CN101824202A - Composite processing stabilizing agent for ABS (Acrylonitrile Butadiene Styrene) and HIPS (High Impact Polystyrene) resins - Google Patents
Composite processing stabilizing agent for ABS (Acrylonitrile Butadiene Styrene) and HIPS (High Impact Polystyrene) resins Download PDFInfo
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- CN101824202A CN101824202A CN201010164672A CN201010164672A CN101824202A CN 101824202 A CN101824202 A CN 101824202A CN 201010164672 A CN201010164672 A CN 201010164672A CN 201010164672 A CN201010164672 A CN 201010164672A CN 101824202 A CN101824202 A CN 101824202A
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Abstract
The invention relates to a composite processing stabilizing agent for ABS (Acrylonitrile Butadiene Styrene) and HIPS (High Impact Polystyrene) resins. The composite processing stabilizing agent for the ABS and HIPS resins comprises the following raw materials in percentage by weight: 5-90 percent of bisphenol mono-acrylic acid antioxidant, 5-90 percent of phenol antioxidant and 5-90 percent of auxiliary antioxidant. In the invention, the bisphenol mono-acrylic acid antioxidant, the phenol antioxidant and the auxiliary antioxidant are ternarily compounded to form a stable melt processing system. The composite processing stabilizing agent can effectively slow down the aging of the ABS and the HIPS resins in the process of melt processing and is beneficial to controlling color changes caused by high-temperature processing on the halogenated flame retardant resins of ABS and HIPS, and the product property is improved.
Description
[technical field]
The present invention relates to the Compound Machining stablizer of a kind of ABS of being used for, the processing of HIPS resin melt, this Compound Machining stablizer is applicable to that also halogen is fire-retardant ABS, HIPS processing.
[background technology]
All the time, ABS, HIPS resin forming are good, cheap is widely used in various products.In China, ABS, HIPS resin have 80% consumption to come from household electrical appliances production, so the flame retardant resistance of this resinoid seems particularly important.ABS, HIPS are a kind of inflammable macromolecular materials, need to add chemical fire retardant, realize the flame retardant resistance of resin.Halogenated flame retardant has been proved to be the effectively fire retardant of a class, although European Union in 2003 has issued RoHS instruction and WEEE instruction; 2006, China issued and RoHS instruction corresponding " China Electronics's information products pollution control management regulations ", has limited the use of part halogenated flame retardant.But halogenated flame retardant is because of flame retarding efficiency height, cost performance height, and usage quantity is listed as before occupying existing each based flame retardant.Except a few halogenated flame retardant that is limited to use, existing most of halogenated flame retardants (as brominated superpolymer) are can reach safe handling to require.In fact, China still mainly adopts halogen system/antimonous oxide system so far, and halogen-free flame retardant ABS, HIPS are also very low in the share of market of China.
Adding halogenated flame retardant can further influence the stability of ABS, HIPS.Halogenated flame retardant itself is very responsive to heat, easily decomposes to produce the degraded that the halogen free radical has caused macromolecular chain simultaneously, and the two keys that particularly cause in ABS, the HIPS macromolecular chain rupture, thereby acceleration ABS, HIPS resin wear out.ABS, HIPS resin through halogen flame retardant are processed under lower temperature than general ABS, HIPS usually, could keep good performance.Under harsh processing environment, as high temperature injection, halogen is often surperficial yellowing of flame-proof ABS, HIPS goods and mechanical properties decrease.Therefore people sacrifice efficient usually, reduce processing temperature, screw speed, to guarantee flame-proof ABS, HIPS stable resin in the course of processing; But also produce another problem simultaneously: resin flow is poor, often can not adapt to the production of making surface requirements height or large thin-wall goods.
The heat aging property of ABS, HIPS resin itself is also bad, and major cause is that the butadiene molecule chain contains double bond structure in the polymkeric substance.Two keys position is very easy to form the active centre, and chainpropagation or branching reaction take place; In the presence of oxygen, oxidation also can take place form carbonyl, ABS, HIPS are degraded, cause the surface and the inner defective that produces of goods, material appearance jaundice, mechanical properties decrease.The factor that causes material aging has many, and wherein processing is the inducing materials aged first road threshold, but also fewer at ABS, HIPS resin treatment Study on Stability at present.In fact improve the processing stability energy of material, can ensure that not only resin processes (reclaim as high temperature injection, mouth of a river material and use) under exacting terms, enlarge the flexibility of operation of material; Can also make the goods hidden danger (active group) after the materials processing few, use properties is more superior.
Synthesis material aging has been studied 168,618,1076/168,1076/618 pairs of influences that general ABS resin is repeatedly extruded processing stability of different processing oxidation inhibitor with application .2008.37 (1) .P22-25..Wherein 1076/168 system can keep ABS resin melt stability in extrusion process repeatedly preferably, but the xanthochromia performance of this system in the control ABS course of processing a little less than.
Generally speaking, the melt stability, particularly halogen that is necessary to improve ABS, HIPS resin is that the processing stability of flame-retarded resin improves Drawing abillity.The present processing stability of control ABS, HIPS resin, usually by add a large amount of phenols, phosphite ester kind antioxidant realizes that effect is general.
[summary of the invention]
At the problems referred to above, the purpose of this invention is to provide a kind of ABS, HIPS resin of can effectively slowing down and wear out the variable color that may command halogen is flame-proof ABS, the HIPS resin causes because of high temperature process, the Compound Machining stablizer of enhancing product performance owing to what melt took place.
For achieving the above object, the technical solution adopted in the present invention is as follows:
The Compound Machining stablizer that a kind of ABS, HIPS resin are used, be made up of the raw material of following mass percent: bis-phenol list vinylformic acid oxidation inhibitor is 5～90%, phenolic antioxidant is 5～90%, auxiliary antioxidant is 5～90%.
Preferably, be made up of the raw material of following mass percent: bis-phenol list vinylformic acid oxidation inhibitor is 10～60%, and phenolic antioxidant is 10～60%, and auxiliary antioxidant is 10～80%.
Preferably, described bis-phenol list vinylformic acid oxidation inhibitor is KY-500.
Preferably, described phenolic antioxidant is antioxidant 1076, antioxidant 1010, oxidation inhibitor WSL, antioxidant 300, oxidation inhibitor 245, oxidation inhibitor 1035, oxidation inhibitor 1222.
Preferably, described auxiliary antioxidant is TNPP, oxidation inhibitor 168, P-EPQ, oxidation inhibitor 626, DLTP, DSTP.
It is 0.1～0.5% that this Compound Machining stablizer adds the mass percent that addition in ABS, the HIPS resin and halogen is flame-proof ABS, HIPS resin to.
Preferably, to add the mass percent that addition in ABS, the HIPS resin and halogen is flame-proof ABS, HIPS resin to be 0.1～0.3% to this Compound Machining stablizer.
Raw material required for the present invention:
KY-500=2-[1-(2-hydroxyl-3,5-two tertiary amyl phenyl) ethylene]-4,6-two tertiary amyl phenyl acrylate, (according to the method that the preparation method the announced self-control that application number is 200510035209.2, denomination of invention is a kind of antioxidant of bisphenol mono acrylic ester);
GX2921＝Irganox?GX2921，CIBA；
AO1=four [β-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester;
AO2=octadecyl-3, two (1, the 1-the dimethyl ethyl)-4-hydroxy benzoic propionates of 5-;
AO3=2, the 6-di-tert-butyl-4-methy phenol;
AO4=4,4 '-thiobis (6-tertiary butyl meta-cresol);
AO5=Wingstay L, europeanized of French Yi Li company produces;
AO6=2,2 '-sulfurous ethyl glycol two [β-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic ester];
The AO7=triglycol is two-3-(3-tertiary butyl-4-hydroxy-5-aminomethyl phenyl) vinyl cyanide;
Phos1=four (2 ,-di-tert-butyl-phenyl-4,4 '-xenyl) bisphosphonate;
Phos2=tetramethylolmethane diphosphite two (2,4-di-tert-butyl phenyl) ester;
The ABS1=acrylonitrile-butadiene-styrene copolymer, PA-765A, Qimei Industry Co., Ltd.;
The ABS2=acrylonitrile-butadiene-styrene copolymer, DP-60, new lake (Changzhou) petrochemical industry company limited;
The ABS3=flame-proof ABS (V-0,1.6mm), FW-630, JinFa Science Co., Ltd;
AS=acrylonitritrile-styrene resin SP23, new lake (Changzhou) petrochemical industry company limited;
The HIPS1=high-impact polystyrene, 825, the Guangzhou petrochemical industry;
The HIPS2=flame-retarding HIPS (V-0,1.6mm), FRHIPS-960, JinFa Science Co., Ltd;
Testing method of the present invention:
(1) outward appearance
Aberration (Δ E) is pressed the test of GB/T 7921-2008 uniform colour space and colour difference formula; Select the daily light source of D65 for use.
(2) oxidation induction period (OIT)
Press ISO 11357-6:2008Plastics-Differential scanning calorimetry (DSC)-Part 6:Determination of oxidation induction time (isothermal OIT) and oxidation inductiontemperature (dynamic OIT) method; Select 170 ℃ for use, heat-up rate 20K/min.
(3) mechanical property
Socle girder notched Izod impact strength (IZOD) is pressed GB/T 1843-1996 plastics izodtest method; A type breach.Tensile strength is pressed GB/T 1040-2006 plastic tensile test method; Select 1A type sample for use, draw speed 10mm/min.
(4) melt flow rate (MFR) (MFR)
Press the mensuration of GB/T 3682-2000 thermoplastics melt mass flow rate and melt volume-flow rate, select 200 ℃ for use, load 10kg.
The bis-phenol list vinylformic acid oxidation inhibitor KY-500 that the present invention uses, its preparation according to application number be 200510035209.2, denomination of invention is a kind of method that the preparation method announced self-control of antioxidant of bisphenol mono acrylic ester.KY-500 is a kind of carbon radicals trapping agent, and the termination of (as extrude, injection process in) ABS, HIPS alkyl diradical can suppress the natural oxidation working cycle immediately under the anoxybiotic condition, and polymkeric substance stable had significant contribution.It is flame-proof ABS, HIPS resin that KY-500 is used for halogen, can guarantee that the melt of high temperature process is stable.The refine benzofuranone Irganox HP136 of company of Ciba also is a kind of carbon radicals trapping agent, but because HP136 produces harm to human body reproductive organ, uses few at present.
The present invention is compound bis-phenol list vinylformic acid oxidation inhibitor and phenolic antioxidant, auxiliary antioxidant ternary, forms the processing stabilising system.This system is compared with traditional oxidation inhibitor, is equivalent to increase in advance the anti-aging defence line one, reduces the peroxy radical quantity that produces subsequently, fundamentally alleviates the burden of main and auxiliary oxidation inhibitor.Kept on the other hand traditional oxidation inhibitor advantage, reduced cost.The present invention is a raw material with bis-phenol list vinylformic acid oxidation inhibitor, phenolic antioxidant, auxiliary antioxidant, proportioning in accordance with regulations adopts the high speed pre-mixing prepared, gained Compound Machining stablizer, being very suitable for need employing halogen such as household electrical appliance, auto parts machinery, finishing material is the field of flame-proof ABS, HIPS material.
[embodiment]
Embodiment 1
Even 5g white oil and 5kgABS1 mixed with resin in kneader, in 200 ℃ Φ, 30 twin screw extruder kind granulation, water-cooled and forced air dryings.With exsiccant pellet with injection injected sample under 200 ℃ temperature.
AO1, the AO2, AO3, AO4, the KY-500 that take by weighing 10g respectively mix in the kneader high speed with the ABS1 of 5kg, after adding 5g white oil is uniformly dispersed, in 200 ℃ Φ, 30 twin screw extruder granulation, water-cooled and forced air dryings.With exsiccant pellet with injector injected sample under 240 ℃ high temperature.What do not add oxidation inhibitor is standard with above-mentioned, and test Δ E the results are shown in Table 1.
The aberration of table 1ABS high temperature process
By table 1 result as can be known, cause aspect the colour-change in control ABS high temperature process, oxidation inhibitor KY-500 is better than all the other four kinds of oxidation inhibitor.
Embodiment 2
1, take by weighing 25gABS2 and the 75gAS resin 10min that plasticates in two roller mills of 165 ℃, sampling and testing OIT the results are shown in Table 2.
2, take by weighing the oxidation inhibitor GX2921 of 0.3g and 25gABS2,75gAS resin alloy, processing conditions is with 1., and sampling and testing OIT the results are shown in Table 2.
3, take by weighing the KY-500 of 1kg and the Phos1 of 2kg and in homogenizer, stir, become the ABS one package stabilizer.
Take by weighing above-mentioned one package stabilizer of 0.3g and 25gABS2,75gAS resin alloy, processing conditions is same 1., and sampling and testing OIT the results are shown in Table 2.
4, take by weighing the KY-500 of 1kg and the Phos2 of 2kg and in homogenizer, stir, become ABS with the compound stablizer that adds.
Take by weighing above-mentioned one package stabilizer of 0.3g and 25gABS2,75gAS resin alloy, processing conditions is same 1., and sampling and testing OIT the results are shown in Table 2.
5, take by weighing the AO2 of KY-500,1kg of 1kg and the Phos2 of 2kg and in homogenizer, stir, obtain Compound Machining stablizer of the present invention.
Take by weighing above-mentioned Compound Machining stablizer of 0.3g and 25gABS2,75gAS resin alloy, processing conditions is same 1., and sampling and testing OIT the results are shown in Table 2
6, take by weighing the AO5 of KY-500,1kg of 1kg and the Phos1 of 2kg and in homogenizer, stir, obtain Compound Machining stablizer of the present invention.
Take by weighing above-mentioned Compound Machining stablizer of 0.3g and 25gABS2,75gAS resin alloy, processing conditions is same 1., and sampling and testing OIT the results are shown in Table 2.
7, take by weighing the AO5 of KY-500,1kg of 1kg and the Phos2 of 1kg and in homogenizer, stir, obtain Compound Machining stablizer of the present invention.
Take by weighing above-mentioned Compound Machining stablizer of 0.3g and 25gABS2,75gAS resin alloy, processing conditions is same 1., and sampling and testing OIT the results are shown in Table 2.
The OIT of table 2ABS
KY-500 is shared as main stabilizer and phosphorous acid ester auxiliary stabilizer, and the OIT time of ABS is short.OIT is a kind of aerobic testing experiment, and KY-500, therefore needs to add the 3rd component a little less than the capture ability to peroxy radical as a kind of carbon radicals trapping agent, as phenolic antioxidant, improves the capture ability to peroxy radical.The oxidation inhibitor ternary is compound to have synergistic effect, has improved the OIT of ABS, part even be better than CIBA company with phenylpropyl alcohol furanone compound oxidation inhibitor GX2921.
Embodiment 3
1, takes by weighing ABS2, AS (1: the 3) mixture of the oxidation inhibitor GX2921 of 30g and 10kg after the kneader high speed mixes, in 200 ℃ Φ, 52 twin screw extruder granulations, water-cooled and forced air drying, pellet drop into granulation in the forcing machine once more, this process repeated multiple times.Difference being extruded the pellet of number of times uses injector 210 ℃ of following injected sample respectively.The sample of extruding with the first time is a standard, and Δ E, the IZOD, the MFR that more repeatedly extrude the results are shown in Table 3.
2, take by weighing the KY-500 of AO5,0.5kg of 0.5kg and the Phos1 oxidation inhibitor of 2kg and in homogenizer, stir, obtain Compound Machining stablizer of the present invention.
ABS2, AS (1: the 3) mixture that takes by weighing above-mentioned Compound Machining stablizer of 30g and 10kg is after the kneader high speed mixes, in 200 ℃ Φ, 52 twin screw extruder granulations, water-cooled and forced air drying, pellet drop into granulation in the forcing machine once more, this process repeated multiple times.Difference being extruded the pellet of number of times uses injector 210 ℃ of following injected sample respectively.The sample of extruding with the first time is a standard, and the Δ E that more repeatedly extrudes and IZOD, the MFR of test material the results are shown in Table 3.
3, take by weighing the KY-500 of AO6,0.5kg of 0.5kg and the Phos1 oxidation inhibitor of 2kg and in homogenizer, stir, obtain Compound Machining stablizer of the present invention.
ABS2, AS (1: the 3) mixture that takes by weighing above-mentioned Compound Machining stablizer of 30g and 10kg is after the kneader high speed mixes, in 200 ℃ Φ, 52 twin screw extruder granulations, water-cooled and forced air drying, pellet drop into granulation in the forcing machine once more, this process repeated multiple times.Difference being extruded the pellet of number of times uses injector 210 ℃ of following injected sample respectively.The sample of extruding with the first time is a standard, and the Δ E that more repeatedly extrudes and IZOD, the MFR of test material the results are shown in Table 3.
The repeatedly extrusion performance of table 3ABS
KY-500 processing stable compound is close with oxidation inhibitor GX2921 to the processing stability of ABS resin, and color control is better than GX2921.
Embodiment 4
1, take by weighing the 100gHIPS1 resin 10min that plasticates in two roller mills of 150 ℃, sampling and testing OIT the results are shown in Table 4.
2, take by weighing the oxidation inhibitor GX2921 of 0.3g and the 100gHIPS1 resin 10min that plasticates in two roller mills of 150 ℃, sampling and testing OIT the results are shown in Table 4.
3, take by weighing the Phos2 of AO7,0.2g of 0.1g and the 100gHIPS1 resin 10min that plasticates in two roller mills of 150 ℃, sampling and testing OIT the results are shown in Table 4.
4, take by weighing the AO7 of KY-500,1kg of 1kg and the Phos2 of 2kg and in homogenizer, stir, obtain Compound Machining stablizer of the present invention.
Take by weighing above-mentioned Compound Machining stablizer of 0.3g and the 100gHIPS1 resin 10min that plasticates in two roller mills of 150 ℃, sampling and testing OIT the results are shown in Table 4.
5, take by weighing the AO5 of KY-500,1kg of 0.5kg and the Phos2 of 2kg and in homogenizer, stir, obtain Compound Machining stablizer of the present invention.
Take by weighing above-mentioned Compound Machining stablizer of 0.3g and the 100gHIPS1 resin 10min that plasticates in two roller mills of 150 ℃, sampling and testing OIT the results are shown in Table 4.
6, take by weighing the AO6 of KY-500,0.5kg of 0.5kg and the Phos1 oxidation inhibitor of 1kg and in homogenizer, stir, obtain Compound Machining stablizer of the present invention.
Take by weighing above-mentioned Compound Machining stablizer of 0.3g and the 100gHIPS1 resin 10min that plasticates in two roller mills of 150 ℃, sampling and testing OIT the results are shown in Table 4.
The OIT of table 4HIPS
KY-500 and phenolic antioxidant, phosphite antioxidant are compound, also can improve the OIT of HIPS resin.
Embodiment 5
1, the HIPS1 that takes by weighing the oxidation inhibitor GX2921 of 50g and 10kg is after the kneader high speed mixes, in 200 ℃ Φ, 52 twin screw extruder granulations, and water-cooled and forced air drying, pellet drops into granulation in the forcing machine once more, this process repeated multiple times.The different MFR that extrude number of times of test.The pellet through once extruding is only used the injector injected sample, test I ZOD respectively under 200 ℃, 220 ℃, 240 ℃, 260 ℃ temperature.The results are shown in Table 5.
2, take by weighing 0.5kgAO5,0.5kgKY-500 and 2kgPhos2 oxidation inhibitor stirs in homogenizer, obtain HIPS Compound Machining stablizer of the present invention.
The HIPS1 that takes by weighing above-mentioned Compound Machining stablizer of 50g and 10kg after the kneader high speed mixes, in 200 ℃ Φ, 52 twin screw extruder granulations, water-cooled and forced air drying, pellet drops into granulation in the forcing machine once more, this process repeated multiple times.The different MFR that extrude number of times of test.The pellet through once extruding is only used the injector injected sample, test I ZOD respectively under 200 ℃, 220 ℃, 240 ℃, 260 ℃ temperature.The results are shown in Table 5.
3, take by weighing 0.5kgAO7,0.5kgKY-500 and 2kgPhos2 oxidation inhibitor stirs in homogenizer, obtain HIPS Compound Machining stablizer of the present invention.
The HIPS1 that takes by weighing above-mentioned Compound Machining stablizer of 50g and 10kg after the kneader high speed mixes, in 200 ℃ Φ, 52 twin screw extruder granulations, water-cooled and forced air drying, pellet drops into granulation in the forcing machine once more, this process repeated multiple times.The different MFR that extrude number of times of test.The pellet through once extruding is only used the injector injected sample, test I ZOD respectively under 200 ℃, 220 ℃, 240 ℃, 260 ℃ temperature.The results are shown in Table 5.
The processing characteristics of table 5HIPS
Use KY-500 processing stable compound to help HIPS under the processing conditions of harshness, still keep good performance.
Embodiment 6
1, takes by weighing the ABS3 of 10kg, forced air drying.With pellet with injector respectively 200 ℃, 260 ℃ following injected sample, be standard with 200 ℃ of injected sample, relatively Δ E the results are shown in Table 6; The mechanical property of 200 ℃ of injected sample of test the results are shown in Table 7.
2, take by weighing the AO5 of KY-500,1kg of 1kg and the Phos1 of 2kg and in homogenizer, stir, obtain Compound Machining stablizer of the present invention.
The ABS3 that takes by weighing above-mentioned Compound Machining stablizer of 10g and 10kg is after the kneader high speed mixes, in 160 ℃ Φ, 30 twin screw extruder granulation, water-cooled and forced air dryings.With pellet with injector respectively 200 ℃, 240 ℃, 260 ℃ following injected sample, be standard with 200 ℃ of injected sample, relatively Δ E the results are shown in Table 6; The mechanical property of 200 ℃ of injected sample of test the results are shown in Table 7.
3, take by weighing the HIPS2 of 10kg, forced air drying.Using injector in 200 ℃, 260 ℃ following injected sample of difference pellet, is standard with 200 ℃ of injected sample, and relatively Δ E the results are shown in Table 6; The mechanical property of 200 ℃ of injected sample of test the results are shown in Table 7.
4, take by weighing 0.5kgAO7,0.5kgKY-500 and 2kgPhos2 oxidation inhibitor stirs in homogenizer, obtain HIPS Compound Machining stablizer of the present invention.
The HIPS2 that takes by weighing above-mentioned Compound Machining stablizer of 10g and 10kg is after the kneader high speed mixes, in 150 ℃ Φ, 30 twin screw extruder granulation, water-cooled and forced air dryings.With pellet with injector respectively 200 ℃, 240 ℃, 260 ℃ following injected sample, be standard with 200 ℃ of injected sample, relatively Δ E the results are shown in Table 6; The mechanical property of 200 ℃ of injected sample of test the results are shown in Table 7.
The Δ E that table 6 flame-proof ABS, HIPS processing cause
Mechanical property after table 7 flame-proof ABS, the HIPS processing
Add a small amount of Compound Machining stablizer of the present invention to help slowing down halogen be flame-proof ABS, HIPS because of processing cause aging, thereby improve the performance of goods.
Claims (7)
1. Compound Machining stablizer that ABS, HIPS resin are used is characterized in that being made up of the raw material of following mass percent: bis-phenol list vinylformic acid oxidation inhibitor is 5～90%, phenolic antioxidant is 5～90%, auxiliary antioxidant is 5～90%.
2. the Compound Machining stablizer that ABS as claimed in claim 1, HIPS resin are used, it is characterized in that being made up of the raw material of following mass percent: bis-phenol list vinylformic acid oxidation inhibitor is 10～60%, phenolic antioxidant is 10～60%, and auxiliary antioxidant is 10～80%.
3. the Compound Machining stablizer that ABS as claimed in claim 1 or 2, HIPS resin are used is characterized in that described bis-phenol list vinylformic acid oxidation inhibitor is KY-500.
4. the Compound Machining stablizer that ABS as claimed in claim 3, HIPS resin are used is characterized in that described phenolic antioxidant is antioxidant 1076, antioxidant 1010, oxidation inhibitor WSL, antioxidant 300, oxidation inhibitor 245, oxidation inhibitor 1035, oxidation inhibitor 1222.
5. the Compound Machining stablizer that ABS as claimed in claim 4, HIPS resin are used is characterized in that described auxiliary antioxidant is TNPP, oxidation inhibitor 168, P-EPQ, oxidation inhibitor 626, DLTP, DSTP.
6. the Compound Machining stablizer that ABS as claimed in claim 5, HIPS resin are used, it is that the mass percent that addition in flame-proof ABS, the HIPS resin and halogen are flame-proof ABS, HIPS resin is 0.1～0.5% that its feature is added halogen at this Compound Machining stablizer.
7. the Compound Machining stablizer that ABS as claimed in claim 6, HIPS resin are used is characterized in that it is that the mass percent that addition in flame-proof ABS, the HIPS resin and halogen are flame-proof ABS, HIPS resin is 0.1～0.3% that this Compound Machining stablizer adds halogen to.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010164672A CN101824202A (en) | 2010-04-29 | 2010-04-29 | Composite processing stabilizing agent for ABS (Acrylonitrile Butadiene Styrene) and HIPS (High Impact Polystyrene) resins |
| CN2010105894500A CN102040798B (en) | 2010-04-29 | 2010-12-15 | Composite capable of improving weather resistances of acrylonitrile butadiene styrene (ABS) and high impact polystyrene (HIPS) |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201010164672A CN101824202A (en) | 2010-04-29 | 2010-04-29 | Composite processing stabilizing agent for ABS (Acrylonitrile Butadiene Styrene) and HIPS (High Impact Polystyrene) resins |
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| CN2010105894500A Expired - Fee Related CN102040798B (en) | 2010-04-29 | 2010-12-15 | Composite capable of improving weather resistances of acrylonitrile butadiene styrene (ABS) and high impact polystyrene (HIPS) |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102040798A (en) * | 2010-04-29 | 2011-05-04 | 广州合成材料研究院有限公司 | Composite capable of improving weather resistances of acrylonitrile butadiene styrene (ABS) and high impact polystyrene (HIPS) |
| CN102516699A (en) * | 2011-12-07 | 2012-06-27 | 广州合成材料研究院有限公司 | ABS (Acrylonitrile Butadiene Styrene) weather-resistant and anti-ageing functional master batch |
| CN107778525A (en) * | 2017-11-02 | 2018-03-09 | 山东省临沂市三丰化工有限公司 | A kind of stabiliser compositions of polyethylene wire and cable PP Pipe Compound |
| CN110157094A (en) * | 2019-04-30 | 2019-08-23 | 南通市东方塑胶有限公司 | Fire-retardant light diffusion PP material with thermo oxidative aging function and preparation method thereof |
| CN115703901A (en) * | 2021-08-10 | 2023-02-17 | 中国石油天然气股份有限公司 | ABS (acrylonitrile butadiene styrene) resin processing aid, preparation method thereof and ABS resin composite processing aid |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102516744B (en) * | 2011-11-22 | 2013-09-04 | 广州合成材料研究院有限公司 | Composite auxiliary agent for resisting color change of polyurethane (PU) and production process |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5884835A (en) * | 1981-11-17 | 1983-05-21 | Sumitomo Chem Co Ltd | Stabilized synthetic rubber composition |
| JPH0764786B2 (en) * | 1987-12-23 | 1995-07-12 | 住友化学工業株式会社 | Phenolic compounds and stabilizers for butadiene polymers containing the same as active ingredients |
| TW303381B (en) * | 1994-12-05 | 1997-04-21 | Ciba Sc Holding Ag | |
| CN101824202A (en) * | 2010-04-29 | 2010-09-08 | 广州合成材料研究院有限公司 | Composite processing stabilizing agent for ABS (Acrylonitrile Butadiene Styrene) and HIPS (High Impact Polystyrene) resins |
-
2010
- 2010-04-29 CN CN201010164672A patent/CN101824202A/en active Pending
- 2010-12-15 CN CN2010105894500A patent/CN102040798B/en not_active Expired - Fee Related
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102040798A (en) * | 2010-04-29 | 2011-05-04 | 广州合成材料研究院有限公司 | Composite capable of improving weather resistances of acrylonitrile butadiene styrene (ABS) and high impact polystyrene (HIPS) |
| CN102040798B (en) * | 2010-04-29 | 2012-07-11 | 广州合成材料研究院有限公司 | Composite capable of improving weather resistances of acrylonitrile butadiene styrene (ABS) and high impact polystyrene (HIPS) |
| CN102516699A (en) * | 2011-12-07 | 2012-06-27 | 广州合成材料研究院有限公司 | ABS (Acrylonitrile Butadiene Styrene) weather-resistant and anti-ageing functional master batch |
| CN102516699B (en) * | 2011-12-07 | 2014-05-14 | 广州合成材料研究院有限公司 | ABS (Acrylonitrile Butadiene Styrene) weather-resistant and anti-ageing functional master batch |
| CN107778525A (en) * | 2017-11-02 | 2018-03-09 | 山东省临沂市三丰化工有限公司 | A kind of stabiliser compositions of polyethylene wire and cable PP Pipe Compound |
| CN107778525B (en) * | 2017-11-02 | 2019-08-13 | 山东省临沂市三丰化工有限公司 | A kind of stabiliser compositions of polyethylene wire and cable PP Pipe Compound |
| CN110157094A (en) * | 2019-04-30 | 2019-08-23 | 南通市东方塑胶有限公司 | Fire-retardant light diffusion PP material with thermo oxidative aging function and preparation method thereof |
| CN115703901A (en) * | 2021-08-10 | 2023-02-17 | 中国石油天然气股份有限公司 | ABS (acrylonitrile butadiene styrene) resin processing aid, preparation method thereof and ABS resin composite processing aid |
| CN115703901B (en) * | 2021-08-10 | 2024-05-07 | 中国石油天然气股份有限公司 | ABS resin processing aid, preparation method thereof and ABS resin composite processing aid |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102040798B (en) | 2012-07-11 |
| CN102040798A (en) | 2011-05-04 |
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