CN102816405A - 一种低烟无卤阻燃热塑性弹性体及其制备方法 - Google Patents
一种低烟无卤阻燃热塑性弹性体及其制备方法 Download PDFInfo
- Publication number
- CN102816405A CN102816405A CN2012103130277A CN201210313027A CN102816405A CN 102816405 A CN102816405 A CN 102816405A CN 2012103130277 A CN2012103130277 A CN 2012103130277A CN 201210313027 A CN201210313027 A CN 201210313027A CN 102816405 A CN102816405 A CN 102816405A
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- Prior art keywords
- thermoplastic elastomer
- low
- retardant
- flame
- free flame
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 59
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 51
- 229920002725 thermoplastic elastomer Polymers 0.000 title claims abstract description 32
- 239000000779 smoke Substances 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title abstract description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 24
- 150000001875 compounds Chemical class 0.000 claims abstract description 12
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 12
- 229920005989 resin Polymers 0.000 claims abstract description 10
- 239000011347 resin Substances 0.000 claims abstract description 10
- 239000000654 additive Substances 0.000 claims abstract description 8
- 229920001971 elastomer Polymers 0.000 claims abstract description 8
- 230000000996 additive effect Effects 0.000 claims abstract description 7
- 239000000806 elastomer Substances 0.000 claims abstract description 7
- 229920000098 polyolefin Polymers 0.000 claims abstract description 7
- 239000002689 soil Substances 0.000 claims abstract description 6
- 238000001125 extrusion Methods 0.000 claims abstract description 3
- 238000004898 kneading Methods 0.000 claims abstract description 3
- 239000002994 raw material Substances 0.000 claims abstract description 3
- 239000000463 material Substances 0.000 claims description 10
- 238000005984 hydrogenation reaction Methods 0.000 claims description 8
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 6
- 229920006380 polyphenylene oxide Polymers 0.000 claims description 6
- 150000003440 styrenes Chemical class 0.000 claims description 6
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 239000008188 pellet Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical group NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 claims description 3
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 150000001336 alkenes Chemical group 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- 229920001400 block copolymer Polymers 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 229940125773 compound 10 Drugs 0.000 claims description 2
- 229940125782 compound 2 Drugs 0.000 claims description 2
- 238000007334 copolymerization reaction Methods 0.000 claims description 2
- 230000004927 fusion Effects 0.000 claims description 2
- ZLVXBBHTMQJRSX-VMGNSXQWSA-N jdtic Chemical compound C1([C@]2(C)CCN(C[C@@H]2C)C[C@H](C(C)C)NC(=O)[C@@H]2NCC3=CC(O)=CC=C3C2)=CC=CC(O)=C1 ZLVXBBHTMQJRSX-VMGNSXQWSA-N 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims description 2
- 230000004048 modification Effects 0.000 claims description 2
- 238000012856 packing Methods 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 2
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 2
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 229920000642 polymer Polymers 0.000 abstract description 2
- 238000004064 recycling Methods 0.000 abstract description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 abstract 1
- 238000010276 construction Methods 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 239000008187 granular material Substances 0.000 abstract 1
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 1
- 239000011707 mineral Substances 0.000 abstract 1
- 239000003921 oil Substances 0.000 abstract 1
- 229920013636 polyphenyl ether polymer Polymers 0.000 abstract 1
- 150000003377 silicon compounds Chemical class 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 7
- 235000019504 cigarettes Nutrition 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 239000003340 retarding agent Substances 0.000 description 4
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000002341 toxic gas Substances 0.000 description 2
- 229920002449 FKM Polymers 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012757 flame retardant agent Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
Abstract
Description
Claims (10)
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CN201210313027.7A CN102816405B (zh) | 2012-08-30 | 2012-08-30 | 一种低烟无卤阻燃热塑性弹性体及其制备方法 |
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CN201210313027.7A CN102816405B (zh) | 2012-08-30 | 2012-08-30 | 一种低烟无卤阻燃热塑性弹性体及其制备方法 |
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CN102816405A true CN102816405A (zh) | 2012-12-12 |
CN102816405B CN102816405B (zh) | 2014-12-24 |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104893299A (zh) * | 2015-07-06 | 2015-09-09 | 刘雷 | 聚丙烯用有机硅阻燃剂及其制备方法 |
CN105111556A (zh) * | 2015-09-14 | 2015-12-02 | 宁波聚泰新材料科技有限公司 | 一种电动汽车充电桩电缆用热塑性弹性体及其制备方法 |
CN105153705A (zh) * | 2015-07-03 | 2015-12-16 | 东至天孚化工有限公司 | 基于有机硅橡胶废料的有机硅-聚酯组合物及方法 |
CN105295216A (zh) * | 2015-06-26 | 2016-02-03 | 山东泰瑞丰新材料有限公司 | 抗疲劳、耐温免充气胎用热塑性弹性体材料及其制备方法 |
CN114369328A (zh) * | 2021-11-18 | 2022-04-19 | 宁波聚泰新材料科技有限公司 | 一种低烟耐老化交联弹性体及其制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101358028A (zh) * | 2008-09-02 | 2009-02-04 | 宁波一舟塑胶有限公司 | 以聚苯醚为基料的无卤阻燃热塑性弹性体电缆料及其制备方法 |
CN101578334A (zh) * | 2007-01-09 | 2009-11-11 | 住友电气工业株式会社 | 无卤阻燃树脂复合材料以及采用该复合材料的电线和电缆 |
CN101831134A (zh) * | 2010-05-10 | 2010-09-15 | 宁波市青湖弹性体科技有限公司 | 电线电缆覆盖材料用热塑性无卤阻燃弹性体组合物 |
CN102585428A (zh) * | 2012-03-15 | 2012-07-18 | 浙江北化阻燃材料有限公司 | 一种柔性无卤阻燃聚苯醚电线电缆护套料及其制备方法 |
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2012
- 2012-08-30 CN CN201210313027.7A patent/CN102816405B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101578334A (zh) * | 2007-01-09 | 2009-11-11 | 住友电气工业株式会社 | 无卤阻燃树脂复合材料以及采用该复合材料的电线和电缆 |
CN101358028A (zh) * | 2008-09-02 | 2009-02-04 | 宁波一舟塑胶有限公司 | 以聚苯醚为基料的无卤阻燃热塑性弹性体电缆料及其制备方法 |
CN101831134A (zh) * | 2010-05-10 | 2010-09-15 | 宁波市青湖弹性体科技有限公司 | 电线电缆覆盖材料用热塑性无卤阻燃弹性体组合物 |
CN102585428A (zh) * | 2012-03-15 | 2012-07-18 | 浙江北化阻燃材料有限公司 | 一种柔性无卤阻燃聚苯醚电线电缆护套料及其制备方法 |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105295216A (zh) * | 2015-06-26 | 2016-02-03 | 山东泰瑞丰新材料有限公司 | 抗疲劳、耐温免充气胎用热塑性弹性体材料及其制备方法 |
CN105295216B (zh) * | 2015-06-26 | 2018-04-10 | 山东泰瑞丰新材料有限公司 | 抗疲劳、耐温免充气胎用热塑性弹性体材料及其制备方法 |
CN105153705A (zh) * | 2015-07-03 | 2015-12-16 | 东至天孚化工有限公司 | 基于有机硅橡胶废料的有机硅-聚酯组合物及方法 |
CN104893299A (zh) * | 2015-07-06 | 2015-09-09 | 刘雷 | 聚丙烯用有机硅阻燃剂及其制备方法 |
CN104893299B (zh) * | 2015-07-06 | 2017-11-14 | 山东龙程矿业科技股份有限公司 | 聚丙烯用有机硅阻燃剂及其制备方法 |
CN105111556A (zh) * | 2015-09-14 | 2015-12-02 | 宁波聚泰新材料科技有限公司 | 一种电动汽车充电桩电缆用热塑性弹性体及其制备方法 |
CN114369328A (zh) * | 2021-11-18 | 2022-04-19 | 宁波聚泰新材料科技有限公司 | 一种低烟耐老化交联弹性体及其制备方法 |
CN114369328B (zh) * | 2021-11-18 | 2023-12-19 | 宁波聚泰新材料科技有限公司 | 一种低烟耐老化交联弹性体及其制备方法 |
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Inventor after: Ying Jiarong Inventor before: Xiang Saifei |
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Denomination of invention: The invention relates to a low smoke halogen-free flame retardant thermoplastic elastomer and a preparation method thereof Effective date of registration: 20211126 Granted publication date: 20141224 Pledgee: Ningbo Tianjin Enterprise Service Co.,Ltd. Pledgor: NINGBO POLYTEC NEW MATERIALS TECHNOLOGY Co.,Ltd. Registration number: Y2021330002376 |
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Denomination of invention: Low smoke halogen-free flame retardant thermoplastic elastomer and its preparation method Effective date of registration: 20221226 Granted publication date: 20141224 Pledgee: Ningbo Tianjin Enterprise Service Co.,Ltd. Pledgor: NINGBO POLYTEC NEW MATERIALS TECHNOLOGY Co.,Ltd. Registration number: Y2022980029173 |
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