CN102321229B - 改性磺化三聚氰胺-甲醛缩聚物减水剂及其制备方法 - Google Patents
改性磺化三聚氰胺-甲醛缩聚物减水剂及其制备方法 Download PDFInfo
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- CN102321229B CN102321229B CN 201110139923 CN201110139923A CN102321229B CN 102321229 B CN102321229 B CN 102321229B CN 201110139923 CN201110139923 CN 201110139923 CN 201110139923 A CN201110139923 A CN 201110139923A CN 102321229 B CN102321229 B CN 102321229B
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- formaldehyde
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- 239000003638 chemical reducing agent Substances 0.000 title claims abstract description 82
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 69
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical class O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims abstract description 26
- 238000009833 condensation Methods 0.000 title abstract description 5
- 230000005494 condensation Effects 0.000 title abstract description 5
- 229920000642 polymer Polymers 0.000 title abstract description 5
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims abstract description 135
- 238000006243 chemical reaction Methods 0.000 claims abstract description 58
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 35
- 238000006277 sulfonation reaction Methods 0.000 claims abstract description 33
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims abstract description 17
- 238000006482 condensation reaction Methods 0.000 claims abstract description 14
- 239000007859 condensation product Substances 0.000 claims description 39
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 claims description 20
- 150000007974 melamines Chemical class 0.000 claims description 15
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical group [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 12
- KSVSZLXDULFGDQ-UHFFFAOYSA-M sodium;4-aminobenzenesulfonate Chemical compound [Na+].NC1=CC=C(S([O-])(=O)=O)C=C1 KSVSZLXDULFGDQ-UHFFFAOYSA-M 0.000 claims description 12
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 claims description 6
- 235000010262 sodium metabisulphite Nutrition 0.000 claims description 6
- XETSAYZRDCRPJY-UHFFFAOYSA-M sodium;4-aminobenzoate Chemical compound [Na+].NC1=CC=C(C([O-])=O)C=C1 XETSAYZRDCRPJY-UHFFFAOYSA-M 0.000 claims description 5
- 235000010265 sodium sulphite Nutrition 0.000 claims description 4
- 230000001143 conditioned effect Effects 0.000 claims description 2
- 238000003860 storage Methods 0.000 abstract description 11
- 229920000877 Melamine resin Polymers 0.000 abstract description 6
- 239000003607 modifier Substances 0.000 abstract description 5
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 abstract description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 abstract 2
- 238000006011 modification reaction Methods 0.000 abstract 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 60
- 239000000243 solution Substances 0.000 description 28
- 230000033228 biological regulation Effects 0.000 description 16
- 239000004568 cement Substances 0.000 description 16
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 14
- 238000000034 method Methods 0.000 description 14
- 239000008098 formaldehyde solution Substances 0.000 description 13
- WPJGWJITSIEFRP-UHFFFAOYSA-N 1,3,5-triazine-2,4,6-triamine;hydrate Chemical compound O.NC1=NC(N)=NC(N)=N1 WPJGWJITSIEFRP-UHFFFAOYSA-N 0.000 description 12
- 238000010792 warming Methods 0.000 description 10
- 230000000694 effects Effects 0.000 description 8
- 239000007788 liquid Substances 0.000 description 7
- 238000010907 mechanical stirring Methods 0.000 description 7
- 239000002002 slurry Substances 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- DGVVJWXRCWCCOD-UHFFFAOYSA-N naphthalene;hydrate Chemical compound O.C1=CC=CC2=CC=CC=C21 DGVVJWXRCWCCOD-UHFFFAOYSA-N 0.000 description 6
- -1 high-sulfonated melamine compound Chemical class 0.000 description 5
- 238000006068 polycondensation reaction Methods 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
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- OVARTBFNCCXQKS-UHFFFAOYSA-N propan-2-one;hydrate Chemical class O.CC(C)=O OVARTBFNCCXQKS-UHFFFAOYSA-N 0.000 description 4
- 239000005357 flat glass Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- CUBCNYWQJHBXIY-UHFFFAOYSA-N benzoic acid;2-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=CC=C1.OC(=O)C1=CC=CC=C1O CUBCNYWQJHBXIY-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- YIBPLYRWHCQZEB-UHFFFAOYSA-N formaldehyde;propan-2-one Chemical class O=C.CC(C)=O YIBPLYRWHCQZEB-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000008707 rearrangement Effects 0.000 description 1
- 238000006462 rearrangement reaction Methods 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- 239000008030 superplasticizer Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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- Phenolic Resins Or Amino Resins (AREA)
Abstract
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CN 201110139923 CN102321229B (zh) | 2011-05-27 | 2011-05-27 | 改性磺化三聚氰胺-甲醛缩聚物减水剂及其制备方法 |
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CN 201110139923 CN102321229B (zh) | 2011-05-27 | 2011-05-27 | 改性磺化三聚氰胺-甲醛缩聚物减水剂及其制备方法 |
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CN102321229A CN102321229A (zh) | 2012-01-18 |
CN102321229B true CN102321229B (zh) | 2012-11-21 |
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CN104788038B (zh) * | 2015-04-02 | 2017-01-11 | 苏州市兴邦化学建材有限公司 | 一种改性三聚氰胺减水剂及其制备方法 |
CN105731857A (zh) * | 2016-02-20 | 2016-07-06 | 深圳爱易瑞科技有限公司 | 一种新型磺化三聚氰胺甲醛树脂及其制备方法 |
CN113105153B (zh) * | 2021-04-08 | 2022-08-12 | 金陵科技学院 | 一种含有硅基、氨基的抗泥保坍型高效减水剂的合成方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1095385A (zh) * | 1994-01-26 | 1994-11-23 | 华南理工大学 | 高磺化三聚氰胺甲醛树脂的制备方法 |
US6555683B1 (en) * | 1995-03-31 | 2003-04-29 | Skw Polymers Gmbh | Condensation products based on amino-s-triazines and the use thereof |
CN101845132A (zh) * | 2010-05-06 | 2010-09-29 | 山东宏艺科技股份有限公司 | 一种低成本改性三聚氰胺高效减水剂 |
-
2011
- 2011-05-27 CN CN 201110139923 patent/CN102321229B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1095385A (zh) * | 1994-01-26 | 1994-11-23 | 华南理工大学 | 高磺化三聚氰胺甲醛树脂的制备方法 |
US6555683B1 (en) * | 1995-03-31 | 2003-04-29 | Skw Polymers Gmbh | Condensation products based on amino-s-triazines and the use thereof |
CN101845132A (zh) * | 2010-05-06 | 2010-09-29 | 山东宏艺科技股份有限公司 | 一种低成本改性三聚氰胺高效减水剂 |
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Owner name: JIANGSU SUBOTE NEW MATERIAL CO., LTD. Free format text: FORMER OWNER: BOTE NEW MATERIAL CO., LTD., JIANGSU Effective date: 20140523 |
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Effective date of registration: 20140523 Address after: 211103, No. 59 West Wan An Road, Jiangning District, Jiangsu, Nanjing Patentee after: Jiangsu Subute New Materials Co., Ltd. Patentee after: Panzhihua Bote Building Materials Co., Ltd. Patentee after: Bote Building Materials (Tianjin) Co., Ltd. Address before: 211103, No. 59 West Wan An Road, Jiangning District, Jiangsu, Nanjing Patentee before: Jiangsu Bote New Materials Co., Ltd. Patentee before: Jiangsu Subute New Materials Co., Ltd. Patentee before: Jiangsu Provincial Architectural Science Institute Ltd. Patentee before: Panzhihua Bote Building Materials Co., Ltd. Patentee before: Bote Building Materials (Tianjin) Co., Ltd. |
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CP02 | Change in the address of a patent holder | ||
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Address after: No.6 shuiyougang, Gulou District, Nanjing City, Jiangsu Province 210013 Patentee after: JIANGSU SUBOTE NEW MATERIALS Co.,Ltd. Patentee after: PANZHIHUA BOTE BUILDING MATERIAL Co.,Ltd. Patentee after: BOTE BUILDING MATERIALS (TIANJIN) Co.,Ltd. Address before: 211103, No. 59 West Wan An Road, Jiangning District, Jiangsu, Nanjing Patentee before: JIANGSU SUBOTE NEW MATERIALS Co.,Ltd. Patentee before: PANZHIHUA BOTE BUILDING MATERIAL Co.,Ltd. Patentee before: BOTE BUILDING MATERIALS (TIANJIN) Co.,Ltd. |