CN102516699A - ABS (Acrylonitrile Butadiene Styrene) weather-resistant and anti-ageing functional master batch - Google Patents
ABS (Acrylonitrile Butadiene Styrene) weather-resistant and anti-ageing functional master batch Download PDFInfo
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- CN102516699A CN102516699A CN2011104034018A CN201110403401A CN102516699A CN 102516699 A CN102516699 A CN 102516699A CN 2011104034018 A CN2011104034018 A CN 2011104034018A CN 201110403401 A CN201110403401 A CN 201110403401A CN 102516699 A CN102516699 A CN 102516699A
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Abstract
The invention discloses an ABS (Acrylonitrile Butadiene Styrene) weather-resistant and anti-ageing functional master batch, which consists of the following raw materials in parts by weight: 20-30 parts of AS (Acrylonitrile Styrene) powder, 6-8 parts of high glue powder, 2-4 parts of a nano-oxide, 1-3 parts of an antioxidant, 5-10 parts of an ultraviolet absorber and 1-2 parts of a processing aid. By adding the functional master batch disclosed by the invention into ABS, the anti-ageing performance and weather resistance of ABS can be enhanced greatly.
Description
Technical field
The present invention relates to the weather-proof anti-aging functional master batch of a kind of ABS.
Background technology
ABS, promptly acrylonitrile-styrene-butadienecopolymer is a kind of moulding that is easy to; And intensity and toughness better polymerization thing have purposes widely, as are used for the shell of air-conditioning; Switch or the like, and, cause its easy slow oxidation owing to often contain two keys in the Acrylonitrile Butadiene; Air-conditioning is elongated duration of service, and its surperficial yellowing is a good illustration, in abominable area of a lot of weather condition such as the Xinjiang region of China; Because its latitude is higher, ultraviolet ray is strong, and weather condition are changeable and abominable; The device (like communication equipment) that causes using the ABS material is easy ageing often, adopts common method of modifying promptly in the ABS matrix, to add oxidation inhibitor, still can not well deal with problems.
Summary of the invention
The purpose of this invention is to provide the weather-proof anti-aging functional master batch of a kind of ABS.
The technical scheme that the present invention taked is:
The weather-proof anti-aging functional master batch of a kind of ABS, its raw material by following mass parts is formed: the nano-oxide of the AS powder of 20-30 part, the ABS high glue powder of 6-8 part, 2-4 part, the oxidation inhibitor of 1-3 part, the UV light absorber of 5-10 part, the processing aid of 1-2 part.
Described nano-oxide is at least a of nano-titanium oxide, nano-cerium oxide, nano zine oxide.
Described oxidation inhibitor is at least a in oxidation inhibitor 168, antioxidant 1076, oxidation inhibitor 215, oxidation inhibitor 561, oxidation inhibitor 626, antioxidant 3114, oxidation inhibitor 225, antioxidant 330, antioxidant 1010, oxidation inhibitor 1098, the oxidation inhibitor 900.
Described UV light absorber is at least a among UV944, UV770, UV9, UV-P, UV531, UV326, the UV327.
Described processing aid is at least a in EBS, calcium stearate, Magnesium Stearate, oleylamide, polyethylene wax, microcrystalline wax, silicone powder, methyl phenyl silicone oil, hydroxy silicon oil, the butyl stearate.
The method for preparing the weather-proof anti-aging functional master batch of a kind of ABS: may further comprise the steps:
1) place mixing machine to mix each raw material in proportion;
2) will go up the compound in step places forcing machine to melt extrude granulation.
The invention has the beneficial effects as follows: functional master batch of the present invention adds among the ABS, the anti-aging and weather resistance of raising ABS that can be bigger.
Embodiment
The preparation method of the weather-proof anti-aging functional master batch of a kind of ABS: may further comprise the steps:
1) place mixing machine to mix each raw material in proportion;
2) will go up the compound in step and place forcing machine to melt extrude granulation, the screw slenderness ratio of forcing machine is 40.
Below in conjunction with specific embodiment prescription of the present invention is done further explanation:
Embodiment 1:
The weather-proof anti-aging functional master batch of a kind of ABS, its prescription is formed like following table:
Embodiment 2:
The weather-proof anti-aging functional master batch of a kind of ABS, its prescription is formed like following table:
Embodiment 3:
The weather-proof anti-aging functional master batch of a kind of ABS, its prescription is formed like following table:
Embodiment 4:
The weather-proof anti-aging functional master batch of a kind of ABS, its prescription is formed like following table:
Embodiment 5:
The weather-proof anti-aging functional master batch of a kind of ABS, its prescription is formed like following table:
Embodiment 6:
The weather-proof anti-aging functional master batch of a kind of ABS, its prescription is formed like following table:
Embodiment 7:
The weather-proof anti-aging functional master batch of a kind of ABS, its prescription is formed like following table:
The used silicone powder of the present invention model is: SK20R.
The masterbatch that embodiment 1 obtains adds ABS (manufacturer: BASF to; Trade(brand)name: Terluran ABS, model: GP-22), after injection molding is batten; Outdoor in Xinjiang (85 ° 9 ' 42 of east longitude "; after north latitude 42 ° 14 ' 16 ") exposes 1 year (2010.09.01-2011.09.01), aberration △ E is changed to 4.1 (identical time same material outdoor in Guangzhou (23 ° 56 ' 16 of north latitude ", east longitude 112 ° 57 ' 15 ") exposes 1 year aberration △ E and is changed to 2.57); (the tensile strength testing standard: ASTM D 882) conservation rate is 82.21% to tensile strength, and (testing standard: ASTM D256) conservation rate is 78.13% to the socle girder notched Izod impact strength.
Because masterbatch of the present invention adds among the ABS, can improve the weathering resistance and the anti-ageing property of material, makes it be particularly useful for the comparatively abominable area of weather condition.
Claims (6)
1. weather-proof anti-aging functional master batch of ABS, it is characterized in that: its raw material by following mass parts is formed: the nano-oxide of the AS powder of 20-30 part, the ABS high glue powder of 6-8 part, 2-4 part, the oxidation inhibitor of 1-3 part, the UV light absorber of 5-10 part, the processing aid of 1-2 part.
2. the weather-proof anti-aging functional master batch of a kind of ABS according to claim 1 is characterized in that: described nano-oxide is at least a of nano-titanium oxide, nano-cerium oxide, nano zine oxide.
3. the weather-proof anti-aging functional master batch of a kind of ABS according to claim 1 is characterized in that: described oxidation inhibitor is at least a in oxidation inhibitor 168, antioxidant 1076, oxidation inhibitor 215, oxidation inhibitor 561, oxidation inhibitor 626, antioxidant 3114, oxidation inhibitor 225, antioxidant 330, antioxidant 1010, oxidation inhibitor 1098, the oxidation inhibitor 900.
4. the weather-proof anti-aging functional master batch of a kind of ABS according to claim 1 is characterized in that: described UV light absorber is at least a among UV944, UV770, UV9, UV-P, UV531, UV326, the UV327.
5. the weather-proof anti-aging functional master batch of a kind of ABS according to claim 1 is characterized in that: described processing aid is at least a in EBS, calcium stearate, Magnesium Stearate, oleylamide, polyethylene wax, microcrystalline wax, silicone powder, methyl phenyl silicone oil, hydroxy silicon oil, the butyl stearate.
6. the method for preparing the weather-proof anti-aging functional master batch of the described a kind of ABS of claim 1: may further comprise the steps:
1) place mixing machine to mix each raw material in proportion;
2) will go up the compound in step places forcing machine to melt extrude granulation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110403401.8A CN102516699B (en) | 2011-12-07 | 2011-12-07 | ABS (Acrylonitrile Butadiene Styrene) weather-resistant and anti-ageing functional master batch |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110403401.8A CN102516699B (en) | 2011-12-07 | 2011-12-07 | ABS (Acrylonitrile Butadiene Styrene) weather-resistant and anti-ageing functional master batch |
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| Publication Number | Publication Date |
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| CN102516699A true CN102516699A (en) | 2012-06-27 |
| CN102516699B CN102516699B (en) | 2014-05-14 |
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| CN201110403401.8A Active CN102516699B (en) | 2011-12-07 | 2011-12-07 | ABS (Acrylonitrile Butadiene Styrene) weather-resistant and anti-ageing functional master batch |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102977597A (en) * | 2012-08-20 | 2013-03-20 | 安徽凯迪电气有限公司 | Polytetrafluoroethylene modified nylon PA66 particle material, as well as its preparation method and application in vehicles |
| CN102977598A (en) * | 2012-08-20 | 2013-03-20 | 安徽凯迪电气有限公司 | PBT modified nylon PA66 particle material, as well as its preparation method and application in vehicles |
| CN104479321A (en) * | 2014-11-20 | 2015-04-01 | 苏州新区佳合塑胶有限公司 | Anti-oxidative ABS/PC plastic for automobile instruments/meters |
| CN106700391A (en) * | 2016-12-02 | 2017-05-24 | 长兴天晟能源科技有限公司 | Functional master batch for improving weather resistance of ABS (acrylonitrile butadiene styrene copolymers) |
| CN107974000A (en) * | 2017-11-22 | 2018-05-01 | 杭州富阳鼎创科技有限公司 | plastic composite function master batch |
| CN110564072A (en) * | 2019-10-25 | 2019-12-13 | 长春工业大学 | Preparation method of high-rigidity, high-toughness and aging-resistant ABS resin |
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| CN101824202A (en) * | 2010-04-29 | 2010-09-08 | 广州合成材料研究院有限公司 | Composite processing stabilizing agent for ABS (Acrylonitrile Butadiene Styrene) and HIPS (High Impact Polystyrene) resins |
| CN101851384A (en) * | 2009-04-03 | 2010-10-06 | 上海锦湖日丽塑料有限公司 | Fireproof anti-ultraviolet anti-static ABS material and preparation method thereof |
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| JP2001253988A (en) * | 2000-03-13 | 2001-09-18 | Toyo Ink Mfg Co Ltd | Colored resin composition and molded article of the same |
| CN101851384A (en) * | 2009-04-03 | 2010-10-06 | 上海锦湖日丽塑料有限公司 | Fireproof anti-ultraviolet anti-static ABS material and preparation method thereof |
| CN101824202A (en) * | 2010-04-29 | 2010-09-08 | 广州合成材料研究院有限公司 | Composite processing stabilizing agent for ABS (Acrylonitrile Butadiene Styrene) and HIPS (High Impact Polystyrene) resins |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102977597A (en) * | 2012-08-20 | 2013-03-20 | 安徽凯迪电气有限公司 | Polytetrafluoroethylene modified nylon PA66 particle material, as well as its preparation method and application in vehicles |
| CN102977598A (en) * | 2012-08-20 | 2013-03-20 | 安徽凯迪电气有限公司 | PBT modified nylon PA66 particle material, as well as its preparation method and application in vehicles |
| CN102977597B (en) * | 2012-08-20 | 2015-08-12 | 安徽凯迪电气有限公司 | A kind of polytetrafluoroethylmodified modified nylon PA66 particle material and preparation method thereof and the application on automobile |
| CN102977598B (en) * | 2012-08-20 | 2015-12-02 | 安徽凯迪电气有限公司 | Nylon PA66 particle material of a kind of PBT modification and preparation method thereof and the application on automobile |
| CN104479321A (en) * | 2014-11-20 | 2015-04-01 | 苏州新区佳合塑胶有限公司 | Anti-oxidative ABS/PC plastic for automobile instruments/meters |
| CN106700391A (en) * | 2016-12-02 | 2017-05-24 | 长兴天晟能源科技有限公司 | Functional master batch for improving weather resistance of ABS (acrylonitrile butadiene styrene copolymers) |
| CN107974000A (en) * | 2017-11-22 | 2018-05-01 | 杭州富阳鼎创科技有限公司 | plastic composite function master batch |
| CN110564072A (en) * | 2019-10-25 | 2019-12-13 | 长春工业大学 | Preparation method of high-rigidity, high-toughness and aging-resistant ABS resin |
| CN110564072B (en) * | 2019-10-25 | 2021-12-21 | 长春工业大学 | Preparation method of high-rigidity, high-toughness and aging-resistant ABS resin |
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| Publication number | Publication date |
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| CN102516699B (en) | 2014-05-14 |
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