CN102502538A - 一种钙辅助低温合成超细氮化铝粉体的方法 - Google Patents
一种钙辅助低温合成超细氮化铝粉体的方法 Download PDFInfo
- Publication number
- CN102502538A CN102502538A CN2011103494743A CN201110349474A CN102502538A CN 102502538 A CN102502538 A CN 102502538A CN 2011103494743 A CN2011103494743 A CN 2011103494743A CN 201110349474 A CN201110349474 A CN 201110349474A CN 102502538 A CN102502538 A CN 102502538A
- Authority
- CN
- China
- Prior art keywords
- calcium
- aluminium
- source
- solution
- nitride powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000843 powder Substances 0.000 title claims abstract description 58
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 title claims abstract description 29
- 229910052791 calcium Inorganic materials 0.000 title claims abstract description 29
- 239000011575 calcium Substances 0.000 title claims abstract description 29
- 238000000034 method Methods 0.000 title claims abstract description 29
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 title claims abstract description 20
- 230000002194 synthesizing effect Effects 0.000 title claims abstract description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 27
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 27
- 238000002156 mixing Methods 0.000 claims abstract description 27
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 26
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 26
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000001816 cooling Methods 0.000 claims abstract description 9
- 239000002904 solvent Substances 0.000 claims abstract description 9
- 238000001354 calcination Methods 0.000 claims abstract description 3
- 229910017083 AlN Inorganic materials 0.000 claims description 31
- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 claims description 31
- 239000004411 aluminium Substances 0.000 claims description 24
- 238000009413 insulation Methods 0.000 claims description 19
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 8
- 239000012299 nitrogen atmosphere Substances 0.000 claims description 7
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 5
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 5
- 229930006000 Sucrose Natural products 0.000 claims description 5
- 239000008103 glucose Substances 0.000 claims description 5
- 239000005720 sucrose Substances 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 4
- 239000008367 deionised water Substances 0.000 claims description 4
- 229910021641 deionized water Inorganic materials 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 claims description 3
- SMZOGRDCAXLAAR-UHFFFAOYSA-N aluminium isopropoxide Chemical compound [Al+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] SMZOGRDCAXLAAR-UHFFFAOYSA-N 0.000 claims description 3
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 3
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 claims description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 2
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 claims description 2
- 239000001639 calcium acetate Substances 0.000 claims description 2
- 229960005147 calcium acetate Drugs 0.000 claims description 2
- 235000011092 calcium acetate Nutrition 0.000 claims description 2
- 239000001110 calcium chloride Substances 0.000 claims description 2
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 2
- 239000000470 constituent Substances 0.000 claims description 2
- 229920000609 methyl cellulose Polymers 0.000 claims description 2
- 239000001923 methylcellulose Substances 0.000 claims description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 8
- 239000000126 substance Substances 0.000 abstract description 8
- 238000002360 preparation method Methods 0.000 abstract description 6
- 238000006722 reduction reaction Methods 0.000 abstract description 5
- 239000012298 atmosphere Substances 0.000 abstract description 4
- 239000002994 raw material Substances 0.000 abstract description 4
- 238000009792 diffusion process Methods 0.000 abstract description 3
- 239000007791 liquid phase Substances 0.000 abstract description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 2
- 238000011946 reduction process Methods 0.000 abstract description 2
- 239000000758 substrate Substances 0.000 abstract description 2
- 238000003786 synthesis reaction Methods 0.000 abstract description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 3
- 229910001873 dinitrogen Inorganic materials 0.000 abstract 2
- 239000000243 solution Substances 0.000 abstract 2
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 230000005496 eutectics Effects 0.000 abstract 1
- 238000000227 grinding Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000011259 mixed solution Substances 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- 238000005303 weighing Methods 0.000 description 12
- ULGYAEQHFNJYML-UHFFFAOYSA-N [AlH3].[Ca] Chemical compound [AlH3].[Ca] ULGYAEQHFNJYML-UHFFFAOYSA-N 0.000 description 9
- 238000005245 sintering Methods 0.000 description 9
- 239000002245 particle Substances 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 238000002441 X-ray diffraction Methods 0.000 description 3
- 238000001000 micrograph Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- REDXJYDRNCIFBQ-UHFFFAOYSA-N aluminium(3+) Chemical compound [Al+3] REDXJYDRNCIFBQ-UHFFFAOYSA-N 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 229910001424 calcium ion Inorganic materials 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000000374 eutectic mixture Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000005121 nitriding Methods 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- FRWYFWZENXDZMU-UHFFFAOYSA-N 2-iodoquinoline Chemical compound C1=CC=CC2=NC(I)=CC=C21 FRWYFWZENXDZMU-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical class [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- JLDSOYXADOWAKB-UHFFFAOYSA-N aluminium nitrate Chemical class [Al+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O JLDSOYXADOWAKB-UHFFFAOYSA-N 0.000 description 1
- 238000004500 asepsis Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- LTPBRCUWZOMYOC-UHFFFAOYSA-N beryllium oxide Inorganic materials O=[Be] LTPBRCUWZOMYOC-UHFFFAOYSA-N 0.000 description 1
- 244000309464 bull Species 0.000 description 1
- 229940043430 calcium compound Drugs 0.000 description 1
- 150000001674 calcium compounds Chemical class 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 125000005909 ethyl alcohol group Chemical group 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000009766 low-temperature sintering Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- -1 metals ion Chemical class 0.000 description 1
- 238000004377 microelectronic Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 238000003836 solid-state method Methods 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000007704 wet chemistry method Methods 0.000 description 1
Images
Landscapes
- Ceramic Products (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Abstract
Description
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 201110349474 CN102502538B (zh) | 2011-11-08 | 2011-11-08 | 一种钙辅助低温合成超细氮化铝粉体的方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 201110349474 CN102502538B (zh) | 2011-11-08 | 2011-11-08 | 一种钙辅助低温合成超细氮化铝粉体的方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102502538A true CN102502538A (zh) | 2012-06-20 |
CN102502538B CN102502538B (zh) | 2013-04-10 |
Family
ID=46214689
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 201110349474 Expired - Fee Related CN102502538B (zh) | 2011-11-08 | 2011-11-08 | 一种钙辅助低温合成超细氮化铝粉体的方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN102502538B (zh) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103320899A (zh) * | 2013-07-01 | 2013-09-25 | 中国计量学院 | 一种纳米氮化铝纤维的制备方法 |
CN104211025A (zh) * | 2014-08-29 | 2014-12-17 | 中国计量学院 | 一种立方相氮化铝纤维的制备方法 |
CN106082149A (zh) * | 2016-06-15 | 2016-11-09 | 潮州三环(集团)股份有限公司 | 氮化铝粉体的制备方法 |
CN106699189A (zh) * | 2016-11-25 | 2017-05-24 | 河北利福光电技术有限公司 | 一种氮化铝陶瓷基板用氮化铝粉体及其制备方法 |
CN108439992A (zh) * | 2018-03-13 | 2018-08-24 | 绍兴文理学院 | 一种致密型氮化铝陶瓷的制备方法 |
CN108862216A (zh) * | 2018-09-26 | 2018-11-23 | 湖南大学 | 一种高纯度、类球形纳米氮化铝颗粒的制备方法 |
CN109264679A (zh) * | 2018-10-29 | 2019-01-25 | 陕西科技大学 | 一种AlN粉体的制备方法 |
CN111302807A (zh) * | 2020-04-02 | 2020-06-19 | 上海闻泰信息技术有限公司 | 一种芯片用散热材料的制备方法、芯片用散热材料、散热芯片及应用 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4746637A (en) * | 1984-11-08 | 1988-05-24 | Kabushiki Kaisha Toshiba | Aluminum nitride sintered body and process for producing the same |
JP2831411B2 (ja) * | 1989-12-28 | 1998-12-02 | 三井化学株式会社 | 窒化アルミニウム粉末の製造方法 |
CN1513756A (zh) * | 2003-06-27 | 2004-07-21 | 中国科学院上海硅酸盐研究所 | 一种六方相纳米氮化铝粉体的制备方法 |
CN101935220A (zh) * | 2010-08-31 | 2011-01-05 | 西安交通大学 | 碳纳米纤维增强氮化铝复相陶瓷及其制备方法 |
-
2011
- 2011-11-08 CN CN 201110349474 patent/CN102502538B/zh not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4746637A (en) * | 1984-11-08 | 1988-05-24 | Kabushiki Kaisha Toshiba | Aluminum nitride sintered body and process for producing the same |
JP2831411B2 (ja) * | 1989-12-28 | 1998-12-02 | 三井化学株式会社 | 窒化アルミニウム粉末の製造方法 |
CN1513756A (zh) * | 2003-06-27 | 2004-07-21 | 中国科学院上海硅酸盐研究所 | 一种六方相纳米氮化铝粉体的制备方法 |
CN101935220A (zh) * | 2010-08-31 | 2011-01-05 | 西安交通大学 | 碳纳米纤维增强氮化铝复相陶瓷及其制备方法 |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103320899A (zh) * | 2013-07-01 | 2013-09-25 | 中国计量学院 | 一种纳米氮化铝纤维的制备方法 |
CN104211025A (zh) * | 2014-08-29 | 2014-12-17 | 中国计量学院 | 一种立方相氮化铝纤维的制备方法 |
CN104211025B (zh) * | 2014-08-29 | 2016-01-20 | 中国计量学院 | 一种立方相氮化铝纤维的制备方法 |
CN106082149A (zh) * | 2016-06-15 | 2016-11-09 | 潮州三环(集团)股份有限公司 | 氮化铝粉体的制备方法 |
CN106082149B (zh) * | 2016-06-15 | 2018-09-25 | 潮州三环(集团)股份有限公司 | 氮化铝粉体的制备方法 |
CN106699189A (zh) * | 2016-11-25 | 2017-05-24 | 河北利福光电技术有限公司 | 一种氮化铝陶瓷基板用氮化铝粉体及其制备方法 |
CN108439992A (zh) * | 2018-03-13 | 2018-08-24 | 绍兴文理学院 | 一种致密型氮化铝陶瓷的制备方法 |
CN108862216A (zh) * | 2018-09-26 | 2018-11-23 | 湖南大学 | 一种高纯度、类球形纳米氮化铝颗粒的制备方法 |
CN108862216B (zh) * | 2018-09-26 | 2021-09-17 | 湖南大学 | 一种高纯度、类球形纳米氮化铝颗粒的制备方法 |
CN109264679A (zh) * | 2018-10-29 | 2019-01-25 | 陕西科技大学 | 一种AlN粉体的制备方法 |
CN111302807A (zh) * | 2020-04-02 | 2020-06-19 | 上海闻泰信息技术有限公司 | 一种芯片用散热材料的制备方法、芯片用散热材料、散热芯片及应用 |
Also Published As
Publication number | Publication date |
---|---|
CN102502538B (zh) | 2013-04-10 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102502538B (zh) | 一种钙辅助低温合成超细氮化铝粉体的方法 | |
CN102502539B (zh) | 一种钇掺杂纳米氮化铝粉体的制备方法 | |
CN101973532B (zh) | 一种纳米氮化铝粉体的制备方法 | |
CN102515767B (zh) | 一种制备SiC-AlN固溶体陶瓷粉末的方法 | |
JP6271665B1 (ja) | 球状窒化アルミニウム粉末の製造方法 | |
CN103539088B (zh) | 一种氮化铝纳米颗粒的合成方法 | |
CN103588182B (zh) | 一种球形氮化铝粉体的制备方法 | |
CN107721429A (zh) | 碳化锆‑碳化硅复合粉体材料及其制备方法 | |
CN106431418A (zh) | 水热法制备纳米AlN粉体的方法和其中间体及产品 | |
CN104973615A (zh) | 一种纳米氧化钆粉体的微波燃烧制备方法 | |
CN108190882A (zh) | 导热石墨纸及其制备方法 | |
CN102924083A (zh) | 一种碳化锆陶瓷粉体的制备方法 | |
CN101698487B (zh) | 一种莫来石粉体的制备方法 | |
CN104725049A (zh) | 一种氮化铝/氮化硼复合陶瓷粉末的制备方法 | |
CN101700980B (zh) | 溶胶凝胶-水热法制备纳米莫来石粉体的方法 | |
CN106431419A (zh) | 一种大功率微电子器件用高导热氮化铝陶瓷基板的制备方法 | |
CN114835473B (zh) | 一种氧化铝陶瓷及其制备方法 | |
CN114621014B (zh) | 一种高强度高热导氮化硅陶瓷材料及其制备方法 | |
CN103011806B (zh) | 一种铁电-介电复相陶瓷材料的原位制备方法 | |
CN102557115B (zh) | 锡掺杂氧化铟球形纳米粉体的制备方法 | |
CN110015900A (zh) | 具有低温烧结性能的复合纳米氮化铝粉体及其制备方法 | |
CN102659131A (zh) | 一种硼化铪HfB2抗烧蚀粉体的制备方法 | |
CN102618263B (zh) | 一种硅酸盐发光材料的制备方法 | |
CN103540316B (zh) | 一种高纯、高亮度AlN:Eu2+蓝色荧光粉的制备方法 | |
CN103274375B (zh) | 一种氮化铝粉体的制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20120620 Assignee: ZHEJIANG SHENGHUI LIGHTING Co.,Ltd. Assignor: China Jiliang University Contract record no.: 2016330000036 Denomination of invention: Method for synthesizing ultrafine aluminum nitride powder at low temperature under assistance of calcium Granted publication date: 20130410 License type: Common License Record date: 20160317 |
|
LICC | Enforcement, change and cancellation of record of contracts on the licence for exploitation of a patent or utility model | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130410 |