TWI469944B - A low melting point glass composition and a conductive paste material using the same - Google Patents
A low melting point glass composition and a conductive paste material using the same Download PDFInfo
- Publication number
- TWI469944B TWI469944B TW100110466A TW100110466A TWI469944B TW I469944 B TWI469944 B TW I469944B TW 100110466 A TW100110466 A TW 100110466A TW 100110466 A TW100110466 A TW 100110466A TW I469944 B TWI469944 B TW I469944B
- Authority
- TW
- Taiwan
- Prior art keywords
- glass
- lead
- conductive paste
- melting glass
- layer
- Prior art date
Links
- 239000011521 glass Substances 0.000 title claims description 59
- 238000002844 melting Methods 0.000 title claims description 21
- 239000000203 mixture Substances 0.000 title claims description 9
- 230000008018 melting Effects 0.000 title claims description 6
- 239000000463 material Substances 0.000 title description 8
- 239000004065 semiconductor Substances 0.000 claims description 22
- 239000000758 substrate Substances 0.000 claims description 22
- 229910052732 germanium Inorganic materials 0.000 claims description 16
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 16
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 9
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 5
- 229910018068 Li 2 O Inorganic materials 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000012776 electronic material Substances 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 20
- 229910052782 aluminium Inorganic materials 0.000 description 17
- 230000000694 effects Effects 0.000 description 7
- 239000000843 powder Substances 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 239000001856 Ethyl cellulose Substances 0.000 description 3
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 229910021419 crystalline silicon Inorganic materials 0.000 description 3
- 229920001249 ethyl cellulose Polymers 0.000 description 3
- 235000019325 ethyl cellulose Nutrition 0.000 description 3
- 238000007496 glass forming Methods 0.000 description 3
- 230000001771 impaired effect Effects 0.000 description 3
- 239000000523 sample Substances 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- WUOACPNHFRMFPN-SECBINFHSA-N (S)-(-)-alpha-terpineol Chemical compound CC1=CC[C@@H](C(C)(C)O)CC1 WUOACPNHFRMFPN-SECBINFHSA-N 0.000 description 1
- VXQBJTKSVGFQOL-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethyl acetate Chemical compound CCCCOCCOCCOC(C)=O VXQBJTKSVGFQOL-UHFFFAOYSA-N 0.000 description 1
- 229910015902 Bi 2 O 3 Inorganic materials 0.000 description 1
- 229910006404 SnO 2 Inorganic materials 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- OVKDFILSBMEKLT-UHFFFAOYSA-N alpha-Terpineol Natural products CC(=C)C1(O)CCC(C)=CC1 OVKDFILSBMEKLT-UHFFFAOYSA-N 0.000 description 1
- 229940088601 alpha-terpineol Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- MZLGASXMSKOWSE-UHFFFAOYSA-N tantalum nitride Chemical compound [Ta]#N MZLGASXMSKOWSE-UHFFFAOYSA-N 0.000 description 1
- 238000002076 thermal analysis method Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/14—Conductive material dispersed in non-conductive inorganic material
- H01B1/16—Conductive material dispersed in non-conductive inorganic material the conductive material comprising metals or alloys
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/02—Details
- H01L31/0224—Electrodes
- H01L31/022408—Electrodes for devices characterised by at least one potential jump barrier or surface barrier
- H01L31/022425—Electrodes for devices characterised by at least one potential jump barrier or surface barrier for solar cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Physics & Mathematics (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Sustainable Energy (AREA)
- General Chemical & Material Sciences (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Electromagnetism (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Glass Compositions (AREA)
- Conductive Materials (AREA)
- Photovoltaic Devices (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010073963A JP5569094B2 (ja) | 2010-03-28 | 2010-03-28 | 低融点ガラス組成物及びそれを用いた導電性ペースト材料 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201141809A TW201141809A (en) | 2011-12-01 |
| TWI469944B true TWI469944B (zh) | 2015-01-21 |
Family
ID=44712080
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW100110466A TWI469944B (zh) | 2010-03-28 | 2011-03-25 | A low melting point glass composition and a conductive paste material using the same |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP5569094B2 (ja) |
| CN (1) | CN102762509B (ja) |
| TW (1) | TWI469944B (ja) |
| WO (1) | WO2011122369A1 (ja) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5888493B2 (ja) * | 2011-02-10 | 2016-03-22 | セントラル硝子株式会社 | 導電性ペースト及び該導電性ペーストを用いた太陽電池素子 |
| CN103915127B (zh) * | 2013-01-03 | 2017-05-24 | 上海匡宇科技股份有限公司 | 用于表面高方阻硅基太阳能电池正面银浆及其制备方法 |
| JP6398351B2 (ja) * | 2013-07-25 | 2018-10-03 | セントラル硝子株式会社 | 蛍光体分散ガラス |
| EP3134903B1 (de) * | 2014-04-25 | 2019-06-12 | CeramTec GmbH | Aluminiumpaste für dickfilmhybride |
| CN104402234B (zh) * | 2014-11-13 | 2016-09-21 | 海安建海新能源有限公司 | 晶体硅太阳能电池正面银浆用玻璃粉及其制备方法 |
| CN110550864B (zh) * | 2019-09-29 | 2022-09-02 | 长沙新材料产业研究院有限公司 | 一种低膨胀系数绝缘介质浆料及其制备方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030228471A1 (en) * | 2002-04-24 | 2003-12-11 | Central Glass Company, Limited | Lead-free low-melting glass |
| US20080314444A1 (en) * | 2006-03-07 | 2008-12-25 | Murata Manufacturing Co., Ltd. | Electrically conductive paste and solar cell |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6029654B2 (ja) * | 1979-08-29 | 1985-07-11 | 株式会社日立製作所 | 磁気ヘッドの製造方法 |
| JP3534684B2 (ja) * | 2000-07-10 | 2004-06-07 | Ｔｄｋ株式会社 | 導電ペーストおよび外部電極とその製造方法 |
| JP2007070196A (ja) * | 2005-09-09 | 2007-03-22 | Central Glass Co Ltd | 無鉛低融点ガラス |
| JP2011502345A (ja) * | 2007-10-18 | 2011-01-20 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 伝導性組成物、および半導体デバイスの製造における使用方法：複数の母線 |
| CN101483207B (zh) * | 2009-01-07 | 2013-02-13 | 范琳 | 一种环保型硅太阳能电池正面栅线电极银导体浆料 |
-
2010
- 2010-03-28 JP JP2010073963A patent/JP5569094B2/ja not_active Expired - Fee Related
-
2011
- 2011-03-18 CN CN201180009596.6A patent/CN102762509B/zh not_active Expired - Fee Related
- 2011-03-18 WO PCT/JP2011/056526 patent/WO2011122369A1/ja active Application Filing
- 2011-03-25 TW TW100110466A patent/TWI469944B/zh not_active IP Right Cessation
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030228471A1 (en) * | 2002-04-24 | 2003-12-11 | Central Glass Company, Limited | Lead-free low-melting glass |
| US20080314444A1 (en) * | 2006-03-07 | 2008-12-25 | Murata Manufacturing Co., Ltd. | Electrically conductive paste and solar cell |
Also Published As
| Publication number | Publication date |
|---|---|
| TW201141809A (en) | 2011-12-01 |
| JP5569094B2 (ja) | 2014-08-13 |
| WO2011122369A1 (ja) | 2011-10-06 |
| CN102762509A (zh) | 2012-10-31 |
| JP2011207629A (ja) | 2011-10-20 |
| CN102762509B (zh) | 2015-11-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Annulment or lapse of patent due to non-payment of fees |