CN102438972B - 通过在含铜非均相催化剂上氢化甘油三脂肪酸酯而制备脂肪醇的方法 - Google Patents
通过在含铜非均相催化剂上氢化甘油三脂肪酸酯而制备脂肪醇的方法 Download PDFInfo
- Publication number
- CN102438972B CN102438972B CN201080021975.2A CN201080021975A CN102438972B CN 102438972 B CN102438972 B CN 102438972B CN 201080021975 A CN201080021975 A CN 201080021975A CN 102438972 B CN102438972 B CN 102438972B
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- China
- Prior art keywords
- hydrogenation
- reactor
- carry out
- stream
- integer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxo-reaction combined with reduction
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
- C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
- C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
- C07C17/156—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of unsaturated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
- C07C29/177—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with simultaneous reduction of a carboxy group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
- C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
- C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Fats And Perfumes (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP09160709.3 | 2009-05-20 | ||
| EP09160709 | 2009-05-20 | ||
| PCT/EP2010/056859 WO2010133619A1 (de) | 2009-05-20 | 2010-05-19 | Verfahren zur herstellung von fettalkoholen durch hydrierung von fettsäuretriglyceriden an einem kupferhaltigen heterogenen katalysator |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102438972A CN102438972A (zh) | 2012-05-02 |
| CN102438972B true CN102438972B (zh) | 2015-09-09 |
Family
ID=42313277
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201080021975.2A Expired - Fee Related CN102438972B (zh) | 2009-05-20 | 2010-05-19 | 通过在含铜非均相催化剂上氢化甘油三脂肪酸酯而制备脂肪醇的方法 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US8946490B2 (enExample) |
| EP (1) | EP2432756B1 (enExample) |
| JP (1) | JP5771192B2 (enExample) |
| KR (1) | KR101742749B1 (enExample) |
| CN (1) | CN102438972B (enExample) |
| BR (1) | BRPI1012167B1 (enExample) |
| ES (1) | ES2619559T3 (enExample) |
| MY (1) | MY156726A (enExample) |
| WO (1) | WO2010133619A1 (enExample) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20130068457A1 (en) * | 2011-09-15 | 2013-03-21 | Chevron U.S.A. Inc. | Method of Manufacture of Guerbet Alcohols For Making Surfactants Used In Petroleum Industry Operations |
| US9422469B2 (en) * | 2013-03-15 | 2016-08-23 | Chevron U.S.A. Inc. | Mixed carbon length synthesis of primary guerbet alcohols |
| US9605198B2 (en) | 2011-09-15 | 2017-03-28 | Chevron U.S.A. Inc. | Mixed carbon length synthesis of primary Guerbet alcohols |
| MX2015011738A (es) | 2013-03-07 | 2015-12-01 | Reg Life Sciences Llc | Procesamiento aguas abajo de composiciones de alcohol graso producidas por celulas huesped recombinantes. |
| WO2015115410A1 (ja) * | 2014-01-28 | 2015-08-06 | 株式会社日本触媒 | 水素化反応方法 |
| US20160280987A2 (en) * | 2014-08-25 | 2016-09-29 | Prochem International BV | Non-toxic and biodegradable surfactants |
| US20180222831A1 (en) * | 2015-08-05 | 2018-08-09 | White Dog Labs, Inc. | Method for the production of at least one derivate of a carboxylic acid |
| CN105061140A (zh) * | 2015-08-11 | 2015-11-18 | 华东师范大学 | 无氢条件下脂肪酸或脂肪酸酯制备脂肪醇的方法以及应用于该方法的催化剂 |
| MX2019005618A (es) * | 2016-11-16 | 2019-08-12 | Archer Daniels Midland Co | Procedimiento para producir 1,2-propanodiol a partir de glicerol. |
| US10072231B2 (en) * | 2016-12-02 | 2018-09-11 | Ag Chem, Llc | Process for the conversion of free fatty acids to glycerol esters and production of novel catalyst systems |
| DE102019131569A1 (de) * | 2019-11-22 | 2021-05-27 | Clariant International Ltd | Chromfreier wasser- und saeurestabiler katalysator fuer hydrierungen |
| EP4549622A1 (en) | 2023-10-31 | 2025-05-07 | Basf Se | Hydrogenation of carbonyl compounds using hydrogen with low deuterium content |
| CN119857488A (zh) * | 2025-01-23 | 2025-04-22 | 浙江工业大学 | 一种大孔径氧化铝负载的铜基催化剂及其制备和应用 |
Family Cites Families (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1154448B (de) | 1961-07-18 | 1963-09-19 | Hydrierwerk Rodleben Veb | Verfahren zur Herstellung hoehermolekularer ein- und mehrwertiger Alkohole |
| DE2909671A1 (de) | 1979-03-12 | 1980-10-02 | Basf Ag | Verfahren zur herstellung von schalenkatalysatoren |
| NL8101637A (nl) | 1981-04-02 | 1982-11-01 | Unilever Nv | Werkwijze voor het selectief hydrogeneren van vetzuurderivaten. |
| US4626604A (en) | 1985-09-11 | 1986-12-02 | Davy Mckee (London) Limited | Hydrogenation process |
| EP0254189B1 (de) | 1986-07-23 | 1992-03-04 | Henkel Kommanditgesellschaft auf Aktien | Verfahren zur Direkthydrierung von Glyceridölen |
| DE3708430A1 (de) | 1987-03-16 | 1988-09-29 | Henkel Kgaa | Verfahren zur direkthydrierung von butterfett |
| DE3809270A1 (de) | 1988-03-19 | 1989-09-28 | Henkel Kgaa | Verfahren zur katalytischen hydrierung von fluessigen fettsaeure-triglyceriden zur gleichzeitigen gewinnung von fettalkoholen und c(pfeil abwaerts)3(pfeil abwaerts)-diolen |
| US5120885A (en) * | 1990-09-21 | 1992-06-09 | Kao Corporation | Process for producing alcohol |
| JPH0699337B2 (ja) * | 1990-12-27 | 1994-12-07 | 花王株式会社 | アルコールの製造方法 |
| MY107920A (en) * | 1990-12-27 | 1996-06-29 | Kao Corp | Process for producing alcohol |
| DE4129622A1 (de) | 1991-09-06 | 1993-03-11 | Henkel Kgaa | Verfahren zur herstellung von ungesaettigten fettalkoholen |
| JPH0734867B2 (ja) * | 1991-10-09 | 1995-04-19 | 花王株式会社 | 水素化用触媒及びその製造方法 |
| DE4242466C2 (de) | 1992-12-16 | 2003-07-03 | Cognis Deutschland Gmbh | Verfahren zur Herstellung von Fettalkoholen |
| US5475160A (en) * | 1994-11-07 | 1995-12-12 | Shell Oil Company | Process for the direct hydrogenation of triglycerides |
| MY129140A (en) * | 1994-11-07 | 2007-03-30 | Shell Int Research | Process and a catalyst for the direct hydrogenation of carboxylic esters |
| DE4442346A1 (de) | 1994-11-29 | 1996-05-30 | Basf Ag | Verfahren zur Herstellung eines Katalysators, bestehend aus einem Trägerkörper und einer auf der Oberfläche des Trägerkörpers aufgebrachten katalytisch aktiven Oxidmasse |
| DE19843798C2 (de) | 1998-09-24 | 2003-01-09 | Cognis Deutschland Gmbh | Verfahren zur Herstellung von Fettalkoholen |
| US20040133049A1 (en) * | 1998-10-07 | 2004-07-08 | Christian Pelzer | Process for the continous fixed-bed hydrogenation of fatty acids and fatty acid esters |
| DE19960428A1 (de) | 1999-12-15 | 2001-07-05 | Cognis Deutschland Gmbh | Oxidische Zink-Aluminium-Katalysatoren |
| DE10313702A1 (de) | 2003-03-27 | 2004-10-07 | Basf Ag | Katalysator und Verfahren zur Hydrierung von Carbonylverbindungen |
| DE102004033556A1 (de) | 2004-07-09 | 2006-02-16 | Basf Ag | Katalysatorformkörper und Verfahren zur Hydrierung von Carbonylverbindungen |
| PL1993985T3 (pl) * | 2006-03-03 | 2018-03-30 | Basf Se | Sposób wytwarzania 1,2-propanodiolu |
| BRPI0815783A2 (pt) | 2007-08-31 | 2015-02-24 | Basf Se | Processo para a preparação de 1,2-propanodiol. |
| PL2200958T3 (pl) | 2007-08-31 | 2016-04-29 | Basf Se | Sposób wytwarzania 1,2-propanodiolu drogą uwodorniania glicerolu w dwustopniowej kaskadzie reaktorów |
| US8273924B2 (en) | 2007-08-31 | 2012-09-25 | Basf Se | Method for producing 1,2-propandiol by low-pressure hydrogenation of glycerine |
| JP5690716B2 (ja) | 2008-04-22 | 2015-03-25 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | エタノールを予備改質する方法 |
| EP2334625A1 (de) | 2008-09-08 | 2011-06-22 | Basf Se | Verfahren zur integrierten herstellung von zellstoff und niedermolekularer wertstoffe |
| WO2010079035A2 (de) | 2008-12-17 | 2010-07-15 | Basf Se | Kontinuierliches verfahren zur herstellung von substituierten cyclohexylmethanolen |
| WO2010084058A1 (de) | 2009-01-20 | 2010-07-29 | Basf Se | Verfahren zur herstellung von polyurethan-hartschaumstoffen |
| WO2010084118A1 (de) | 2009-01-21 | 2010-07-29 | Basf Se | Verfahren zur herstellung von desodoriertem 1,2-propandiol |
| WO2010121899A1 (de) | 2009-04-20 | 2010-10-28 | Basf Se | Verfahren zur herstellung von reaktivem zink durch elektrochemische reduktion |
-
2010
- 2010-05-19 WO PCT/EP2010/056859 patent/WO2010133619A1/de not_active Ceased
- 2010-05-19 US US13/319,830 patent/US8946490B2/en active Active
- 2010-05-19 EP EP10723029.4A patent/EP2432756B1/de not_active Not-in-force
- 2010-05-19 ES ES10723029.4T patent/ES2619559T3/es active Active
- 2010-05-19 BR BRPI1012167-6A patent/BRPI1012167B1/pt not_active IP Right Cessation
- 2010-05-19 JP JP2012511272A patent/JP5771192B2/ja not_active Expired - Fee Related
- 2010-05-19 MY MYPI2011005538A patent/MY156726A/en unknown
- 2010-05-19 KR KR1020117030548A patent/KR101742749B1/ko not_active Expired - Fee Related
- 2010-05-19 CN CN201080021975.2A patent/CN102438972B/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JP2012527427A (ja) | 2012-11-08 |
| BRPI1012167A2 (pt) | 2017-10-24 |
| KR20120017076A (ko) | 2012-02-27 |
| EP2432756A1 (de) | 2012-03-28 |
| MY156726A (en) | 2016-03-15 |
| WO2010133619A1 (de) | 2010-11-25 |
| ES2619559T3 (es) | 2017-06-26 |
| BRPI1012167B1 (pt) | 2018-06-19 |
| EP2432756B1 (de) | 2016-12-21 |
| CN102438972A (zh) | 2012-05-02 |
| US8946490B2 (en) | 2015-02-03 |
| JP5771192B2 (ja) | 2015-08-26 |
| KR101742749B1 (ko) | 2017-06-01 |
| US20120083631A1 (en) | 2012-04-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150909 |