CN102503265A - Environmentally-friendly cement mortar containing rice husk - Google Patents

Environmentally-friendly cement mortar containing rice husk Download PDF

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Publication number
CN102503265A
CN102503265A CN2011103244983A CN201110324498A CN102503265A CN 102503265 A CN102503265 A CN 102503265A CN 2011103244983 A CN2011103244983 A CN 2011103244983A CN 201110324498 A CN201110324498 A CN 201110324498A CN 102503265 A CN102503265 A CN 102503265A
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China
Prior art keywords
rice husk
cement
weight ratio
cement mortar
additive
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CN2011103244983A
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CN102503265B (en
Inventor
卢再传
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Zhuhai Baichen Imp. & Exp. Co., Ltd.
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TAIWAN BUSINESSES TECHNOLOGY DEVELOPMENT ZONE Co Ltd OF ZHUHAI BONDED AREA
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Priority to CN201110324498.3A priority Critical patent/CN102503265B/en
Publication of CN102503265A publication Critical patent/CN102503265A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Panels For Use In Building Construction (AREA)

Abstract

The invention discloses environmentally-friendly cement mortar containing rice husk, which provides environmentally-friendly cement mortar with high strength, good permeability, water proofness, heat insulation performance and crack-prevention performance. The cement mortar comprises cement mortar main body at least comprising cement and sandstone. A rice husk wetting additive is mixed with the cement mortar main body uniformly, and comprises rice husk and an additive, wherein a weight ratio of cement in the cement mortar main body to the rice husk wetting additive is (55-5):1. The invention can be widely applied to the field of environmentally-friendly cement mortar.

Description

Environment protecting cement mortar with rice husk
Technical field
The present invention relates to a kind of environment protecting cement mortar with rice husk.
Background technology
General sand-cement slurry regular meeting is according to user's different demands; Like ventilative, waterproof, heat insulation or anti-be full of cracks etc.; Thereby need to add different additives, as adding man-made fiber with the hardness of strengthening the sand-cement slurry moulding and prevent that it is cracked, but the man-made fiber water-repellancy is relatively poor and engages difficult with sand-cement slurry; Perhaps add Baolilong to increase effect of heat insulation and to alleviate the weight of sand-cement slurry moulding, can not cause bad environment pollution but Baolilong a century is mashed, the while Baolilong is not firmer and engage difficult with sand-cement slurry; Perhaps add cement blowing agent (like aluminium powder) in order to increasing effect of heat insulation and to alleviate the weight of sand-cement slurry moulding, but the cement blowing agent water-absorbent by force and not firmlyer also be not durable; Perhaps add chemicaladditives (like silicon) and be used to strengthen the effect of waterproof, anticracking, increase the intensity of sand-cement slurry moulding simultaneously, be detrimental to health but chemicaladditives can discharge objectionable impurities with temperature.
As everyone knows; Rice husk is a crude substance, and many wood materials of processing with discarded rice husk or other wood fibres or wood-plastic composite etc. are arranged, and announces [method for makings of rice husk combination building materials] No. 042468 like the Taiwan patent of invention; Wherein be earlier to use clear water to wash to nearly neutrality after via water retting the rice husk base material; With 80% to 85% of this rice husk, cement is about 10% to 13%, and edible seaweed powder about 2% to 5% and micro-sanitas are mixed water and mixed; It is filled in the mould building materials person who is pressed into different shape through height, yet:
It mainly uses a high proportion of rice husk to make wooden building materials, and the cement of a small amount of ratio increases building materials intensity, but it does not still belong to the cement building material of HS.
Therefore based on the rice husk self character, and the HS of cement itself, rice husk that the investigator attempts adding a small amount of ratio is arranged gradually in cement, to replace many syntheticses.
Summary of the invention
Technical problem to be solved by this invention is the deficiency that overcomes prior art; A kind of environment protecting cement building materials composition is provided; It is by adding the rice husk composition to sand-cement slurry; Replace tradition and use chemical additives such as man-made fiber goods Baolilong, thereby increase effects such as HS after the sand-cement slurry moulding, ventilative, waterproof, heat insulation and anti-be full of cracks.
The technical scheme that the present invention adopted is: the above-mentioned purpose according to the present invention; The present invention develops a kind of environment protecting cement mortar with rice husk; It comprises the cement mortar main body, and said cement mortar main body comprises cement and sandstone at least, evenly sneaks into the moistening auxiliary agent of rice husk in the said cement mortar main body; The moistening auxiliary agent of said rice husk then comprises rice husk and additive, and the weight ratio of the intravital cement of wherein said cement mortar master and the moistening auxiliary agent of said rice husk is in 55 to 1 to 5 to 1 the scope.
Because the rice husk surface has fine hair, sneak into the usage quantity that not only can reduce the sand-cement slurry main body in the sand-cement slurry main body, alleviate the weight after the moulding of sand-cement slurry main body; Fine hair can be strengthened the intersubjective force of cohesion of sand-cement slurry by the rice husk surface simultaneously, the intensity after the moulding of increase sand-cement slurry main body, and rice husk has natural silicon; Can increase water-repellancy and hardness after the moulding of sand-cement slurry main body, and silicon belongs to alkalescence, the sand-cement slurry main body also is alkalescence; The two mixes the incompatible situation of chemical classes soda acid that do not have; And the rice husk surface has one deck natural wax, belongs to not perishable for a long time not mashed fiber, sneaks into and does not have rotten problem in the sand-cement slurry main body.
Further, the intravital cement of said sand-cement slurry master is 50 to 1 with the weight ratio of the moistening auxiliary agent of said rice husk.
Further, the intravital cement of said sand-cement slurry master is 10 to 1 with the weight ratio of the moistening auxiliary agent of said rice husk.
Further, said additive comprises moisture and regulates composition.
Further, in the moistening auxiliary agent of said rice husk, said rice husk is 18 to 30 to 18 to 20 with the weight ratio of said additive, is more preferred from 18 to 25.
Further, the weight ratio of this moisture and said adjusting composition is in 5 to 1 to 3 to 1,13 to 3 to 7 to 3,6.5 to 1 to 3.5 to 1 or 8 to 1 to 4 to 1 in any proportional range, is more preferred from 4 to 1.
Further; Said adjusting composition comprises that weight percent is respectively 61.2% to 74.8% chlorinated wax, 1.8% to 2.2% dispersion agent, 9% to 11% terepthaloyl moietie, 4.5% to 5.5% wax powder, 4.5% to 5.5% dextrin and 9% to 11% the white cigarette of middle rank, is more preferred from 68% chlorinated wax, 2% dispersion agent, 10% terepthaloyl moietie, 5% wax powder, 5% dextrin and 10% the white cigarette of middle rank.
Further, in the moistening auxiliary agent of said rice husk, said rice husk is 7 to 16 to 7 to 10 with the weight ratio of said additive, is more preferred from 7 to 13.
Further, said moisture is 13 to 3 to 7 to 3 with the weight ratio of said adjusting composition, is more preferred from 10 to 3.
Further; Said adjusting composition comprises that weight percent is respectively 49.5% to 40.5% chlorinated wax, 1.8% to 2.2% dispersion agent, 55% to 45% terepthaloyl moietie and 4.5% to 5.5% the white cigarette of middle rank; Be more preferred from 45% chlorinated wax, 2% dispersion agent, 48% terepthaloyl moietie and 5% the white cigarette of middle rank.
Further, in the moistening auxiliary agent of said rice husk, said rice husk is 39 to 43 to 39 to 37 with the weight ratio of said additive, is more preferred from 39 to 40.
Further, said moisture is 6.5 to 1 to 3.5 to 1 with the weight ratio of said adjusting composition, is more preferred from 5 to 1.
Further; Said adjusting composition comprises that weight percent is respectively 70.2% to 85.8% chlorinated wax, 1.8% to 2.2% dispersion agent, 13.5% to 16.5% Teflon and 4.5% to 5.5% the white cigarette of middle rank; Be more preferred from 78% chlorinated wax, 2% dispersion agent, 15% Teflon and 5% the white cigarette of middle rank.
Further, in the moistening auxiliary agent of said rice husk, said rice husk is 44 to 40 to 44 to 30 with the weight ratio of said additive, is more preferred from 44 to 35.
Further, said moisture is 8 to 1 to 4 to 1 with the weight ratio of said adjusting composition, is more preferred from 6 to 1.
Further; Said adjusting composition comprises that weight percent is respectively 43.2% to 52.8% chlorinated wax, 1.8% to 2.2% dispersion agent, 31.5% to 38.5% Teflon and 13.5% to 16.5% terepthaloyl moietie, is more preferred from 48% chlorinated wax, 2% dispersion agent, 35% Teflon and 15% terepthaloyl moietie.
The invention has the beneficial effects as follows: the present invention utilizes the moistening auxiliary agent of said rice husk to replace man-made fiber, Baolilong, cement blowing agent or other chemicaladditivess that tradition is sneaked into the sand-cement slurry main body; To meet the environmental protection demand, when satisfying requirement of strength, also can have effects such as ventilative, waterproof or be full of cracks.
Embodiment
Comprehensive above-mentioned technical characterictic, the main effect of the present invention can appear in following embodiment is clear.
Present embodiment will provide a kind of environment protecting cement mortar of tool rice husk; It comprises the cement mortar main body; Said cement mortar main body comprises cement and sandstone at least; Evenly sneak into the moistening auxiliary agent of rice husk in the said cement mortar main body; The moistening auxiliary agent of said rice husk then comprises rice husk and additive; The weight ratio of the intravital cement of wherein said cement mortar master and the moistening auxiliary agent of said rice husk is in 55 to 1 to 5 to 1 the scope, and present embodiment is further to be respectively in 50 to 1 to 5 to 1 the scope with the weight ratio of the intravital cement of said sand-cement slurry master and the moistening auxiliary agent of said rice husk, and present embodiment is further to be respectively 50 to 1 and 10 to 1 with the weight ratio of the intravital cement of this sand-cement slurry master and the moistening auxiliary agent of said rice husk to experimentize; Wherein wt is that [cement 1000cc is about 1170 grams with the moistening auxiliary agent 800cc mixing of sandstone 2400cc, cement 8000cc and rice husk back than the composition that is 50 to 1; Rice husk 500cc then is about 122 grams { rough being equal to the moistening auxiliary agent weight of the rice husk of volume }, and its weight ratio just is 50 to 1], volume is the test piece of 300mm*300mm*25mm behind the excision forming; Weight ratio is that 10 to 1 composition is that excision forming is that volume is the test piece of 300mm*300mm*25mm after mixing with the moistening auxiliary agent 500cc of husky 3000cc, cement 1000cc and rice husk.
In the present embodiment, the moisture and the ratio of said adjusting composition and kind, the blending ratio of said adjusting composition are to experimentize with following A to four kinds of ratios of D in the rice husk in the moistening auxiliary agent of said rice husk and the weight ratio of additive, the said additive:
A. in the moistening auxiliary agent of said rice husk, said rice husk is 18 to 30 to 18 to 20 with the weight ratio of said additive, and weight ratio 18 to 25 is got in this experiment; Said moisture is 5 to 1 to 3 to 1 with the weight ratio of said adjusting composition, and it is 4 to 1 that weight ratio is got in this experiment; Said adjusting composition comprises that then per-cent is respectively 61.2% to 74.8% chlorinated wax, 1.8% to 2.2% dispersion agent, 9% to 11% terepthaloyl moietie, 4.5% to 5.5% wax powder, 4.5% to 5.5% dextrin and 9% to 11% the white cigarette of middle rank, and it is 68% chlorinated wax, 2% dispersion agent, 10% terepthaloyl moietie, 5% wax powder, 5% dextrin and 10% the white cigarette of middle rank that this experiment reaches weight percent; { rice husk 500cc is about 122 grams to regulate composition 100 grams, moisture 500 grams and 1500cc rice husk in the wherein various compositions; About 366 grams of 1500cc } mix; Just satisfy aforementioned ratio, afterwards with of the test piece test of the intravital cement of said sand-cement slurry master with the weight ratio 10 to 1 of the moistening auxiliary agent of said rice husk.
B. in the moistening auxiliary agent of said rice husk, said rice husk is 7 to 16 to 7 to 10 with the weight ratio of said additive, and it is 7 to 13 that weight ratio is got in this test; Said moisture is 13 to 3 to 7 to 3 with the weight ratio of said adjusting composition, and it is 10 to 3 that weight ratio is got in this test; Said adjusting composition comprises that weight percent is respectively 49.5% to 40.5% chlorinated wax, 1.8% to 2.2% dispersion agent, 55% to 45% terepthaloyl moietie and 4.5% to 5.5% the white cigarette of middle rank, and it is 45% chlorinated wax, 2% dispersion agent, 48% terepthaloyl moietie and 5% the white cigarette of middle rank that weight percent is got in this test; Wherein { rice husk 500cc is about 122 grams to regulate composition 150 grams, moisture 500 grams and 1500cc rice husk in each composition; 1500cc is about 366 grams } mix; Just satisfy aforementioned ratio, make an experiment with of the test piece of the intravital cement of said sand-cement slurry master afterwards with the weight ratio 10 to 1 of the moistening auxiliary agent of said rice husk.
C. in the moistening auxiliary agent of said rice husk, said rice husk is 39 to 43 to 39 to 37 with the weight ratio of said additive, and it is 39 to 40 that weight ratio is got in this test; Said moisture is 6.5 to 1 to 3.5 to 1 with the weight ratio of said adjusting composition, and it is 5 to 1 that weight ratio is got in this test; Said adjusting composition comprises that weight percent is respectively 70.2% to 85.8% chlorinated wax, 1.8% to 2.2% dispersion agent, 13.5% to 16.5% Teflon and 4.5% to 5.5% the white cigarette of middle rank, and it is 78% chlorinated wax, 2% dispersion agent, 15% Teflon and 5% the white cigarette of middle rank that weight percent is got in this test; Wherein { rice husk 500cc is about 122 grams to regulate composition 100 grams, moisture 500 grams and 2400cc rice husk in each composition; 2400cc is about 585 grams } mix; Just satisfy aforementioned ratio, make an experiment with of the test piece of the intravital cement of said sand-cement slurry master afterwards with the weight ratio 10 to 1 of the moistening auxiliary agent of said rice husk.
D. in the moistening auxiliary agent of said rice husk, said rice husk is 44 to 40 to 44 to 30 with the weight ratio of said additive, and it is 44 to 35 that weight ratio is got in this experiment; Said moisture is 8 to 1 to 4 to 1 with the weight ratio of said adjusting composition, and it is 6 to 1 that weight ratio is got in this experiment; Said adjusting composition comprises that weight percent is respectively 43.2% to 52.8% chlorinated wax, 1.8% to 2.2% dispersion agent, 31.5% to 38.5% Teflon and 13.5% to 16.5% terepthaloyl moietie, and it is 48% chlorinated wax, 2% dispersion agent, 35% Teflon and 15% terepthaloyl moietie that weight percent is got in this test; Wherein { 500cc is about 122 grams to regulate composition 100 grams, moisture 600 grams and 3600cc rice husk in each composition; About 880 grams of 3600cc } mix; Just satisfy aforementioned ratio, be respectively 10 to 1 test piece with the weight ratio of the intravital cement of said sand-cement slurry master and the moistening auxiliary agent of rice husk afterwards and 50 to 1 test piece makes an experiment.
Aforementioned each experimental result shows, when the adjusting composition in the moistening auxiliary agent of said rice husk contains chlorinated wax, can increase water-repellancy and drainage effect thereof after the moulding of said sand-cement slurry main body; When containing dispersion agent, can make each composition of said adjusting composition have the effect of oil-water emulsion; When containing terepthaloyl moietie, then as the plasticizer of said adjusting composition; When containing the white cigarette { being the refinement thing of oxidation silicon } of middle rank, can increase the intensity and the density of said sand-cement slurry main body moulding; Contain dextrin then as the temporary viscose of said adjusting composition and the effect of preserving moisture; When containing Teflon, can increase the anti-water-repellancy after the moulding of said sand-cement slurry main body and hinder hot; When containing the wax powder, can increase the anti-water-repellancy after the moulding of said sand-cement slurry main body.
The present invention can be widely used in environment protecting cement mortar field.

Claims (10)

1. environment protecting cement mortar with rice husk; Comprise the cement mortar main body; Said cement mortar main body comprises cement and sandstone at least; It is characterized in that: evenly sneak into the moistening auxiliary agent of rice husk in the said cement mortar main body, the moistening auxiliary agent of said rice husk then comprises rice husk and additive, and the weight ratio of the intravital cement of wherein said cement mortar master and the moistening auxiliary agent of said rice husk is in 55 to 1 to 5 to 1 the scope.
2. the environment protecting cement mortar with rice husk according to claim 1; It is characterized in that: said additive comprises moisture and regulates composition, and the weight ratio of said moisture and said adjusting composition is in 5 to 1 to 3 to 1,13 to 3 to 7 to 3,6.5 to 1 to 3.5 to 1 or 8 to 1 to 4 to 1 in any proportional range.
3. the environmental protection water mortar with rice husk according to claim 2 is characterized in that: in the moistening auxiliary agent of said rice husk, said rice husk is 18 to 30 to 18 to 20 with the weight ratio of said additive.
4. the environmental protection water mortar with rice husk according to claim 3 is characterized in that: said adjusting composition comprises that weight percent is respectively 61.2% to 74.8% oxidized petroleum waves, 1.8% to 2.2% dispersion agent, 9% to 11% terepthaloyl moietie, 4.5% to 5.5% wax powder, 4.5% to 5.5% dextrin and 9% to 11% the white cigarette of middle rank.
5. the environmental protection water mortar with rice husk according to claim 2 is characterized in that: said rice husk is 7 to 16 to 7 to 10 with the weight ratio of said additive.
6. the environmental protection water mortar with rice husk according to claim 5 is characterized in that: said adjusting composition comprises that weight percent is respectively 49.5% to 40.5% oxidized petroleum waves, 1.8% to 2.2% dispersion agent, 55% to 45% terepthaloyl moietie and 4.5% to 5.5% the white cigarette of middle rank.
7. the environmental protection water mortar with rice husk according to claim 2 is characterized in that: in the moistening auxiliary agent of said rice husk, said rice husk is 39 to 43 to 39 to 37 with the weight ratio of said additive.
8. the environmental protection water mortar with rice husk according to claim 7 is characterized in that: said adjusting composition comprises that weight percent is respectively 70.2% to 85.8% oxidized petroleum waves, 1.8% to 2.2% dispersion agent, 13.5% to 16.5% Teflon and 4.5% to 5.5% the white cigarette of middle rank.
9. the environmental protection water mortar with rice husk according to claim 2 is characterized in that: in the moistening auxiliary agent of said rice husk, said rice husk is 44 to 40 to 44 to 30 with the weight ratio of said additive.
10. the environmental protection water mortar with rice husk according to claim 9 is characterized in that: said adjusting composition comprises that weight percent is respectively 43.2% to 52.8% oxidized petroleum waves, 1.8% to 2.2% dispersion agent, 31.5% to 38.5% Teflon and 13.5% to 16.5% terepthaloyl moietie.
CN201110324498.3A 2011-10-24 2011-10-24 Environmentally-friendly cement mortar containing rice husk Expired - Fee Related CN102503265B (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6096559A (en) * 1983-10-27 1985-05-30 ジェイエスアール株式会社 Hydraulic composition deformable after curing
CN85104573A (en) * 1985-06-14 1986-12-10 第23国营建筑工程公司 The manufacture method of base substrate, particularly building unit
CN1142472A (en) * 1996-04-30 1997-02-12 交通部公路科学研究所 Rice-hull cement concrete
CN101255026A (en) * 2007-03-02 2008-09-03 王武添 Paddy powder, cement and cement mortar polymer mixed with the same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6096559A (en) * 1983-10-27 1985-05-30 ジェイエスアール株式会社 Hydraulic composition deformable after curing
CN85104573A (en) * 1985-06-14 1986-12-10 第23国营建筑工程公司 The manufacture method of base substrate, particularly building unit
CN1142472A (en) * 1996-04-30 1997-02-12 交通部公路科学研究所 Rice-hull cement concrete
CN101255026A (en) * 2007-03-02 2008-09-03 王武添 Paddy powder, cement and cement mortar polymer mixed with the same

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