water water one time in two to three days, water the water yield and want sufficient, make each furrow management consistent.
Pilot survey
(1) this test sowing date: on October 8th, 2012, investigate room temperature, ground temperature and Chinese sorghum in the booth situation of emerging in process of the test, concrete data see the following form (greenhouse gardening field management record).
Greenhouse gardening field management record
(2), after emerging, the growing state of investigation plant is as follows:
1. plant height, root length, plant fresh weight, root fresh weight, plant dry weight and the root dry weight of investigating 100 strains, investigation result is as follows:
Each plant growing way situation of processing
Test-results
Obtain related conclusions by this test as follows:
1. respectively process growing way comparison (comprising: plant height, root are long, plant is dry, fresh weight, root are dry, fresh weight): (arranging by order from big to small)
Process four > process three > process two > process five > process one.
2. this time investigation result is as follows: amino acid multi-element biological compound organic and inorganic fertilizer (formula one proportioning one) fertilizer efficiency is best, plant growing way is best, next is biological organic fertilizer (proportioning one), the 3rd is micro-fertilizer in amino acid (proportioning one), and what fertilizer efficiency was the poorest is to add inorganic composite fertilizer.
Attached: booth soil and castor protein powder survey report
Note: above result is all calculated with wet basis.
Be understandable that, above about specific descriptions of the present invention, only for being described, the present invention is not limited to the described technical scheme of the embodiment of the present invention, those of ordinary skill in the art is to be understood that, still can modify or be equal to replacement the present invention, to reach identical technique effect; Use needs as long as meet, all within protection scope of the present invention.