CN102267840A - Chitosan-fulvic acid compound fertilizer and preparation method thereof - Google Patents
Chitosan-fulvic acid compound fertilizer and preparation method thereof Download PDFInfo
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Abstract
The invention discloses a chitosan-fulvic acid compound fertilizer and a preparation method thereof. The compound fertilizer comprises chitosan, fulvic acid, nitric phosphate, urea, urea formaldehyde, diammonium phosphate, potassium sulphate, medium and trace elements and rare earth elements. In the preparation method, the medium and trace elements are chelated by taking chitosan and fulvic acid as chelating agents, and a chelated liquid is taken as a bonding agent for producing and granulating simultaneously. The invention has the advantages that: the chitosan-fulvic acid compound fertilizer is only applied once without additional application in the entire growing period of crops, so that the cost can be lowered, the labor productivity is lowered, the problems of slow fertilizing at an early stage and insufficient fertilizing at a later stage existing in an ordinary fertilizer are solved, mutual help is given in an emergency, and the utilization ratio of the fertilizer is increased; the medium and trace elements are chelated by using the chitosan and the fulvic acid respectively, so that the chelating efficiency of the medium and trace elements is increased, and the absorption and utilization ratio of crops on the medium and trace elements is increased; and the chelated liquid is taken as a granulating bonding agent, so that the granulating rate is high, the production efficiency is high, other bonding agents do not need to be added, and the cost is saved.
Description
Technical field
The present invention relates to a kind of composite fertilizer, specifically a kind of chitin xanthohumic acid composite fertilizer and preparation method belong to the agriculture production fertilizer field.
Background technology
At present, ordinary compound fertilizer or early stage are for fertile fast, or the later stage is for fertile not enough, and nutritive element is not comprehensive, and is very difficult consistent with plant growth cycle nutrient demand, repeatedly uses, make easily that farm crop excessive growth, lodging, disease resistance are poor, poor quality, yield poorly, and cause soil compaction, nutrient loss, contaminate environment, after using ordinary compound fertilizer, crop blade face pore openness is big, and root system is undeveloped, and the drought resisting anti-adversity ability is poor.
Summary of the invention
In order to address the above problem, the invention provides a kind of chitin xanthohumic acid composite fertilizer and preparation method, described compound fertilizer can be supplied the nutritive element of farm crop whole growing, uses and once can satisfy the demand of crop whole growing to nutritive element, reduce nutrient loss, prevent crop excessive growth, lodging, and can improve soil physical and chemical property, increase rhizospheric microorganism, stimulate root growth, improve the crop disease-resistant drought-resistant ability, increase output and improve quality.
Technical scheme of the present invention is:
A kind of chitin xanthohumic acid composite fertilizer, the composition of described composite fertilizer comprises:
Chitin, xanthohumic acid, nitric acid phosphorus, urea, urea formaldehyde, diammonium phosphate, vitriolate of tartar, middle trace element and rare earth element;
Described chitin is for example to extract the organisms such as shell of shrimp, crab, insect from joint animal to be prepared from, and is a kind of water miscible biological polyoses; Chitin is a kind of water miscible biological polyoses, contains in its molecular structure-NH
2(amino) produces sequestering action with middle trace element, the validity of trace element in can increasing, and chitin is the good substratum of soil microorganisms simultaneously, can promote that soil microorganisms grows, and stimulates root system development, strengthens the crop drought resistance lodging tolerance;
Described xanthohumic acid is to be raw material with plant slag body, through biological fermentation, and a kind of multivalence phenol type aromatics produced and the polycondensate of nitrogen compound; The solvability of xanthohumic acid is good, and micro-ability is strong in the chelating, can improve the soil simultaneously, increases soil fertility, and improves the crop drought resistance resistance against diseases;
Trace element is nitrocalcite, sal epsom, zinc sulfate, ferrous sulfate, manganous sulfate, copper sulfate, boric acid and ammonium molybdate in described; Trace elements are the necessary nutritive elements of plant growth in various, lack to cause easily that crop disease-resistant is poor, dysplasia, yield poorly even have no harvest poor quality;
Described rare earth element comprises one or more in rare earth nitrate, rare earth chloride, sulfuric acid rare earth, the acetic acid rare earth, and described rare earth comprises one or more in lanthanum, cerium, praseodymium, the neodymium; Rare earth has the crop of adjusting bulk-growth, strengthens drought resisting, cold-resistant, disease resistance, the effect of improvement quality of agricultural product and increase output.
Each composition is according to the following weight parts proportioning in the described composite fertilizer:
Chitin 3~8kg, xanthohumic acid 3~8 kg, nitric acid phosphorus 10~30kg, urea 10~30 kg, urea formaldehyde 10~30 kg, diammonium phosphate 15~30 kg, vitriolate of tartar 10~40kg, nitrocalcite 0~2 kg, sal epsom 0~2 kg, zinc sulfate 0~1 kg, ferrous sulfate 0~1 kg, manganous sulfate 0~1 kg, copper sulfate 0~1 kg, boric acid 0~1 kg, ammonium molybdate 0~0.5 kg, rare earth element 0.1~0.5 kg.
Preferably, each composition is according to the following weight parts proportioning in the described composite fertilizer: chitin 4~7kg, xanthohumic acid 4~7 kg, nitric acid phosphorus 12~28kg, urea 12~28 kg, urea formaldehyde 12~28 kg, diammonium phosphate 17~28kg, vitriolate of tartar 12~38 kg, nitrocalcite 0.5~1.5kg, sal epsom 0.5~1.5kg, zinc sulfate 0.2~0.8kg, ferrous sulfate 0.2~0.8 kg, manganous sulfate 0.2~0.8kg, copper sulfate 0.2~0.8kg, boric acid 0.2~0.8kg, ammonium molybdate 0.1~0.4 kg, rare earth element 0.2~0. 4kg.
Preferably, each composition is according to the following weight parts proportioning in the described composite fertilizer: chitin 4kg, xanthohumic acid 4 kg, nitric acid phosphorus 15kg, urea 20kg, urea formaldehyde 15 kg, diammonium phosphate 25kg, vitriolate of tartar 20 kg, nitrocalcite 0.6kg, sal epsom 0.6kg, zinc sulfate 0.5 kg, ferrous sulfate 0.2 kg, manganous sulfate 0.2 kg, copper sulfate 0.3 kg, boric acid 0.4kg, ammonium molybdate 0.1kg, rare earth element 0.3kg.
Contain quadriform nitrogen in the composite fertilizer of the present invention: nitric nitrogen, ammonium nitrogen, acyl ammonium nitrogen and urea formaldehyde nitrogen-be slow-release nitrogen.Nitric nitrogen derives from nitric acid phosphorus, and ammonium nitrogen derives from nitric acid phosphorus and diammonium phosphate, and the acyl ammonium nitrogen derives from urea, and the urea formaldehyde nitrogen source is in urea formaldehyde.Nitric nitrogen is electronegative, is difficult for being adsorbed by soil colloid, easily runs off, but instant effect, can satisfy the demand to nitrogen in crop early stage rapidly; Ammonium nitrogen is positively charged can be adsorbed by soil colloid; Amidonitrogen-be could be absorbed by crop after needing urase to resolve into ammonium nitrogen after urea is manured into soil, and ammonium nitrogen and amidonitrogen satisfy the demand to nitrogen in crop mid-term; Change ammonium nitrogen into after urea formaldehyde nitrogen is manured into soil under the soil microorganisms effect and absorbed by crop, nitrogen can be controlled in 2~December time of releasing, can satisfy the demand of crop later stage to nitrogen; The reasonably combined demand that can satisfy the Different Crop whole growing of the nitrogen of four kinds of forms to nitrogen nutrient.
A kind of method for preparing above-mentioned chitin xanthohumic acid composite fertilizer may further comprise the steps:
(1) in reactor, adds entry, be warming up to 60~70 ℃, add chitin and xanthohumic acid, stirring and dissolving;
(2) add nitrocalcite again after the dissolving, stirring and dissolving and constant temperature 15-20 minute complete to chelatropic reaction;
(3) with the solution of chelating in the above-mentioned steps (2) after fully, add load weighted sal epsom, zinc sulfate, ferrous sulfate, manganous sulfate, copper sulfate, boric acid, ammonium molybdate, rare earth element successively, be stirred to whole dissolvings;
Described rare earth element comprises one or more in rare earth nitrate, rare earth chloride, sulfuric acid rare earth, the acetic acid rare earth, and described rare earth comprises one or more in lanthanum, cerium, praseodymium, the neodymium;
(4) with the solution after all dissolving in the above-mentioned steps (3), be warming up to 80~90 ℃, constant temperature 20~30 minutes, complete to chelatropic reaction, making mass concentration is 70~80% thick chelating liquid;
(5) chelating liquid is sprayed in the compound of load weighted nitric acid phosphorus, urea, urea formaldehyde, diammonium phosphate and vitriolate of tartar as binding agent, carry out granulation, after drying, cooling, the screening, obtain product.
The invention has the advantages that: compare with existing composite fertilizer, composite fertilizer of the present invention is only used once in the crop whole growing, exempts to topdress, can reduce cost, the productivity that lightens one's labor has solved common fertilizer and has supplied fertile unhappyly in earlier stage, and the later stage is for fertile insufficient problem, emergency is helped mutually, improved utilization rate of fertilizer, strengthened disease-resistant crops, drought resisting, resistance such as cold-resistant, improved the soil, improve crop yield, improve crop quality; Centering is trace element chelated respectively to use chitin and xanthohumic acid, in trace element chelated rate improve, thereby improved crop to its absorption rate; Utilize chelating liquid as adhesive for granulating, the granulating rate height, the production efficiency height need not add other binding agent, saves cost.
Embodiment
Below the preferred embodiments of the present invention are described, should be appreciated that preferred embodiment described herein only is used for description and interpretation the present invention, and be not used in qualification the present invention.
Embodiment 1
A kind of chitin xanthohumic acid composite fertilizer, the weight part proportioning of each composition is: chitin 4kg, xanthohumic acid 4 kg, nitric acid phosphorus 15kg, urea 20kg, urea formaldehyde 15 kg, diammonium phosphate 25kg, vitriolate of tartar 20 kg, nitrocalcite 0.6kg, sal epsom 0.6kg, zinc sulfate 0.5 kg, ferrous sulfate 0.2 kg, manganous sulfate 0.2 kg, copper sulfate 0.3 kg, boric acid 0.4kg, ammonium molybdate 0.1kg, rare earth element-praseodymium nitrate 0.3kg.
The preparation method is as follows:
(1) at first by above-mentioned weight proportion raw materials weighing;
(2) in reactor, add entry then, be warming up to 65 ℃, add the chitin and the xanthohumic acid that weigh up, stirring and dissolving; Add load weighted nitrocalcite after the dissolving again, stirring and dissolving and constant temperature 15-20 minute complete to chelatropic reaction;
(3) chelating fully after, add load weighted sal epsom, zinc sulfate, ferrous sulfate, manganous sulfate, copper sulfate, boric acid, ammonium molybdate, rare earth element-praseodymium nitrate more successively, all dissolving;
(4) after whole dissolvings, be warming up to 85 ℃, constant temperature 25 minutes, complete to chelatropic reaction, making mass concentration is 75% thick chelating liquid;
(5) chelating liquid is sprayed in the compound of load weighted nitric acid phosphorus, urea, urea formaldehyde, diammonium phosphate and vitriolate of tartar as binding agent, carry out granulation, after dry, cooling, the screening, enter the coating machine back metering packing of filming and obtain product.
Wheat is used this composite fertilizer and general fertilizer (N-P
2O
5-K
2O:15-15-15) use simultaneous test as base fertilizer:
In 50 mu of wheat paddock tests of Distributions in Liaocheng of Shandong Province, two groups of divisional processing and contrasts, treatment group is used 40 kilograms every mu of this composite fertilizers, control group is used the general fertilizer of equivalent, and test-results is: use this composite fertilizer treatment group and emerge soon well developed root system in earlier stage, seedling is full strong sprout, drought-resistant ability obviously shows when turning green, and mid-term, cane was sturdy, does not have the lodging phenomenon, wheat lures disease to reduce, 492 kilograms of every mu of mean level (ML) output, comparison is according to 426 kilograms of mean yields, every mu of volume increase 15.5%, reduce pesticide dosage 21%, and that control group is emerged in earlier stage is uneven, the delay of turning green because the weather arid is turned green, and mid-term, lodging reached 34%, wheat lures disease to be higher than and handles 34%, 426 kilograms of every mu of mean yields, treatment group is used this composite fertilizer effect and obviously is better than control group, and effect of increasing production is obvious.
Embodiment 2
A kind of chitin xanthohumic acid composite fertilizer, the weight part proportioning of each composition is: chitin 5kg, xanthohumic acid 5 kg, nitric acid phosphorus 10kg, urea 10kg, urea formaldehyde 10 kg, diammonium phosphate 25kg, vitriolate of tartar 35kg, nitrocalcite 2kg, sal epsom 0.5 kg, zinc sulfate 0.5 kg, copper sulfate 0.5kg, boric acid 1 kg, rare earth element-Cerium II Chloride 0.3kg.
The preparation method is as follows:
(1) at first by above-mentioned weight proportion raw materials weighing;
(2) in reactor, add entry then, be warming up to 60 ℃, add the chitin and the xanthohumic acid that weigh up, stirring and dissolving; Add load weighted nitrocalcite after the dissolving again, stirring and dissolving and constant temperature 15-20 minute complete to chelatropic reaction;
(3) chelating fully after, add load weighted sal epsom, zinc sulfate, ferrous sulfate, manganous sulfate, copper sulfate, boric acid, ammonium molybdate, rare earth element-Cerium II Chloride more successively, all dissolving;
(4) after whole dissolvings, be warming up to 80 ℃, constant temperature 20 minutes, complete to chelatropic reaction, making mass concentration is 70% thick chelating liquid;
(5) chelating liquid is sprayed in the compound of load weighted nitric acid phosphorus, urea, urea formaldehyde, diammonium phosphate and vitriolate of tartar as binding agent, carry out granulation, after dry, cooling, the screening, enter the coating machine back metering packing of filming and obtain product.
White muskmelon is used this composite fertilizer and general fertilizer (N-P
2O
5-K
2O:15-10-20) use simultaneous test as base fertilizer
Test in 20 mu of white muskmelons field, Changyi, Shandong city, two groups of divisional processing and contrasts, treatment group is used every mu of 120 kg of this composite fertilizer, and control group is used the general fertilizer of equivalent, in February, 2010, successive cloudy days were just caught up with in cultivation, because illumination is few, ground temperature is low, uses this composite fertilizer treatment group well developed root system, cold tolerance is strong, it is complete to emerge, and does not have seedling death phenomenon, and the dead seedling of control group is serious, again fill the gaps with seedlings, the climing sturdy but not prosperous length of treatment group melon in mid-term, downy mildew, angular leaf spot do not have morbidity and the result many, ripe early, went on the market ahead of time 15 days, 4.5 yuan of per kilogram prices, 2545 kilograms of per mu yields, comparison is according to 675 kilograms of field volume increase, and selling price exceeds 0.8 yuan of contrast per kilogram, surplus treatment group increases income 5000 than the average mu of control group yuan, the product mouthfeel is good, the commodity height, obvious effect of increasing production.
Embodiment 3
A kind of chitin xanthohumic acid composite fertilizer, the weight part proportioning of each composition is: chitin 6kg, xanthohumic acid 6 kg, nitric acid phosphorus 10kg, urea 10kg, urea formaldehyde 15 kg, 0.2 kilogram of diammonium phosphate 30kg, vitriolate of tartar 30kg, nitrocalcite 5kg, sal epsom 3 kg, zinc sulfate 5 kg, copper sulfate 0.3kg, manganous sulfate, boric acid 0.5kg, rare earth element-lanthanum sulfat 0.4 kg.
The preparation method is as follows:
(1) at first by above-mentioned weight proportion raw materials weighing;
(2) in reactor, add entry then, be warming up to 70 ℃, add the chitin and the xanthohumic acid that weigh up, stirring and dissolving; Add load weighted nitrocalcite after the dissolving again, stirring and dissolving and constant temperature 15-20 minute complete to chelatropic reaction;
(3) chelating fully after, add load weighted sal epsom, zinc sulfate, ferrous sulfate, manganous sulfate, copper sulfate, boric acid, ammonium molybdate, rare earth element-lanthanum sulfat more successively, all dissolving;
(4) after whole dissolvings, be warming up to 90 ℃, constant temperature 30 minutes, complete to chelatropic reaction, making mass concentration is 80% thick chelating liquid;
(5) chelating liquid is sprayed in the compound of load weighted nitric acid phosphorus, urea, urea formaldehyde, diammonium phosphate and vitriolate of tartar as binding agent, carry out granulation, after dry, cooling, the screening, enter the coating machine back metering packing of filming and obtain product.
Apple is used this composite fertilizer and general fertilizer (N-P
2O
5-K
2O:15-10-20) use simultaneous test as base fertilizer
An orchard in the Qixia, township of apple, because the fruit tree age of tree is long and manage not in place causing a little less than the fruit tree tree vigo(u)r, root growth is bad, this composite fertilizer (treatment group) of price (identical) such as in half orchard, used in 2009 with conventional fertilizer mu fertilise cost, all the other use conventional fertilizer (control group), used the back veteran in 1 year and radiate vigour again, the root growth vigor strengthens, tree vigo(u)r is strong, has extracted new branch and blade again out; 1 year spring, the treatment group tree vigo(u)r was prosperous, and it is many to bear fruit, and the quality of fruit and output all increased significantly when gathered in the crops autumn, the fruit type just, mass color is good, uniform coloring, color and luster is vivid, and the one-level fruit is many, and the market value comparison is according to the high 0.6-0.8 of per kilogram unit, mu increases income and reaches more than 3000 yuan, and test shows that using this composite fertilizer can activate the root system vigor, promotes root system development, improve fruit quality simultaneously, improve disease-resistant anti-adversity ability, increase output, improve farmers' income.
Embodiment 4
A kind of chitin xanthohumic acid composite fertilizer, the weight part proportioning of each composition is: chitin 3kg, xanthohumic acid 3 kg, nitric acid phosphorus 10kg, urea 10 kg, urea formaldehyde 10kg, diammonium phosphate 15kg, vitriolate of tartar 10kg, rare earth element-acetic acid neodymium 0.1kg.
Embodiment 5
A kind of chitin xanthohumic acid composite fertilizer, the weight part proportioning of each composition is: chitin 8kg, xanthohumic acid 8 kg, nitric acid phosphorus 30kg, urea 30 kg, urea formaldehyde 30 kg, diammonium phosphate 30 kg, vitriolate of tartar 40kg, nitrocalcite 2 kg, sal epsom 2 kg, zinc sulfate 1 kg, ferrous sulfate 1 kg, manganous sulfate 1 kg, copper sulfate 1 kg, boric acid 1 kg, ammonium molybdate 0.5 kg, rare earth element-acetic acid neodymium 0.25 kg and lanthanum sulfat 0.25 kg.
Embodiment 6
A kind of chitin xanthohumic acid composite fertilizer, the weight part proportioning of each composition is: chitin 7kg, xanthohumic acid 7 kg, nitric acid phosphorus 28kg, urea 28 kg, urea formaldehyde 28 kg, diammonium phosphate 28kg, vitriolate of tartar 38 kg, nitrocalcite 1.5kg, sal epsom 1.5kg, zinc sulfate 0.8kg, ferrous sulfate 0.8 kg, manganous sulfate 0.8kg, copper sulfate 0.8kg, boric acid 0.8kg, ammonium molybdate 0.4 kg, rare earth element-lanthanum sulfat 0.1kg, Cerium II Chloride 0.1kg, praseodymium nitrate 0.1kg, acetic acid neodymium 0.1kg.
Embodiment 7
A kind of chitin xanthohumic acid composite fertilizer, the weight part proportioning of each composition is: chitin 4kg, xanthohumic acid 4 kg, nitric acid phosphorus 12kg, urea 12 kg, urea formaldehyde 12 kg, diammonium phosphate 17kg, vitriolate of tartar 12kg, nitrocalcite 0.5kg, sal epsom 0.5kg, zinc sulfate 0.2kg, ferrous sulfate 0.2kg, manganous sulfate 0.2kg, copper sulfate 0.2kg, boric acid 0.2kg, ammonium molybdate 0.1kg, rare earth element-acetic acid neodymium 0.2kg.
Among each embodiment of the present invention, used chemical industry material is used material in the production of this area, all can obtain from market, and can not exert an influence for the production result; The equipment of using in each operation all adopts conventional equipment used in the current production, there is no special feature.
It should be noted that at last: the above only is the preferred embodiments of the present invention, be not limited to the present invention, although the present invention is had been described in detail with reference to previous embodiment, for a person skilled in the art, it still can be made amendment to the technical scheme that aforementioned each embodiment put down in writing, and perhaps part technical characterictic wherein is equal to replacement.Within the spirit and principles in the present invention all, any modification of being done, be equal to replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (6)
1. chitin xanthohumic acid composite fertilizer, it is characterized in that: the composition of described composite fertilizer comprises:
Chitin, xanthohumic acid, nitric acid phosphorus, urea, urea formaldehyde, diammonium phosphate, vitriolate of tartar, middle trace element and rare earth element;
Trace element is nitrocalcite, sal epsom, zinc sulfate, ferrous sulfate, manganous sulfate, copper sulfate, boric acid and ammonium molybdate in described.
2. a kind of chitin xanthohumic acid composite fertilizer according to claim 1 is characterized in that: each composition is according to the following weight parts proportioning in the described composite fertilizer:
Chitin 3~8kg, xanthohumic acid 3~8 kg, nitric acid phosphorus 10~30kg, urea 10~30 kg, urea formaldehyde 10~30 kg, diammonium phosphate 15~30 kg, vitriolate of tartar 10~40kg, nitrocalcite 0~2 kg, sal epsom 0~2 kg, zinc sulfate 0~1 kg, ferrous sulfate 0~1 kg, manganous sulfate 0~1 kg, copper sulfate 0~1 kg, boric acid 0~1 kg, ammonium molybdate 0~0.5 kg, rare earth element 0.1~0.5 kg.
3. a kind of chitin xanthohumic acid composite fertilizer according to claim 2 is characterized in that: each composition is according to the following weight parts proportioning in the described composite fertilizer:
Chitin 4~7kg, xanthohumic acid 4~7 kg, nitric acid phosphorus 12~28kg, urea 12~28 kg, urea formaldehyde 12~28 kg, diammonium phosphate 17~28kg, vitriolate of tartar 12~38 kg, nitrocalcite 0.5~1.5kg, sal epsom 0.5~1.5kg, zinc sulfate 0.2~0.8kg, ferrous sulfate 0.2~0.8 kg, manganous sulfate 0.2~0.8kg, copper sulfate 0.2~0.8kg, boric acid 0.2~0.8kg, ammonium molybdate 0.1~0.4 kg, rare earth element 0.2~0. 4kg.
4. a kind of chitin xanthohumic acid composite fertilizer according to claim 3 is characterized in that: each composition is according to the following weight parts proportioning in the described composite fertilizer:
Chitin 4kg, xanthohumic acid 4 kg, nitric acid phosphorus 15kg, urea 20kg, urea formaldehyde 15 kg, diammonium phosphate 25kg, vitriolate of tartar 20 kg, nitrocalcite 0.6kg, sal epsom 0.6kg, zinc sulfate 0.5 kg, ferrous sulfate 0.2 kg, manganous sulfate 0.2 kg, copper sulfate 0.3 kg, boric acid 0.4kg, ammonium molybdate 0.1kg, rare earth element 0.3kg.
5. according to any described a kind of chitin xanthohumic acid composite fertilizer among the claim 1-4, it is characterized in that:
Described rare earth element comprises one or more in rare earth nitrate, rare earth chloride, sulfuric acid rare earth, the acetic acid rare earth, and described rare earth comprises one or more in lanthanum, cerium, praseodymium, the neodymium.
6. the preparation method of a chitin xanthohumic acid composite fertilizer as claimed in claim 1 is characterized in that, may further comprise the steps:
(1) in reactor, adds entry, be warming up to 60~70 ℃, add chitin and xanthohumic acid, stirring and dissolving;
(2) add nitrocalcite again after the dissolving, stirring and dissolving and constant temperature 15-20 minute complete to chelatropic reaction;
(3) with the complete back of above-mentioned steps (2) chelating solution, add sal epsom, zinc sulfate, ferrous sulfate, manganous sulfate, copper sulfate, boric acid, ammonium molybdate, rare earth element more successively, be stirred to whole dissolvings;
(4) after whole dissolvings, be warming up to 80~90 ℃, constant temperature 20~30 minutes, complete to chelatropic reaction, making mass concentration is 70~80% thick chelating liquid;
(5) the resulting chelating liquid of above-mentioned steps (4) is sprayed into as binding agent in the compound of nitric acid phosphorus, urea, urea formaldehyde, diammonium phosphate and vitriolate of tartar, carry out granulation, after drying, cooling, the screening, obtain product.
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