CN102898740A - 聚氯乙烯防水卷材 - Google Patents
聚氯乙烯防水卷材 Download PDFInfo
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- CN102898740A CN102898740A CN2012103601449A CN201210360144A CN102898740A CN 102898740 A CN102898740 A CN 102898740A CN 2012103601449 A CN2012103601449 A CN 2012103601449A CN 201210360144 A CN201210360144 A CN 201210360144A CN 102898740 A CN102898740 A CN 102898740A
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- 239000004800 polyvinyl chloride Substances 0.000 title claims description 26
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 18
- 239000004593 Epoxy Substances 0.000 claims abstract description 9
- 229910052919 magnesium silicate Inorganic materials 0.000 claims abstract description 9
- 235000019792 magnesium silicate Nutrition 0.000 claims abstract description 9
- 239000000391 magnesium silicate Substances 0.000 claims abstract description 9
- 229920000570 polyether Polymers 0.000 claims abstract description 9
- 239000003381 stabilizer Substances 0.000 claims abstract description 9
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 claims abstract 4
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 25
- BJUPZVQSAAGZJL-UHFFFAOYSA-N 2-methyloxirane;propane-1,2,3-triol Chemical compound CC1CO1.OCC(O)CO BJUPZVQSAAGZJL-UHFFFAOYSA-N 0.000 claims description 8
- 235000010216 calcium carbonate Nutrition 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 239000000463 material Substances 0.000 abstract description 8
- 239000002253 acid Substances 0.000 abstract description 6
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 1
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 1
- 239000012188 paraffin wax Substances 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
- ZADYMNAVLSWLEQ-UHFFFAOYSA-N magnesium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[Mg+2].[Si+4] ZADYMNAVLSWLEQ-UHFFFAOYSA-N 0.000 description 5
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- -1 polyethylene Polymers 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- 206010001557 Albinism Diseases 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- TXHIDIHEXDFONW-UHFFFAOYSA-N benzene;propan-2-one Chemical compound CC(C)=O.C1=CC=CC=C1 TXHIDIHEXDFONW-UHFFFAOYSA-N 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 1
- 238000000578 dry spinning Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 238000002166 wet spinning Methods 0.000 description 1
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Abstract
聚氯乙烯防水卷材，按质量份计包括：聚氯乙烯100～150份，轻质碳酸钙20～30份，硅酸镁1～5份，环氧丙烷甘油聚醚20～30份，氯化石蜡5～8份，环氧稳定剂1～5份。本发明对现有的防水卷材成份进行改进，提供的防水卷材拉伸强度为6～7MPa，耐热温度达到90～100℃，酸碱服饰条件下不起皮不脱落，适用于电梯轿厢的包覆材料。
Description
技术领域
本发明属于防水材料技术领域，尤其涉及一种聚氯乙烯防水卷材。
背景技术
聚氯乙烯本色为微黄色半透明状，有光泽。透明度胜于聚乙烯、聚丙烯，差于聚苯乙烯，随助剂用量不同，分为软、硬聚氯乙烯，软制品柔而韧，手感粘，硬制品的硬度高于低密度聚乙烯，而低于聚丙烯，在屈折处会出现白化现象。常见制品：板材、管材、鞋底、玩具、门窗、电线外皮、文具等。是一种使用一个氯原子取代聚乙烯中的一个氢原子的高分子材料。
聚氯乙烯简称PVC，由氯乙烯在引发剂作用下聚合而成的热塑性树脂。是氯乙烯的均聚物。氯乙烯均聚物和氯乙烯共聚物统称为氯乙烯树脂。PVC为无定形结构的白色粉末，支化度较小。工业生产的PVC分子量一般在5万～12万范围内，具有较大的多分散性，分子量随聚合温度的降低而增加；无固定熔点，80～85℃开始软化，130℃变为粘弹态，160～180℃开始转变为粘流态；有较好的机械性能，抗张强度60MPa左右，冲击强度5～10kJ/m2；有优异的介电性能。但对光和热的稳定性差，在100℃以上或经长时间阳光曝晒，就会分解而产生氯化氢，并进一步自动催化分解，引起变色，物理机械性能也迅速下降，在实际应用中必须加入稳定剂以提高对热和光的稳定性。PVC很坚硬，溶解性也很差，只能溶于环己酮、二氯乙烷和四氢呋喃等少数溶剂中，对有机和无机酸、碱、盐均稳定，化学稳定性随使用温度的升高而降低。PVC溶解在丙酮-二硫化碳或丙酮－苯混合溶剂中，用于干法纺丝或湿法纺丝而成纤维，称氯纶。具有难燃、耐酸碱、抗微生物、耐磨并具有较好的保暖性和弹性。
发明内容
解决的技术问题： 本发明对现有的防水卷材成份进行改进，提供了一种拉伸强度好，耐热耐腐蚀的防水卷材，适用于电梯轿厢的包覆材料。
技术方案：聚氯乙烯防水卷材，按质量份计包括：聚氯乙烯100～150份，轻质碳酸钙 20～30份，硅酸镁 1～5份，环氧丙烷甘油聚醚20～30份，氯化石蜡 5～8份，环氧稳定剂 1～5份。
优选方案1：所述聚氯乙烯120份，轻质碳酸钙 20份，硅酸镁3份，环氧丙烷甘油聚醚25份，氯化石蜡8份，环氧稳定剂 3份。
优选方案2：所述聚氯乙烯150份，轻质碳酸钙 30份，硅酸镁 1份，环氧丙烷甘油聚醚20份，氯化石蜡 5份，环氧稳定剂 1份。
有益效果：本发明对现有的防水卷材成份进行改进，提供的防水卷材拉伸强度为6～7MPa，耐热温度达到90～100℃，酸碱服饰条件下不起皮不脱落，适用于电梯轿厢的包覆材料。
具体实施方式
实施例1：
聚氯乙烯防水卷材，按质量份计包括：聚氯乙烯120份，轻质碳酸钙 20份，硅酸镁3份，环氧丙烷甘油聚醚25份，氯化石蜡8份，环氧稳定剂 3份。
该防水卷材拉伸强度为7MPa，耐热温度达到90℃，酸碱服饰条件下不起皮不脱落，适用于电梯轿厢的包覆材料。
实施例2
聚氯乙烯防水卷材，按质量份计包括：所述聚氯乙烯150份，轻质碳酸钙 30份，硅酸镁 1份，环氧丙烷甘油聚醚20份，氯化石蜡 5份，环氧稳定剂 1份。
该防水卷材拉伸强度为6MPa，耐热温度达到100℃，酸碱服饰条件下不起皮不脱落，适用于电梯轿厢的包覆材料。
Claims (3)
1.聚氯乙烯防水卷材，其特征在于按质量份计包括：聚氯乙烯100～150份，轻质碳酸钙 20～30份，硅酸镁 1～5份，环氧丙烷甘油聚醚20～30份，氯化石蜡 5～8份，环氧稳定剂 1～5份。
2.根据权利要求1所述的聚氯乙烯防水卷材，其特征在于所述聚氯乙烯120份，轻质碳酸钙 20份，硅酸镁3份，环氧丙烷甘油聚醚25份，氯化石蜡8份，环氧稳定剂 3份。
3.根据权利要求1所述的聚氯乙烯防水卷材，其特征在于所述聚氯乙烯150份，轻质碳酸钙 30份，硅酸镁 1份，环氧丙烷甘油聚醚20份，氯化石蜡 5份，环氧稳定剂 1份。
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210360144.9A CN102898740B (zh) | 2012-09-25 | 2012-09-25 | 聚氯乙烯防水卷材 |
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| CN201210360144.9A CN102898740B (zh) | 2012-09-25 | 2012-09-25 | 聚氯乙烯防水卷材 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103589092A (zh) * | 2013-10-17 | 2014-02-19 | 天津市禹红建筑防水材料有限公司 | 一种环保型耐寒聚氯乙烯防水卷材及其制作工艺 |
| CN110919949A (zh) * | 2019-11-22 | 2020-03-27 | 安徽喜宝高分子材料有限公司 | 一种耐腐蚀防水阻燃弹性卷材的制备方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1493754A (zh) * | 2002-10-30 | 2004-05-05 | 毅 赵 | 膨胀防火包覆型（卷）材 |
| CN101578328A (zh) * | 2006-12-14 | 2009-11-11 | 路博润有限公司 | 填充的塑料材料组合物 |
| CN102131863A (zh) * | 2008-08-13 | 2011-07-20 | 路博润高级材料公司 | 填充的聚氯乙烯组合物 |
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- 2012-09-25 CN CN201210360144.9A patent/CN102898740B/zh not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1493754A (zh) * | 2002-10-30 | 2004-05-05 | 毅 赵 | 膨胀防火包覆型（卷）材 |
| CN101578328A (zh) * | 2006-12-14 | 2009-11-11 | 路博润有限公司 | 填充的塑料材料组合物 |
| CN102131863A (zh) * | 2008-08-13 | 2011-07-20 | 路博润高级材料公司 | 填充的聚氯乙烯组合物 |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103589092A (zh) * | 2013-10-17 | 2014-02-19 | 天津市禹红建筑防水材料有限公司 | 一种环保型耐寒聚氯乙烯防水卷材及其制作工艺 |
| CN103589092B (zh) * | 2013-10-17 | 2016-03-23 | 天津市禹红建筑防水材料有限公司 | 一种环保型耐寒聚氯乙烯防水卷材及其制作工艺 |
| CN110919949A (zh) * | 2019-11-22 | 2020-03-27 | 安徽喜宝高分子材料有限公司 | 一种耐腐蚀防水阻燃弹性卷材的制备方法 |
| CN110919949B (zh) * | 2019-11-22 | 2022-02-18 | 安徽喜宝高分子材料有限公司 | 一种耐腐蚀防水阻燃弹性卷材的制备方法 |
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Address after: 215213 Dachao Village, Jinjiaba Community, Lili Town, Wujiang District, Suzhou City, Jiangsu Province Patentee after: Easy Access Elevator (Suzhou) Co.,Ltd. Address before: 215213 Dachao Village, Jinjiaba Community, Lili Town, Wujiang District, Suzhou City, Jiangsu Province Patentee before: Zhongjin Intelligent Elevator (Suzhou) Co.,Ltd. Address after: 215213 Dachao Village, Jinjiaba Community, Lili Town, Wujiang District, Suzhou City, Jiangsu Province Patentee after: Zhongjin Intelligent Elevator (Suzhou) Co.,Ltd. Address before: 215213 Dachao Village, Jinjiaba Community, Lili Town, Wujiang District, Suzhou City, Jiangsu Province Patentee before: SUZHOU FENHU ELEVATOR TECHNOLOGY Co.,Ltd. |
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