CN102544505A - 磷酸铁锂正极材料的表面改性方法 - Google Patents
磷酸铁锂正极材料的表面改性方法 Download PDFInfo
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- CN102544505A CN102544505A CN2011104196173A CN201110419617A CN102544505A CN 102544505 A CN102544505 A CN 102544505A CN 2011104196173 A CN2011104196173 A CN 2011104196173A CN 201110419617 A CN201110419617 A CN 201110419617A CN 102544505 A CN102544505 A CN 102544505A
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- China
- Prior art keywords
- iron phosphate
- lithium iron
- phosphate positive
- reactor
- plasma
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- GELKBWJHTRAYNV-UHFFFAOYSA-K lithium iron phosphate Chemical compound [Li+].[Fe+2].[O-]P([O-])([O-])=O GELKBWJHTRAYNV-UHFFFAOYSA-K 0.000 title claims abstract description 93
- 239000010406 cathode material Substances 0.000 title abstract description 5
- 238000002715 modification method Methods 0.000 title abstract 3
- 239000000463 material Substances 0.000 claims abstract description 137
- 238000000034 method Methods 0.000 claims abstract description 57
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 34
- 239000000178 monomer Substances 0.000 claims abstract description 33
- 239000000843 powder Substances 0.000 claims abstract description 29
- 229920001940 conductive polymer Polymers 0.000 claims abstract description 28
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 11
- 238000003682 fluorination reaction Methods 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 239000007789 gas Substances 0.000 claims description 41
- 229910052493 LiFePO4 Inorganic materials 0.000 claims description 31
- 229910010707 LiFePO 4 Inorganic materials 0.000 claims description 25
- 239000002322 conducting polymer Substances 0.000 claims description 23
- 238000005516 engineering process Methods 0.000 claims description 23
- 238000012986 modification Methods 0.000 claims description 20
- 230000004048 modification Effects 0.000 claims description 20
- 239000012159 carrier gas Substances 0.000 claims description 17
- 150000003254 radicals Chemical class 0.000 claims description 16
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 14
- 238000007599 discharging Methods 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 13
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims description 12
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 claims description 12
- 229910052760 oxygen Inorganic materials 0.000 claims description 10
- 229910052698 phosphorus Inorganic materials 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 8
- 230000009471 action Effects 0.000 claims description 7
- 229920002521 macromolecule Polymers 0.000 claims description 7
- 229920000128 polypyrrole Polymers 0.000 claims description 6
- 229920000123 polythiophene Polymers 0.000 claims description 6
- 229930192474 thiophene Natural products 0.000 claims description 6
- 230000005495 cold plasma Effects 0.000 claims description 5
- 150000003233 pyrroles Chemical class 0.000 claims description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 4
- 229920000767 polyaniline Polymers 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- 229910052786 argon Inorganic materials 0.000 claims description 2
- 239000001307 helium Substances 0.000 claims description 2
- 229910052734 helium Inorganic materials 0.000 claims description 2
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 229910052731 fluorine Inorganic materials 0.000 abstract description 4
- 229910052717 sulfur Inorganic materials 0.000 abstract description 4
- 238000004073 vulcanization Methods 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 238000005253 cladding Methods 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 230000002441 reversible effect Effects 0.000 description 32
- 239000000126 substance Substances 0.000 description 11
- 238000003760 magnetic stirring Methods 0.000 description 10
- 239000007788 liquid Substances 0.000 description 8
- 238000005303 weighing Methods 0.000 description 8
- 239000010405 anode material Substances 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 229910001416 lithium ion Inorganic materials 0.000 description 5
- 239000004065 semiconductor Substances 0.000 description 5
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 229910021645 metal ion Inorganic materials 0.000 description 3
- 239000003607 modifier Substances 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000011268 mixed slurry Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 238000005987 sulfurization reaction Methods 0.000 description 2
- 230000002194 synthesizing effect Effects 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000005955 Ferric phosphate Substances 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000001312 dry etching Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 229940032958 ferric phosphate Drugs 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 238000009616 inductively coupled plasma Methods 0.000 description 1
- WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 description 1
- 229910000399 iron(III) phosphate Inorganic materials 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000010532 solid phase synthesis reaction Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103985845A (zh) * | 2014-05-29 | 2014-08-13 | 中国科学院长春应用化学研究所 | 一种改性磷酸亚铁锂复合材料的制备方法 |
CN104264487A (zh) * | 2014-10-21 | 2015-01-07 | 苏州大学 | 导电化学纤维的制备方法及其制备装置 |
CN104358011A (zh) * | 2014-10-21 | 2015-02-18 | 苏州大学 | 导电纤维的制备方法及其制备装置 |
JP2016518958A (ja) * | 2013-03-08 | 2016-06-30 | コリア ベーシック サイエンス インスティテュート | リチウム遷移金属酸化物をfパッシベーションする方法 |
CN106298066A (zh) * | 2016-08-17 | 2017-01-04 | 梅庆波 | 一种柔性透明导电膜的制备方法 |
CN106654234A (zh) * | 2017-02-06 | 2017-05-10 | 深圳市斯诺实业发展股份有限公司 | 一种锂电池正极材料及其制备方法 |
CN107140696A (zh) * | 2017-05-25 | 2017-09-08 | 宁波工程学院 | 一种锂离子电池高镍正极材料的等离子体强化氧化焙烧方法 |
CN107293713A (zh) * | 2017-06-19 | 2017-10-24 | 中国科学院长春应用化学研究所 | 一种超低温锂离子电池复合正极材料及其制备方法 |
CN108448100A (zh) * | 2018-04-14 | 2018-08-24 | 齐鲁工业大学 | 一种表面化学修饰的磷酸铁锂及其应用 |
CN109461933A (zh) * | 2018-10-30 | 2019-03-12 | 东南大学 | 一种提升锂离子电池正极材料磷酸铁锂性能的改性方法 |
CN109935809A (zh) * | 2019-02-28 | 2019-06-25 | 湖北锂诺新能源科技有限公司 | 一种氟化铝包覆磷酸钒锂正极材料的制备方法 |
WO2020001561A1 (zh) * | 2018-06-29 | 2020-01-02 | 比亚迪股份有限公司 | 锂离子电池正极材料及其制备方法、锂离子电池正极和全固态锂电池 |
CN111933939A (zh) * | 2020-07-27 | 2020-11-13 | 山东宏匀纳米科技有限公司 | 包覆正极材料的方法、电池和制备电池的方法 |
CN112209362A (zh) * | 2020-09-27 | 2021-01-12 | 电子科技大学 | 一种等离子体诱导活化氟化碳的方法及锂一次电池制备 |
CN115775883A (zh) * | 2023-02-13 | 2023-03-10 | 四川富临新能源科技有限公司 | 磷酸铁锂正极材料的表面改性方法 |
CN116281933A (zh) * | 2023-01-05 | 2023-06-23 | 电子科技大学 | 氟代磷酸铁材料及制备方法与应用 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20090286157A1 (en) * | 2008-05-16 | 2009-11-19 | Zonghai Chen | Surface modification agents for lithium batteries |
CN102148368A (zh) * | 2011-02-24 | 2011-08-10 | 宁波工程学院 | 一种锂离子电池正极复合材料的制备方法及其专用装置 |
-
2011
- 2011-12-15 CN CN201110419617.3A patent/CN102544505B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20090286157A1 (en) * | 2008-05-16 | 2009-11-19 | Zonghai Chen | Surface modification agents for lithium batteries |
CN102148368A (zh) * | 2011-02-24 | 2011-08-10 | 宁波工程学院 | 一种锂离子电池正极复合材料的制备方法及其专用装置 |
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016518958A (ja) * | 2013-03-08 | 2016-06-30 | コリア ベーシック サイエンス インスティテュート | リチウム遷移金属酸化物をfパッシベーションする方法 |
CN103985845A (zh) * | 2014-05-29 | 2014-08-13 | 中国科学院长春应用化学研究所 | 一种改性磷酸亚铁锂复合材料的制备方法 |
CN104264487A (zh) * | 2014-10-21 | 2015-01-07 | 苏州大学 | 导电化学纤维的制备方法及其制备装置 |
CN104358011A (zh) * | 2014-10-21 | 2015-02-18 | 苏州大学 | 导电纤维的制备方法及其制备装置 |
CN106298066A (zh) * | 2016-08-17 | 2017-01-04 | 梅庆波 | 一种柔性透明导电膜的制备方法 |
CN106298066B (zh) * | 2016-08-17 | 2017-07-28 | 石狮市森科智能科技有限公司 | 一种柔性透明导电膜的制备方法 |
CN106654234A (zh) * | 2017-02-06 | 2017-05-10 | 深圳市斯诺实业发展股份有限公司 | 一种锂电池正极材料及其制备方法 |
CN107140696A (zh) * | 2017-05-25 | 2017-09-08 | 宁波工程学院 | 一种锂离子电池高镍正极材料的等离子体强化氧化焙烧方法 |
CN107293713A (zh) * | 2017-06-19 | 2017-10-24 | 中国科学院长春应用化学研究所 | 一种超低温锂离子电池复合正极材料及其制备方法 |
CN108448100A (zh) * | 2018-04-14 | 2018-08-24 | 齐鲁工业大学 | 一种表面化学修饰的磷酸铁锂及其应用 |
WO2020001561A1 (zh) * | 2018-06-29 | 2020-01-02 | 比亚迪股份有限公司 | 锂离子电池正极材料及其制备方法、锂离子电池正极和全固态锂电池 |
CN109461933A (zh) * | 2018-10-30 | 2019-03-12 | 东南大学 | 一种提升锂离子电池正极材料磷酸铁锂性能的改性方法 |
CN109935809A (zh) * | 2019-02-28 | 2019-06-25 | 湖北锂诺新能源科技有限公司 | 一种氟化铝包覆磷酸钒锂正极材料的制备方法 |
CN111933939A (zh) * | 2020-07-27 | 2020-11-13 | 山东宏匀纳米科技有限公司 | 包覆正极材料的方法、电池和制备电池的方法 |
CN111933939B (zh) * | 2020-07-27 | 2022-02-08 | 山东宏匀纳米科技有限公司 | 包覆正极材料的方法、电池和制备电池的方法 |
CN112209362A (zh) * | 2020-09-27 | 2021-01-12 | 电子科技大学 | 一种等离子体诱导活化氟化碳的方法及锂一次电池制备 |
CN112209362B (zh) * | 2020-09-27 | 2021-12-03 | 电子科技大学 | 一种等离子体诱导活化氟化碳的方法及锂一次电池制备 |
CN116281933A (zh) * | 2023-01-05 | 2023-06-23 | 电子科技大学 | 氟代磷酸铁材料及制备方法与应用 |
CN115775883A (zh) * | 2023-02-13 | 2023-03-10 | 四川富临新能源科技有限公司 | 磷酸铁锂正极材料的表面改性方法 |
CN115775883B (zh) * | 2023-02-13 | 2023-06-02 | 四川富临新能源科技有限公司 | 磷酸铁锂正极材料的表面改性方法 |
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Effective date of registration: 20201209 Address after: No. 111, Huaguo Road, Zhangwan District, Shiyan City, Hubei Province 442000 Patentee after: HUBEI WANRUN NEW ENERGY TECHNOLOGY DEVELOPMENT Co.,Ltd. Address before: No. 111, Huaguo Road, Zhangwan District, Shiyan City, Hubei Province Patentee before: HUBEI WANRUN NEW ENERGY TECHNOLOGY DEVELOPMENT Co.,Ltd. Patentee before: Ningbo University of Technology |