CN108384390A - Anti-slip heat-preservation sound-insulation environment-friendly floor coating and preparation method thereof - Google Patents

Anti-slip heat-preservation sound-insulation environment-friendly floor coating and preparation method thereof Download PDF

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CN108384390A
CN108384390A CN201810239461.2A CN201810239461A CN108384390A CN 108384390 A CN108384390 A CN 108384390A CN 201810239461 A CN201810239461 A CN 201810239461A CN 108384390 A CN108384390 A CN 108384390A
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parts
sound insulation
agent
resin
floor coating
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王磊
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Hefei Yakeli New Building Materials Co ltd
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Hefei Yakeli New Building Materials Co ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • C09D7/62Additives non-macromolecular inorganic modified by treatment with other compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2244Oxides; Hydroxides of metals of zirconium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Wood Science & Technology (AREA)
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  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)
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Abstract

The invention discloses an anti-slip heat-insulation sound-insulation environment-friendly floor coating and a preparation method thereof, wherein the coating comprises the following raw materials in parts by weight: 90-100 parts of modified compound resin, 7-11 parts of sound insulation additive, 8-14 parts of heat insulation filler, 6-10 parts of anti-skid additive, 20-30 parts of tackifying resin, 2-4 parts of insect-repelling degerming extract, 10-20 parts of mixed dibasic acid ester, 15-20 parts of propylene glycol monomethyl ether acetate, 3-5 parts of titanium dioxide, 0.5-1.5 parts of anti-settling agent, 1-2 parts of film forming agent, 0.4-0.8 part of defoaming agent, 0.8-1.4 parts of flatting agent and 2-4 parts of dispersing agent. The floor coating provided by the invention has the advantages that the floor coating is fine and smooth in surface, excellent in leveling property and touch, good in heat preservation and sound insulation performance, and excellent in skid resistance, friction resistance and corrosion resistance; meanwhile, the raw material components of the invention are safe and reliable, nontoxic and harmless, the raw materials are easy to obtain, the cost is lower, the process is simple, the operation and the realization of industrial production are easy, and the invention has higher practical value and good application prospect.

Description

A kind of Anti-slide insulation sound insulation environmental protection floor coating and preparation method thereof
Technical field
The present invention relates to technical field of coatings, and in particular to a kind of Anti-slide insulation sound insulation environmental protection floor coating and its preparation side Method.
Background technology
The major function of floor coating is decoration and protection flooring, keeps floor cleaning beautiful, with other ornament materials Hydraulic type indoor environment is created together.In order to obtain good decorative effect, not according to some use occasions and effect requirements Together, height also more is required to the making of coating.Common paint adhesion is inadequate, is easy to peel off after drying up;Although having anti- Alkaline energy, but antiacid corrosive power is relatively not good enough;And the texture of common coating is poor.And it is reached using antiskid effect after coating Less than standard, it is also to weigh that can cause unnecessary injury, the anti-skidding and wear-resisting property of floor coating to old man and child in this way One major criterion of coating property, because the non-skid property of coating is directly related to the safety in utilization of people, and wearability In close relations with the service life of dope layer, wearability, which not enough can not only increase cost of material, can also increase construction cost.
In addition every year because of indoor furniture is fitted up being poisoned to death of occurring or sick number rises year by year, it is seen then that choosing It is most important to the health of household to select the ornament materials of health, especially healthy coating, but many coating of domestic market Middle benzene, the exceeded of VOC (volatile organic compounds) seriously affect health.Benzene, VOC are exceeded will to cause room organic contamination, It is serious to cause the symptoms such as occupant's headache, sore-throat, it is detrimental to health.Free toluene diisocyanate (TDI) is that have The organic compound of intense irritation gas.There are intense stimulus effect, Long Term Contact or high concentration to skin, eyes and respiratory tract TDI gases can cause bronchitis, allergic asthma, pneumonia, pulmonary edema.In addition, the use of existing floor paint top grade Synthetic fatty acid and acrylic acid system performance are good but of high cost, and market is difficult to receive;Other system prices are advantageous, but film Performance is general, and construction problem is more.
Flooring needs certain heat-insulating property and sound insulation value, existing coating this respect to be also weak simultaneously.
Invention content
In view of the drawbacks of the prior art, the object of the present invention is to provide a kind of Anti-slide insulation sound insulation environmental protection floor coatings, should Coating is as floor coating, and surface exquisiteness, levelability and sense of touch are more excellent, heat preservation and soundproof better performances, anti-skidding, antifriction It wipes, fine corrosion resistance;The raw material components of the present invention are safe and reliable simultaneously, and nontoxic, raw material is easy to get, and cost is relatively low, work Skill is concise, industrialized production easy to operate and realize, has higher practical value and good application prospect.
The present invention solves technical problem and adopts the following technical scheme that:
The present invention provides a kind of Anti-slide insulation sound insulation environmental protection floor coatings, include the raw material of following parts by weight:
Modified 90-100 parts of resin of compounding, 7-11 parts of sound insulation additive, 8-14 parts of thermal insulating filling, additive 6-10 parts anti-skidding, increasing 20-30 parts of resin of property, 2-4 parts of expelling parasite degerming extracting solution, 10-20 parts of mixed dibasic acid ester, propylene glycol methyl ether acetate 15-20 Part, is divided 3-5 parts of titanium dioxide, 0.5-1.5 parts of anti-settling agent, 1-2 parts of film forming agent, 0.4-0.8 parts of antifoaming agent, 0.8-1.4 parts of levelling agent 2-4 parts of powder.
Preferably, the Anti-slide insulation sound insulation environmental protection floor coating includes the raw material of following parts by weight:
Modified 95 parts of resin of compounding, 11 parts of thermal insulating filling, 8 parts of anti-skidding additive, 25 parts of resin of increasing property, drives 9 parts of sound insulation additive 3 parts of worm degerming extracting solution, 15 parts of mixed dibasic acid ester, 18 parts of propylene glycol methyl ether acetate, 4 parts of titanium dioxide, 1 part of anti-settling agent, at 1.5 parts of film, 0.6 part of antifoaming agent, 1.1 parts of levelling agent, 3 parts of dispersant.
Preferably, the sound insulation additive is glass bead, hollow glass fibre, floating bead according to weight ratio 3:1:2 compositions Mixture;
The thermal insulating filling is attapulgite, oyster shell whiting, silica flour, talcum powder according to weight ratio 3:2:1:The mixture of 2 compositions, The specification of the high temperature resistant filler was 400 mesh.
Preferably, the anti-skidding additive is nano zircite, nano ceramics micro mist, nano quartz sand according to weight ratio 4: 2:3 are modified, and the method for modifying is:Nano-mixture is added to the azido silanes coupling agent for being equivalent to total weight 3-5% The ethoxylated alkylamine of S-3046 and total weight 1-3%, stir 2-3h under the conditions of temperature is 55-65 DEG C, and filtering is sent to vacuum It is 0.08-0.10Mpa in vacuum degree, under conditions of temperature is 85-95 DEG C after dry heat 1-2h in drying box to obtain the final product.
Preferably, the modified compounding process for preparing resins is:By polyorganosiloxane resin, epoxy resin, acrylic resin According to weight ratio 2:3:1 dissolving in organic solvent, stirs and is warming up to 80-90 DEG C, be added hydroxyl-terminated injecting two methyl siloxane, Coupling agent and catalyst are uniformly mixed, isothermal reaction 2-4h, after reaction vacuum distillation removal low molecular compound and molten Then graphene is added in agent into mixture again, be stirred to react 1-2h to get.
Preferably, the reinforced resin is for fatty acid modified low viscosity short oil alkyd resin and without the high hydroxyl short oil alcohol of benzene Acid resin is according to weight ratio 3:The mixture of 2 compositions.
Preferably, the expelling parasite degerming extracting solution is:Aloe, Eupatorium adenophorum, tea tree, folium artemisiae argyi, Dalmatian chrysanthemum extracting solution press According to weight ratio 3:1:2:1:The mixture of 2 compositions.
Preferably, the anti-settling agent is polyolefin-wax;The film forming agent is Hydroxylated acrylic resin, and the antifoaming agent is to have Organosilicon polymer and vinethene are modified acrylic acid copolymer according to weight ratio 2:The mixture of 1 composition, the levelling agent are poly- third Olefin(e) acid ester copolymer, the dispersant are sodium polycarboxylate salt form dispersant.
The present invention also provides a kind of preparation methods of Anti-slide insulation sound insulation environmental protection floor coating, include the following steps:
Step 1 weighs prepare each component raw material as required;
Step 2, by mixed dibasic acid ester, increasing property resin, sound insulation additive, thermal insulating filling, anti-skidding additive, mixing is sent into high In temperature be 70-80 DEG C of rotating speed it is 250-350r/min in fast blender, stirs 15-25 minutes, obtain mixture A;
Step 3 modified compounding resin, propylene glycol methyl ether acetate, titanium dioxide, anti-settling agent is added in homogenizer, rotating speed To continue stirring 15-25 minutes under 400-600r/min, ultrasonic disperse 20-30min systems in ultrasonic wave are placed in dispersant is added Obtain mixture B;
Step 4 by the mixture B of mixture A, step 3 preparation prepared by film forming agent, antifoaming agent, levelling agent, step 2, is driven The mixing of worm degerming extracting solution is added in high speed dispersor, rotating speed 5000-6000r/min, and temperature is to be dispersed with stirring at 65-75 DEG C 25-35 minutes, the Anti-slide insulation sound insulation environmental protection floor coating of invention was made in natural cooling.
Preferably, the preparation process of the Anti-slide insulation sound insulation environmental protection floor coating is:
Step 1 weighs prepare each component raw material as required;
Step 2, by mixed dibasic acid ester, increasing property resin, sound insulation additive, thermal insulating filling, anti-skidding additive, mixing is sent into high In temperature be 75 DEG C of rotating speeds it is 300r/min in fast blender, stirs 20 minutes, obtain mixture A;
Step 3 modified compounding resin, propylene glycol methyl ether acetate, titanium dioxide, anti-settling agent is added in homogenizer, rotating speed To continue stirring 20 minutes under 500r/min, the obtained mixture B of ultrasonic disperse 25min in ultrasonic wave are placed in dispersant is added;
Step 4 by the mixture B of mixture A, step 3 preparation prepared by film forming agent, antifoaming agent, levelling agent, step 2, is driven The mixing of worm degerming extracting solution is added in high speed dispersor, rotating speed 5500r/min, and temperature is to be dispersed with stirring 30 minutes at 70 DEG C, The Anti-slide insulation sound insulation environmental protection floor coating of invention is made in natural cooling.
Compared with prior art, the present invention has following advantageous effect:
(1)A kind of sound insulation additive of Anti-slide insulation sound insulation environmental protection floor coating addition of the present invention is glass bead, hollow glass Glass fiber, floating bead, the hollow structure of several persons can effectively prevent the propagation of sound, while also certain heat-insulation warm keeping performance.
(2)The present invention a kind of Anti-slide insulation sound insulation environmental protection floor coating addition thermal insulating filling be mainly attapulgite, Oyster shell whiting, silica flour, talcum powder can be effectively improved the heat preservation and insulation of coating, and oyster shell whiting also has certain kill in addition Bacterium performance improves the corrosion resistance of coating, while a few persons can form fine and close lotion so that coating is not easy to draw because of overheat Cracking is played, the performance of coating is improved.
(3)A kind of anti-skidding additive of Anti-slide insulation sound insulation environmental protection floor coating addition of the present invention is predominantly nano oxidized Zirconium, nano ceramics micro mist, nano quartz sand, several persons can greatly improve the scratch-resistant performance of material, prevent coating surface excessively It is dangerous caused by smooth, while anti-skidding additive is prepared by modified so that its amalgamation between other compositions is more preferable, in conjunction with more It is close.
(4)A kind of Anti-slide insulation sound insulation environmental protection floor coating of the present invention, either bulk composition, solvent, auxiliary agent are not Containing the carcinogens such as benzene and triphen, heavy metal is free of, health performance is excellent, and what is used compounds resin using modified so that The coating of preparation has preferable levelability, glossiness and flexibility, all strictly controls the amount of volatile organic matter, environmental-protecting performance It is superior.
(5)A kind of reinforced resin of Anti-slide insulation sound insulation environmental protection floor coating addition of the present invention is predominantly fatty acid modified Low viscosity short oil alkyd resin and without the high hydroxyl short oil-ity alcohol acid resin of benzene, can effectively improve the sense of touch of coating, bond Performance is more preferable, and sagging performance is more excellent.
(6)A kind of expelling parasite degerming extracting solution of Anti-slide insulation sound insulation environmental protection floor coating addition of the present invention is mainly reed Luxuriant growth, Eupatorium adenophorum, tea tree, folium artemisiae argyi, Dalmatian chrysanthemum extracting solution, on the one hand its can effectively kill worm's ovum and mould, prevent terrace The spot caused by overlong time and worm bite, and on the other hand use vegetal substance, and the chemical combination agent avoided is to human body Harm.
(7)The present invention a kind of Anti-slide insulation sound insulation environmental protection floor coating be used as floor coating, surface exquisiteness, levelability and Sense of touch is more excellent, heat preservation and soundproof better performances, anti-skidding, rub resistance, fine corrosion resistance;The raw material group of the present invention simultaneously Divide securely and reliably, nontoxic, raw material is easy to get, and cost is relatively low, and technique is concise, and industrialized production easy to operate and realize has Higher practical value and good application prospect.
Specific implementation mode
With reference to specific embodiment, technical scheme in the embodiment of the invention is clearly and completely described, shows So, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the reality in the present invention Example is applied, every other embodiment obtained by those of ordinary skill in the art without making creative efforts all belongs to In the scope of protection of the invention.
Embodiment 1.
A kind of Anti-slide insulation sound insulation environmental protection floor coating of the present embodiment, includes the raw material of following parts by weight:
Modified 90 parts of resin of compounding, 8 parts of thermal insulating filling, 6 parts of anti-skidding additive, 20 parts of resin of increasing property, drives 7 parts of sound insulation additive 2 parts of worm degerming extracting solution, 10 parts of mixed dibasic acid ester, 15 parts of propylene glycol methyl ether acetate, 3 parts of titanium dioxide, 0.5 part of anti-settling agent, 1 part of film forming agent, 0.4 part of antifoaming agent, 0.8 part of levelling agent, 2 parts of dispersant.
Sound insulation additive in the present embodiment is glass bead, hollow glass fibre, floating bead according to weight ratio 3:1:2 compositions Mixture;
The thermal insulating filling is attapulgite, oyster shell whiting, silica flour, talcum powder according to weight ratio 3:2:1:The mixture of 2 compositions, The specification of the high temperature resistant filler was 400 mesh.
Anti-skidding additive in the present embodiment is nano zircite, nano ceramics micro mist, nano quartz sand according to weight ratio 4:2:3 are modified, and the method for modifying is:Nano-mixture is added to the azido silanes coupling agent for being equivalent to total weight 3% The ethoxylated alkylamine of S-3046 and total weight 1%, stir 2h under the conditions of temperature is 55 DEG C, and filtering is sent to vacuum drying chamber It is interior, it is 0.08Mpa in vacuum degree, under conditions of temperature is 85 DEG C after dry heat 1h to obtain the final product.
Being modified in the present embodiment compounds process for preparing resins:By polyorganosiloxane resin, epoxy resin, acrylic resin According to weight ratio 2:3:1 dissolving in organic solvent, stirs and is warming up to 80 DEG C, addition hydroxyl-terminated injecting two methyl siloxane, idol Join agent and catalyst, be uniformly mixed, isothermal reaction 2h, after reaction vacuum distillation removal low molecular compound and solvent, so Graphene is added into mixture again afterwards, be stirred to react 1h to get.
Reinforced resin in the present embodiment is for fatty acid modified low viscosity short oil alkyd resin and without the high hydroxyl short oil of benzene Alkyd resin is according to weight ratio 3:The mixture of 2 compositions.
Expelling parasite degerming extracting solution in the present embodiment is:Aloe, Eupatorium adenophorum, tea tree, folium artemisiae argyi, Dalmatian chrysanthemum extracting solution press According to weight ratio 3:1:2:1:The mixture of 2 compositions.
Anti-settling agent in the present embodiment is polyolefin-wax;The film forming agent is Hydroxylated acrylic resin, and the antifoaming agent is Organosilicon polymer and vinethene are modified acrylic acid copolymer according to weight ratio 2:The mixture of 1 composition, the levelling agent is poly- Acrylate interpolymer, the dispersant are sodium polycarboxylate salt form dispersant.
A kind of preparation method of Anti-slide insulation sound insulation environmental protection floor coating of the present embodiment, includes the following steps:
Step 1 weighs prepare each component raw material as required;
Step 2, by mixed dibasic acid ester, increasing property resin, sound insulation additive, thermal insulating filling, anti-skidding additive, mixing is sent into high In temperature be 70 DEG C of rotating speeds it is 250r/min in fast blender, stirs 15 minutes, obtain mixture A;
Step 3 modified compounding resin, propylene glycol methyl ether acetate, titanium dioxide, anti-settling agent is added in homogenizer, rotating speed To continue stirring 15 minutes under 400r/min, the obtained mixture B of ultrasonic disperse 20min in ultrasonic wave are placed in dispersant is added;
Step 4 by the mixture B of mixture A, step 3 preparation prepared by film forming agent, antifoaming agent, levelling agent, step 2, is driven The mixing of worm degerming extracting solution is added in high speed dispersor, rotating speed 5000r/min, and temperature is to be dispersed with stirring 25 minutes at 65 DEG C, The Anti-slide insulation sound insulation environmental protection floor coating of invention is made in natural cooling.
Embodiment 2.
A kind of Anti-slide insulation sound insulation environmental protection floor coating of the present embodiment, includes the raw material of following parts by weight:
Modified 100 parts of resin of compounding, 11 parts of sound insulation additive, 14 parts of thermal insulating filling, 10 parts of anti-skidding additive, increasing property resin 30 Part, 4 parts of expelling parasite degerming extracting solution, 20 parts of mixed dibasic acid ester, 20 parts of propylene glycol methyl ether acetate, 5 parts of titanium dioxide, anti-settling agent 1.5 parts, 2 parts of film forming agent, 0.8 part of antifoaming agent, 1.4 parts of levelling agent, 4 parts of dispersant.
Sound insulation additive in the present embodiment is glass bead, hollow glass fibre, floating bead according to weight ratio 3:1:2 compositions Mixture;
The thermal insulating filling is attapulgite, oyster shell whiting, silica flour, talcum powder according to weight ratio 3:2:1:The mixture of 2 compositions, The specification of the high temperature resistant filler was 400 mesh.
Anti-skidding additive in the present embodiment is nano zircite, nano ceramics micro mist, nano quartz sand according to weight ratio 4:2:3 are modified, and the method for modifying is:Nano-mixture is added to the azido silanes coupling agent for being equivalent to total weight 5% The ethoxylated alkylamine of S-3046 and total weight 3%, stir 3h under the conditions of temperature is 65 DEG C, and filtering is sent to vacuum drying chamber It is interior, it is 0.10Mpa in vacuum degree, under conditions of temperature is 95 DEG C after dry heat 2h to obtain the final product.
Being modified in the present embodiment compounds process for preparing resins:By polyorganosiloxane resin, epoxy resin, acrylic resin According to weight ratio 2:3:1 dissolving in organic solvent, stirs and is warming up to 90 DEG C, addition hydroxyl-terminated injecting two methyl siloxane, idol Join agent and catalyst, be uniformly mixed, isothermal reaction 4h, after reaction vacuum distillation removal low molecular compound and solvent, so Graphene is added into mixture again afterwards, be stirred to react 2h to get.
Reinforced resin in the present embodiment is for fatty acid modified low viscosity short oil alkyd resin and without the high hydroxyl short oil of benzene Alkyd resin is according to weight ratio 3:The mixture of 2 compositions.
Expelling parasite degerming extracting solution in the present embodiment is:Aloe, Eupatorium adenophorum, tea tree, folium artemisiae argyi, Dalmatian chrysanthemum extracting solution press According to weight ratio 3:1:2:1:The mixture of 2 compositions.
Anti-settling agent in the present embodiment is polyolefin-wax;The film forming agent is Hydroxylated acrylic resin, and the antifoaming agent is Organosilicon polymer and vinethene are modified acrylic acid copolymer according to weight ratio 2:The mixture of 1 composition, the levelling agent is poly- Acrylate interpolymer, the dispersant are sodium polycarboxylate salt form dispersant.
A kind of preparation method of Anti-slide insulation sound insulation environmental protection floor coating of the present embodiment, includes the following steps:
Step 1 weighs prepare each component raw material as required;
Step 2, by mixed dibasic acid ester, increasing property resin, sound insulation additive, thermal insulating filling, anti-skidding additive, mixing is sent into high In temperature be 80 DEG C of rotating speeds it is 350r/min in fast blender, stirs 25 minutes, obtain mixture A;
Step 3 modified compounding resin, propylene glycol methyl ether acetate, titanium dioxide, anti-settling agent is added in homogenizer, rotating speed To continue stirring 25 minutes under 600r/min, the obtained mixture B of ultrasonic disperse 30min in ultrasonic wave are placed in dispersant is added;
Step 4 by the mixture B of mixture A, step 3 preparation prepared by film forming agent, antifoaming agent, levelling agent, step 2, is driven The mixing of worm degerming extracting solution is added in high speed dispersor, rotating speed 6000r/min, and temperature is to be dispersed with stirring 35 minutes at 75 DEG C, The Anti-slide insulation sound insulation environmental protection floor coating of invention is made in natural cooling.
Embodiment 3.
A kind of Anti-slide insulation sound insulation environmental protection floor coating of the present embodiment, includes the raw material of following parts by weight:
Modified 95 parts of resin of compounding, 11 parts of thermal insulating filling, 8 parts of anti-skidding additive, 25 parts of resin of increasing property, drives 9 parts of sound insulation additive 3 parts of worm degerming extracting solution, 15 parts of mixed dibasic acid ester, 18 parts of propylene glycol methyl ether acetate, 4 parts of titanium dioxide, 1 part of anti-settling agent, at 1.5 parts of film, 0.6 part of antifoaming agent, 1.1 parts of levelling agent, 3 parts of dispersant.
Sound insulation additive in the present embodiment is glass bead, hollow glass fibre, floating bead according to weight ratio 3:1:2 compositions Mixture;
The thermal insulating filling is attapulgite, oyster shell whiting, silica flour, talcum powder according to weight ratio 3:2:1:The mixture of 2 compositions, The specification of the high temperature resistant filler was 400 mesh.
Anti-skidding additive in the present embodiment is nano zircite, nano ceramics micro mist, nano quartz sand according to weight ratio 4:2:3 are modified, and the method for modifying is:Nano-mixture is added to the azido silanes coupling agent for being equivalent to total weight 4% The ethoxylated alkylamine of S-3046 and total weight 2%, stir 2.5h under the conditions of temperature is 60 DEG C, and filtering is sent to vacuum drying In case, under the conditions of vacuum degree is 0.09Mpa, is at a temperature of 90 °C after dry heat 1.5h to obtain the final product.
Being modified in the present embodiment compounds process for preparing resins:By polyorganosiloxane resin, epoxy resin, acrylic resin According to weight ratio 2:3:1 dissolving in organic solvent, stirs and is warming up to 85 DEG C, addition hydroxyl-terminated injecting two methyl siloxane, idol Join agent and catalyst, be uniformly mixed, isothermal reaction 3h, after reaction vacuum distillation removal low molecular compound and solvent, so Graphene is added into mixture again afterwards, be stirred to react 1.5h to get.
Reinforced resin in the present embodiment is for fatty acid modified low viscosity short oil alkyd resin and without the high hydroxyl short oil of benzene Alkyd resin is according to weight ratio 3:The mixture of 2 compositions.
Expelling parasite degerming extracting solution in the present embodiment is:Aloe, Eupatorium adenophorum, tea tree, folium artemisiae argyi, Dalmatian chrysanthemum extracting solution press According to weight ratio 3:1:2:1:The mixture of 2 compositions.
Anti-settling agent in the present embodiment is polyolefin-wax;The film forming agent is Hydroxylated acrylic resin, and the antifoaming agent is Organosilicon polymer and vinethene are modified acrylic acid copolymer according to weight ratio 2:The mixture of 1 composition, the levelling agent is poly- Acrylate interpolymer, the dispersant are sodium polycarboxylate salt form dispersant.
A kind of preparation method of Anti-slide insulation sound insulation environmental protection floor coating of the present embodiment, includes the following steps:
Step 1 weighs prepare each component raw material as required;
Step 2, by mixed dibasic acid ester, increasing property resin, sound insulation additive, thermal insulating filling, anti-skidding additive, mixing is sent into high In temperature be 75 DEG C of rotating speeds it is 300r/min in fast blender, stirs 20 minutes, obtain mixture A;
Step 3 modified compounding resin, propylene glycol methyl ether acetate, titanium dioxide, anti-settling agent is added in homogenizer, rotating speed To continue stirring 20 minutes under 500r/min, the obtained mixture B of ultrasonic disperse 25min in ultrasonic wave are placed in dispersant is added;
Step 4 by the mixture B of mixture A, step 3 preparation prepared by film forming agent, antifoaming agent, levelling agent, step 2, is driven The mixing of worm degerming extracting solution is added in high speed dispersor, rotating speed 5500r/min, and temperature is to be dispersed with stirring 30 minutes at 70 DEG C, The Anti-slide insulation sound insulation environmental protection floor coating of invention is made in natural cooling.
A kind of Anti-slide insulation sound insulation environmental protection floor coating of the present invention is used as floor coating, and surface is fine and smooth, levelability and tactile Feel more excellent, heat preservation and soundproof better performances, anti-skidding, rub resistance, fine corrosion resistance;The raw material components of the present invention simultaneously Securely and reliably, nontoxic, raw material is easy to get, and cost is relatively low, and technique is concise, industrialized production easy to operate and realize, have compared with High practical value and good application prospect.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power Profit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent requirements of the claims Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art The other embodiment being appreciated that.

Claims (10)

1. a kind of Anti-slide insulation sound insulation environmental protection floor coating, which is characterized in that include the raw material of following parts by weight:
Modified 90-100 parts of resin of compounding, 7-11 parts of sound insulation additive, 8-14 parts of thermal insulating filling, additive 6-10 parts anti-skidding, increasing 20-30 parts of resin of property, 2-4 parts of expelling parasite degerming extracting solution, 10-20 parts of mixed dibasic acid ester, propylene glycol methyl ether acetate 15-20 Part, is divided 3-5 parts of titanium dioxide, 0.5-1.5 parts of anti-settling agent, 1-2 parts of film forming agent, 0.4-0.8 parts of antifoaming agent, 0.8-1.4 parts of levelling agent 2-4 parts of powder.
2. a kind of Anti-slide insulation sound insulation environmental protection floor coating according to claim 1, which is characterized in that the Anti-slide insulation Sound insulation environmental protection floor coating includes the raw material of following parts by weight:
Modified 95 parts of resin of compounding, 11 parts of thermal insulating filling, 8 parts of anti-skidding additive, 25 parts of resin of increasing property, drives 9 parts of sound insulation additive 3 parts of worm degerming extracting solution, 15 parts of mixed dibasic acid ester, 18 parts of propylene glycol methyl ether acetate, 4 parts of titanium dioxide, 1 part of anti-settling agent, at 1.5 parts of film, 0.6 part of antifoaming agent, 1.1 parts of levelling agent, 3 parts of dispersant.
3. a kind of Anti-slide insulation sound insulation environmental protection floor coating according to claim 1 or 2, which is characterized in that the sound insulation Additive is glass bead, hollow glass fibre, floating bead according to weight ratio 3:1:The mixture of 2 compositions;
The thermal insulating filling is attapulgite, oyster shell whiting, silica flour, talcum powder according to weight ratio 3:2:1:The mixture of 2 compositions, The specification of the high temperature resistant filler was 400 mesh.
4. a kind of Anti-slide insulation sound insulation environmental protection floor coating according to claim 1 or 2, which is characterized in that described anti-skidding Additive is nano zircite, nano ceramics micro mist, nano quartz sand according to weight ratio 4:2:3 are modified, the modification side Method is:Nano zircite, nano ceramics micro mist, nano quartz sand are mixed, the azido silanes for being equivalent to total weight 3-5% are added The ethoxylated alkylamine of coupling agent S-3046 and total weight 1-3% stir 2-3h under the conditions of temperature is 55-65 DEG C, and filtering is sent It is 0.08-0.10Mpa in vacuum degree, under conditions of temperature is 85-95 DEG C after dry heat 1-2h i.e. to vacuum drying chamber .
5. a kind of Anti-slide insulation sound insulation environmental protection floor coating according to claim 1 or 2, which is characterized in that the modification Compounding process for preparing resins is:By polyorganosiloxane resin, epoxy resin, acrylic resin according to weight ratio 2:3:1 has been dissolved in In solvent, stirs and be warming up to 80-90 DEG C, addition hydroxyl-terminated injecting two methyl siloxane, coupling agent and catalyst mix equal Even, isothermal reaction 2-4h, vacuum distillation removal low molecular compound and solvent, are then added into mixture again after reaction Graphene, be stirred to react 1-2h to get.
6. a kind of Anti-slide insulation sound insulation environmental protection floor coating according to claim 1 or 2, which is characterized in that the enhancing Resin is for fatty acid modified low viscosity short oil alkyd resin and without the high hydroxyl short oil-ity alcohol acid resin of benzene according to weight ratio 3:2 compositions Mixture.
7. a kind of Anti-slide insulation sound insulation environmental protection floor coating according to claim 1 or 2, which is characterized in that the expelling parasite Degerming extracting solution is:Aloe, Eupatorium adenophorum, tea tree, folium artemisiae argyi, Dalmatian chrysanthemum extracting solution according to weight ratio 3:1:2:1:2 compositions Mixture.
8. a kind of Anti-slide insulation sound insulation environmental protection floor coating according to claim 1 or 2, which is characterized in that described anti-settling Agent is polyolefin-wax;The film forming agent is Hydroxylated acrylic resin, and the antifoaming agent is that organosilicon polymer and vinethene are modified Acrylic acid copolymer is according to weight ratio 2:The mixture of 1 composition, the levelling agent are polyacrylate copolymer, the dispersant For sodium polycarboxylate salt form dispersant.
9. a kind of method preparing Anti-slide insulation sound insulation environmental protection floor coating as claimed in claim 1 or 2, which is characterized in that Include the following steps:
Step 1 weighs prepare each component raw material as required;
Step 2, by mixed dibasic acid ester, increasing property resin, sound insulation additive, thermal insulating filling, anti-skidding additive, mixing is sent into high In temperature be 70-80 DEG C of rotating speed it is 250-350r/min in fast blender, stirs 15-25 minutes, obtain mixture A;
Step 3 modified compounding resin, propylene glycol methyl ether acetate, titanium dioxide, anti-settling agent is added in homogenizer, rotating speed To continue stirring 15-25 minutes under 400-600r/min, ultrasonic disperse 20-30min systems in ultrasonic wave are placed in dispersant is added Obtain mixture B;
Step 4 by the mixture B of mixture A, step 3 preparation prepared by film forming agent, antifoaming agent, levelling agent, step 2, is driven The mixing of worm degerming extracting solution is added in high speed dispersor, rotating speed 5000-6000r/min, and temperature is to be dispersed with stirring at 65-75 DEG C 25-35 minutes, the Anti-slide insulation sound insulation environmental protection floor coating of invention was made in natural cooling.
10. a kind of preparation method of Anti-slide insulation sound insulation environmental protection floor coating according to claim 9, which is characterized in that The step is:
Step 1 weighs prepare each component raw material as required;
Step 2, by mixed dibasic acid ester, increasing property resin, sound insulation additive, thermal insulating filling, anti-skidding additive, mixing is sent into high In temperature be 75 DEG C of rotating speeds it is 300r/min in fast blender, stirs 20 minutes, obtain mixture A;
Step 3 modified compounding resin, propylene glycol methyl ether acetate, titanium dioxide, anti-settling agent is added in homogenizer, rotating speed To continue stirring 20 minutes under 500r/min, the obtained mixture B of ultrasonic disperse 25min in ultrasonic wave are placed in dispersant is added;
Step 4 by the mixture B of mixture A, step 3 preparation prepared by film forming agent, antifoaming agent, levelling agent, step 2, is driven The mixing of worm degerming extracting solution is added in high speed dispersor, rotating speed 5500r/min, and temperature is to be dispersed with stirring 30 minutes at 70 DEG C, The Anti-slide insulation sound insulation environmental protection floor coating of invention is made in natural cooling.
CN201810239461.2A 2018-03-22 2018-03-22 Anti-slip heat-preservation sound-insulation environment-friendly floor coating and preparation method thereof Withdrawn CN108384390A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109231506A (en) * 2018-09-05 2019-01-18 盐城项远环保设备有限公司 A kind of monomer water treatment facilities
CN110183940A (en) * 2019-06-28 2019-08-30 江苏道蓬科技有限公司 The preparation method of sound insulation epoxy coating
CN110436862A (en) * 2019-07-11 2019-11-12 华南理工大学 A kind of heat-insulating sound-insulating lime white building decoration materials and preparation method thereof
CN111019527A (en) * 2018-10-09 2020-04-17 珠海市沃德科技有限公司 High pressure resistant coating
CN111560205A (en) * 2020-07-08 2020-08-21 百草春天大生物科技(青岛)有限公司 Artemisia argyi antioxidant water-based paint and preparation method thereof
CN112205900A (en) * 2020-10-13 2021-01-12 海宁天三纸制品有限公司 PP chopping board and manufacturing process thereof
CN113248992A (en) * 2021-06-09 2021-08-13 广东盛世宝建筑新技术有限公司 Building coating with insect prevention and sound insulation functions and preparation method thereof
CN115651511A (en) * 2022-11-15 2023-01-31 广东电网有限责任公司 Thermal insulation spraying material and preparation method and application thereof

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109231506A (en) * 2018-09-05 2019-01-18 盐城项远环保设备有限公司 A kind of monomer water treatment facilities
CN111019527A (en) * 2018-10-09 2020-04-17 珠海市沃德科技有限公司 High pressure resistant coating
CN110183940A (en) * 2019-06-28 2019-08-30 江苏道蓬科技有限公司 The preparation method of sound insulation epoxy coating
CN110436862A (en) * 2019-07-11 2019-11-12 华南理工大学 A kind of heat-insulating sound-insulating lime white building decoration materials and preparation method thereof
CN111560205A (en) * 2020-07-08 2020-08-21 百草春天大生物科技(青岛)有限公司 Artemisia argyi antioxidant water-based paint and preparation method thereof
CN111560205B (en) * 2020-07-08 2021-11-09 百草边大生物科技(青岛)有限公司 Artemisia argyi antioxidant water-based paint and preparation method thereof
CN112205900A (en) * 2020-10-13 2021-01-12 海宁天三纸制品有限公司 PP chopping board and manufacturing process thereof
CN113248992A (en) * 2021-06-09 2021-08-13 广东盛世宝建筑新技术有限公司 Building coating with insect prevention and sound insulation functions and preparation method thereof
CN115651511A (en) * 2022-11-15 2023-01-31 广东电网有限责任公司 Thermal insulation spraying material and preparation method and application thereof

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