CN102753511B - 在混合配体加氢甲酰化工艺中通过控制合成气分压来控制正构:异构醛的比率 - Google Patents

在混合配体加氢甲酰化工艺中通过控制合成气分压来控制正构:异构醛的比率 Download PDF

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CN102753511B
CN102753511B CN201080063170.4A CN201080063170A CN102753511B CN 102753511 B CN102753511 B CN 102753511B CN 201080063170 A CN201080063170 A CN 201080063170A CN 102753511 B CN102753511 B CN 102753511B
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ligand
ratio
catalyst
partial pressure
hydroformylation
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CN102753511A (zh
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T·C·埃森施米德
J·S·索雷
G·A·米勒
M·A·布拉默
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Dow Technology Investments LLC
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B61/00—Other general methods
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CN201080063170.4A 2009-12-22 2010-12-15 在混合配体加氢甲酰化工艺中通过控制合成气分压来控制正构:异构醛的比率 Active CN102753511B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US28911509P 2009-12-22 2009-12-22
US61/289,115 2009-12-22
PCT/US2010/060471 WO2011087688A1 (en) 2009-12-22 2010-12-15 Controlling the normal:iso aldehyde ratio in a mixed ligand hydroformylation process by controlling the syngas partial pressure

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CN102753511A CN102753511A (zh) 2012-10-24
CN102753511B true CN102753511B (zh) 2014-11-19

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Country Link
US (1) US8598389B2 (enExample)
EP (2) EP2722325B2 (enExample)
JP (2) JP2013515058A (enExample)
KR (2) KR101815328B1 (enExample)
CN (1) CN102753511B (enExample)
CA (1) CA2784943C (enExample)
ES (1) ES2446722T5 (enExample)
MX (1) MX365495B (enExample)
MY (1) MY159684A (enExample)
PL (2) PL2722325T5 (enExample)
RU (1) RU2546110C2 (enExample)
TW (1) TWI516470B (enExample)
WO (1) WO2011087688A1 (enExample)
ZA (1) ZA201204577B (enExample)

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MY159684A (en) * 2009-12-22 2017-01-13 Dow Technology Investments Llc Controlling the normal:iso aldehyde ratio in a mixed ligand hydroformylation process by controlling the syngas partial pressure
US8598390B2 (en) * 2009-12-22 2013-12-03 Dow Technology Investments Llc Controlling the normal:ISO aldehyde ratio in a mixed ligand hydroformylation process
JP5912084B2 (ja) † 2009-12-22 2016-04-27 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー オレフィン分圧の制御による、混合リガンドヒドロホルミル化プロセスにおけるノルマル：イソアルデヒド比の制御
CN102826967B (zh) * 2011-06-17 2015-07-22 中国石油化工股份有限公司 一种烯烃氢甲酰化反应制备醛的方法
JP2015523344A (ja) * 2012-06-01 2015-08-13 インヴィスタ テクノロジーズ エスアエルエル 加水分解触媒およびプロセス
WO2013181097A1 (en) * 2012-06-01 2013-12-05 Invista Technologies S.A.R.L. Stabilized hydrocyanation ligand composition
BR112015003762B1 (pt) * 2012-08-29 2021-04-13 Dow Technology Investments Llc Processo para a formação de um catalisador de hidroformilação
CN106256893A (zh) * 2015-06-18 2016-12-28 中国石油化工股份有限公司 一种喷气燃料的制备方法
CA3014177C (en) * 2016-02-11 2023-12-12 Dow Technology Investments Llc Processes for converting olefins to alcohols, ethers, or combinations thereof
KR102073732B1 (ko) 2016-07-08 2020-02-05 주식회사 엘지화학 하이드로포밀화 촉매, 이를 포함하는 촉매 조성물 및 이를 이용한 알데히드 제조방법
KR102610473B1 (ko) * 2018-10-16 2023-12-05 주식회사 엘지화학 알데히드의 제조방법
CN114929660A (zh) * 2019-12-19 2022-08-19 陶氏技术投资有限责任公司 用于制备异戊二烯和包含至少六个碳原子的单烯烃的方法
US11370737B2 (en) * 2020-09-25 2022-06-28 Lyondell Chemical Technology, L.P. Co-feeding ethylene with allyl alcohol in hydroformylation to make 1,4-butanediol and n-propanol
CN116478023B (zh) * 2022-01-13 2025-03-14 中国科学院大连化学物理研究所 一种合成气直接转化合成多碳醛酮的方法
CN114931961B (zh) * 2022-06-10 2024-02-27 万华化学集团股份有限公司 一种氢甲酰化催化剂及其应用
WO2025006020A1 (en) 2023-06-26 2025-01-02 Dow Technology Investments Llc Methods of controlling hydroformylation processes

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Also Published As

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KR20120095474A (ko) 2012-08-28
JP6151743B2 (ja) 2017-06-21
RU2012131275A (ru) 2014-01-27
CN102753511A (zh) 2012-10-24
EP2722325B2 (en) 2019-01-16
EP2722325A1 (en) 2014-04-23
PL2516372T3 (pl) 2014-07-31
CA2784943C (en) 2016-09-06
RU2546110C2 (ru) 2015-04-10
KR101918054B1 (ko) 2018-11-13
JP2013515058A (ja) 2013-05-02
MX365495B (es) 2019-06-05
MX2012007453A (es) 2012-11-23
PL2722325T3 (pl) 2015-12-31
PL2516372T5 (pl) 2020-08-10
EP2722325B1 (en) 2015-08-05
JP2015180694A (ja) 2015-10-15
US8598389B2 (en) 2013-12-03
EP2516372B1 (en) 2014-01-22
KR20180004304A (ko) 2018-01-10
ZA201204577B (en) 2013-08-28
EP2516372A1 (en) 2012-10-31
MY159684A (en) 2017-01-13
PL2722325T5 (pl) 2019-07-31
WO2011087688A1 (en) 2011-07-21
TW201129537A (en) 2011-09-01
ES2446722T5 (es) 2020-03-20
ES2446722T3 (es) 2014-03-10
CA2784943A1 (en) 2011-07-21
KR101815328B1 (ko) 2018-01-04
EP2516372B2 (en) 2019-08-21
US20120253081A1 (en) 2012-10-04
TWI516470B (zh) 2016-01-11

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