CN102202788B - 含有金属的有机二氧化硅催化剂;其制备工艺和用途 - Google Patents

含有金属的有机二氧化硅催化剂;其制备工艺和用途 Download PDF

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CN102202788B
CN102202788B CN200980130708.6A CN200980130708A CN102202788B CN 102202788 B CN102202788 B CN 102202788B CN 200980130708 A CN200980130708 A CN 200980130708A CN 102202788 B CN102202788 B CN 102202788B
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metal
solution
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CN102202788A (zh
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罗萨丽亚·西里明娜
马里奥·帕赫利阿罗
乔瓦尼·帕尔米萨诺
瓦莱丽卡·潘达鲁斯
林达·特伦布莱
弗朗索瓦·贝兰德
马蒂厄·西马德
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Silicycle Inc
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    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/123—Organometallic polymers, e.g. comprising C-Si bonds in the main chain or in subunits grafted to the main chain
    • B01J31/124—Silicones or siloxanes or comprising such units
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
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    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
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    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
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    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
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    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
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    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
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    • B01J2231/4205—C-C cross-coupling, e.g. metal catalyzed or Friedel-Crafts type
    • B01J2231/4211—Suzuki-type, i.e. RY + R'B(OR)2, in which R, R' are optionally substituted alkyl, alkenyl, aryl, acyl and Y is the leaving group
    • B01J2231/4227—Suzuki-type, i.e. RY + R'B(OR)2, in which R, R' are optionally substituted alkyl, alkenyl, aryl, acyl and Y is the leaving group with Y= Cl
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    • B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
    • B01J2231/4205—C-C cross-coupling, e.g. metal catalyzed or Friedel-Crafts type
    • B01J2231/4266—Sonogashira-type, i.e. RY + HC-CR' triple bonds, in which R=aryl, alkenyl, alkyl and R'=H, alkyl or aryl
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    • B01J2231/643—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of R2C=O or R2C=NR (R= C, H)
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    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN200980130708.6A 2008-08-04 2009-08-04 含有金属的有机二氧化硅催化剂;其制备工艺和用途 Active CN102202788B (zh)

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US8602208P 2008-08-04 2008-08-04
US61/086,022 2008-08-04
PCT/CA2009/001098 WO2010015081A1 (en) 2008-08-04 2009-08-04 Metal-containing organosilica catalyst; process of preparation and use thereof

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CN102202788A CN102202788A (zh) 2011-09-28
CN102202788B true CN102202788B (zh) 2015-01-21

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US (1) US20110190115A1 (cg-RX-API-DMAC7.html)
EP (1) EP2318134A4 (cg-RX-API-DMAC7.html)
JP (1) JP5758802B2 (cg-RX-API-DMAC7.html)
CN (1) CN102202788B (cg-RX-API-DMAC7.html)
WO (1) WO2010015081A1 (cg-RX-API-DMAC7.html)

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EP3142966B1 (en) 2014-05-12 2020-01-29 Virdia, Inc. Hydrogenation of oxygenated molecules from biomass refining
US10294312B2 (en) 2014-12-12 2019-05-21 Exxonmobil Research And Engineering Company Olefin polymerization catalyst system comprising mesoporous organosilica support
CA2967047A1 (en) 2014-12-12 2016-06-16 Exxonmobil Research And Engineering Company Organosilica materials and uses thereof
WO2016094769A1 (en) 2014-12-12 2016-06-16 Exxonmobil Research And Engineering Company Aromatic hydrogenation catalysts and uses thereof
WO2016094820A1 (en) 2014-12-12 2016-06-16 Exxonmobil Research And Engineering Company Adsorbent for heteroatom species removal and uses thereof
US10155826B2 (en) 2014-12-12 2018-12-18 Exxonmobil Research And Engineering Company Olefin polymerization catalyst system comprising mesoporous organosilica support
US10576453B2 (en) 2014-12-12 2020-03-03 Exxonmobil Research And Engineering Company Membrane fabrication methods using organosilica materials and uses thereof
US10351639B2 (en) 2014-12-12 2019-07-16 Exxonmobil Research And Engineering Company Organosilica materials for use as adsorbents for oxygenate removal
US10207249B2 (en) 2014-12-12 2019-02-19 Exxonmobil Research And Engineering Company Organosilica materials and uses thereof
CN105859495B (zh) * 2016-05-05 2018-03-06 陕西师范大学 炔酮促进CuI催化Sonogashira偶联反应的方法
JP6726768B2 (ja) 2016-06-10 2020-07-22 エクソンモービル リサーチ アンド エンジニアリング カンパニーＥｘｘｏｎ Ｒｅｓｅａｒｃｈ Ａｎｄ Ｅｎｇｉｎｅｅｒｉｎｇ Ｃｏｍｐａｎｙ オルガノシリカポリマー触媒およびその製造方法
WO2017213667A1 (en) 2016-06-10 2017-12-14 Exxonmobil Research And Engineering Company Organosilica materials, methods of making, and uses thereof
BR112019006741B1 (pt) * 2016-10-05 2023-12-05 Monsanto Technology Llc Processo para regeneração de catalisador
US10179839B2 (en) 2016-11-18 2019-01-15 Exxonmobil Research And Engineering Company Sulfur terminated organosilica materials and uses thereof
CN109320398B (zh) * 2018-08-28 2022-03-18 浙江工业大学 一种由二苯甲酮催化加氢合成二苯甲醇的方法
CN112661618B (zh) * 2019-10-16 2024-04-09 中国石油化工股份有限公司 一种环戊酮的铜催化制备方法
JP7840118B2 (ja) * 2021-04-21 2026-04-03 千代田化工建設株式会社 水素化触媒ならびにこれを用いたフロー式有機合成システム及び水素化有機化合物の製造方法
CN114471540B (zh) * 2022-02-22 2023-08-08 北京化工大学 一种亚纳米Pt选择性加氢催化剂、制备方法及其应用
CN116139879B (zh) * 2023-02-14 2024-01-26 安徽大学 二氧化硅负载铱镍催化剂IrNi/SiO2及其高选择性催化苯甲腈、巴豆醛和苄叉丙酮中的加氢方法和应用

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