CN107828174A - A kind of non-yellowing key and its manufacture method - Google Patents
A kind of non-yellowing key and its manufacture method Download PDFInfo
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- CN107828174A CN107828174A CN201710948411.7A CN201710948411A CN107828174A CN 107828174 A CN107828174 A CN 107828174A CN 201710948411 A CN201710948411 A CN 201710948411A CN 107828174 A CN107828174 A CN 107828174A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/2224—Magnesium hydroxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
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Abstract
The present invention relates to key technical field, and in particular to a kind of non-yellowing key and its manufacture method, the non-yellowing key include the raw material of following parts by weight：50 90 parts of ABS resin, 20 40 parts of AS resins, 10 20 parts of halogen-free flame retardants, 15 parts of compatilizer, 13 parts of color inhibition agent, 0.5 1.5 parts of UV resistant agent.For the non-yellowing key of the present invention by using AS resins, color inhibition agent and UV resistant agent, color inhibition effect is good, can keep original white effect for a long time；Also there is good mechanical and physical performance.
Description
Technical field
The present invention relates to key technical field, and in particular to a kind of non-yellowing key and its manufacture method.
Background technology
Conventional white key plastic-injection materials'use is the material of high-light ABS 757, under conventional environment, by about 1~
After the time use of 2 years, these originally white key surfaces can start jaundice discoloration, it is impossible to the influence of tenable environment factor,
Extremely unsightly.
The content of the invention
In order to overcome shortcoming and defect present in prior art, it is an object of the invention to provide a kind of non-yellowing qin
Key, the non-yellowing key color inhibition effect is good, can keep original white effect for a long time；Also there is good mechanical-physical
Energy.
Another object of the present invention is to provide a kind of manufacture method of non-yellowing key, the manufacture method step is simple,
Convenient operation and control, steady quality, production efficiency is high, and production cost is low, can large-scale industrial production.
The purpose of the present invention is achieved through the following technical solutions：A kind of non-yellowing key, the non-yellowing key are included such as
The raw material of lower parts by weight：
The non-yellowing key of the present invention strictly controls each original by using AS resins, color inhibition agent and UV resistant agent
The weight proportion of material, obtained non-yellowing key color inhibition effect is good, can keep original white effect for a long time；Also have good
Mechanical and physical performance.
Preferably, the ABS resin be acrylonitrile unit content in 15%-25%, butadiene unit content in 25%-
35%th, acrylonitrile-butadiene-styrene copolymer of the styrene units content in 40%-60%.
The present invention is by using acrylonitrile unit content in 15%-25%, butadiene unit content in 25%-35%, benzene
Acetate unit content 40%-60% acrylonitrile-butadiene-styrene copolymer as ABS resin, have excellent dimensions steady
Qualitative, prominent impact resistance, heat resistance, dielectricity, wearability, lustrous surface is good, the advantages that easy application and coloring.
Preferably, the AS resins are acrylonitrile unit weight content in the acrylonitrile-styrene copolymerized of 60%-80%
Thing.
The present invention by using acrylonitrile unit weight content 60%-80% acrylonitritrile-styrene resin conduct
AS resins, the anti-yellowing property of non-yellowing key can be improved.
Preferably, the fire retardant is with weight by poly cyanamid cyanurate, triphenyl phosphate, magnesium hydroxide and montmorillonite
Than the mixture of 1-2: 0.8-1.2: 1: 0.4-0.8 composition.
The present invention answers by using poly cyanamid cyanurate, triphenyl phosphate, magnesium hydroxide and montmorillonite as fire retardant
With use, and it is 1-2: 0.8-1.2: 1: 0.4-0.8 to control its weight ratio so that material has preferable fire resistance.
Preferably, the compatilizer is by methyl styrene, methacrylonitrile, methacrylic acid and methyl methacrylate
The quaternary atactic copolymer formed is copolymerized than 2-4: 2-4: 0.8-1.2: 0.5-1.5 with weight.
The present invention is by using methyl styrene, methacrylonitrile, methacrylic acid and methyl methacrylate as phase
Hold agent compounding use, and it is 2-4: 2-4: 0.8-1.2: 0.5-1.5 to control its weight ratio, can improve inorganic filler and organic resin
Compatibility, the tensile strength and tearing strength of material are improved, realize high filling, reduce resin demand, improve rheological performance, carry
High surface finish is scratch resistant white.
Preferably, the color inhibition agent is by 2- (2 '-hydroxyl -3 ', 5 '-diamyl phenyl)-BTA, dibutyl hydroxyl
The mixture that base toluene and 2-hydroxy-4-n-octoxybenzophenone are formed with weight ratio 0.5-1.5: 1.5-2.5: 1.
The present invention by using 2- (2 '-hydroxyl -3 ', 5 '-diamyl phenyl)-BTA, dibutyl hydroxy toluene and
2-hydroxy-4-n-octoxybenzophenone is as color inhibition agent compounding use, and it is 0.5-1.5: 1.5-2.5 to control its weight ratio
: 1, obtained non-yellowing key color inhibition effect is good, can keep original white effect for a long time.
Preferably, the UV resistant agent is by 2,2,6,6- tetramethyl -4- piperidyls stearates, 4- benzoxies
Base -2,2,6,6- tetramethyl piperidines and 2-hydroxy-4-n-octoxybenzophenone are formed with weight ratio 1: 0.8-1.2: 1.4-2.2
Mixture.
The present invention is by using 2,2,6,6- tetramethyl -4- piperidyls stearates, 4- benzoyloxys -2,2, and 6,6- tetra-
Methyl piperidine and 2-hydroxy-4-n-octoxybenzophenone are as UV resistant agent compounding use, and it is 1 to control weight ratio:
0.8-1.2: 1.4-2.2, ultraviolet can be absorbed strongly, so as to improve the anti-yellowing property of non-yellowing key.
Preferably, the non-yellowing key also includes filler 5-15 parts, and the filler is by diatomite, clay and stone
The mixture that English powder is formed with weight than 1: 1.5-2.5: 0.5-1.5.
The present invention, as filler compounding use, and controls its weight ratio as 1 by using diatomite, clay and silica flour
: 1.5-2.5: 0.5-1.5, the intensity and shock resistance of non-yellowing key can be improved.
Preferably, the non-yellowing key also includes antioxidant 0.5-1.5 parts, and the antioxidant is by four [β-(3,5- bis-
Tert-butyl-hydroxy phenyl) propionic acid] pentaerythrite, β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid octadecanol ester and three
The mixture that (2,4- di-tert-butyl-phenyls) phosphite ester is formed with weight than 1-2: 0.5-1.5: 1.
The present invention is by using four [β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid] pentaerythrites, the β-(uncles of 3,5- bis-
Butyl -4- hydroxy phenyls) propionic acid octadecanol ester and three (2,4- di-tert-butyl-phenyls) phosphite esters make as antioxidant compounding
With, and it is 1-2: 0.5-1.5: 1 to control its weight ratio, can delay or suppress the progress of material oxidation process, so as to prevent material
The aging of material simultaneously extends its service life.
A kind of manufacture method of non-yellowing key, each component is weighed by proportioning, and after being well mixed, melting mixing, extrusion is made
Grain, injection molding, non-yellowing key is made.
The beneficial effects of the present invention are：The non-yellowing key of the present invention is by using AS resins, color inhibition agent and anti-purple
Outside line agent, color inhibition effect is good, can keep original white effect for a long time；Also there is good mechanical and physical performance.
The manufacture method step of the present invention is simple, convenient operation and control, steady quality, and production efficiency is high, and production cost is low,
Can large-scale industrial production.
Embodiment
For the ease of the understanding of those skilled in the art, with reference to embodiment, the present invention is further illustrated, real
The content that the mode of applying refers to not is limitation of the invention.
Embodiment 1
A kind of non-yellowing key, the non-yellowing key include the raw material of following parts by weight：
The ABS resin is for acrylonitrile unit content in 15%, butadiene unit content in 25%, styrene units content
In 60% acrylonitrile-butadiene-styrene copolymer.
The AS resins are acrylonitritrile-styrene resin of the acrylonitrile unit weight content 60%.
The fire retardant is with weight ratio 1: 0.8 by poly cyanamid cyanurate, triphenyl phosphate, magnesium hydroxide and montmorillonite
: the mixture of 1: 0.4 composition.
The compatilizer is with weight by methyl styrene, methacrylonitrile, methacrylic acid and methyl methacrylate
The quaternary atactic copolymer formed than 2: 2: 0.8: 0.5 copolymerization.
The color inhibition agent is by 2- (2 '-hydroxyl -3 ', 5 '-diamyl phenyl)-BTA, dibutyl hydroxy toluene
The mixture formed with 2-hydroxy-4-n-octoxybenzophenone with weight ratio 0.5: 1.5: 1.
The UV resistant agent is by 2,2,6,6- tetramethyl -4- piperidyls stearates, 4- benzoyloxys -2,26,
The mixture that 6- tetramethyl piperidines and 2-hydroxy-4-n-octoxybenzophenone are formed with weight ratio 1: 0.8: 1.4.
The non-yellowing key also includes 5 parts of filler, and the filler is with weight by diatomite, clay and silica flour
Than the mixture of 1: 1.5: 0.5 composition.
The non-yellowing key also includes 0.5 part of antioxidant, and the antioxidant is by four [β-(3,5- di-t-butyl -4- hydroxyls
Base phenyl) propionic acid] pentaerythrite, β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid octadecanol ester and three (bis- tertiary fourths of 2,4-
Base phenyl) mixture that is formed with weight than 1: 0.5: 1 of phosphite ester.
A kind of manufacture method of non-yellowing key, each component is weighed by proportioning, and after being well mixed, melting mixing, extrusion is made
Grain, injection molding, non-yellowing key is made.
Embodiment 2
The difference of the present embodiment and above-described embodiment 1 is：The non-yellowing key includes the original of following parts by weight
Material：
The ABS resin is for acrylonitrile unit content in 17.5%, butadiene unit content in 27.5%, styrene units
Acrylonitrile-butadiene-styrene copolymer of the content 55%.
The AS resins are acrylonitritrile-styrene resin of the acrylonitrile unit weight content 65%.
The fire retardant is with weight ratio 1.2 by poly cyanamid cyanurate, triphenyl phosphate, magnesium hydroxide and montmorillonite:
The mixture of 0.9: 1: 0.5 composition.
The compatilizer is with weight by methyl styrene, methacrylonitrile, methacrylic acid and methyl methacrylate
The quaternary atactic copolymer formed than 2.5: 2.5: 0.9: 0.8 copolymerization.
The color inhibition agent is by 2- (2 '-hydroxyl -3 ', 5 '-diamyl phenyl)-BTA, dibutyl hydroxy toluene
The mixture formed with 2-hydroxy-4-n-octoxybenzophenone with weight ratio 0.8: 1.8: 1.
The UV resistant agent is by 2,2,6,6- tetramethyl -4- piperidyls stearates, 4- benzoyloxys -2,26,
The mixture that 6- tetramethyl piperidines and 2-hydroxy-4-n-octoxybenzophenone are formed with weight ratio 1: 0.9: 1.6.
The non-yellowing key also includes 8 parts of filler, and the filler is with weight by diatomite, clay and silica flour
Than the mixture of 1: 1.8: 0.8 composition.
The non-yellowing key also includes 0.8 part of antioxidant, and the antioxidant is by four [β-(3,5- di-t-butyl -4- hydroxyls
Base phenyl) propionic acid] pentaerythrite, β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid octadecanol ester and three (bis- tertiary fourths of 2,4-
Base phenyl) mixture that is formed with weight than 1.2: 0.8: 1 of phosphite ester.
Embodiment 3
The difference of the present embodiment and above-described embodiment 1 is：The non-yellowing key includes the original of following parts by weight
Material：
The ABS resin is for acrylonitrile unit content in 20%, butadiene unit content in 30%, styrene units content
In 50% acrylonitrile-butadiene-styrene copolymer.
The AS resins are acrylonitritrile-styrene resin of the acrylonitrile unit weight content 70%.
The fire retardant is with weight ratio 1.5: 1 by poly cyanamid cyanurate, triphenyl phosphate, magnesium hydroxide and montmorillonite
: the mixture of 1: 0.6 composition.
The compatilizer is with weight by methyl styrene, methacrylonitrile, methacrylic acid and methyl methacrylate
The quaternary atactic copolymer formed than 3: 3: 1: 1 copolymerization.
The color inhibition agent is by 2- (2 '-hydroxyl -3 ', 5 '-diamyl phenyl)-BTA, dibutyl hydroxy toluene
The mixture formed with 2-hydroxy-4-n-octoxybenzophenone with weight ratio 1: 2: 1.
The UV resistant agent is by 2,2,6,6- tetramethyl -4- piperidyls stearates, 4- benzoyloxys -2,26,
The mixture that 6- tetramethyl piperidines and 2-hydroxy-4-n-octoxybenzophenone are formed with weight ratio 1: 1: 1.8.
The non-yellowing key also includes 10 parts of filler, and the filler is with weight by diatomite, clay and silica flour
Mixture of the amount than 1: 2: 1 composition.
The non-yellowing key also includes 1 part of antioxidant, and the antioxidant is by four [β-(3,5- di-t-butyl -4- hydroxyls
Phenyl) propionic acid] pentaerythrite, β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid octadecanol ester and three (2,4- di-t-butyls
Phenyl) mixture that is formed with weight than 1.5: 1: 1 of phosphite ester.
Embodiment 4
The difference of the present embodiment and above-described embodiment 1 is：The non-yellowing key includes the original of following parts by weight
Material：
The ABS resin is for acrylonitrile unit content in 22.5%, butadiene unit content in 32.5%, styrene units
Acrylonitrile-butadiene-styrene copolymer of the content 45%.
The AS resins are acrylonitritrile-styrene resin of the acrylonitrile unit weight content 75%.
The fire retardant is with weight ratio 1.8 by poly cyanamid cyanurate, triphenyl phosphate, magnesium hydroxide and montmorillonite:
The mixture of 1.1: 1: 0.7 compositions.
The compatilizer is with weight by methyl styrene, methacrylonitrile, methacrylic acid and methyl methacrylate
The quaternary atactic copolymer formed than 3.5: 3.5: 1.1: 1.2 copolymerization.
The color inhibition agent is by 2- (2 '-hydroxyl -3 ', 5 '-diamyl phenyl)-BTA, dibutyl hydroxy toluene
The mixture formed with 2-hydroxy-4-n-octoxybenzophenone with weight ratio 1.2: 2.2: 1.
The UV resistant agent is by 2,2,6,6- tetramethyl -4- piperidyls stearates, 4- benzoyloxys -2,26,
The mixture that 6- tetramethyl piperidines and 2-hydroxy-4-n-octoxybenzophenone are formed with weight ratio 1: 1.1: 2.
The non-yellowing key also includes 12 parts of filler, and the filler is with weight by diatomite, clay and silica flour
Mixture of the amount than 1: 2.2: 1.2 composition.
The non-yellowing key also includes 1.2 parts of antioxidant, and the antioxidant is by four [β-(3,5- di-t-butyl -4- hydroxyls
Base phenyl) propionic acid] pentaerythrite, β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid octadecanol ester and three (bis- tertiary fourths of 2,4-
Base phenyl) mixture that is formed with weight than 1.8: 1.2: 1 of phosphite ester.
Embodiment 5
The difference of the present embodiment and above-described embodiment 1 is：The non-yellowing key includes the original of following parts by weight
Material：
The ABS resin is for acrylonitrile unit content in 25%, butadiene unit content in 35%, styrene units content
In 40% acrylonitrile-butadiene-styrene copolymer.
The AS resins are acrylonitritrile-styrene resin of the acrylonitrile unit weight content 80%.
The fire retardant is with weight ratio 2: 1.2 by poly cyanamid cyanurate, triphenyl phosphate, magnesium hydroxide and montmorillonite
: the mixture of 1: 0.8 composition.
The compatilizer is with weight by methyl styrene, methacrylonitrile, methacrylic acid and methyl methacrylate
The quaternary atactic copolymer formed than 4: 4: 1.2: 1.5 copolymerization.
The color inhibition agent is by 2- (2 '-hydroxyl -3 ', 5 '-diamyl phenyl)-BTA, dibutyl hydroxy toluene
The mixture formed with 2-hydroxy-4-n-octoxybenzophenone with weight ratio 1.5: 2.5: 1.
The UV resistant agent is by 2,2,6,6- tetramethyl -4- piperidyls stearates, 4- benzoyloxys -2,26,
The mixture that 6- tetramethyl piperidines and 2-hydroxy-4-n-octoxybenzophenone are formed with weight ratio 1: 1.2: 2.2.
The non-yellowing key also includes 15 parts of filler, and the filler is with weight by diatomite, clay and silica flour
Mixture of the amount than 1: 2.5: 1.5 composition.
The non-yellowing key also includes 1.5 parts of antioxidant, and the antioxidant is by four [β-(3,5- di-t-butyl -4- hydroxyls
Base phenyl) propionic acid] pentaerythrite, β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid octadecanol ester and three (bis- tertiary fourths of 2,4-
Base phenyl) mixture that is formed with weight than 2: 1.5: 1 of phosphite ester.
For the non-yellowing key of the present invention by using AS resins, color inhibition agent and UV resistant agent, color inhibition effect is good, can
To keep original white effect for a long time；Also there is good mechanical and physical performance.
The tensile strength of non-yellowing key produced by the present invention can reach 50-60MPa, and bending strength can reach 90-
100MPa, Rockwell hardness can reach 80-120, and elongation at break can reach 30%-50%, and specific insulation can reach 4
×1016-8×1016Ω cm, fire resistance can reach V0 levels.
Above-described embodiment is the preferable implementation of the present invention, and in addition, the present invention can be realized with other manner,
Do not depart from and any on the premise of present inventive concept obviously replace within protection scope of the present invention.
Claims (10)
- A kind of 1. non-yellowing key, it is characterised in that：The non-yellowing key includes the raw material of following parts by weight：
- A kind of 2. non-yellowing key according to claim 1, it is characterised in that：The ABS resin contains for acrylonitrile unit Measure 15%-25%, butadiene unit content 25%-35%, styrene units content 40%-60% acrylic nitrile-butadiene Diene-styrene copolymer.
- A kind of 3. non-yellowing key according to claim 1, it is characterised in that：The AS resins are acrylonitrile unit weight Acrylonitritrile-styrene resin of the content in 60%-80%.
- A kind of 4. non-yellowing key according to claim 1, it is characterised in that：The fire retardant is by poly cyanamid cyanuric acid Salt, triphenyl phosphate, magnesium hydroxide and montmorillonite compare 1-2 with weight:0.8-1.2:1:The mixture of 0.4-0.8 compositions.
- A kind of 5. non-yellowing key according to claim 1, it is characterised in that：The compatilizer be by methyl styrene, Methacrylonitrile, methacrylic acid and methyl methacrylate compare 2-4 with weight：2-4：0.8-1.2：0.5-1.5 copolymerization forms Quaternary atactic copolymer.
- A kind of 6. non-yellowing key according to claim 1, it is characterised in that：The color inhibition agent is by 2- (2 '-hydroxyls Base -3 ', 5 '-diamyl phenyl)-BTA, dibutyl hydroxy toluene and 2-hydroxy-4-n-octoxybenzophenone be with weight Compare 0.5-1.5:1.5-2.5:The mixture of 1 composition.
- A kind of 7. non-yellowing key according to claim 1, it is characterised in that：The UV resistant agent is by 2,2,6,6- Tetramethyl -4- piperidyls stearate, 4- benzoyloxys -2,2,6,6- tetramethyl piperidines and 2- hydroxyl -4- n-octyloxies two Benzophenone is with weight than 1:0.8-1.2:1.4-2.2 the mixture of composition.
- A kind of 8. non-yellowing key according to claim 1, it is characterised in that：The non-yellowing key also includes filler 5-15 parts, the filler are with weight ratio 1 by diatomite, clay and silica flour:1.5-2.5:The mixing of 0.5-1.5 compositions Thing.
- A kind of 9. non-yellowing key according to claim 1, it is characterised in that：The non-yellowing key also includes antioxidant 0.5-1.5 parts, the antioxidant are by four [β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythrites, β-(3,5- bis- Tert-butyl-hydroxy phenyl) propionic acid octadecanol ester and three (2,4- di-tert-butyl-phenyls) phosphite esters compare 1-2 with weight: 0.5-1.5:The mixture of 1 composition.
- A kind of 10. manufacture method of non-yellowing key as described in claim any one of 1-9, it is characterised in that：Claim by proportioning Each component is taken, after being well mixed, melting mixing, extruding pelletization, injection molding, non-yellowing key is made.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710948411.7A CN107828174A (en) | 2017-10-12 | 2017-10-12 | A kind of non-yellowing key and its manufacture method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710948411.7A CN107828174A (en) | 2017-10-12 | 2017-10-12 | A kind of non-yellowing key and its manufacture method |
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| CN107828174A true CN107828174A (en) | 2018-03-23 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108676313A (en) * | 2018-05-29 | 2018-10-19 | 佛山市顺德区镒诚吸塑有限公司 | A kind of nonmetallic advertisement plank and its processing method |
| CN109280339A (en) * | 2018-09-19 | 2019-01-29 | 北京盛科瑞达科技有限公司 | A kind of material and preparation method thereof for key |
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| CN101851384A (en) * | 2009-04-03 | 2010-10-06 | 上海锦湖日丽塑料有限公司 | Fireproof anti-ultraviolet anti-static ABS material and preparation method thereof |
| CN103044846A (en) * | 2012-12-25 | 2013-04-17 | 江苏金发科技新材料有限公司 | High-flow and weather-proof bulk ABS modified material and preparation method thereof |
| CN106633525A (en) * | 2016-12-25 | 2017-05-10 | 合肥会通新材料有限公司 | 5VA flame-retardant PVC/ABS (polyvinyl chloride/acrylonitrile-butadiene-styrene) composite material with high weathering resistance and high impact resistance and preparation method thereof |
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- 2017-10-12 CN CN201710948411.7A patent/CN107828174A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101676328A (en) * | 2008-09-18 | 2010-03-24 | Lg化学株式会社 | Thermoplastic resin composition having superior flame retardancy, coloring property and scratch-resistance |
| CN101851384A (en) * | 2009-04-03 | 2010-10-06 | 上海锦湖日丽塑料有限公司 | Fireproof anti-ultraviolet anti-static ABS material and preparation method thereof |
| CN103044846A (en) * | 2012-12-25 | 2013-04-17 | 江苏金发科技新材料有限公司 | High-flow and weather-proof bulk ABS modified material and preparation method thereof |
| CN106633525A (en) * | 2016-12-25 | 2017-05-10 | 合肥会通新材料有限公司 | 5VA flame-retardant PVC/ABS (polyvinyl chloride/acrylonitrile-butadiene-styrene) composite material with high weathering resistance and high impact resistance and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108676313A (en) * | 2018-05-29 | 2018-10-19 | 佛山市顺德区镒诚吸塑有限公司 | A kind of nonmetallic advertisement plank and its processing method |
| CN109280339A (en) * | 2018-09-19 | 2019-01-29 | 北京盛科瑞达科技有限公司 | A kind of material and preparation method thereof for key |
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