CN102516699B - ABS (Acrylonitrile Butadiene Styrene) weather-resistant and anti-ageing functional master batch - Google Patents
ABS (Acrylonitrile Butadiene Styrene) weather-resistant and anti-ageing functional master batch Download PDFInfo
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Abstract
The invention discloses an ABS (Acrylonitrile Butadiene Styrene) weather-resistant and anti-ageing functional master batch, which consists of the following raw materials in parts by weight: 20-30 parts of AS (Acrylonitrile Styrene) powder, 6-8 parts of high glue powder, 2-4 parts of a nano-oxide, 1-3 parts of an antioxidant, 5-10 parts of an ultraviolet absorber and 1-2 parts of a processing aid. By adding the functional master batch disclosed by the invention into ABS, the anti-ageing performance and weather resistance of ABS can be enhanced greatly.
Description
Technical field
The present invention relates to the weather-proof anti-aging functional master batch of a kind of ABS.
Background technology
ABS, it is acrylonitrile-butadiene-styrene copolymer, that one is easy to moulding, and the good polymkeric substance of intensity and toughness, tool has been widely used, as the shell for air-conditioning, switch etc., and owing to often containing two keys in Acrylonitrile Butadiene—Styrene copolymer, cause its easy slow oxidation, air-conditioning is elongated duration of service, its surperficial yellowing is a good illustration, in the severe area of a lot of weather condition as the Xinjiang region of China, because its latitude is higher, ultraviolet ray is strong, weather condition are changeable and severe, the device (as communication equipment) that causes using ABS material is often easily aging, adopt common method of modifying in ABS matrix, to add oxidation inhibitor, still can not well deal with problems.
Summary of the invention
The object of this invention is to provide the weather-proof anti-aging functional master batch of a kind of ABS.
The technical solution used in the present invention is:
The weather-proof anti-aging functional master batch of a kind of ABS, its raw material by following mass parts forms: the nano-oxide of the AS powder of 20-30 part, the ABS high glue powder of 6-8 part, 2-4 part, the oxidation inhibitor of 1-3 part, the UV light absorber of 5-10 part, the processing aid of 1-2 part.
Described nano-oxide is at least one of nano-titanium oxide, nano-cerium oxide, nano zine oxide.
Described oxidation inhibitor is at least one in irgasfos 168, antioxidant 1076, oxidation inhibitor 215, oxidation inhibitor 561, oxidation inhibitor 626, antioxidant 3114, oxidation inhibitor 225, antioxidant 330, antioxidant 1010, oxidation inhibitor 1098, oxidation inhibitor 900.
Described UV light absorber is at least one in UV944, UV770, UV9, UV-P, UV531, UV326, UV327.
Described processing aid is at least one in EBS, calcium stearate, Magnesium Stearate, oleylamide, polyethylene wax, microcrystalline wax, silicone powder, methyl phenyl silicone oil, hydroxy silicon oil, butyl stearate.
Prepare the method for the weather-proof anti-aging functional master batch of a kind of ABS: comprise the following steps:
1) in proportion each raw material being placed in to mixing machine mixes;
2) compound of upper step is placed in to forcing machine and melt extrudes granulation.
The invention has the beneficial effects as follows: functional master batch of the present invention adds in ABS the anti-aging and weather resistance of raising ABS that can be larger.
Embodiment
The preparation method of the weather-proof anti-aging functional master batch of a kind of ABS: comprise the following steps:
1) in proportion each raw material being placed in to mixing machine mixes;
2) compound of upper step is placed in to forcing machine and melt extrudes granulation, the screw slenderness ratio of forcing machine is 40.
Below in conjunction with specific embodiment, formula of the present invention is described further:
Embodiment 1:
The weather-proof anti-aging functional master batch of a kind of ABS, its table composed as follows of filling a prescription:
Embodiment 2:
The weather-proof anti-aging functional master batch of a kind of ABS, its table composed as follows of filling a prescription:
Embodiment 3:
The weather-proof anti-aging functional master batch of a kind of ABS, its table composed as follows of filling a prescription:
Embodiment 4:
The weather-proof anti-aging functional master batch of a kind of ABS, its table composed as follows of filling a prescription:
Embodiment 5:
The weather-proof anti-aging functional master batch of a kind of ABS, its table composed as follows of filling a prescription:
Embodiment 6:
The weather-proof anti-aging functional master batch of a kind of ABS, its table composed as follows of filling a prescription:
Embodiment 7:
The weather-proof anti-aging functional master batch of a kind of ABS, its table composed as follows of filling a prescription:
The present invention's silicone powder used model is: SK20R.
The masterbatch that embodiment 1 obtains adds ABS(manufacturer: BASF to, trade(brand)name: Terluran ABS, model: GP-22) in, after injection molding is batten, in open air, Xinjiang (85 ° 9 ' 42 of east longitude ", after north latitude 42 ° 14 ' 16 ") exposes 1 year (2010.09.01-2011.09.01), aberration △ E be changed to 4.1(same time same material in open air, Guangzhou (23 ° 56 ' 16 of north latitude ", east longitude 112 ° 57 ' 15 ") exposes 1 year aberration △ E and is changed to 2.57), tensile strength (tensile strength testing standard: ASTM D 882) conservation rate is 82.21%, socle girder notched Izod impact strength (testing standard: ASTM D256) conservation rate is 78.13%.
Because masterbatch of the present invention adds in ABS, can improve weathering resistance and the anti-ageing property of material, make it be particularly useful for the comparatively severe area of weather condition.
Claims (8)
1. the weather-proof anti-aging functional master batch of ABS, it is characterized in that: its raw material by following mass parts forms: the AS powder of 28.4 parts, the ABS high glue powder HR-181 of 7.1 parts, the mass ratio of 2.5 parts is the nano-titanium oxide of 1:1:1, nano-cerium oxide, the mixture of nano zine oxide, the antioxidant 1076 of 1.5 parts, the irgasfos 168 of 0.6 part, the UV light absorber UV327 of 3.38 parts, the UV light absorber UV770 of 3.38 parts, the UV light absorber UV944 of 1.58 parts, the mass ratio of 1.35 parts is the EBS of 1:1:1, calcium stearate, the mixture of silicone powder SK20R.
2. the weather-proof anti-aging functional master batch of ABS, is characterized in that: its raw material by following mass parts forms: the mixture of EBS that the mixture of nano-titanium oxide that the AS powder of 26.9 parts, the ABS high glue powder HR-181 of 7 parts, the mass ratio of 3 parts are 1:1:2, nano-cerium oxide, nano zine oxide, the antioxidant 1076 of 1.7 parts, the irgasfos 168 of 0.7 part, UV light absorber UV327, the UV light absorber UV770 of 4 parts, the UV light absorber UV944 of 1.86 parts, the mass ratio of 1.35 parts of 4 parts are 1:1:2, calcium stearate, silicone powder SK20R.
3. the weather-proof anti-aging functional master batch of ABS, is characterized in that: its raw material by following mass parts forms: the mixture of EBS that the mixture of nano-titanium oxide that the AS powder of 28.4 parts, the ABS high glue powder HR-181 of 7.1 parts, the mass ratio of 2.5 parts are 1:2:2, nano-cerium oxide, nano zine oxide, the antioxidant 1076 of 1.7 parts, the irgasfos 168 of 0.6 part, UV light absorber UV327, the UV light absorber UV770 of 4.5 parts, the UV light absorber UV944 of 1.7 parts, the mass ratio of 1.4 parts of 5 parts are 1:2:2, calcium stearate, silicone powder SK20R.
4. the weather-proof anti-aging functional master batch of ABS, it is characterized in that: its raw material by following mass parts forms: the AS powder of 28.4 parts, the ABS high glue powder HR-181 of 7.1 parts, the mass ratio of 2.5 parts is the nano-titanium oxide of 1:2:2, nano-cerium oxide, the mixture of nano zine oxide, the antioxidant 1076 of 1.5 parts, the irgasfos 168 of 0.6 part, the UV light absorber UV327 of 3.38 parts, the UV light absorber UV770 of 3.38 parts, the UV light absorber UV944 of 1.58 parts, the mass ratio of 1.35 parts is the EBS of 1:2:2, calcium stearate, the mixture of silicone powder SK20R.
5. the weather-proof anti-aging functional master batch of ABS, is characterized in that: its raw material by following mass parts forms: the mixture of EBS that the mixture of nano-titanium oxide that the AS powder of 20 parts, the ABS high glue powder HR-181 of 6 parts, the mass ratio of 2 parts are 1:2:2, nano-cerium oxide, nano zine oxide, the antioxidant 1076 of 0.5 part, the irgasfos 168 of 0.5 part, UV light absorber UV327, the UV light absorber UV770 of 1 part, the UV light absorber UV944 of 3 parts, the mass ratio of 1 part of 1 part are 1:2:2, calcium stearate, silicone powder SK20R.
6. the weather-proof anti-aging functional master batch of ABS, is characterized in that: its raw material by following mass parts forms: the mixture of EBS that the mixture of nano-titanium oxide that the AS powder of 30 parts, the ABS high glue powder HR-181 of 8 parts, the mass ratio of 4 parts are 1:2:2, nano-cerium oxide, nano zine oxide, the antioxidant 1076 of 1.5 parts, the irgasfos 168 of 1.5 parts, UV light absorber UV327, the UV light absorber UV770 of 4 parts, the UV light absorber UV944 of 3 parts, the mass ratio of 2 parts of 3 parts are 1:2:2, calcium stearate, silicone powder SK20R.
7. the weather-proof anti-aging functional master batch of ABS, is characterized in that: its raw material by following mass parts forms: the mixture of EBS that the mixture of nano-titanium oxide that the AS powder of 25 parts, the ABS high glue powder HR-181 of 7 parts, the mass ratio of 3.5 parts are 1:2:2, nano-cerium oxide, nano zine oxide, the antioxidant 1076 of 1.2 parts, the irgasfos 168 of 0.8 part, UV light absorber UV327, the UV light absorber UV770 of 2 parts, the UV light absorber UV944 of 3 parts, the mass ratio of 1.5 parts of 2 parts are 1:2:2, calcium stearate, silicone powder SK20R.
8. the method for the weather-proof anti-aging functional master batch of a kind of ABS described in any one in preparation claim 1-7: comprise the following steps:
1) in proportion each raw material being placed in to mixing machine mixes;
2) compound of upper step is placed in to forcing machine and melt extrudes granulation.
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| CN201110403401.8A CN102516699B (en) | 2011-12-07 | 2011-12-07 | ABS (Acrylonitrile Butadiene Styrene) weather-resistant and anti-ageing functional master batch |
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| CN201110403401.8A CN102516699B (en) | 2011-12-07 | 2011-12-07 | ABS (Acrylonitrile Butadiene Styrene) weather-resistant and anti-ageing functional master batch |
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| CN102516699B true CN102516699B (en) | 2014-05-14 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102977597B (en) * | 2012-08-20 | 2015-08-12 | 安徽凯迪电气有限公司 | A kind of polytetrafluoroethylmodified modified nylon PA66 particle material and preparation method thereof and the application on automobile |
| CN102977598B (en) * | 2012-08-20 | 2015-12-02 | 安徽凯迪电气有限公司 | Nylon PA66 particle material of a kind of PBT modification and preparation method thereof and the application on automobile |
| CN104479321A (en) * | 2014-11-20 | 2015-04-01 | 苏州新区佳合塑胶有限公司 | Anti-oxidative ABS/PC plastic for automobile instruments/meters |
| CN106700391A (en) * | 2016-12-02 | 2017-05-24 | 长兴天晟能源科技有限公司 | Functional master batch for improving weather resistance of ABS (acrylonitrile butadiene styrene copolymers) |
| CN107974000A (en) * | 2017-11-22 | 2018-05-01 | 杭州富阳鼎创科技有限公司 | plastic composite function master batch |
| CN110564072B (en) * | 2019-10-25 | 2021-12-21 | 长春工业大学 | Preparation method of high-rigidity, high-toughness and aging-resistant ABS resin |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101824202A (en) * | 2010-04-29 | 2010-09-08 | 广州合成材料研究院有限公司 | Composite processing stabilizing agent for ABS (Acrylonitrile Butadiene Styrene) and HIPS (High Impact Polystyrene) resins |
| CN101851384A (en) * | 2009-04-03 | 2010-10-06 | 上海锦湖日丽塑料有限公司 | Fireproof anti-ultraviolet anti-static ABS material and preparation method thereof |
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| JP2001253988A (en) * | 2000-03-13 | 2001-09-18 | Toyo Ink Mfg Co Ltd | Colored resin composition and molded article of the same |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101851384A (en) * | 2009-04-03 | 2010-10-06 | 上海锦湖日丽塑料有限公司 | Fireproof anti-ultraviolet anti-static ABS material and preparation method thereof |
| CN101824202A (en) * | 2010-04-29 | 2010-09-08 | 广州合成材料研究院有限公司 | Composite processing stabilizing agent for ABS (Acrylonitrile Butadiene Styrene) and HIPS (High Impact Polystyrene) resins |
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| JP特开2001-253988A 2001.09.18 |
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