CN102317345B - 由二噻吩基亚乙烯基共聚物制备的半导体材料 - Google Patents

由二噻吩基亚乙烯基共聚物制备的半导体材料 Download PDF

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CN102317345B
CN102317345B CN2009801567882A CN200980156788A CN102317345B CN 102317345 B CN102317345 B CN 102317345B CN 2009801567882 A CN2009801567882 A CN 2009801567882A CN 200980156788 A CN200980156788 A CN 200980156788A CN 102317345 B CN102317345 B CN 102317345B
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ppm
polymer
mmol
polymers
methanol
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CN102317345A (zh
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A·K·米什拉
S·瓦伊迪耶纳森
H·诺古基
F·德兹
S·克勒
M·卡斯特勒
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Feilisi Co Ltd
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POLYERA CORP
BASF SE
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  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Thin Film Transistor (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Electroluminescent Light Sources (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
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CN2009801567882A 2008-12-18 2009-12-16 由二噻吩基亚乙烯基共聚物制备的半导体材料 Expired - Fee Related CN102317345B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP08172061.7 2008-12-18
EP08172061 2008-12-18
EP09169242.6 2009-09-02
EP09169242 2009-09-02
PCT/EP2009/067330 WO2010079064A2 (en) 2008-12-18 2009-12-16 Semiconductor materials prepared from dithienylvinylene copolymers

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CN102317345A CN102317345A (zh) 2012-01-11
CN102317345B true CN102317345B (zh) 2013-07-10

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US (2) US9221944B2 (enExample)
EP (2) EP2379617B1 (enExample)
JP (1) JP5502103B2 (enExample)
KR (1) KR101719379B1 (enExample)
CN (1) CN102317345B (enExample)
TW (1) TWI495656B (enExample)
WO (1) WO2010079064A2 (enExample)

Families Citing this family (20)

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Publication number Priority date Publication date Assignee Title
US8927971B2 (en) 2009-04-06 2015-01-06 University Of Kentucky Research Foundation Semiconducting compounds and devices incorporating same
JP5685778B2 (ja) * 2009-09-04 2015-03-18 ソルベイ ユーエスエイ インコーポレイテッド 光電池およびジケトンベースのポリマーを含む、有機電子素子およびポリマー
EP2507287A4 (en) * 2009-11-30 2014-04-30 Univ Laval NEW PHOTOACTIVE POLYMERS
DE102010030500A1 (de) 2010-06-24 2011-12-29 Heliatek Gmbh Verdampfbares organisch halbleitendes Material und dessen Verwendung in einem optoelektronischen Bauelement
US20130144065A1 (en) * 2010-08-05 2013-06-06 Polyera Corporation Semiconductor materials prepared from bridged bithiazole copolymers
EP2617754A4 (en) * 2010-09-13 2014-10-22 Oceans King Lighting Science FLUORIN-SUSTAINABLE ORGANIC SEMICONDUCTOR MATERIAL, METHOD OF MANUFACTURE AND USE THEREOF
WO2012102066A1 (ja) * 2011-01-25 2012-08-02 コニカミノルタホールディングス株式会社 有機光電変換層材料組成物、有機光電変換素子、有機光電変換素子の製造方法及び太陽電池
JP2012207104A (ja) * 2011-03-29 2012-10-25 Mitsubishi Chemicals Corp ヨウ素化縮合チオフェン化合物を用いたコポリマーの製造方法、及びヨウ素化ジオキソピロロチオフェン化合物
KR101401424B1 (ko) * 2012-11-29 2014-06-02 서울대학교산학협력단 유기물 반도체 물질, 이를 이용한 트랜지스터 소자 및 트랜지스터 소자의 제조방법
KR101408160B1 (ko) * 2014-03-17 2014-06-19 서울대학교산학협력단 유기물 반도체 물질, 이를 이용한 트랜지스터 소자 및 트랜지스터 소자의 제조방법
CN104927030B (zh) * 2015-06-09 2017-09-26 中国科学院化学研究所 吲哚‑2‑酮类聚合物及其制备方法与应用
JP6665536B2 (ja) * 2016-01-12 2020-03-13 株式会社リコー 酸化物半導体
CN108780844B (zh) * 2016-03-16 2022-04-29 富士胶片株式会社 有机半导体组合物、有机薄膜晶体管的制造方法及有机薄膜晶体管
KR102113219B1 (ko) * 2017-10-25 2020-05-21 광주과학기술원 단일벽탄소나노튜브의 선택적 분리를 위한 공액 고분자
WO2020046669A1 (en) * 2018-08-29 2020-03-05 Corning Incorporated Semiconducting co-polymers of methylenedihydropyrazines with fused thiophenes
CN110606858B (zh) * 2019-10-09 2022-07-26 上海博栋化学科技有限公司 一种噻吩类有机半导体材料中间体的制备方法
CN112940228B (zh) * 2021-01-14 2023-11-28 中国科学院长春应用化学研究所 含拉电子取代基的聚噻吩类共轭聚合物及制备方法与应用
CN115651169B (zh) * 2022-09-30 2024-11-26 广州大学 一种多组分有机半导体材料及其制备方法与应用
CN118621448B (zh) * 2024-08-12 2025-02-07 浙江大学 一种大面积单层单晶畴有机半导体单晶的制备方法
CN119899382B (zh) * 2025-01-20 2025-11-21 烟台大学 一种二芳基乙烯聚合物及制备方法和应用

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009098253A1 (en) * 2008-02-05 2009-08-13 Basf Se Naphthalene-imide semiconductor polymers

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994004592A1 (en) * 1992-08-24 1994-03-03 Research Corporation Technologies, Inc. Photoconductive polymers
US5597890A (en) * 1993-11-01 1997-01-28 Research Corporation Technologies, Inc. Conjugated polymer exciplexes and applications thereof
JP3132630B2 (ja) * 1994-08-25 2001-02-05 科学技術振興事業団 チオフェン誘導体の重合体とその製造法
CN2432837Y (zh) 2000-08-15 2001-06-06 盈太企业有限公司 带抽屉式置物篮定位结构的组合式置物架
US6855950B2 (en) * 2002-03-19 2005-02-15 The Ohio State University Method for conductance switching in molecular electronic junctions
US7105237B2 (en) * 2003-10-01 2006-09-12 The University Of Connecticut Substituted thieno[3,4-B]thiophene polymers, method of making, and use thereof
KR101209378B1 (ko) * 2004-05-18 2012-12-06 메르크 파텐트 게엠베하 모노-, 올리고- 및 폴리티에노［3,2-ｂ］티오펜
KR101190933B1 (ko) 2004-07-30 2012-10-12 스미또모 가가꾸 가부시키가이샤 고분자 화합물, 고분자 박막 및 이것을 사용한 고분자 박막소자
JP2006063334A (ja) * 2004-07-30 2006-03-09 Sumitomo Chemical Co Ltd 高分子化合物、高分子薄膜およびそれを用いた高分子薄膜素子
EP1839339A2 (en) 2004-12-23 2007-10-03 Northwestern University Siloxane-polymer dielectric compositions and related organic field-effect transistors
US20080003422A1 (en) * 2005-07-27 2008-01-03 Sumitomo Chemical Company, Limited Polymer Compound, Polymer Thin Film and Polymer Thin Film Device Using the Same
US7678463B2 (en) 2005-12-20 2010-03-16 Northwestern University Intercalated superlattice compositions and related methods for modulating dielectric property
WO2009144205A1 (en) 2008-05-30 2009-12-03 Basf Se Rylene-based semiconductor materials and methods of preparation and use thereof
CA2729714A1 (en) 2008-07-02 2010-01-07 Max-Planck-Gesellschaft Zur Foerderung Der Wissenschaften E.V. High performance solution processable semiconducting polymers based on alternating donor acceptor copolymers
TWI471328B (zh) 2008-07-02 2015-02-01 巴地斯顏料化工廠 以二噻吩并〔２，３－ｄ：２’，３’－ｄ’〕苯并〔１，２－ｂ：４，５－ｂ’〕二噻吩為主之高效能溶液可加工之半導體
JP5735418B2 (ja) 2008-07-02 2015-06-17 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ ポリ（５，５’−ビス（チオフェン−２−イル）−ベンゾ［２，１−ｂ；３，４−ｂ’］ジチオフェン）、及び半導体ポリマーを加工可能な高機能溶液としてのその使用方法
JP2011530635A (ja) 2008-08-11 2011-12-22 ビーエーエスエフ ソシエタス・ヨーロピア ポリベンゾチオフェンポリマー及びその製造方法

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009098253A1 (en) * 2008-02-05 2009-08-13 Basf Se Naphthalene-imide semiconductor polymers

Non-Patent Citations (7)

* Cited by examiner, † Cited by third party
Title
Chen-Jen Yang,etc..Electronic energy transfer in new polymer nanocomposite assemblies.《Supramolecular Science》.1994,第1卷第91-101页. *
Dae Sung Chung,etc..High Performance Amorphous Polymeric Thin-Film Transistors Based on Poly[(1,2-bis-(2′-thienyl)vinyl-5′,5′′-diyl)-alt-(9,9-dioctylfluorene-2,7-diyl] Semiconductors.《Chem. Mater.》.2008,第20卷第3450-3456页. *
Fluorene-Based Copolymers for Red-Light-Emitting Diodes;Serge Beaupr,etc.;《Adv. Funct. Mater.》;20021231;第12卷;第192-196页 *
Jonghee Lee,etc..Emission color tuning of new fluorene-based alternating copolymers containing low band gap dyes.《Synthetic Metals》.2005,第155卷第73-79页. *
Spectral and Photophysical Studies of Poly[2,6-(1,5-dioctylnaphthalene)]thiophenes;J. Pina,etc.;《J. Phys. Chem. C》;20071231;第111卷;第7185-7191页 *
Synthesis and Characterization of New Copolymers of Thiophene and Vinylene: Poly(thienylenevinylene)s and Poly(terthienylenevinylene)s with Thioether Side Chains;FRANCESCA GOLDONI,etc.;《Journal of Polymer Science: Part A: Polymer Chemistry》;19991231;第37卷;第4629-4639页 *
Youjun He,etc..Poly(thienylene-benzothiadiazole-thienylene-vinylene): A narrow bandgap polymer with broad absorption from visible to infrared region.《Polymer》.2009,第50卷第5055-5058页. *

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