CN102762509B - 低熔点玻璃组合物及使用其的导电性糊剂材料 - Google Patents
低熔点玻璃组合物及使用其的导电性糊剂材料 Download PDFInfo
- Publication number
- CN102762509B CN102762509B CN201180009596.6A CN201180009596A CN102762509B CN 102762509 B CN102762509 B CN 102762509B CN 201180009596 A CN201180009596 A CN 201180009596A CN 102762509 B CN102762509 B CN 102762509B
- Authority
- CN
- China
- Prior art keywords
- glass
- solar cell
- conductive paste
- semiconductor substrate
- zno
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000011521 glass Substances 0.000 title claims abstract description 61
- 239000000203 mixture Substances 0.000 title claims description 17
- 238000002844 melting Methods 0.000 title description 12
- 230000008018 melting Effects 0.000 title description 12
- 239000000463 material Substances 0.000 title description 11
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 29
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 29
- 239000010703 silicon Substances 0.000 claims abstract description 29
- 238000003723 Smelting Methods 0.000 claims abstract description 9
- 229910004298 SiO 2 Inorganic materials 0.000 claims abstract description 6
- 239000000758 substrate Substances 0.000 claims description 26
- 239000004065 semiconductor Substances 0.000 claims description 23
- 229910052782 aluminium Inorganic materials 0.000 claims description 20
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 19
- 239000004411 aluminium Substances 0.000 claims description 17
- 239000000843 powder Substances 0.000 claims description 16
- 239000012776 electronic material Substances 0.000 claims description 3
- 239000008012 organic excipient Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000013078 crystal Substances 0.000 abstract description 5
- 230000000694 effects Effects 0.000 description 8
- 230000006978 adaptation Effects 0.000 description 6
- 239000001856 Ethyl cellulose Substances 0.000 description 3
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000003667 anti-reflective effect Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000004939 coking Methods 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 229920001249 ethyl cellulose Polymers 0.000 description 3
- 235000019325 ethyl cellulose Nutrition 0.000 description 3
- 238000007496 glass forming Methods 0.000 description 3
- 230000001771 impaired effect Effects 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- 239000004594 Masterbatch (MB) Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000007650 screen-printing Methods 0.000 description 2
- WUOACPNHFRMFPN-SECBINFHSA-N (S)-(-)-alpha-terpineol Chemical compound CC1=CC[C@@H](C(C)(C)O)CC1 WUOACPNHFRMFPN-SECBINFHSA-N 0.000 description 1
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- 229910002796 Si–Al Inorganic materials 0.000 description 1
- 229910006404 SnO 2 Inorganic materials 0.000 description 1
- OVKDFILSBMEKLT-UHFFFAOYSA-N alpha-Terpineol Natural products CC(=C)C1(O)CCC(C)=CC1 OVKDFILSBMEKLT-UHFFFAOYSA-N 0.000 description 1
- 229940088601 alpha-terpineol Drugs 0.000 description 1
- 150000001398 aluminium Chemical class 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 238000004299 exfoliation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000002076 thermal analysis method Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/14—Conductive material dispersed in non-conductive inorganic material
- H01B1/16—Conductive material dispersed in non-conductive inorganic material the conductive material comprising metals or alloys
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/02—Details
- H01L31/0224—Electrodes
- H01L31/022408—Electrodes for devices characterised by at least one potential jump barrier or surface barrier
- H01L31/022425—Electrodes for devices characterised by at least one potential jump barrier or surface barrier for solar cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Physics & Mathematics (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Sustainable Energy (AREA)
- General Chemical & Material Sciences (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Electromagnetism (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Glass Compositions (AREA)
- Conductive Materials (AREA)
- Photovoltaic Devices (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010073963A JP5569094B2 (ja) | 2010-03-28 | 2010-03-28 | 低融点ガラス組成物及びそれを用いた導電性ペースト材料 |
| JP2010-073963 | 2010-03-28 | ||
| PCT/JP2011/056526 WO2011122369A1 (ja) | 2010-03-28 | 2011-03-18 | 低融点ガラス組成物及びそれを用いた導電性ペースト材料 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102762509A CN102762509A (zh) | 2012-10-31 |
| CN102762509B true CN102762509B (zh) | 2015-11-25 |
Family
ID=44712080
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201180009596.6A Expired - Fee Related CN102762509B (zh) | 2010-03-28 | 2011-03-18 | 低熔点玻璃组合物及使用其的导电性糊剂材料 |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP5569094B2 (ja) |
| CN (1) | CN102762509B (ja) |
| TW (1) | TWI469944B (ja) |
| WO (1) | WO2011122369A1 (ja) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5888493B2 (ja) * | 2011-02-10 | 2016-03-22 | セントラル硝子株式会社 | 導電性ペースト及び該導電性ペーストを用いた太陽電池素子 |
| CN103915127B (zh) * | 2013-01-03 | 2017-05-24 | 上海匡宇科技股份有限公司 | 用于表面高方阻硅基太阳能电池正面银浆及其制备方法 |
| JP6398351B2 (ja) * | 2013-07-25 | 2018-10-03 | セントラル硝子株式会社 | 蛍光体分散ガラス |
| EP3134903B1 (de) * | 2014-04-25 | 2019-06-12 | CeramTec GmbH | Aluminiumpaste für dickfilmhybride |
| CN104402234B (zh) * | 2014-11-13 | 2016-09-21 | 海安建海新能源有限公司 | 晶体硅太阳能电池正面银浆用玻璃粉及其制备方法 |
| CN110550864B (zh) * | 2019-09-29 | 2022-09-02 | 长沙新材料产业研究院有限公司 | 一种低膨胀系数绝缘介质浆料及其制备方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007070196A (ja) * | 2005-09-09 | 2007-03-22 | Central Glass Co Ltd | 無鉛低融点ガラス |
| CN101483207A (zh) * | 2009-01-07 | 2009-07-15 | 范琳 | 一种环保型硅太阳能电池正面栅线电极银导体浆料 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6029654B2 (ja) * | 1979-08-29 | 1985-07-11 | 株式会社日立製作所 | 磁気ヘッドの製造方法 |
| JP3534684B2 (ja) * | 2000-07-10 | 2004-06-07 | Ｔｄｋ株式会社 | 導電ペーストおよび外部電極とその製造方法 |
| DE60318517T2 (de) * | 2002-04-24 | 2009-07-23 | Central Glass Co., Ltd., Ube | Bleifreies niedrigschmelzendes Glas |
| EP1993144A4 (en) * | 2006-03-07 | 2011-05-11 | Murata Manufacturing Co | CONDUCTIVE PASTE AND SOLAR CELL |
| JP2011502345A (ja) * | 2007-10-18 | 2011-01-20 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 伝導性組成物、および半導体デバイスの製造における使用方法：複数の母線 |
-
2010
- 2010-03-28 JP JP2010073963A patent/JP5569094B2/ja not_active Expired - Fee Related
-
2011
- 2011-03-18 CN CN201180009596.6A patent/CN102762509B/zh not_active Expired - Fee Related
- 2011-03-18 WO PCT/JP2011/056526 patent/WO2011122369A1/ja active Application Filing
- 2011-03-25 TW TW100110466A patent/TWI469944B/zh not_active IP Right Cessation
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007070196A (ja) * | 2005-09-09 | 2007-03-22 | Central Glass Co Ltd | 無鉛低融点ガラス |
| CN101483207A (zh) * | 2009-01-07 | 2009-07-15 | 范琳 | 一种环保型硅太阳能电池正面栅线电极银导体浆料 |
Also Published As
| Publication number | Publication date |
|---|---|
| TW201141809A (en) | 2011-12-01 |
| JP5569094B2 (ja) | 2014-08-13 |
| WO2011122369A1 (ja) | 2011-10-06 |
| CN102762509A (zh) | 2012-10-31 |
| TWI469944B (zh) | 2015-01-21 |
| JP2011207629A (ja) | 2011-10-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20151125 Termination date: 20210318 |