CN102668201B - 具有纳米结构化催化剂和分散催化剂亚层的燃料电池电极 - Google Patents

具有纳米结构化催化剂和分散催化剂亚层的燃料电池电极 Download PDF

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Publication number
CN102668201B
CN102668201B CN201080059082.7A CN201080059082A CN102668201B CN 102668201 B CN102668201 B CN 102668201B CN 201080059082 A CN201080059082 A CN 201080059082A CN 102668201 B CN102668201 B CN 102668201B
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China
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catalyst
nstf
subgrade
sublayer
anode
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Expired - Fee Related
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CN201080059082.7A
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English (en)
Chinese (zh)
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CN102668201A (zh
Inventor
安德鲁·T·豪格
苏珊·M·亨德里克斯
安德鲁·J·L·斯坦巴克
格雷戈里·M·豪根
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3M Innovative Properties Co
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3M Innovative Properties Co
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Publication of CN102668201A publication Critical patent/CN102668201A/zh
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8647—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites
    • H01M4/8657—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites layered
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88—Processes of manufacture
    • H01M4/8803—Supports for the deposition of the catalytic active composition
    • H01M4/881—Electrolytic membranes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88—Processes of manufacture
    • H01M4/8803—Supports for the deposition of the catalytic active composition
    • H01M4/8814—Temporary supports, e.g. decal
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M2008/1095—Fuel cells with polymeric electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88—Processes of manufacture
    • H01M4/8825—Methods for deposition of the catalytic active composition
    • H01M4/8828—Coating with slurry or ink
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88—Processes of manufacture
    • H01M4/8825—Methods for deposition of the catalytic active composition
    • H01M4/8867—Vapour deposition
    • H01M4/8871—Sputtering
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/92—Metals of platinum group
    • H01M4/921—Alloys or mixtures with metallic elements
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Composite Materials (AREA)
  • Inert Electrodes (AREA)
  • Fuel Cell (AREA)
  • Catalysts (AREA)
CN201080059082.7A 2009-12-22 2010-12-22 具有纳米结构化催化剂和分散催化剂亚层的燃料电池电极 Expired - Fee Related CN102668201B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US28888209P 2009-12-22 2009-12-22
US61/288,882 2009-12-22
PCT/US2010/061798 WO2011087842A1 (en) 2009-12-22 2010-12-22 Fuel cell electrode with nanostructured catalyst and dispersed catalyst sublayer

Publications (2)

Publication Number Publication Date
CN102668201A CN102668201A (zh) 2012-09-12
CN102668201B true CN102668201B (zh) 2015-05-20

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201080059082.7A Expired - Fee Related CN102668201B (zh) 2009-12-22 2010-12-22 具有纳米结构化催化剂和分散催化剂亚层的燃料电池电极

Country Status (5)

Country Link
US (1) US9570756B2 (enExample)
EP (1) EP2517290B1 (enExample)
JP (2) JP6001455B2 (enExample)
CN (1) CN102668201B (enExample)
WO (1) WO2011087842A1 (enExample)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2774203B8 (en) 2011-11-04 2016-06-01 Greenerity GmbH Method for the preparation of catalyst-coated membranes
CN103849885B (zh) * 2012-12-06 2016-12-21 清华大学 阴极催化剂，阴极材料及其制备方法及反应器
EP3083039A2 (en) * 2013-12-18 2016-10-26 King Abdullah University Of Science And Technology Methods of making supported ni/pt bimetallic nanoparticles and ni/pt multilayer core-shell structures and their uses for co2 reforming
US9468909B2 (en) * 2014-06-27 2016-10-18 Ford Global Technologies, Llc Metal oxide stabilized platinum-based ORR catalyst
CN108075139B (zh) * 2016-11-18 2020-11-10 中国科学院大连化学物理研究所 基于金属氧化物纳米带的有序化膜电极及其制备和应用
JP6809897B2 (ja) * 2016-12-20 2021-01-06 スリーエム イノベイティブ プロパティズ カンパニー 膜電極接合体及び固体高分子形燃料電池
US12300824B2 (en) * 2016-12-20 2025-05-13 Kyocera Corporation Cell, cell stack device, module, and module housing device
WO2018185616A1 (en) 2017-04-03 2018-10-11 3M Innovative Properties Company Water electrolyzers
US20200017980A1 (en) * 2017-04-03 2020-01-16 3M Innovative Properties Company Water electrolyzers
WO2018226444A1 (en) * 2017-06-05 2018-12-13 3M Innovative Properties Company Electrode catalyst-containing dispersion compositions and articles therefrom
KR102335927B1 (ko) * 2019-02-08 2021-12-06 한국전력공사 막-전극 집합체 제조방법

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070269699A1 (en) * 2006-05-16 2007-11-22 Samsung Sdi Co., Ltd. Catalyst coated membrane, membrane electrode assembly containing the same, method of producing the same, and fuel cell including the membrane electrode assembly
CN101263620A (zh) * 2005-09-13 2008-09-10 3M创新有限公司 多层纳米结构化薄膜
US20090017363A1 (en) * 2004-12-09 2009-01-15 Nanosys, Inc. Nanowire-Based Membrane Electrode Assemblies for Fuel Cells
WO2009068958A1 (en) * 2007-11-27 2009-06-04 Toyota Jidosha Kabushiki Kaisha Membrane electrode assembly for fuel cell, fuel cell, and fuel cell system

Family Cites Families (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4340276A (en) * 1978-11-01 1982-07-20 Minnesota Mining And Manufacturing Company Method of producing a microstructured surface and the article produced thereby
US4568598A (en) * 1984-10-30 1986-02-04 Minnesota Mining And Manufacturing Company Article with reduced friction polymer sheet support
US5039561A (en) * 1986-08-25 1991-08-13 Minnesota Mining And Manufacturing Company Method for preparing an article having surface layer of uniformly oriented, crystalline, organic microstructures
US4812352A (en) * 1986-08-25 1989-03-14 Minnesota Mining And Manufacturing Company Article having surface layer of uniformly oriented, crystalline, organic microstructures
US5176786A (en) 1988-07-13 1993-01-05 Minnesota Mining And Manufacturing Company Organic thin film controlled molecular epitaxy
US5336558A (en) * 1991-06-24 1994-08-09 Minnesota Mining And Manufacturing Company Composite article comprising oriented microstructures
US5338430A (en) 1992-12-23 1994-08-16 Minnesota Mining And Manufacturing Company Nanostructured electrode membranes
US5728485A (en) * 1995-03-15 1998-03-17 Tanaka Kikinzoku Kogyo K.K. Electrode for polymer electrolyte electrochemical cell and process of preparing same
US5879827A (en) 1997-10-10 1999-03-09 Minnesota Mining And Manufacturing Company Catalyst for membrane electrode assembly and method of making
US5879828A (en) 1997-10-10 1999-03-09 Minnesota Mining And Manufacturing Company Membrane electrode assembly
US7098163B2 (en) * 1998-08-27 2006-08-29 Cabot Corporation Method of producing membrane electrode assemblies for use in proton exchange membrane and direct methanol fuel cells
US6287717B1 (en) * 1998-11-13 2001-09-11 Gore Enterprise Holdings, Inc. Fuel cell membrane electrode assemblies with improved power outputs
US6238534B1 (en) * 1999-05-14 2001-05-29 3M Innovative Properties Company Hybrid membrane electrode assembly
US6482763B2 (en) * 1999-12-29 2002-11-19 3M Innovative Properties Company Suboxide fuel cell catalyst for enhanced reformate tolerance
CA2407202C (en) * 2001-10-11 2009-11-03 Honda Giken Kogyo Kabushiki Kaisha Electrode for polymer electrolyte fuel cell
DE10159476A1 (de) * 2001-12-04 2003-07-17 Omg Ag & Co Kg Verfahren zur Herstellung von Membran-Elektrodeneinheiten für Brennstoffzellen
US20030190517A1 (en) 2002-04-08 2003-10-09 John Elter Fuel cell
US6946362B2 (en) 2002-09-06 2005-09-20 Hewlett-Packard Development Company, L.P. Method and apparatus for forming high surface area material films and membranes
US20040116742A1 (en) * 2002-12-17 2004-06-17 3M Innovative Properties Company Selective reaction of hexafluoropropylene oxide with perfluoroacyl fluorides
US6624328B1 (en) * 2002-12-17 2003-09-23 3M Innovative Properties Company Preparation of perfluorinated vinyl ethers having a sulfonyl fluoride end-group
US7348088B2 (en) * 2002-12-19 2008-03-25 3M Innovative Properties Company Polymer electrolyte membrane
US7419741B2 (en) * 2003-09-29 2008-09-02 3M Innovative Properties Company Fuel cell cathode catalyst
JP4482352B2 (ja) * 2004-03-11 2010-06-16 本田技研工業株式会社 固体高分子型燃料電池
JP4031463B2 (ja) * 2004-04-26 2008-01-09 株式会社東芝 液体燃料型固体高分子燃料電池用アノード電極、液体燃料型固体高分子燃料電池用膜電極複合体及び液体燃料型固体高分子燃料電池
CA2505653A1 (en) * 2004-04-28 2005-10-28 National Research Council Of Canada Composite catalyst layer, electrode and passive mixing flow field for compressionless fuel cells
KR101030046B1 (ko) 2004-06-30 2011-04-20 삼성에스디아이 주식회사 막-전극 접합체 및 이를 포함하는 연료전지
US8101317B2 (en) * 2004-09-20 2012-01-24 3M Innovative Properties Company Durable fuel cell having polymer electrolyte membrane comprising manganese oxide
US7572534B2 (en) * 2004-09-20 2009-08-11 3M Innovative Properties Company Fuel cell membrane electrode assembly
US7622217B2 (en) * 2005-10-12 2009-11-24 3M Innovative Properties Company Fuel cell nanocatalyst
US20070082814A1 (en) 2005-10-12 2007-04-12 3M Innovative Properties Company Ternary nanocatalyst and method of making
TW200723580A (en) * 2005-12-12 2007-06-16 Antig Tech Co Ltd Membrane electrode assembly structure of fuel cell and method of manufacturing the same
CN100468836C (zh) 2005-12-14 2009-03-11 胜光科技股份有限公司 燃料电池的膜电极组及其制造方法
JP4957047B2 (ja) 2006-03-31 2012-06-20 大日本印刷株式会社 燃料電池用触媒層−電解質膜積層体
CN101682050B (zh) * 2007-06-12 2013-05-15 佳能株式会社 膜电极组件的制造方法、燃料电池的制造方法、膜电极组件和燃料电池
KR100908720B1 (ko) * 2007-09-14 2009-07-22 삼성에스디아이 주식회사 연료 전지용 막-전극 어셈블리, 및 이를 포함하는 연료전지 시스템
JP5196988B2 (ja) 2007-12-21 2013-05-15 スリーエム イノベイティブ プロパティズ カンパニー インク組成物、その製造方法、そのインク組成物を用いて形成した電極触媒層及びこれらの用途

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090017363A1 (en) * 2004-12-09 2009-01-15 Nanosys, Inc. Nanowire-Based Membrane Electrode Assemblies for Fuel Cells
CN101263620A (zh) * 2005-09-13 2008-09-10 3M创新有限公司 多层纳米结构化薄膜
US20070269699A1 (en) * 2006-05-16 2007-11-22 Samsung Sdi Co., Ltd. Catalyst coated membrane, membrane electrode assembly containing the same, method of producing the same, and fuel cell including the membrane electrode assembly
WO2009068958A1 (en) * 2007-11-27 2009-06-04 Toyota Jidosha Kabushiki Kaisha Membrane electrode assembly for fuel cell, fuel cell, and fuel cell system

Also Published As

Publication number Publication date
EP2517290A1 (en) 2012-10-31
EP2517290B1 (en) 2018-08-29
CN102668201A (zh) 2012-09-12
WO2011087842A1 (en) 2011-07-21
JP6001455B2 (ja) 2016-10-05
JP2013515350A (ja) 2013-05-02
JP2016192411A (ja) 2016-11-10
US9570756B2 (en) 2017-02-14
US20110151353A1 (en) 2011-06-23

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