CN102892751A - 由双氰胺制备环状胍的方法和含有该环状胍的涂料组合物 - Google Patents
由双氰胺制备环状胍的方法和含有该环状胍的涂料组合物 Download PDFInfo
- Publication number
- CN102892751A CN102892751A CN2011800192345A CN201180019234A CN102892751A CN 102892751 A CN102892751 A CN 102892751A CN 2011800192345 A CN2011800192345 A CN 2011800192345A CN 201180019234 A CN201180019234 A CN 201180019234A CN 102892751 A CN102892751 A CN 102892751A
- Authority
- CN
- China
- Prior art keywords
- reaction
- coating composition
- polyamines
- reaction product
- cyclic guanidine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D471/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
- C07D471/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
- C07D471/04—Ortho-condensed systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C277/00—Preparation of guanidine or its derivatives, i.e. compounds containing the group, the singly-bound nitrogen atoms not being part of nitro or nitroso groups
- C07C277/02—Preparation of guanidine or its derivatives, i.e. compounds containing the group, the singly-bound nitrogen atoms not being part of nitro or nitroso groups of guanidine from cyanamide, calcium cyanamide or dicyandiamides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/04—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
- C07D233/28—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D233/44—Nitrogen atoms not forming part of a nitro radical
- C07D233/48—Nitrogen atoms not forming part of a nitro radical with acyclic hydrocarbon or substituted acyclic hydrocarbon radicals, attached to said nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D487/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
- C07D487/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains two hetero rings
- C07D487/04—Ortho-condensed systems
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
- C08G59/4014—Nitrogen containing compounds
- C08G59/4021—Ureas; Thioureas; Guanidines; Dicyandiamides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D179/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen, or carbon only, not provided for in groups C09D161/00 - C09D177/00
- C09D179/02—Polyamines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
- C09D5/4419—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications with polymers obtained otherwise than by polymerisation reactions only involving carbon-to-carbon unsaturated bonds
- C09D5/4461—Polyamides; Polyimides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
- C09D5/4488—Cathodic paints
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Molecular Biology (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Epoxy Resins (AREA)
Abstract
Description
1–在<50次穿透到基材 |
2–在50-100次穿透 |
3–非常严重地损坏。容易刮擦至金属 |
4–仅在摩擦的区域损坏。能够刮擦至金属 |
5–在摩擦区域上损坏,能够刮擦至金属 |
6–在刮擦区域的中心均匀地损坏,困难,但是可能刮擦到金属 |
7–在摩擦区域上没有均匀的损坏,不能刮擦至金属 |
8–刮擦,非常小地损坏摩擦区域,不能刮擦至金属 |
9–轻微刮擦摩擦区域,不能刮擦至金属 |
10–没有可见损坏 |
Claims (20)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/720,971 | 2010-03-10 | ||
US12/720,971 US8288504B2 (en) | 2010-03-10 | 2010-03-10 | Method of making a cyclic guanidine from dicyandiamide and coating compositions containing same |
PCT/US2011/027567 WO2011112594A1 (en) | 2010-03-10 | 2011-03-08 | Method of making cyclic guanidine from dicyandiamide and coating compositions containing same |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102892751A true CN102892751A (zh) | 2013-01-23 |
CN102892751B CN102892751B (zh) | 2016-04-06 |
Family
ID=43877219
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201180019234.5A Active CN102892751B (zh) | 2010-03-10 | 2011-03-08 | 由双氰胺制备环状胍的方法和含有该环状胍的涂料组合物 |
Country Status (10)
Country | Link |
---|---|
US (1) | US8288504B2 (zh) |
EP (1) | EP2545031B1 (zh) |
KR (1) | KR101515273B1 (zh) |
CN (1) | CN102892751B (zh) |
CA (1) | CA2792261C (zh) |
ES (1) | ES2556775T3 (zh) |
HK (1) | HK1181032A1 (zh) |
MX (1) | MX2012010437A (zh) |
RU (1) | RU2544238C2 (zh) |
WO (1) | WO2011112594A1 (zh) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105229089A (zh) * | 2013-03-15 | 2016-01-06 | Ppg工业俄亥俄公司 | 用于含有环胍的可电沉积涂料组合物的酚类混合物 |
CN111556863A (zh) * | 2017-11-08 | 2020-08-18 | 赫尔辛基大学 | 制备双环胍及其衍生物的方法 |
CN112094273A (zh) * | 2020-08-07 | 2020-12-18 | 天津全和诚科技有限责任公司 | 一种的双环胍的合成方法 |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101885503B1 (ko) | 2009-12-24 | 2018-08-07 | 사우디 아람코 테크놀로지스 컴퍼니 | 폴리사이클릭 구아니딘 화합물의 합성방법 |
US8148490B2 (en) * | 2010-03-10 | 2012-04-03 | Ppg Industries Ohio, Inc. | Method of making a cyclic guanidine from a guanidinium salt and a weak acid and coating compositions containing the same |
CN103172639B (zh) * | 2013-03-18 | 2015-08-12 | 惠州市莱佛士制药技术有限公司 | 一种基于盐酸胍的六元二环胍的制备方法 |
US9688874B2 (en) | 2013-10-25 | 2017-06-27 | Ppg Industries Ohio, Inc. | Method of making a bicyclic guanidine-cured acrylic coating |
CN106046948A (zh) * | 2016-07-28 | 2016-10-26 | 江苏昌悦重工科技有限公司 | 一种逆变器箱 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2473111A (en) * | 1949-06-14 | Process for production of z-amino | ||
CN1218037A (zh) * | 1997-11-04 | 1999-06-02 | Basf公司 | 取代的胍衍生物的制备方法 |
CN1265392A (zh) * | 1999-02-11 | 2000-09-06 | Basf公司 | 制备胍衍生物的方法 |
US20090042060A1 (en) * | 2007-08-08 | 2009-02-12 | Zawacky Steven R | Electrodepositable coating composition containing a cyclic guanidine |
RU2381215C1 (ru) * | 2008-07-31 | 2010-02-10 | Государственное образовательное учреждение высшего профессионального образования "Ивановский государственный химико-технологический университет" (ИГХТУ) | Способ получения 2-имино-4-тиобиурета |
Family Cites Families (16)
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US3909200A (en) * | 1967-05-22 | 1975-09-30 | Petrolite Corp | Use of guanidine derived compounds as corrosion inhibitors |
US3724386A (en) * | 1970-06-24 | 1973-04-03 | Us Air Force | Ablative nose tips and method for their manufacture |
US3828122A (en) * | 1970-09-29 | 1974-08-06 | Bendix Corp | Tv area correlation tracker |
US4793867A (en) | 1986-09-26 | 1988-12-27 | Chemfil Corporation | Phosphate coating composition and method of applying a zinc-nickel phosphate coating |
BR9307434A (pt) | 1992-10-30 | 1999-06-01 | Ppg Industries Inc | Composição formadora de película carável |
TW242644B (zh) | 1992-10-30 | 1995-03-11 | Ppg Industries Inc | |
US5588989A (en) | 1994-11-23 | 1996-12-31 | Ppg Industries, Inc. | Zinc phosphate coating compositions containing oxime accelerators |
ATE305019T1 (de) | 1999-07-30 | 2005-10-15 | Ppg Ind Ohio Inc | Beschichtungszusammensetzungen mit verbesserter kratzfestigkeit und beschichtete oberflächen |
MX270896B (es) | 1999-07-30 | 2009-10-14 | Composiciones de recubrimiento que tienen una mejor resistencia a las raspaduras, sustratos recubiertos, y metodos relacionados con lo mismo. | |
US6875800B2 (en) | 2001-06-18 | 2005-04-05 | Ppg Industries Ohio, Inc. | Use of nanoparticulate organic pigments in paints and coatings |
US6894086B2 (en) | 2001-12-27 | 2005-05-17 | Ppg Industries Ohio, Inc. | Color effect compositions |
US7438972B2 (en) | 2004-06-24 | 2008-10-21 | Ppg Industries Ohio, Inc. | Nanoparticle coatings for flexible and/or drawable substrates |
US8334380B2 (en) * | 2008-05-09 | 2012-12-18 | Ppg Industries Ohio, Inc. | Method for producing bicyclic guanidines by use of a cyclic urea and a dehydrating agent |
US8039618B2 (en) * | 2008-05-09 | 2011-10-18 | Ppg Industries Ohio, Inc. | Method for producing bicyclic guanidines by use of a cyclic urea |
US8492542B2 (en) * | 2008-05-15 | 2013-07-23 | Ppg Industries Ohio, Inc. | Method for producing bicyclic guanidines by use of a cyclic thiourea |
KR101885503B1 (ko) | 2009-12-24 | 2018-08-07 | 사우디 아람코 테크놀로지스 컴퍼니 | 폴리사이클릭 구아니딘 화합물의 합성방법 |
-
2010
- 2010-03-10 US US12/720,971 patent/US8288504B2/en active Active
-
2011
- 2011-03-08 CN CN201180019234.5A patent/CN102892751B/zh active Active
- 2011-03-08 WO PCT/US2011/027567 patent/WO2011112594A1/en active Application Filing
- 2011-03-08 ES ES11712075.8T patent/ES2556775T3/es active Active
- 2011-03-08 KR KR1020127026353A patent/KR101515273B1/ko active IP Right Grant
- 2011-03-08 EP EP11712075.8A patent/EP2545031B1/en active Active
- 2011-03-08 MX MX2012010437A patent/MX2012010437A/es active IP Right Grant
- 2011-03-08 CA CA2792261A patent/CA2792261C/en active Active
- 2011-03-08 RU RU2012143203/04A patent/RU2544238C2/ru active
-
2013
- 2013-07-12 HK HK13108221.9A patent/HK1181032A1/zh unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2473111A (en) * | 1949-06-14 | Process for production of z-amino | ||
CN1218037A (zh) * | 1997-11-04 | 1999-06-02 | Basf公司 | 取代的胍衍生物的制备方法 |
CN1265392A (zh) * | 1999-02-11 | 2000-09-06 | Basf公司 | 制备胍衍生物的方法 |
US20090042060A1 (en) * | 2007-08-08 | 2009-02-12 | Zawacky Steven R | Electrodepositable coating composition containing a cyclic guanidine |
RU2381215C1 (ru) * | 2008-07-31 | 2010-02-10 | Государственное образовательное учреждение высшего профессионального образования "Ивановский государственный химико-технологический университет" (ИГХТУ) | Способ получения 2-имино-4-тиобиурета |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105229089A (zh) * | 2013-03-15 | 2016-01-06 | Ppg工业俄亥俄公司 | 用于含有环胍的可电沉积涂料组合物的酚类混合物 |
CN111556863A (zh) * | 2017-11-08 | 2020-08-18 | 赫尔辛基大学 | 制备双环胍及其衍生物的方法 |
CN111556863B (zh) * | 2017-11-08 | 2023-05-02 | 赫尔辛基大学 | 制备双环胍及其衍生物的方法 |
CN112094273A (zh) * | 2020-08-07 | 2020-12-18 | 天津全和诚科技有限责任公司 | 一种的双环胍的合成方法 |
Also Published As
Publication number | Publication date |
---|---|
EP2545031A1 (en) | 2013-01-16 |
EP2545031B1 (en) | 2015-11-25 |
US8288504B2 (en) | 2012-10-16 |
RU2012143203A (ru) | 2014-04-20 |
WO2011112594A1 (en) | 2011-09-15 |
RU2544238C2 (ru) | 2015-03-20 |
US20110224403A1 (en) | 2011-09-15 |
ES2556775T3 (es) | 2016-01-20 |
KR20120132543A (ko) | 2012-12-05 |
MX2012010437A (es) | 2013-06-18 |
CA2792261C (en) | 2015-12-01 |
CA2792261A1 (en) | 2011-09-15 |
CN102892751B (zh) | 2016-04-06 |
KR101515273B1 (ko) | 2015-04-24 |
HK1181032A1 (zh) | 2013-11-01 |
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Application publication date: 20130123 Assignee: PPG coatings (Zhangjiagang) Co., Ltd. Assignor: PPG Industries, Inc. Contract record no.: 2017990000077 Denomination of invention: Method of making cyclic guanidine from dicyandiamide and coating compositions containing same Granted publication date: 20160406 License type: Common License Record date: 20170310 Application publication date: 20130123 Assignee: Czech coatings (Wuhu) Co., Ltd. Assignor: PPG Industries, Inc. Contract record no.: 2017990000079 Denomination of invention: Method of making cyclic guanidine from dicyandiamide and coating compositions containing same Granted publication date: 20160406 License type: Common License Record date: 20170310 |
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Application publication date: 20130123 Assignee: PPG Ind Ohio Inc. Assignor: PPG Industries, Inc. Contract record no.: 2017990000096 Denomination of invention: Method of making cyclic guanidine from dicyandiamide and coating compositions containing same Granted publication date: 20160406 License type: Common License Record date: 20170329 |