CN102428919A - Postemergence cassava field herbicide with mesotrion as active component - Google Patents

Postemergence cassava field herbicide with mesotrion as active component Download PDF

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Publication number
CN102428919A
CN102428919A CN2011103440917A CN201110344091A CN102428919A CN 102428919 A CN102428919 A CN 102428919A CN 2011103440917 A CN2011103440917 A CN 2011103440917A CN 201110344091 A CN201110344091 A CN 201110344091A CN 102428919 A CN102428919 A CN 102428919A
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China
Prior art keywords
cassava
mesotrione
weeds
herbicide
mesotrion
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Pending
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CN2011103440917A
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Chinese (zh)
Inventor
李莉
安峰明
李现玲
郭泽旺
刘玉生
莫宇星
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Guangxi Tianyuan Biochemical Co Ltd
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Guangxi Tianyuan Biochemical Co Ltd
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Priority to CN2011103440917A priority Critical patent/CN102428919A/en
Publication of CN102428919A publication Critical patent/CN102428919A/en
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Abstract

The invention provides a postemergence cassava field herbicide with mesotrion as an active component, which comprises the mesotrion as the active component, and after being added with suitable adjuvant and carrier, the postemergence cassava field herbicide can be prepared into various agent forms such as suspension, water-dispersible granules, wettable powder, aerosol, slow-release agent, granules, emulsion in water, microemulsion or effervescent tablets. As selective herbicide for cassava fields, the herbicide cannot cause chemical resistance, has a good control effect on gramineous weeds, latifolious weeds and cyperaceae weeds, can comprehensively prevent and eliminate a variety of weeds in cassava fields, is safe and low in toxicity and residue for cassava, is easy to popularize, decreases labor intensity, and reduces the production cost.

Description

A kind of is the cassava field post-seedling chemical herbicide of active ingredient with the mesotrione
Technical field
The present invention relates to pesticide field, particularly a kind of agricultural chemicals list agent that contains mesotrione is mainly used in the comprehensive management of weeds of cassava Tian Miaohou.
Background technology
Cassava is introduced China in 1820s, has been distributed widely in the South China at present.In this area, cassava has become the fifth-largest crop that is only second to paddy rice, sweet potato, sugarcane and corn, is one of important source of finance of peasant household, and under the promotion of Ministry of Agriculture's encouragement policy, and its cultivated area is also in year by year increase.On the main application of China cassava is feeding and industry, develop, piece root starch is that one of main system starch material is gone up in industry; On fermentation industry, but tapioca or dry plate preparing alcohol, citric acid, glutamic acid, lysine, protein cassava matter, glucose, fructose etc., and these products all have important use at aspects such as food, beverage, medicine, weaving (dying cloth), papermaking; The micromicro of piece root utilizes with as fertilizer sources and animal feed once more; Discarded fiber can be used as flocculant and is used for mining industry after drying, the low concentration starch that in precipitation process, runs off then can be used as pig feed; Simultaneously, under our times food and energy crisis, cassava is used for producing alcohol and has the simple and low advantage of cost of technology as a kind of new biomass energy, has become a kind of desirable substitute products, and development cassava industry is all paid much attention in the whole world.Because domestic some areas vehicle has been brought into use ethanol petrol, impels the alcohol consumption market conditions to be expected to rise, and has stimulated the great amount of investment of Alcohol Production industry.On June 7th, 2007; State Council holds the renewable energy resources meeting, and industrial policy is adjusted, and prohibites with corn and makees raw material production alcohol; The industry cassava that begins to be widely used does and makes non-grain ethanol as primary raw material, has spurred the great demand to cassava thus more.Only Guangxi cassava area has just reached more than 450 ten thousand mu now, and number is surprising, yet influences the archenemy of cassava production and quality---and the cassava field weed is corroding the people's interests day by day.
The cassava owner of farmland will receive grassy weed, broad leaved weed, sedge weed harm seriously at present.Harm in cassava seedling phase weeds is particularly serious, because cassava is slow at seedling phase plant strain growth, seedling is less; It is wide that seeding row spacing shows, and exposed space, ground is big, and this moment, weeds were prone to growth; Growth conditionss such as these weeds and cassava contention illumination, moisture, space; Suppress the growth of cassava, have a strong impact on output and the quality of cassava, yet it is less to be applied to the medicament kind of cassava postemergence weed control at home; Except that minority only to the control grassy weed efficacious agents, domestic also do not have can integrated control cassava field grass family, the selectivity medicament of broad-leaved and sedge weed.The cassava weed killer herbicide of peasant's use is now mainly accomplished through closed soil before the seedling, but because the sealing weed killer herbicide receives Effect of Environmental easily, so sealing effect is unsatisfactory; In the face of unfavorable effect; Peasant household also adopts directed method of spraying paraquat, glyphosate to remedy, but these means to save the situation danger are very big, are easy to cassava is caused serious poisoning; And operating difficulties, waste of manpower, material resources, financial resources.
The activity of weeding of active ingredient mesotrione is to play a role through the activity that suppresses the two oxidase (HPPD) of p-hydroxybenzene pyruvic acid; HPPD can be converted into plastoquinone with amino acid Lip river propylhomoserin; Plastoquinone is the co-factor of phytoene desaturase, and the phytoene biosynthetic key enzyme that is carotenoid.Use 3~5 days implants meristematic tissue of mesotrione the yellow symptom to occur and cause withered spot thereupon, spread all over whole strain plant behind the fortnight.Help the performance of its drug effect when temperature is high, dispenser after 1 hour rainfall its drug effect is not had influence.Mesotrione all has preventive effect preferably to grassy weed, broad leaved weed and sedge weed.This composition has been developed on corn, paddy rice and sugarcane and has been used, but does not also have the relevant information of Application and Development on cassava.
Summary of the invention
The purpose of this invention is to provide a kind of weeding agricultural chemicals list agent that can effectively prevent and kill off cassava Tian Miaohou weeds.
The present invention will be made into the agent of agricultural chemicals list through mesotrione, be controlling object with cassava Tian Miaohou weeds mainly, be used for the weeding of cassava field as selective herbicide.
The active ingredient weed killer herbicide that the present invention relates to is:
Mesotrione mesotrione C 14H 13NO 7S 339.32
Figure BDA0000105307150000021
Weeding agricultural chemicals list of the present invention agent is that mesotrione is formed by active ingredient.The weight percentage of said active ingredient is: 1%~90%.After adding proper assistant and carrier, process various formulations such as water-dispersible granules, suspending agent, wetting powder, granule, aerosol, sustained release agent, aqueous emulsion, microemulsion or effervescent tablet, be used for the weeding of cassava field.
Advantage of the present invention is:
1. whole new set of applications does not have pesticide resistance.
2. can comprehensively prevent and kill off multiple weeds in the cassava field, grassy weed, broad leaved weed and sedge weed are all had preventive effect preferably.2-4 leaf phase weeds are shown excellent preventive effect.
3. safer to cassava, recommending to cassava safety, to strengthen dosage under the consumption use, slight albefaction appears in the cassava leaves sector-meeting, but can recover normal after the week, does not influence the cassava normal growth.
4. efficient, low toxicity, low-residual have reduced the pollution to environment.
5. easy and simple to handle, be prone to promote, eliminated peasant household uses the directed spraying weed killer herbicide behind seedling danger, saving manpower, financial resources, material resources have alleviated labour intensity, reduced production cost.
Embodiment
Following examples are elaborated to the present invention, but are not limited to these embodiment.
Embodiment 1
1% mesotrione granule compound method
Mesotrione 1kg
Methyl alcohol 7kg
Polyvinyl alcohol 5kg
Sand grains complements to 100kg.
Mesotrione is used dissolve with methanol, and the back is with this solution of sand grains absorption, does seed coating medicine with polyvinyl alcohol again and wraps in the outer oven dry of sand grains and promptly obtain product.
Embodiment 2
1% mesotrione wettable powder agent compounding method
Mesotrione 1kg
Naphthalene sulfonic acid formaldehyde condensation polymer 2kg
Lauryl sodium sulfate 5kg
Kaolin complements to 100kg.
Various compositions are mixed, promptly obtain product through 325 eye mesh screens through comminution by gas stream.
Embodiment 3
5% mesotrione microemulsion compound method
Various compositions are mixed, in mixing kettle, be stirred to homogeneous transparent, promptly get product.
Embodiment 4
8% mesotrione aqueous emulsion compound method
Various compositions are mixed, in shearing still, be trimmed to the active ingredient particle diameter, promptly get product less than 3 μ m.
Embodiment 5
15% mesotrione suspending agent agent compounding method
Figure BDA0000105307150000043
Said mixture is evenly mixed, add in the sand mill pulverize, sand milling to active ingredient particle diameter is less than 2 μ m, promptly gets product.
Embodiment 6
20% mesotrione wettable powder agent compounding method
Mesotrione 20kg
Naphthalene sulfonic acid formaldehyde condensation polymer 2kg
Lauryl sodium sulfate 5kg
Kaolin complements to 100kg.
Various compositions are mixed, promptly obtain product through 325 eye mesh screens through comminution by gas stream.
Embodiment 7
25% mesotrione suspending agent compound method
Figure BDA0000105307150000051
Said mixture is evenly mixed, add in the sand mill pulverize, sand milling to active ingredient particle diameter is less than 2 μ m, promptly gets product.
Embodiment 8
30% mesotrione water-dispersible granules compound method
Figure BDA0000105307150000052
Various compositions are mixed, pulverize, mix suitable water spray granulating and drying and get water-dispersible granules.
Embodiment 9
50% mesotrione water-dispersible granules compound method
Various compositions are mixed, pulverize, mix suitable water spray granulating and drying and get water-dispersible granules.
Embodiment 10
70% mesotrione wettable powder agent compounding method
Mesotrione 70kg
Naphthalene sulfonic acid formaldehyde condensation polymer 3kg
Lauryl sodium sulfate 5kg
Kaolin complements to 100kg.
Various compositions are mixed, promptly obtain product through 325 eye mesh screens through comminution by gas stream.
Embodiment 11
90% mesotrione wettable powder agent compounding method
Mesotrione 90kg
Naphthalene sulfonic acid formaldehyde condensation polymer 2kg
Lauryl sodium sulfate 5kg
Kaolin complements to 100kg.
Various compositions are mixed, promptly obtain product through 325 eye mesh screens through comminution by gas stream.
The auxiliary agent that the present invention selected for use, carrier are the commercially available prod, are pesticide producing assistant agents commonly used.
The present invention is to the control efficiency of cassava field weed:
For the control efficiency of clear and definite mesotrione list time spent to the cassava field weed, Wuming County doube bridge town cassava planting site has carried out field control effectiveness test and production benefit analysis to applicant in 2010 in Guangxi.
Field control effectiveness test:
Handle 1:1% mesotrione granule 600g/667m 2
Handle 2:1% mesotrione wetting powder 600g/667m 2
Handle 3:5% mesotrione microemulsion 120ml/667m 2
Handle 4:8% mesotrione aqueous emulsion 75ml/667m 2
Handle 5:15% mesotrione suspending agent 40ml/667m 2
Handle 6:20% mesotrione wetting powder 30g/667m 2
Handle 7:25% mesotrione suspending agent 24ml/667m 2
Handle 8:30% mesotrione water-dispersible granules 20g/667m 2
Handle 9:50% mesotrione water-dispersible granules 12g/667m 2
Handle 10:70% mesotrione wetting powder 8.6g/667m 2
Handle 11:90% mesotrione wetting powder 6.7g/667m 2
Handle 12:200g/L paraquat aqua 150ml/667m 2
Handle 13: blank
Adopt five-point type sampling survey method (9m 2/ sub-district) investigation obtains table 1 data, can be known that by table 1 preparation of mesotrione different dosage form or content is all higher to cassava field weed preventive effect; Safer to cassava, 2~4d after the dispenser, symptom of chemical damage just appears in weeds; Show as meristematic tissue and begin albefaction and engender withered spot, growth is suppressed, and generally just has the part weeds withered at 7 days; About 15 days, show good effect, preventive effect reached the highest in 20 days, and preventive effect is between 89~96%; Though and traditional medicament shows good effect in a short time, short, poor stability of lasting period, so in sum, mesotrione is a kind of new component that is far superior to traditional medicament.
The effect of table 1 different disposal control cassava field weed
Figure BDA0000105307150000081
The production benefit analysis is surveyed the product result by table 2 and is shown; All there is obvious raising the output in each chemicals treatment district than blank district; Using of mesotrione medicament controlled the harm of cassava field weed to cassava preferably, and the cassava raising the output is comparatively obvious; Rate of growth is about 50~61%, and the rate of growth of traditional medicament is merely 26%.
The investigation of table 2 cassava production
Figure BDA0000105307150000082
Figure BDA0000105307150000091
To sum up can draw, the control that mesotrione is used for the cassava field weed is to consider all to be superior to traditional medicament 200g/L paraquat aqua from many-sided factor such as safety, lasting effect, rate of growth.

Claims (3)

1. one kind is the cassava field post-seedling chemical herbicide of active ingredient with the mesotrione, it is characterized in that: be that active ingredient is formed with the mesotrione, be used for the weeding of cassava field.
2. according to claim 1 is the cassava field post-seedling chemical herbicide of active ingredient with the mesotrione, and it is characterized in that: the weight percentage of said active ingredient is: 1%~90%.
3. according to claim 1 is the cassava field post-seedling chemical herbicide of active ingredient with the mesotrione, and it is characterized in that: single agent can be processed into water-dispersible granules, suspending agent, wetting powder, aqueous emulsion, microemulsion or granule.
CN2011103440917A 2011-11-03 2011-11-03 Postemergence cassava field herbicide with mesotrion as active component Pending CN102428919A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016079035A1 (en) 2014-11-18 2016-05-26 Bayer Cropscience Aktiengesellschaft Use of certain herbicide combinations in tuberous root crop plants
WO2016173972A1 (en) 2015-04-27 2016-11-03 Bayer Cropscience Aktiengesellschaft Use of certain herbicide combinations in tuberous root crop plants
WO2016173964A1 (en) 2015-04-27 2016-11-03 Bayer Cropscience Aktiengesellschaft Use of certain herbicide combinations in tuberous root crop plants
WO2017050635A1 (en) 2015-09-22 2017-03-30 Bayer Cropscience Aktiengesellschaft Use of certain active ingredient combinations in tuberous root crop plants

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009027027A2 (en) * 2007-08-27 2009-03-05 Syngenta Participations Ag Herbicidal composition and method of use thereof
CN101647437A (en) * 2009-07-15 2010-02-17 深圳诺普信农化股份有限公司 Methyl sulcotrione oil suspension concentrate combination
CN101971805A (en) * 2010-11-17 2011-02-16 南京扬子鸿利源化学品有限责任公司 Oil-suspension agricultural mesotrione preparation as well as preparation method and applications thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009027027A2 (en) * 2007-08-27 2009-03-05 Syngenta Participations Ag Herbicidal composition and method of use thereof
CN101647437A (en) * 2009-07-15 2010-02-17 深圳诺普信农化股份有限公司 Methyl sulcotrione oil suspension concentrate combination
CN101971805A (en) * 2010-11-17 2011-02-16 南京扬子鸿利源化学品有限责任公司 Oil-suspension agricultural mesotrione preparation as well as preparation method and applications thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016079035A1 (en) 2014-11-18 2016-05-26 Bayer Cropscience Aktiengesellschaft Use of certain herbicide combinations in tuberous root crop plants
WO2016173972A1 (en) 2015-04-27 2016-11-03 Bayer Cropscience Aktiengesellschaft Use of certain herbicide combinations in tuberous root crop plants
WO2016173964A1 (en) 2015-04-27 2016-11-03 Bayer Cropscience Aktiengesellschaft Use of certain herbicide combinations in tuberous root crop plants
WO2017050635A1 (en) 2015-09-22 2017-03-30 Bayer Cropscience Aktiengesellschaft Use of certain active ingredient combinations in tuberous root crop plants

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Application publication date: 20120502