CN102656199B - 二氯化镁-水加合物和由其制成的催化剂组分 - Google Patents

二氯化镁-水加合物和由其制成的催化剂组分 Download PDF

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Publication number
CN102656199B
CN102656199B CN201080058862.XA CN201080058862A CN102656199B CN 102656199 B CN102656199 B CN 102656199B CN 201080058862 A CN201080058862 A CN 201080058862A CN 102656199 B CN102656199 B CN 102656199B
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China
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adduct
compound
solid
catalytic component
mgcl
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Expired - Fee Related
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English (en)
Chinese (zh)
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CN102656199A (zh
Inventor
D.埃万格利斯蒂
B.加迪
D.布里塔
G.科利纳
A.法伊特
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Basell Poliolefine Italia SRL
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Basell Poliolefine Italia SRL
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F5/00—Compounds of magnesium
    • C01F5/26—Magnesium halides
    • C01F5/30—Chlorides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C08F4/022—Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/14—Pore volume
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymerization Catalysts (AREA)
  • Catalysts (AREA)
CN201080058862.XA 2010-01-11 2010-12-17 二氯化镁-水加合物和由其制成的催化剂组分 Expired - Fee Related CN102656199B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP10150409 2010-01-11
EP10150409.0 2010-01-11
PCT/EP2010/070010 WO2011076669A2 (en) 2009-12-23 2010-12-17 Magnesium dichloride-water adducts and catalyst components obtained therefrom

Publications (2)

Publication Number Publication Date
CN102656199A CN102656199A (zh) 2012-09-05
CN102656199B true CN102656199B (zh) 2016-08-31

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Country Status (6)

Country Link
US (1) US20120283402A1 (https=)
EP (1) EP2516487A2 (https=)
JP (1) JP5890316B2 (https=)
KR (1) KR20120120178A (https=)
CN (1) CN102656199B (https=)
WO (1) WO2011076669A2 (https=)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101872196B1 (ko) * 2010-12-24 2018-06-28 바셀 폴리올레핀 이탈리아 에스.알.엘 마그네슘 디클로라이드-에탄올 부가물 및 그로부터 수득한 촉매 성분
US9862781B2 (en) 2011-08-08 2018-01-09 Basell Poliolefine Italia S.R.L. Magnesium dichloride-ethanol adducts and catalyst components obtained therefrom
EP2692743A1 (en) 2012-08-03 2014-02-05 Basell Poliolefine Italia S.r.l. Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom
EP2746299A1 (en) 2012-12-19 2014-06-25 Basell Poliolefine Italia S.r.l. Multistage process for the polymerization of ethylene
JP6758165B2 (ja) * 2016-11-28 2020-09-23 三井化学株式会社 固体状錯体化合物の製造方法、固体状チタン触媒成分の製造方法、オレフィン重合用触媒の製造方法およびオレフィン重合体の製造方法
KR102287924B1 (ko) * 2017-11-09 2021-08-06 롯데케미칼 주식회사 고밀도 폴리에틸렌 중합용 촉매의 제조방법

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5151397A (en) * 1991-12-16 1992-09-29 Phillips Petroleum Company Method of producing metal halide catalyst
CN1226901A (zh) * 1997-03-29 1999-08-25 蒙特尔技术有限公司 氯化镁－醇加合物、其制备方法以及从中获得的催化剂组分
CN101583636A (zh) * 2007-01-15 2009-11-18 霍尼韦尔国际公司 制备氧化聚烯烃蜡的方法

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE755185A (fr) * 1969-08-22 1971-02-24 Hoechst Ag Procede de polymerisation d'alpha-olefines
LU65587A1 (https=) * 1972-06-22 1973-12-27
IT969340B (it) * 1972-09-13 1974-03-30 Montedison Spa Catalizzatori per la polimerizza zione delle olefine a polimeri in forma sferica
US3953414A (en) * 1972-09-13 1976-04-27 Montecatini Edison S.P.A., Catalysts for the polymerization of olefins to spherically shaped polymers
IT1096661B (it) 1978-06-13 1985-08-26 Montedison Spa Procedimento per la preparazione di prodotti in forma sferoidale solidi a temperatura ambiente
IT1098272B (it) 1978-08-22 1985-09-07 Montedison Spa Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine
ZA818152B (en) * 1980-11-24 1982-10-27 Nat Distillers Chem Corp Intermetallic compounds of polymeric transition metal oxide alkoxides
CA1225080A (en) * 1983-01-28 1987-08-04 Gil R. Hawley Polyolefin polymerization process and catalyst
US4563511A (en) * 1983-08-19 1986-01-07 Phillips Petroleum Company Polyolefin polymerization process and catalyst
US4585749A (en) * 1983-09-28 1986-04-29 Phillips Petroleum Company Process for the preparation of an olefin polymerization catalyst
US4853444A (en) * 1983-10-28 1989-08-01 Phillips Petroleum Company Magnesium halide hydrates and polymerization catalysts prepared therefrom
US4520121A (en) * 1983-10-28 1985-05-28 Inkrott Kenneth E Magnesium halide hydrates and polymerization catalysts prepared therefrom
FI80055C (fi) 1986-06-09 1990-04-10 Neste Oy Foerfarande foer framstaellning av katalytkomponenter foer polymerisation av olefiner.
IT1230134B (it) 1989-04-28 1991-10-14 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine.
JP2879347B2 (ja) * 1989-10-02 1999-04-05 チッソ株式会社 オレフィン重合用触媒の製法
US4988655A (en) * 1989-11-30 1991-01-29 Phillips Petroleum Company Polyolefin polymerization catalyst and method of production use
US5206314A (en) * 1992-08-31 1993-04-27 Phillips Petroleum Company Polyolefin polymerization process, process of producing catalyst, and catalyst
CA2100143A1 (en) * 1992-10-23 1994-04-24 Kent Edward Mitchell Olefin polymerization catalyst and use
ZA974798B (en) * 1996-05-31 1998-11-30 Sastech Pty Ltd Termpolymerization
US6407028B1 (en) * 1997-03-29 2002-06-18 Basell Technology Company Bv Magnesium dichloride-alcohol adducts, process for their preparation and catalyst components obtained therefrom
US6323152B1 (en) * 1998-03-30 2001-11-27 Basell Technology Company Bv Magnesium dichloride-alcohol adducts process for their preparation and catalyst components obtained therefrom
CA2510254A1 (en) * 2002-12-18 2004-07-01 Basell Poliolefine Italia S.P.A. Magnesium dichloride-based adducts and catalyst components obtained therefrom
BRPI0409017B1 (pt) * 2003-03-27 2014-02-25 Adutos de dicloreto de magnésio-álcool, componentes catalíticos obtidos a partir deles, catalisador e processo para a polimerização de olefinas
WO2008074674A1 (en) * 2006-12-20 2008-06-26 Basell Poliolefine Italia S.R.L. Catalyst components for the polymerization of olefins and catalysts therefrom obtained
JP5583973B2 (ja) * 2006-12-22 2014-09-03 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ オレフィン重合用の触媒成分及びそれから得られる触媒

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5151397A (en) * 1991-12-16 1992-09-29 Phillips Petroleum Company Method of producing metal halide catalyst
CN1226901A (zh) * 1997-03-29 1999-08-25 蒙特尔技术有限公司 氯化镁－醇加合物、其制备方法以及从中获得的催化剂组分
CN101583636A (zh) * 2007-01-15 2009-11-18 霍尼韦尔国际公司 制备氧化聚烯烃蜡的方法

Also Published As

Publication number Publication date
WO2011076669A2 (en) 2011-06-30
WO2011076669A3 (en) 2011-09-29
JP2013515797A (ja) 2013-05-09
CN102656199A (zh) 2012-09-05
KR20120120178A (ko) 2012-11-01
JP5890316B2 (ja) 2016-03-22
US20120283402A1 (en) 2012-11-08
EP2516487A2 (en) 2012-10-31

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Termination date: 20191217