CN102558517A - 生态多功能三元共聚petg聚酯及其制备方法和由该聚酯制备单向拉伸热收缩膜的方法 - Google Patents
生态多功能三元共聚petg聚酯及其制备方法和由该聚酯制备单向拉伸热收缩膜的方法 Download PDFInfo
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- CN102558517A CN102558517A CN2012100173552A CN201210017355A CN102558517A CN 102558517 A CN102558517 A CN 102558517A CN 2012100173552 A CN2012100173552 A CN 2012100173552A CN 201210017355 A CN201210017355 A CN 201210017355A CN 102558517 A CN102558517 A CN 102558517A
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- Prior art keywords
- polyester
- terpolymer
- petg
- heat
- shrinkable film
- Prior art date
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- 229920000728 polyester Polymers 0.000 title claims abstract description 51
- 229920005644 polyethylene terephthalate glycol copolymer Polymers 0.000 title claims abstract description 40
- 229920006257 Heat-shrinkable film Polymers 0.000 title claims abstract description 27
- 238000000034 method Methods 0.000 title claims abstract description 18
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 title claims abstract description 16
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 238000007334 copolymerization reaction Methods 0.000 title claims abstract description 10
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 title claims abstract description 8
- -1 Polyethylene Terephthalate Polymers 0.000 title abstract description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 title abstract description 3
- 239000005020 polyethylene terephthalate Substances 0.000 title abstract 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims abstract description 34
- 238000004519 manufacturing process Methods 0.000 claims abstract description 16
- 238000005886 esterification reaction Methods 0.000 claims abstract description 14
- 229920001897 terpolymer Polymers 0.000 claims description 30
- 230000032050 esterification Effects 0.000 claims description 12
- 238000007669 thermal treatment Methods 0.000 claims description 11
- 230000004927 fusion Effects 0.000 claims description 10
- 239000003054 catalyst Substances 0.000 claims description 6
- 238000000465 moulding Methods 0.000 claims description 6
- 125000002524 organometallic group Chemical group 0.000 claims description 6
- 229920006302 stretch film Polymers 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 5
- 239000000155 melt Substances 0.000 claims description 5
- 229910052787 antimony Inorganic materials 0.000 claims description 4
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical group [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 4
- 239000000178 monomer Substances 0.000 abstract description 3
- 238000006116 polymerization reaction Methods 0.000 abstract 3
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 abstract 2
- 239000002994 raw material Substances 0.000 abstract 1
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 10
- 239000000463 material Substances 0.000 description 7
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 5
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Natural products OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 241000282326 Felis catus Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- 238000010009 beating Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000000048 melt cooling Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- GOLXNESZZPUPJE-UHFFFAOYSA-N spiromesifen Chemical compound CC1=CC(C)=CC(C)=C1C(C(O1)=O)=C(OC(=O)CC(C)(C)C)C11CCCC1 GOLXNESZZPUPJE-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
Abstract
Description
| 实施例1 | 实施例2 | 实施例3 | 实施例4 | |
| 对苯二甲酸 | 9.08kg | 9.08kg | 9.08kg | 9.08kg |
| 新戊二醇 | 2.65kg | 0.5688kg | 1.72kg | 3.69kg |
| 乙二醇 | 4.5kg | 5.9kg | 5.3kg | 4.1kg |
| 乙二醇锑 | 8.1g | 7.0g | 9.0g | 8.1g |
| 稳定剂 | 磷酸三苯酯1.7g，亚磷酸三苯酯1.7g | 磷酸三苯酯1.7g，亚磷酸三苯酯1.7g | 磷酸三苯酯1.6g，亚磷酸三苯酯1.5g | 磷酸三苯酯1.5g，亚磷酸三苯酯1.9g |
| 特性粘度（η） | 0.756 | 0.782 | 0.761 | 0.778 |
| 熔点 | 235℃ | 165℃～180℃ | 232℃ | 170℃～185℃ |
Claims (10)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210017355.2A CN102558517B (zh) | 2012-01-19 | 2012-01-19 | 生态多功能三元共聚petg聚酯及其制备方法和由该聚酯制备单向拉伸热收缩膜的方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210017355.2A CN102558517B (zh) | 2012-01-19 | 2012-01-19 | 生态多功能三元共聚petg聚酯及其制备方法和由该聚酯制备单向拉伸热收缩膜的方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102558517A true CN102558517A (zh) | 2012-07-11 |
| CN102558517B CN102558517B (zh) | 2014-03-19 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210017355.2A Active CN102558517B (zh) | 2012-01-19 | 2012-01-19 | 生态多功能三元共聚petg聚酯及其制备方法和由该聚酯制备单向拉伸热收缩膜的方法 |
Country Status (1)
| Country | Link |
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| CN (1) | CN102558517B (zh) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103602043A (zh) * | 2013-11-21 | 2014-02-26 | 中国纺织科学研究院 | 聚酯薄膜及其制备方法 |
| CN107459636A (zh) * | 2017-09-18 | 2017-12-12 | 江苏景宏新材料科技有限公司 | 一种具有低起始收缩温度的聚酯热收缩膜及其制备方法 |
| TWI681989B (zh) * | 2018-05-21 | 2020-01-11 | 南韓商Ｓｋｃ股份有限公司 | 熱收縮膜及其製備方法 |
| CN111205441A (zh) * | 2019-12-30 | 2020-05-29 | 长垣县源宏包装新材料有限公司 | 一种包装用高收缩率、高热封粘性聚酯产品的制备工艺 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004123984A (ja) * | 2002-10-04 | 2004-04-22 | Toyobo Co Ltd | 共重合ポリエステル |
| JP2005187562A (ja) * | 2003-12-25 | 2005-07-14 | Toyobo Co Ltd | インサート成形用ポリエステルフィルム |
| CN101959927A (zh) * | 2008-03-07 | 2011-01-26 | 伊士曼化工公司 | 相溶的聚酯共混物以及由此制备的收缩膜 |
-
2012
- 2012-01-19 CN CN201210017355.2A patent/CN102558517B/zh active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004123984A (ja) * | 2002-10-04 | 2004-04-22 | Toyobo Co Ltd | 共重合ポリエステル |
| JP2005187562A (ja) * | 2003-12-25 | 2005-07-14 | Toyobo Co Ltd | インサート成形用ポリエステルフィルム |
| CN101959927A (zh) * | 2008-03-07 | 2011-01-26 | 伊士曼化工公司 | 相溶的聚酯共混物以及由此制备的收缩膜 |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103602043A (zh) * | 2013-11-21 | 2014-02-26 | 中国纺织科学研究院 | 聚酯薄膜及其制备方法 |
| CN103602043B (zh) * | 2013-11-21 | 2015-12-09 | 中国纺织科学研究院 | 聚酯薄膜及其制备方法 |
| CN107459636A (zh) * | 2017-09-18 | 2017-12-12 | 江苏景宏新材料科技有限公司 | 一种具有低起始收缩温度的聚酯热收缩膜及其制备方法 |
| CN107459636B (zh) * | 2017-09-18 | 2021-04-13 | 江苏景宏新材料科技有限公司 | 一种具有低起始收缩温度的聚酯热收缩膜及其制备方法 |
| TWI681989B (zh) * | 2018-05-21 | 2020-01-11 | 南韓商Ｓｋｃ股份有限公司 | 熱收縮膜及其製備方法 |
| US10994880B2 (en) | 2018-05-21 | 2021-05-04 | Skc Co., Ltd. | Heat shrinkable film and preparation method thereof |
| US11655062B2 (en) | 2018-05-21 | 2023-05-23 | Sk Microworks Co., Ltd. | Heat shrinkable film and preparation method thereof |
| CN111205441A (zh) * | 2019-12-30 | 2020-05-29 | 长垣县源宏包装新材料有限公司 | 一种包装用高收缩率、高热封粘性聚酯产品的制备工艺 |
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| Publication number | Publication date |
|---|---|
| CN102558517B (zh) | 2014-03-19 |
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Owner name: YAN YINFENG Free format text: FORMER OWNER: YAO XUEYUAN Effective date: 20141219 Owner name: WEIHUI YINJINDA FILM CO., LTD. Free format text: FORMER OWNER: YAN YOUMEI Effective date: 20141219 |
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Inventor after: Yao Xueyuan Inventor after: Yan Dimei Inventor after: Yan Yinfeng Inventor before: Yao Xueyuan Inventor before: Yan Dimei |
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Free format text: CORRECT: ADDRESS; FROM: 213002 CHANGZHOU, JIANGSU PROVINCE TO: 453000 XINXIANG, HENAN PROVINCE Free format text: CORRECT: INVENTOR; FROM: YAO XUEYUAN YAN YOUMEI TO: YAO XUEYUAN YAN YOUMEI YAN YINFENG |
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Effective date of registration: 20141219 Address after: 301 room 2, unit 35, Jianye garden, Xinxiang, Henan 453000, China Patentee after: Yan Yinfeng Patentee after: YINJINDA FILM CO., LTD. WEIHUI CITY Address before: 213002, Room 302, unit 25, new North Lane, bell tower area, Changzhou, Jiangsu Patentee before: Yao Xueyuan Patentee before: Yan Dimei |
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Denomination of invention: Ecological multifunctional ternary copolymerization PETG (Polyethylene Terephthalate Glycol) polyester, preparation method of polyester, and method for preparing unidirectional stretching heat-shrinkable film from polyester Effective date of registration: 20150408 Granted publication date: 20140319 Pledgee: Weihui City Finance Bureau Pledgor: Yan Yinfeng|Weihui City, the silver of the film Limited Registration number: 2015990000267 |
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Address after: 301 room 2, unit 35, Jianye garden, Xinxiang, Henan 453000, China Patentee after: Yan Yinfeng Patentee after: Henan silver Kingdom new materials Limited by Share Ltd Address before: 301 room 2, unit 35, Jianye garden, Xinxiang, Henan 453000, China Patentee before: Yan Yinfeng Patentee before: YINJINDA FILM CO., LTD. WEIHUI CITY |
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Change date: 20180425 Registration number: 2015990000267 Pledgor after: Yan Yin Feng Pledgor after: Henan silver Jin Da new material Limited by Share Ltd Pledgor before: Yan Yin Feng Pledgor before: Weihui Yinjinda Film Co., Ltd. |
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Effective date of registration: 20181127 Address after: 453000 Tangzhuang Town, Weihui City, Xinxiang City, Henan Province Patentee after: Henan silver Kingdom new materials Limited by Share Ltd Address before: Room 301, Unit 2, Building 35, Jianye Garden, Xinxiang City, Henan Province Co-patentee before: Henan silver Kingdom new materials Limited by Share Ltd Patentee before: Yan Yinfeng |
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Denomination of invention: Ecological multifunctional ternary copolymerization PETG (Polyethylene Terephthalate Glycol) polyester, preparation method of polyester, and method for preparing unidirectional stretching heat-shrinkable film from polyester Effective date of registration: 20190419 Granted publication date: 20140319 Pledgee: Weihui Investment Group Limited Pledgor: Henan silver Kingdom new materials Limited by Share Ltd Registration number: 2019990000343 |
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