CN102718894B - 一种单分散聚合物微球的低温合成方法 - Google Patents
一种单分散聚合物微球的低温合成方法 Download PDFInfo
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- CN102718894B CN102718894B CN201210220312.4A CN201210220312A CN102718894B CN 102718894 B CN102718894 B CN 102718894B CN 201210220312 A CN201210220312 A CN 201210220312A CN 102718894 B CN102718894 B CN 102718894B
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- 239000012965 benzophenone Substances 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
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- RIWRBSMFKVOJMN-UHFFFAOYSA-N 2-methyl-1-phenylpropan-2-ol Chemical compound CC(C)(O)CC1=CC=CC=C1 RIWRBSMFKVOJMN-UHFFFAOYSA-N 0.000 description 4
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- DZFGVGDQHQHOKZ-UHFFFAOYSA-N 2-dodecylsulfanylcarbothioylsulfanyl-2-methylpropanoic acid Chemical compound CCCCCCCCCCCCSC(=S)SC(C)(C)C(O)=O DZFGVGDQHQHOKZ-UHFFFAOYSA-N 0.000 description 2
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- KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical compound C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 description 1
- UHFFVFAKEGKNAQ-UHFFFAOYSA-N 2-benzyl-2-(dimethylamino)-1-(4-morpholin-4-ylphenyl)butan-1-one Chemical compound C=1C=C(N2CCOCC2)C=CC=1C(=O)C(CC)(N(C)C)CC1=CC=CC=C1 UHFFVFAKEGKNAQ-UHFFFAOYSA-N 0.000 description 1
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- XHIKSLHIZYVEQI-UHFFFAOYSA-N CC1=C(C(=O)[PH2]=O)C(=CC(=C1)C)C Chemical compound CC1=C(C(=O)[PH2]=O)C(=CC(=C1)C)C XHIKSLHIZYVEQI-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
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- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
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- 229910052751 metal Inorganic materials 0.000 description 1
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- 238000012703 microemulsion polymerization Methods 0.000 description 1
- 229920002189 poly(glycerol 1-O-monomethacrylate) polymer Polymers 0.000 description 1
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- 239000002994 raw material Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
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- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
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Families Citing this family (8)
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CN103145886B (zh) * | 2013-02-06 | 2015-10-28 | 上海维凯光电新材料有限公司 | 以液态二氧化碳为介质的聚合物微球的制备方法 |
CN106279469B (zh) * | 2016-08-29 | 2018-06-08 | 中山大学 | 一种快速制备干净聚合物微球的方法 |
CN106366217B (zh) * | 2016-08-29 | 2018-06-08 | 中山大学 | 一种可切除稳定剂的聚合物功能微球及其制备方法 |
CN106554446B (zh) * | 2016-10-28 | 2018-08-17 | 佛山科学技术学院 | 一种多功能性含氟聚合物微球的快速制备方法 |
CN110511307A (zh) * | 2019-07-17 | 2019-11-29 | 山东科技大学 | 一种高效节能合成亚微米级pmma微球的方法 |
CN110330585B (zh) * | 2019-07-23 | 2020-07-24 | 淮阴工学院 | 超声诱导raft沉淀聚合制备单分散微球的方法 |
CN110878131B (zh) * | 2019-09-03 | 2021-04-02 | 中山大学 | 一种氧化还原引发的分散聚合制备单分散聚合物微球的方法 |
CN112646067B (zh) * | 2020-12-10 | 2021-09-28 | 中山大学 | 一种纯水介质中合成单分散聚合物微球的方法 |
Citations (4)
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CN101423567A (zh) * | 2008-11-28 | 2009-05-06 | 北京化工大学 | Uv光场中利用光活性聚合物微球制备非对称球的方法 |
CN101870760A (zh) * | 2010-07-19 | 2010-10-27 | 湘潭大学 | 一种微凝胶树脂的制备方法及其用微凝胶树脂制备的紫外光固化抗沾污涂料 |
CN102010476A (zh) * | 2010-11-02 | 2011-04-13 | 江南大学 | 一种紫外光辐照聚合制备单分散高分子微球的方法 |
WO2012062334A1 (en) * | 2010-11-12 | 2012-05-18 | Coloplast A/S | New routes to polyacrylates |
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KR100514293B1 (ko) * | 2003-12-29 | 2005-09-13 | 학교법인 성균관대학 | 계면활성제 작용기가 도입된 이니퍼터(개시제)를 이용하여제조한 단분산성 고분자 입자 및 그의 제조방법 |
WO2009111725A1 (en) * | 2008-03-07 | 2009-09-11 | Carnegie Mellon University | Improved controlled radical polymerization processes |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN101423567A (zh) * | 2008-11-28 | 2009-05-06 | 北京化工大学 | Uv光场中利用光活性聚合物微球制备非对称球的方法 |
CN101870760A (zh) * | 2010-07-19 | 2010-10-27 | 湘潭大学 | 一种微凝胶树脂的制备方法及其用微凝胶树脂制备的紫外光固化抗沾污涂料 |
CN102010476A (zh) * | 2010-11-02 | 2011-04-13 | 江南大学 | 一种紫外光辐照聚合制备单分散高分子微球的方法 |
WO2012062334A1 (en) * | 2010-11-12 | 2012-05-18 | Coloplast A/S | New routes to polyacrylates |
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