CN102832414B - 胶体电解质混合装置、胶体电解质及其制备方法 - Google Patents
胶体电解质混合装置、胶体电解质及其制备方法 Download PDFInfo
- Publication number
- CN102832414B CN102832414B CN201110157070.4A CN201110157070A CN102832414B CN 102832414 B CN102832414 B CN 102832414B CN 201110157070 A CN201110157070 A CN 201110157070A CN 102832414 B CN102832414 B CN 102832414B
- Authority
- CN
- China
- Prior art keywords
- colloidal electrolyte
- storage battery
- sulfuric acid
- tank body
- nano silicon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003792 electrolyte Substances 0.000 title claims abstract description 94
- 238000002156 mixing Methods 0.000 title abstract description 32
- 238000002360 preparation method Methods 0.000 title abstract description 9
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 78
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 33
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 16
- 235000019795 sodium metasilicate Nutrition 0.000 claims abstract description 16
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 16
- 239000001509 sodium citrate Substances 0.000 claims abstract description 15
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 claims abstract description 15
- 229940038773 trisodium citrate Drugs 0.000 claims abstract description 15
- 239000002245 particle Substances 0.000 claims description 3
- 230000008901 benefit Effects 0.000 abstract description 6
- 238000002474 experimental method Methods 0.000 abstract description 2
- 239000000463 material Substances 0.000 description 22
- 230000000052 comparative effect Effects 0.000 description 20
- 239000002994 raw material Substances 0.000 description 18
- 238000003756 stirring Methods 0.000 description 17
- 238000000034 method Methods 0.000 description 16
- 239000000203 mixture Substances 0.000 description 13
- 239000002253 acid Substances 0.000 description 12
- 238000007599 discharging Methods 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
- 238000005516 engineering process Methods 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- 238000011056 performance test Methods 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 238000004945 emulsification Methods 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 239000003381 stabilizer Substances 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 239000000084 colloidal system Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000011149 active material Substances 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229920002401 polyacrylamide Polymers 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 238000013517 stratification Methods 0.000 description 2
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000006664 bond formation reaction Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000009194 climbing Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- -1 there are cheap Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Battery Electrode And Active Subsutance (AREA)
- Silicon Compounds (AREA)
- Secondary Cells (AREA)
Abstract
Description
Claims (3)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201110157070.4A CN102832414B (zh) | 2011-06-13 | 2011-06-13 | 胶体电解质混合装置、胶体电解质及其制备方法 |
CN201410255443.5A CN104001444B (zh) | 2011-06-13 | 2011-06-13 | 胶体电解质混合装置、胶体电解质及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201110157070.4A CN102832414B (zh) | 2011-06-13 | 2011-06-13 | 胶体电解质混合装置、胶体电解质及其制备方法 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201410255443.5A Division CN104001444B (zh) | 2011-06-13 | 2011-06-13 | 胶体电解质混合装置、胶体电解质及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102832414A CN102832414A (zh) | 2012-12-19 |
CN102832414B true CN102832414B (zh) | 2015-07-29 |
Family
ID=47335445
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201110157070.4A Expired - Fee Related CN102832414B (zh) | 2011-06-13 | 2011-06-13 | 胶体电解质混合装置、胶体电解质及其制备方法 |
CN201410255443.5A Expired - Fee Related CN104001444B (zh) | 2011-06-13 | 2011-06-13 | 胶体电解质混合装置、胶体电解质及其制备方法 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201410255443.5A Expired - Fee Related CN104001444B (zh) | 2011-06-13 | 2011-06-13 | 胶体电解质混合装置、胶体电解质及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (2) | CN102832414B (zh) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105186047B (zh) * | 2015-06-25 | 2017-06-16 | 天能集团江苏科技有限公司 | 一种高性能铅酸电池胶体电解液及其制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1978507A (zh) * | 2006-11-24 | 2007-06-13 | 江苏鑫华富能源有限公司 | 铅酸蓄电池用高分子纳米聚合物电解液及其配制方法 |
CN101504987A (zh) * | 2009-03-10 | 2009-08-12 | 于文学 | 电动汽车用高容量铅酸蓄电池的纳米硅胶体电解质 |
CN101740818A (zh) * | 2008-11-13 | 2010-06-16 | 中国科学院合肥物质科学研究院 | 铅酸蓄电池胶体电解液及其制备方法 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN2813091Y (zh) * | 2005-06-08 | 2006-09-06 | 周凤举 | 内置冷激式导流筒的上轴流搅拌反应釜 |
CN201543418U (zh) * | 2009-10-22 | 2010-08-11 | 中国石油天然气股份有限公司 | 一种内循环超重力反应装置 |
CN201832626U (zh) * | 2010-10-15 | 2011-05-18 | 中国石油化工股份有限公司 | 一种自吸式气液反应器 |
CN102013521B (zh) * | 2010-10-27 | 2013-08-07 | 华南师范大学 | 一种用于铅酸蓄电池中的硅混溶胶胶体电解液 |
-
2011
- 2011-06-13 CN CN201110157070.4A patent/CN102832414B/zh not_active Expired - Fee Related
- 2011-06-13 CN CN201410255443.5A patent/CN104001444B/zh not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1978507A (zh) * | 2006-11-24 | 2007-06-13 | 江苏鑫华富能源有限公司 | 铅酸蓄电池用高分子纳米聚合物电解液及其配制方法 |
CN101740818A (zh) * | 2008-11-13 | 2010-06-16 | 中国科学院合肥物质科学研究院 | 铅酸蓄电池胶体电解液及其制备方法 |
CN101504987A (zh) * | 2009-03-10 | 2009-08-12 | 于文学 | 电动汽车用高容量铅酸蓄电池的纳米硅胶体电解质 |
Also Published As
Publication number | Publication date |
---|---|
CN104001444B (zh) | 2016-03-23 |
CN104001444A (zh) | 2014-08-27 |
CN102832414A (zh) | 2012-12-19 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN104900876B (zh) | 一种铅酸蓄电池用新型石墨烯负极活性物质及其制备方法 | |
CN102201575B (zh) | 一种硫酸铅-石墨烯复合电极材料及包含其的铅酸电池负极铅膏 | |
CN103000882B (zh) | 一种铅碳电池负极铅膏及其制备方法 | |
CN104795541B (zh) | 一种锂离子电池负极浆料制备方法 | |
CN105428614B (zh) | 一种氮元素掺杂多孔复合负极材料及其制备方法 | |
CN103367753B (zh) | 一种石墨烯分散液改性的铅酸电池负极铅膏及其制备方法 | |
CN106684329A (zh) | 一种锂离子电池正极浆料的分散方法 | |
CN103794798B (zh) | 一种电池负极浆料及制备方法 | |
CN103413976B (zh) | 一种高性能动力型蓄电池及其制备方法 | |
CN103456931B (zh) | 基于高强度氧化石墨烯凝胶的铅炭电池负极材料的制备方法 | |
CN107887591A (zh) | 提高铅酸蓄电池正极板栅与铅膏结合力的铅膏和膏及其制备方法 | |
CN106374095A (zh) | 一种作为锂硫电池正极材料的复合材料的制备方法 | |
CN102412421B (zh) | 一种铅酸蓄电池电解液的制备方法 | |
CN107069017B (zh) | 一种纳米硅基二次颗粒的制备方法 | |
CN103943881B (zh) | 一种铅钙内化成胶体电解液及其制备方法 | |
CN106684343A (zh) | 一种钛酸锂/碳复合材料及其制备方法和锂离子电池 | |
CN101740818B (zh) | 铅酸蓄电池胶体电解液及其制备方法 | |
CN107978749A (zh) | 一种锂离子电池正极材料浆料及其制备方法 | |
CN105428704B (zh) | 一种改性氧化还原型固态电解质及其制备方法和应用 | |
CN102832414B (zh) | 胶体电解质混合装置、胶体电解质及其制备方法 | |
CN107863500A (zh) | 一种纯铅铅炭电池的制备方法及纯铅铅炭电池 | |
CN101242006A (zh) | 一种铅酸蓄电池用胶体电解质 | |
CN103633331A (zh) | 一种铅酸动力电池用正极活性物质及其制备方法 | |
CN103418300B (zh) | 用于锂离子电池制造的搅拌装置的搅拌工艺 | |
CN203469902U (zh) | 用于锂离子电池制造的搅拌装置 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C53 | Correction of patent of invention or patent application | ||
CB03 | Change of inventor or designer information |
Inventor after: Liu Peng Inventor after: Zhao Hengxiang Inventor after: Pan Yuepeng Inventor after: Yu Guiling Inventor after: Liu Yi Inventor before: Liu Yi Inventor before: Zhao Hengxiang Inventor after: Liu Peng Inventor after: Zhao Hengxiang Inventor after: Pan Yuepeng Inventor after: Yu Guiling Inventor after: Liu Yi Inventor before: Liu Yi Inventor before: Zhao Hengxiang |
|
COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: LIU YI ZHAO HENGXIANG TO: LIU PENG ZHAO HENGXIANG PAN YUEPENG YU GUILING LIU YI |
|
C53 | Correction of patent of invention or patent application | ||
CB03 | Change of inventor or designer information |
Inventor after: Zhao Hengxiang Inventor before: Liu Peng Inventor before: Zhao Hengxiang Inventor before: Pan Yuepeng Inventor before: Yu Guiling Inventor before: Liu Yi Inventor after: Zhao Hengxiang Inventor before: Liu Peng Inventor before: Zhao Hengxiang Inventor before: Pan Yuepeng Inventor before: Yu Guiling Inventor before: Liu Yi |
|
COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: LIU PENG ZHAO HENGXIANG PAN YUEPENG YU GUILING LIU YI TO: ZHAO HENGXIANG |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150729 Termination date: 20190613 |
|
CF01 | Termination of patent right due to non-payment of annual fee |