CN102695740B - 新的树脂固化剂 - Google Patents

新的树脂固化剂 Download PDF

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Publication number
CN102695740B
CN102695740B CN201180005677.9A CN201180005677A CN102695740B CN 102695740 B CN102695740 B CN 102695740B CN 201180005677 A CN201180005677 A CN 201180005677A CN 102695740 B CN102695740 B CN 102695740B
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curable resin
arrangement
chain
curing agent
resin
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Chinese (zh)
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CN102695740A (zh
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J.考斯
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Hexcel Composites Ltd
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Hexcel Composites Ltd
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
    • C07C69/78—Benzoic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C229/00—Compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C229/52—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton
    • C07C229/54—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton with amino and carboxyl groups bound to carbon atoms of the same non-condensed six-membered aromatic ring
    • C07C229/60—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton with amino and carboxyl groups bound to carbon atoms of the same non-condensed six-membered aromatic ring with amino and carboxyl groups bound in meta- or para- positions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/34—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by amino groups
    • C07C233/42—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by amino groups with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by a carbon atom of a six-membered aromatic ring
    • C07C233/43—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by amino groups with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by a carbon atom of a six-membered aromatic ring having the carbon atom of the carboxamide group bound to a hydrogen atom or to a carbon atom of a saturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C237/00—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups
    • C07C237/28—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atom of at least one of the carboxamide groups bound to a carbon atom of a non-condensed six-membered aromatic ring of the carbon skeleton
    • C07C237/34—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atom of at least one of the carboxamide groups bound to a carbon atom of a non-condensed six-membered aromatic ring of the carbon skeleton having the nitrogen atom of the carboxamide group bound to an acyclic carbon atom of a hydrocarbon radical substituted by nitrogen atoms not being part of nitro or nitroso groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C237/00—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups
    • C07C237/28—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atom of at least one of the carboxamide groups bound to a carbon atom of a non-condensed six-membered aromatic ring of the carbon skeleton
    • C07C237/38—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atom of at least one of the carboxamide groups bound to a carbon atom of a non-condensed six-membered aromatic ring of the carbon skeleton having the nitrogen atom of the carboxamide group bound to a carbon atom of a ring other than a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C07D303/28—Ethers with hydroxy compounds containing oxirane rings
    • C07D303/30—Ethers of oxirane-containing polyhydroxy compounds in which all hydroxyl radicals are etherified with oxirane-containing hydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/36—Compounds containing oxirane rings with hydrocarbon radicals, substituted by nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22—Di-epoxy compounds
    • C08G59/28—Di-epoxy compounds containing acyclic nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/32—Epoxy compounds containing three or more epoxy groups
    • C08G59/3227—Compounds containing acyclic nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C08G59/5033—Amines aromatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C08G59/504—Amines containing an atom other than nitrogen belonging to the amine group, carbon and hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C08G59/54—Amino amides>
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/20—Carboxylic acid amides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Epoxy Resins (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Reinforced Plastic Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CN201180005677.9A 2010-01-07 2011-01-06 新的树脂固化剂 Active CN102695740B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
GB1000182.4 2010-01-07
GBGB1000182.4A GB201000182D0 (en) 2010-01-07 2010-01-07 Novel curable resins and curing agents therefor
GB1004722.3 2010-03-22
GB1004722A GB2476841A (en) 2010-01-07 2010-03-22 Curable resins and curing agents therefor
PCT/GB2011/050011 WO2011083329A2 (en) 2010-01-07 2011-01-06 Novel resin curing agents

Publications (2)

Publication Number Publication Date
CN102695740A CN102695740A (zh) 2012-09-26
CN102695740B true CN102695740B (zh) 2015-03-25

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CN201180005677.9A Active CN102695740B (zh) 2010-01-07 2011-01-06 新的树脂固化剂

Country Status (7)

Country Link
US (1) US8981033B2 (https=)
EP (1) EP2521747B1 (https=)
JP (2) JP5829622B2 (https=)
CN (1) CN102695740B (https=)
ES (1) ES2881208T3 (https=)
GB (2) GB201000182D0 (https=)
WO (1) WO2011083329A2 (https=)

Families Citing this family (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB201402053D0 (en) 2014-02-06 2014-03-26 Hexcel Composites Ltd Amino benzoates or benzamides as curing agents for epoxy resins
US10119001B2 (en) 2014-02-06 2018-11-06 Hexcel Corporation Extended room temperature storage of epoxy resins
US10377916B2 (en) * 2015-09-01 2019-08-13 United States Of America As Represented By The Administrator Of Nasa Coatings with molecular flexibility for ice adhesion mitigation
CN105254851A (zh) * 2015-11-14 2016-01-20 华玉叶 一种高粘度固化剂组合物
CN105219294A (zh) * 2015-11-14 2016-01-06 华玉叶 一种高粘度固化剂组合物
CN105237738A (zh) * 2015-11-14 2016-01-13 华玉叶 一种高粘度固化剂组合物
CN105254852A (zh) * 2015-11-14 2016-01-20 华玉叶 一种高粘度固化剂组合物
CN105237742A (zh) * 2015-11-14 2016-01-13 华玉叶 一种高粘度固化剂组合物
CN105295808A (zh) * 2015-11-14 2016-02-03 华玉叶 一种用于粘接窄边框显示设备的密封剂组合物
CN105294998A (zh) * 2015-11-14 2016-02-03 华玉叶 一种高粘度固化剂组合物
CN105295001A (zh) * 2015-11-14 2016-02-03 华玉叶 一种高粘度固化剂组合物
CN105237743A (zh) * 2015-11-14 2016-01-13 华玉叶 一种高粘度固化剂组合物
CN105218786A (zh) * 2015-11-14 2016-01-06 华玉叶 一种高粘度固化剂组合物
CN105295807A (zh) * 2015-11-14 2016-02-03 华玉叶 一种用于粘接窄边框显示设备的密封剂组合物
CN105295770A (zh) * 2015-11-14 2016-02-03 华玉叶 一种高粘度固化剂组合物
CN105295802A (zh) * 2015-11-14 2016-02-03 华玉叶 一种用于粘接窄边框显示设备的密封剂组合物
CN105294997A (zh) * 2015-11-14 2016-02-03 华玉叶 一种高粘度固化剂组合物
CN105295798A (zh) * 2015-11-14 2016-02-03 华玉叶 一种用于粘接窄边框显示设备的密封剂组合物
CN105199080A (zh) * 2015-11-14 2015-12-30 华玉叶 一种高粘度固化剂组合物
CN105255386A (zh) * 2015-11-14 2016-01-20 华玉叶 一种高粘度固化剂组合物
CN105219334A (zh) * 2015-11-14 2016-01-06 华玉叶 一种用于粘接窄边框显示设备的密封剂组合物
CN105219296A (zh) * 2015-11-14 2016-01-06 华玉叶 一种高粘度固化剂组合物
CN105315438A (zh) * 2015-11-14 2016-02-10 华玉叶 一种高粘度固化剂组合物
CN105295002A (zh) * 2015-11-14 2016-02-03 华玉叶 一种高粘度固化剂组合物
CN105238318A (zh) * 2015-11-14 2016-01-13 华玉叶 一种用于粘接窄边框显示设备的密封剂组合物
CN105295004A (zh) * 2015-11-14 2016-02-03 华玉叶 一种高粘度固化剂组合物
CN105219332A (zh) * 2015-11-14 2016-01-06 华玉叶 一种用于粘接窄边框显示设备的密封剂组合物
CN105294996A (zh) * 2015-11-14 2016-02-03 华玉叶 一种高粘度固化剂组合物
CN105219293A (zh) * 2015-11-14 2016-01-06 华玉叶 一种高粘度固化剂组合物
CN105273674A (zh) * 2015-11-14 2016-01-27 华玉叶 一种用于粘接窄边框显示设备的密封剂组合物
CN105219333A (zh) * 2015-11-14 2016-01-06 华玉叶 一种用于粘接窄边框显示设备的密封剂组合物
CN105218787A (zh) * 2015-11-14 2016-01-06 华玉叶 一种高粘度固化剂组合物
CN105295003A (zh) * 2015-11-14 2016-02-03 华玉叶 一种高粘度固化剂组合物
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CN105237744A (zh) * 2015-11-14 2016-01-13 华玉叶 一种高粘度固化剂组合物
CN105238319A (zh) * 2015-11-14 2016-01-13 华玉叶 一种用于粘接窄边框显示设备的密封剂组合物
CN105295005A (zh) * 2015-11-14 2016-02-03 华玉叶 一种高粘度固化剂组合物
CN105349083A (zh) * 2015-11-14 2016-02-24 华玉叶 一种用于粘接窄边框显示设备的密封剂组合物
CN105238317A (zh) * 2015-11-14 2016-01-13 华玉叶 一种用于粘接窄边框显示设备的密封剂组合物
CN105219295A (zh) * 2015-11-14 2016-01-06 华玉叶 一种高粘度固化剂组合物
CN105349082A (zh) * 2015-11-14 2016-02-24 华玉叶 一种用于粘接窄边框显示设备的密封剂组合物
CN105295000A (zh) * 2015-11-14 2016-02-03 华玉叶 一种高粘度固化剂组合物
CN105602505A (zh) * 2015-11-14 2016-05-25 华玉叶 一种用于粘接窄边框显示设备的密封剂组合物
CN105294999A (zh) * 2015-11-14 2016-02-03 华玉叶 一种高粘度固化剂组合物
CN105219330A (zh) * 2015-11-14 2016-01-06 华玉叶 一种用于粘接窄边框显示设备的密封剂组合物
TWI766025B (zh) * 2017-06-28 2022-06-01 日商迪愛生股份有限公司 活性酯化合物及硬化性組成物
CN107337819A (zh) * 2017-06-29 2017-11-10 福清市汇华塑胶制品有限公司 一种橡胶材料的制备方法
CN108329222A (zh) * 2017-12-29 2018-07-27 江苏湘园化工有限公司 一种制备醚、烷基二醇-双-对氨基苯甲酸酯的方法
CN111039795A (zh) * 2019-12-18 2020-04-21 厦门本素药业有限公司 (1r,2r)-(-)-n,n`-二甲基-1,2-环己二胺的制备方法
CN111019554B (zh) * 2019-12-23 2021-09-10 天津渤海化学股份有限公司 固化树脂调节剂、双组分环氧体系胶黏剂及其制备方法

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1141206A (en) * 1966-04-20 1969-01-29 Atomic Energy Authority Uk Improvements in or relating to epoxy resins
DE1720680A1 (de) * 1967-07-06 1971-07-15 Bayer Ag Verfahren zur Herstellung von Formkoerpern,UEberzuegen,Filmen und Verklebungen
DE1962602A1 (de) * 1969-12-13 1971-06-24 Bayer Ag Segmentierte Polyurethanelastomere
US3932360A (en) * 1974-03-14 1976-01-13 Polaroid Corporation Polyurethane elastomers prepared from diamine curing agents
US4636535A (en) * 1983-08-01 1987-01-13 American Cyanamid Company Curable epoxy resin compositions
US4645803A (en) * 1984-02-29 1987-02-24 American Cyanamid Company Curable epoxy resin compositions
JPS60195122A (ja) * 1984-03-19 1985-10-03 Sanyo Chem Ind Ltd エポキシ樹脂用硬化剤
JPS61103922A (ja) * 1984-10-26 1986-05-22 Toray Ind Inc 複合材料用エポキシ樹脂組成物
JPS61126126A (ja) * 1984-11-22 1986-06-13 Toray Ind Inc 炭素繊維プリプレグ用エポキシ樹脂組成物
JPS61223020A (ja) * 1985-03-29 1986-10-03 Toshiba Corp 光硬化性エポキシ樹脂系組成物
US4746718A (en) * 1987-04-06 1988-05-24 Amoco Corporation Novel oligomeric diamine hardeners and their use for curing epoxy resin systems
JPH0796607B2 (ja) * 1987-09-07 1995-10-18 富山県 高分子圧電材及びその製造方法
DE4012946A1 (de) * 1990-04-24 1991-10-31 Basf Ag Prepreg fuer hochleistungsverbundwerkstoffe
US5268442A (en) * 1990-11-13 1993-12-07 Brigham Young University Chiral copolymers with oligosiloxane spacers
US6111129A (en) * 1998-11-04 2000-08-29 Uniroyal Chemical Company, Inc. Process for the preparation of alkanediol-diaminobenzoates
US20090124690A1 (en) * 2000-04-03 2009-05-14 Alberte Randall S Generation of Combinatorial Synthetic Libraries and Screening for Novel Proadhesins and Nonadhesins
CN1286875C (zh) * 2001-11-07 2006-11-29 东丽株式会社 纤维强化复合材料用环氧树脂组合物、纤维强化复合材料的制法以及纤维强化复合材料
US20030109646A1 (en) 2001-11-21 2003-06-12 Daikin Institute Of Advanced Chemistry And Technology Resin composition and method of producing shaped articles
GB2460050A (en) * 2008-05-14 2009-11-18 Hexcel Composites Ltd Epoxy composite

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Publication number Publication date
JP2013516533A (ja) 2013-05-13
US8981033B2 (en) 2015-03-17
EP2521747B1 (en) 2021-06-16
GB201000182D0 (en) 2010-02-24
JP2015214711A (ja) 2015-12-03
WO2011083329A3 (en) 2011-11-24
GB201004722D0 (en) 2010-05-05
JP6236044B2 (ja) 2017-11-22
CN102695740A (zh) 2012-09-26
WO2011083329A2 (en) 2011-07-14
US20130217803A1 (en) 2013-08-22
ES2881208T3 (es) 2021-11-29
GB2476841A (en) 2011-07-13
EP2521747A2 (en) 2012-11-14
JP5829622B2 (ja) 2015-12-09

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