CN102199888A - Method for transferring patterns of fabrics or fur quilts - Google Patents
Method for transferring patterns of fabrics or fur quilts Download PDFInfo
- Publication number
- CN102199888A CN102199888A CN 201110038659 CN201110038659A CN102199888A CN 102199888 A CN102199888 A CN 102199888A CN 201110038659 CN201110038659 CN 201110038659 CN 201110038659 A CN201110038659 A CN 201110038659A CN 102199888 A CN102199888 A CN 102199888A
- Authority
- CN
- China
- Prior art keywords
- transfer
- water
- fabric
- soluble
- fur coat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 71
- 238000000034 method Methods 0.000 title claims abstract description 58
- 238000012546 transfer Methods 0.000 claims abstract description 88
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 34
- 238000007639 printing Methods 0.000 claims abstract description 21
- 239000000126 substance Substances 0.000 claims abstract description 17
- 239000003960 organic solvent Substances 0.000 claims abstract description 13
- 239000011259 mixed solution Substances 0.000 claims abstract description 10
- 239000002985 plastic film Substances 0.000 claims abstract description 10
- 229920006255 plastic film Polymers 0.000 claims abstract description 10
- 239000011248 coating agent Substances 0.000 claims abstract description 7
- 238000000576 coating method Methods 0.000 claims abstract description 7
- 238000012545 processing Methods 0.000 claims abstract description 5
- 238000010438 heat treatment Methods 0.000 claims abstract description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 63
- 229920001223 polyethylene glycol Polymers 0.000 claims description 63
- 239000000975 dye Substances 0.000 claims description 54
- 238000010023 transfer printing Methods 0.000 claims description 51
- 239000004831 Hot glue Substances 0.000 claims description 37
- 239000000243 solution Substances 0.000 claims description 30
- 239000000463 material Substances 0.000 claims description 29
- 229920001451 polypropylene glycol Polymers 0.000 claims description 27
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 24
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 16
- 235000018167 Reynoutria japonica Nutrition 0.000 claims description 15
- 240000001341 Reynoutria japonica Species 0.000 claims description 15
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 15
- 239000000985 reactive dye Substances 0.000 claims description 15
- 230000032050 esterification Effects 0.000 claims description 14
- 238000005886 esterification reaction Methods 0.000 claims description 14
- 229920000642 polymer Polymers 0.000 claims description 14
- 239000002253 acid Substances 0.000 claims description 13
- 239000004677 Nylon Substances 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 229920001778 nylon Polymers 0.000 claims description 12
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 claims description 9
- 239000000980 acid dye Substances 0.000 claims description 9
- 239000000986 disperse dye Substances 0.000 claims description 9
- 238000006396 nitration reaction Methods 0.000 claims description 9
- 150000003839 salts Chemical class 0.000 claims description 9
- 239000004952 Polyamide Substances 0.000 claims description 8
- 239000006096 absorbing agent Substances 0.000 claims description 8
- 239000004202 carbamide Substances 0.000 claims description 8
- 239000000835 fiber Substances 0.000 claims description 8
- 229920002647 polyamide Polymers 0.000 claims description 8
- 229920000728 polyester Polymers 0.000 claims description 8
- 150000001768 cations Chemical class 0.000 claims description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- 238000005576 amination reaction Methods 0.000 claims description 6
- 239000012752 auxiliary agent Substances 0.000 claims description 6
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 6
- 239000012528 membrane Substances 0.000 claims description 6
- 150000007524 organic acids Chemical class 0.000 claims description 6
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 6
- 229920002635 polyurethane Polymers 0.000 claims description 6
- 239000004814 polyurethane Substances 0.000 claims description 6
- 210000002268 wool Anatomy 0.000 claims description 6
- 229920002799 BoPET Polymers 0.000 claims description 5
- 229920000742 Cotton Polymers 0.000 claims description 5
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 claims description 5
- 229920001577 copolymer Polymers 0.000 claims description 5
- 239000003292 glue Substances 0.000 claims description 5
- 238000002844 melting Methods 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 5
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 4
- 229920004934 Dacron® Polymers 0.000 claims description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 4
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 4
- 239000001110 calcium chloride Substances 0.000 claims description 4
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 150000001447 alkali salts Chemical class 0.000 claims description 3
- 229920006378 biaxially oriented polypropylene Polymers 0.000 claims description 3
- 239000011127 biaxially oriented polypropylene Substances 0.000 claims description 3
- 239000001913 cellulose Substances 0.000 claims description 3
- 229920002678 cellulose Polymers 0.000 claims description 3
- 238000007334 copolymerization reaction Methods 0.000 claims description 3
- HDERJYVLTPVNRI-UHFFFAOYSA-N ethene;ethenyl acetate Chemical group C=C.CC(=O)OC=C HDERJYVLTPVNRI-UHFFFAOYSA-N 0.000 claims description 3
- 235000011187 glycerol Nutrition 0.000 claims description 3
- 150000007529 inorganic bases Chemical class 0.000 claims description 3
- 150000007522 mineralic acids Chemical class 0.000 claims description 3
- 150000007530 organic bases Chemical class 0.000 claims description 3
- 239000002798 polar solvent Substances 0.000 claims description 3
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 3
- 239000011118 polyvinyl acetate Substances 0.000 claims description 3
- 229940075065 polyvinyl acetate Drugs 0.000 claims description 3
- -1 vinyl acetate-butenol Chemical compound 0.000 claims description 3
- RPAJSBKBKSSMLJ-DFWYDOINSA-N (2s)-2-aminopentanedioic acid;hydrochloride Chemical compound Cl.OC(=O)[C@@H](N)CCC(O)=O RPAJSBKBKSSMLJ-DFWYDOINSA-N 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 238000013461 design Methods 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 2
- 238000005096 rolling process Methods 0.000 abstract description 20
- 238000005406 washing Methods 0.000 abstract description 5
- 238000004043 dyeing Methods 0.000 abstract description 4
- 238000001035 drying Methods 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 230000007423 decrease Effects 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 230000000694 effects Effects 0.000 description 11
- 238000005516 engineering process Methods 0.000 description 10
- 230000008569 process Effects 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
- 238000012805 post-processing Methods 0.000 description 9
- 239000002585 base Substances 0.000 description 7
- 230000003647 oxidation Effects 0.000 description 7
- 238000007254 oxidation reaction Methods 0.000 description 7
- 238000009736 wetting Methods 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 6
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 239000000661 sodium alginate Substances 0.000 description 5
- 235000010413 sodium alginate Nutrition 0.000 description 5
- 229940005550 sodium alginate Drugs 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 241001465754 Metazoa Species 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 238000004821 distillation Methods 0.000 description 4
- 239000012943 hotmelt Substances 0.000 description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 4
- 235000011121 sodium hydroxide Nutrition 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 3
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 3
- 235000011130 ammonium sulphate Nutrition 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 3
- 235000015165 citric acid Nutrition 0.000 description 3
- 238000009940 knitting Methods 0.000 description 3
- 229920002521 macromolecule Polymers 0.000 description 3
- 125000004334 oxygen containing inorganic group Chemical group 0.000 description 3
- 238000010022 rotary screen printing Methods 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 2
- DHKHKXVYLBGOIT-UHFFFAOYSA-N 1,1-Diethoxyethane Chemical compound CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- 229920002972 Acrylic fiber Polymers 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 241000345998 Calamus manan Species 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- SAQSTQBVENFSKT-UHFFFAOYSA-M TCA-sodium Chemical compound [Na+].[O-]C(=O)C(Cl)(Cl)Cl SAQSTQBVENFSKT-UHFFFAOYSA-M 0.000 description 2
- 239000011354 acetal resin Substances 0.000 description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- LQJVOKWHGUAUHK-UHFFFAOYSA-L disodium 5-amino-4-hydroxy-3-phenyldiazenylnaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].OC1=C2C(N)=CC(S([O-])(=O)=O)=CC2=CC(S([O-])(=O)=O)=C1N=NC1=CC=CC=C1 LQJVOKWHGUAUHK-UHFFFAOYSA-L 0.000 description 2
- TUXJTJITXCHUEL-UHFFFAOYSA-N disperse red 11 Chemical compound C1=CC=C2C(=O)C3=C(N)C(OC)=CC(N)=C3C(=O)C2=C1 TUXJTJITXCHUEL-UHFFFAOYSA-N 0.000 description 2
- 238000010021 flat screen printing Methods 0.000 description 2
- 235000019253 formic acid Nutrition 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000001630 malic acid Substances 0.000 description 2
- 235000011090 malic acid Nutrition 0.000 description 2
- 230000011987 methylation Effects 0.000 description 2
- 238000007069 methylation reaction Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 229920006324 polyoxymethylene Polymers 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 235000012950 rattan cane Nutrition 0.000 description 2
- 235000017550 sodium carbonate Nutrition 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 description 1
- 125000001340 2-chloroethyl group Chemical class [H]C([H])(Cl)C([H])([H])* 0.000 description 1
- 241000282421 Canidae Species 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 241001062009 Indigofera Species 0.000 description 1
- 241000282342 Martes americana Species 0.000 description 1
- 241000772415 Neovison vison Species 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- AQLLBJAXUCIJSR-UHFFFAOYSA-N OC(=O)C[Na] Chemical class OC(=O)C[Na] AQLLBJAXUCIJSR-UHFFFAOYSA-N 0.000 description 1
- 241000283973 Oryctolagus cuniculus Species 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 235000004443 Ricinus communis Nutrition 0.000 description 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 241000283925 Spermophilus Species 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 1
- HGAZMNJKRQFZKS-UHFFFAOYSA-N chloroethene;ethenyl acetate Chemical compound ClC=C.CC(=O)OC=C HGAZMNJKRQFZKS-UHFFFAOYSA-N 0.000 description 1
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical class ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 1
- XTHPWXDJESJLNJ-UHFFFAOYSA-N chlorosulfonic acid Substances OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 description 1
- 238000006266 etherification reaction Methods 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 description 1
- 239000011654 magnesium acetate Substances 0.000 description 1
- 235000011285 magnesium acetate Nutrition 0.000 description 1
- 229940069446 magnesium acetate Drugs 0.000 description 1
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 1
- 235000019799 monosodium phosphate Nutrition 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- FYRHIOVKTDQVFC-UHFFFAOYSA-M potassium phthalimide Chemical compound [K+].C1=CC=C2C(=O)[N-]C(=O)C2=C1 FYRHIOVKTDQVFC-UHFFFAOYSA-M 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 230000001180 sulfating effect Effects 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- YNJBWRMUSHSURL-UHFFFAOYSA-N trichloroacetic acid Chemical compound OC(=O)C(Cl)(Cl)Cl YNJBWRMUSHSURL-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Landscapes
- Coloring (AREA)
Abstract
The invention discloses a method for transferring patterns of fabrics or fur quilts, comprising the following steps of: dissolving a high-molecular substance in water or a mixed solution containing water and an organic solvent, coating paper or plastic films with the obtained mixed solution, drying the paper or plastic films, followed by rolling for backup; printing patterns on the paper or plastic films by using dye printing ink or dye ink to produce transfer paper or transfer films; sticking the printing surfaces of the transfer paper or transfer films to the fabrics or fur quilts to be printed, placing them into a transfer machine, followed by heating and pressurization to accomplish printing; peeling off the transfer paper or transfer films and performing a dye fixation treatment; and washing the fabrics or fur quilts, followed by fixing processing to complete the transfer. The transfer method provided by the invention breaks through conventional transfer thinking, omits the dewing procedure, saves processing time, reduces production cost and decreases the dyeing and printing difficulty.
Description
Technical field
The present invention relates to the dyeing method of a kind of fabric or fur coat fleece, relate in particular to the transfer method of a kind of fabric or fur coat fleece flower type.
Background technology
Traditional textiles thermal transfer printing method starts from late 1960s.It is that the DISPERSE DYES that will distil easily earlier is imprinted on the transfer printing base stock, and then with modes such as hot pressing, the DISPERSE DYES distillation is transferred on the fabric, forms a kind of printing method of pattern.It has, and colored type is true to nature, and technology is simple, advantage that three waste discharge is few or the like.It is only applicable to the stamp of dacron, at polyamide fibre, and acrylic fibers, and poor effect on the natural fabric.
In order to realize the transfer printing of natural fabric, the wet transfer printing of REACTIVE DYES and ACID DYES has obtained domestic and international many colourists' attention.Patent 200410041034.1, and patent 200510026661.2 all discloses a kind of wet transfer printing method of natural fabric separately.Patent 200710025329.3 also discloses the wet transfer printing method of a kind of natural fabric and nylon fabric.
But they all have more jointly, must be earlier that fabric to be transferred is wetting, more under pressure, make on the lining with moisture dissolving transfer paper or the water-soluble dye on the transfer film, last or cold dome, or decatize, or bake, dyestuff is combined with fiber, finish transfer printing.
And wet transfer printing is in implementation process, and the humidity control when fabric is wetting has suitable difficulty, because fabric variety is numerous, thickness differs greatly, institutional framework closely differs, and very easily because the wetting dye transfer that causes inadequately is bad, or humidity causes colored pattern to stick with paste drawbacks such as unclear too greatly.
Fur coat claims fur or leather and fur again.It is meant made clothes or the articles for daily use of fur with animal.The animal that is commonly used to make fur coat comprises sheep, horse, ox, domestic animal or foxes such as rabbit, mink, castor, wild animals such as ground squirrel.
The fleece stamp of fur coat mainly contains dual mode in the prior art:
A kind of mode is to use oxidation dye with silk screen or hollow out version stamp.Use the oxidation dye stamp, fur coat must be used the oxidation dye stamp more earlier with bichromate preliminary treatment mordant dyeing.In this process, bichromate is the heavily contaminated material, can cause very big harm to environment and operative employee's health.And oxidation dye is the lower-molecular substance of aniline structure, and it also has strong carcinogenic.The chromatogram of oxidation dye own is incomplete in addition, lack bright-coloured red, Huang, indigo plant.So fur coat is progressively eliminated with the oxidation dye stamp.
Another kind of substitute technology is with silk screen or hollow out version, uses the ACID DYES stamp.Its is plate-making earlier, more direct stamp on fur coat.Last decatize, washing.Because directly stamp on fur coat very easily causes substandard products, the high price of fur coat is so waste is very big.Because general fur coat factory there is no technical staff such as printing, so this method also is difficult to promote.
Summary of the invention
Technical problem to be solved by this invention provides the transfer method of a kind of fabric or fur coat fleece flower type, to solve the difficult difficult problem of humidity control that fabric wet transfer printing exists, solves the low problem of complex process, fastness that fur coat fleece flower type shifts simultaneously.
For solving the problems of the technologies described above, thinking of the present invention is, adopts brand-new heat-transferring method, promptly is configured to Yin Mo with REACTIVE DYES or ACID DYES or cation dyes or common difficult distillation DISPERSE DYES, is printed on the carrier, makes transfer film or transfer paper.Again with transfer film or directly transfer printing on fabric or fur coat of transfer paper, pass through at last post processing PRINTED FABRIC or stamp fur coat.
For solving the problems of the technologies described above, the technical solution used in the present invention is as follows:
The transfer method of a kind of fabric or fur coat fleece flower type, this method comprises the steps:
(1) mixed solution of polymer substance is water-soluble or water and organic solvent adds auxiliary agent according to one of following three kinds of modes of different choice of dyestuff and fabric to be transferred or fur coat fleece kind and continues mixed solution that dissolving obtains that paper or plastic film are carried out coating, oven dry, clot is standby; Three kinds of modes are:
It is cotton reactive dye that a works as dyestuff, when material to be transferred is cellulose base fiber fabric or real silk fabric, the water absorbing agent (the percentage implication is the ratio of weight of the solution of the weight of single auxiliary agent and polymer substance) that adds the alkaline agent, 2～25% (w/w) of 0.5～10% (w/w) in the solution of above-mentioned polymer substance preferably adds the water absorbing agent of the alkaline agent, 8～15% (w/w) of 2～4% (w/w);
B when dyestuff be ACID DYES, reactive dye for wool, polyamide fibre with REACTIVE DYES or cation dyes, when material to be transferred is real silk fabric, wool fabric, nylon fabric, acrylic fabric or fur coat fleece, the water absorbing agent (the percentage implication is the ratio of weight of the solution of the weight of single auxiliary agent and polymer substance) that adds the sour agent, 2～25% (w/w) of 0.5～10% (w/w) in the solution of above-mentioned polymer substance preferably adds the water absorbing agent of the sour agent, 8～15% (w/w) of 2～3% (w/w);
It is DISPERSE DYES that c works as dyestuff, and material to be transferred is a dacron, does not add any auxiliary agent;
Wherein, described alkaline agent is the material that energy ionization generates hydroxide ion in solution, and it generally comprises inorganic base, organic base, several classes of basic salt or strong base-weak acid salt.Described inorganic base is a NaOH, calcium hydroxide, potassium hydroxide or the like, organic base is an ethylenediamine, triethanolamine or the like, basic salt is an alkali formula calcium chloride etc., and what use was maximum in printing with reactive dye is strong acid weak base salt, and it mainly contains: sodium bicarbonate, saleratus, potash, sodium trichloroacetate, tertiary sodium phosphate or soda ash.
Wherein, described water absorbing agent is the material of energy deliquescence suction in air, and it generally comprises urea, glycerine, calcium chloride or magnesium chloride.
Wherein, described sour agent is for ionization producing hydrionic material in solution, and it comprises organic acid, inorganic acid, and several classes such as acid salt or strong acid weak base salt, wherein organic acid is generally formic acid, acetate, oxalic acid, citric acid, malic acid, trichloroacetic acid or the like.Inorganic acid is generally hydrochloric acid, sulfuric acid, phosphoric acid, nitric acid or the like.Acid salt is generally niter cake, sodium dihydrogen phosphate or the like.Strong acid weak base salt is generally ammonium sulfate etc.
Wherein, described polymer substance is a water-soluble hot-melt adhesive, perhaps the mixture of any one or a few in polyethylene glycol, polypropylene oxide, polyethylene glycol oxide, end-blocking polyethylene glycol oxide, end-blocking polypropylene oxide and the end-blocking polyethylene glycol and water-soluble hot-melt adhesive.Wherein, described water-soluble hot-melt adhesive, kind is a lot, and it comprises any one or a few the combination in water-soluble polyester hot melting glue, soluble polyurethane hot melt adhesive, water soluble polyamide hot melt adhesive, vinyl pyrrolidone-vinyl acetate copolymer (water-soluble EVA hot melt adhesive), water-soluble poly vinyl acetate hot melt adhesive, water-soluble poval hot melt adhesive, water-soluble ethylene-vinyl acetate copolymer hot melt adhesive, water-soluble poly oxirane graft copolymerization body heat melten gel, water-soluble vinyl acetate-ethylene alcohol hot melt adhesive, the water-soluble vinyl acetate-butenol hot melt adhesive.
Described end-blocking polyethylene glycol oxide is that hydroxyl in the polyethylene glycol oxide is by etherificate, esterification, carboxylated, amination or nitration;
Described end-blocking polypropylene oxide is that hydroxyl in the polypropylene oxide is by etherificate, esterification, carboxylated, amination or nitration;
Described end-blocking polyethylene glycol is that hydroxyl in the polyethylene glycol is by etherificate, esterification, carboxylated, amination or nitration.
(2) utilize dye ink or dyestuff ink that paper or the plastic film that step (1) obtains carried out stamp, make transfer paper or transfer film;
(3) with printing surface and the fabric to be transferred or the applying of fur coat fleece of transfer paper or transfer film, together enter transfer machine, heating, pressurization realize stamp;
(4) earlier transfer paper or transfer film are peeled off, carried out the dyestuff set again; Perhaps, carry out the dyestuff set earlier, again transfer paper or transfer film are peeled off;
(5) transfer printing is finished in transfer printing fabric or fur coat fleece are washed, finalized the design processing.
In the step (1), described organic solvent is an intensive polar solvent, including but not limited to as acetonitrile, methyl alcohol, acetone and ethanol etc.
In the step (1), it is the solution of 1～40% (w/w) that described polymer substance mixed solution water-soluble or water and organic solvent forms concentration.
In the step (1), described plastic film is PET film, BOPP film, PE film or nylon membrane.
In the step (2), described dye ink comprises following components in weight percentage: dyestuff 0.1～60% connects material 1～20%, organic solvent 20～98.9%, preferably comprise following components in weight percentage: dyestuff 2～30% connects material 2～15%, organic solvent 55～96%.Wherein, dyestuff is REACTIVE DYES, ACID DYES, cation dyes or the DISPERSE DYES that is difficult for distillation; Connecting material is the polymer substance that can be dissolved in organic solvent and can form viscous solution, and it includes but not limited to polyvinyl acetal resin, vinyl chloride-vinyl acetate resin, polyethylene glycol and cellulosic plastics etc.; Organic solvent is the intensive polar solvent of energy dissolving dye, and it includes but not limited to methyl alcohol, ethanol, oxolane etc.
In the step (2), described dyestuff ink comprises following components in weight percentage: dyestuff 0.1～30% connects material 1～20%, water 50～98.9%, preferably comprise following components in weight percentage: dyestuff 2～20% connects material 2～20%, water 60～96%.Wherein, dyestuff is REACTIVE DYES, ACID DYES, cation dyes or the DISPERSE DYES that is difficult for distillation; Connecting material is the polymer substance that can be dissolved in water and can form viscous solution, and it includes but not limited to sodium alginate, sodium carboxymethylcellulose, carboxymethyl starch etc.
In the step (2), the stamp mode is intaglio plate stamp, PLATE SCREAM PRINTING, ROTARY SCREAM PRINTING, flexographic plate stamp or ink-jet printed.
Those skilled in the art can prepare corresponding dye ink or ink according to the difference of fabric to be transferred or fur coat fleece fiber species, select the stamp mode that is fit to.For example cellulose base fiber fabric, wool fabric, nylon fabric, fur coat fleece, real silk fabric can be used REACTIVE DYES; Nylon fabric, wool fabric, fur coat fleece, real silk fabric can be used ACID DYES; Acrylic fabric can be used cation dyes; Dacron can be used DISPERSE DYES; The use of printing ink or ink is accustomed to adjusting according to shop equipment and workman; These all are technology well known in the art.Technology of the present invention is not at certain specific fabric or fur coat fleece or limit the prescription and the stamp mode of printing ink, ink, and being intended to change the printing and dyeing flow process of being used to, fabric that uses in the existing transfering printing process or fur coat fleece and supporting dye formulation and stamp mode thereof all are applicable to process of the present invention.
In the step (3), be heated to 70～250 ℃, preferred 150～200 ℃, be forced into 0.5～50Kg/cm
2, preferred 15～30Kg/cm
2
In the step (3), fabric to be transferred or fur coat fleece can the rolling transfer printings, can the garment piece transfer printing, and also can the ready-made clothes transfer printing.
In the step (3), transfer machine can be a pulley type, also can be flat.
In the step (4), dyestuff set mode has dewing cold dome, decatize or bakes.Those skilled in the art can be according to the corresponding dyestuff set of the different choice mode of transfer printing fabric or fur coat fleece, for example three kinds of set modes of REACTIVE DYES all can adopt, ACID DYES and cation dyes only can adopt the set of decatize mode, DISPERSE DYES can adopt decatize or bake the mode set, and above-mentioned dyestuff set mode all is a technology well known to those skilled in the art.
By technical scheme of the present invention, those skilled in the art can not need the fabric to be transferred in the step (3) or fur coat fleece are carried out conventional wetting, oven dry preliminary treatment, promptly do not need to use in advance the Wetting Solution of different formulations to handle fabric to be transferred or fur coat fleece and do not need process to its oven dry.By technical solution of the present invention, can make material to be transferred without any processing, printing surface direct and transfer paper or transfer film is fitted, and together enters transfer machine, and heating, pressurization realize stamp.
Among the present invention program, it is as follows that described water-soluble hot-melt adhesive prepares scheme:
Water-soluble hot melt preparation method of polyester hot melt adhesive referenced patent 200510038276.X;
Preparation method's reference of water-soluble hot melt polyurethane hot melt [Yuan Jing. synthesizing of soluble polyurethane hot melt adhesive. use chemical industry [J], 2009 the 38th the 5th phases of volume, 672-674 page or leaf].
Preparation method's referenced patent 200410026949.5 of water-soluble hot melt polyamide hot;
Vinyl pyrrolidone-vinyl acetate copolymer (water-soluble EVA hot melt adhesive), water-soluble poly vinyl acetate hot melt adhesive, water-soluble poval hot melt adhesive, water-soluble ethylene-vinyl acetate copolymer hot melt adhesive, water-soluble poly oxirane graft copolymerization body heat melten gel, water-soluble vinyl acetate-ethylene alcohol hot melt adhesive, water-soluble vinyl acetate-butenol hot melt adhesive provide by Shanghai adhesive research and development centre.
Among the present invention program, the preparation technology of described end-blocking polyethylene glycol oxide, end-blocking polypropylene oxide, end-blocking polyethylene glycol is as follows:
Polyethylene glycol oxide H-(OCH
2CH
2-)
n-OH, polypropylene oxide HO-[-(C
3H
6)-O-] n-H, polyethylene glycol HO-(CH
2CH
2O-)
n-H, n are natural number, and three kinds of materials are backbone, be hydroxyl (OH), when above three kinds of materials are shifted as cotton reactive dye heat, their hydroxyl (OH) will consume the part dyestuff in their both ends or one end, cause the Dry Sack of thermal transfer printing shallow, dye utilization rate is not high.For the utilization rate of higher color depth and raising dyestuff is arranged.The hydroxyl at above three kinds of material two ends can be sealed.The main method of sealing has the hydroxyl etherificate, and hydroxy esterification is carboxylated with hydroxyl, with hydroxyl aminoization, with hydroxyl nitration or the like several different methods.The present invention does not limit the method for sealing hydroxyl, can make the hydroxy functional group conversion in every organic chemistry, and the method that makes it to lose with the REACTIVE DYES respond all is suitable for the present invention.And the method for these sealing hydroxyls is technology well-known to those skilled in the art.
The etherification method of polyethylene glycol oxide, polypropylene oxide, polyethylene glycol the most frequently used methylates, ethylization or hydroxyethylation, hydroxypropylation or carboxy methylation.
A methylates, ethylizes: be earlier polyethylene glycol oxide, polypropylene oxide or polyethylene glycol to be handled with caustic soda, (H OH) is obtained the macromolecule that alkalizes by the Na replacement with hydroxyl, cook etherifying agent with chloromethanes or chloroethanes again, the high molecular weight reactive that makes it and alkalize promptly gets and methylates or ethylating polyethylene glycol oxide, polypropylene oxide or polyethylene glycol.
B hydroxyethylation, hydroxypropylation: be earlier polyethylene glycol oxide, polypropylene oxide or polyethylene glycol to be handled with caustic soda, (H OH) is obtained the macromolecule that alkalizes by the Na replacement with hydroxyl, again under vacuum condition, add oxirane or expoxy propane and carry out etherificate as etherifying agent, after etherificate finishes, add acetic acid and neutralize.
C carboxy methylation: be earlier polyethylene glycol oxide, polypropylene oxide or polyethylene glycol to be handled with caustic soda, (H OH) is obtained the macromolecule that alkalizes by the Na replacement with hydroxyl, the organic solvent solution that adds monochloroacetic acid under high-speed stirred carries out etherificate again, generate the carboxymethyl sodium salt of polyethylene glycol oxide, polypropylene oxide or polyethylene glycol, wash with alcohol again after the final drying.
The esterification process of polyethylene glycol oxide, polypropylene oxide, polyethylene glycol is that hydroxyl (OH) follows carboxylic acid or oxygen-containing inorganic acid to generate the reaction of ester and water.(OH) reaction and inorganic oxacid are with hydroxyl (reaction two classes OH) with hydroxyl to be divided into carboxylic acid.
A and organic acid esterification: polyethylene glycol oxide, polypropylene oxide or polyethylene glycol dissolving back are mixed with organic acid, activate 2～24 hours down at 40 ℃～110 ℃, organic acid can be formic acid or acetate, activation back added the acid anhydrides and the concentrated sulfuric acid, 25 ℃～110 ℃ following esterifications 3～24 hours; After the esterification, the concentrated sulfuric acid that stays with esterification in the magnesium acetate of adding capacity precipitates in ethanol water then, filters, and will be drying to obtain described polyethylene glycol oxide after the washing of precipitate, the carboxylate of polypropylene oxide or polyethylene glycol.
The esterification of B and oxygen-containing inorganic acid: a lot of with the esterification kind of oxygen-containing inorganic acid; sulfating reaction for example; now with polyethylene glycol oxide; any one is dissolved in polypropylene oxide or polyethylene glycol in the dimethyl formamide under vacuum condition; stir; placed 10-15 hour; under protection of nitrogen gas; under 25～30 ℃ of conditions, drip chlorosulfonic acid, dripping quantity is a 3-4 times of mol ratio; after dripping end; stir with homogenizer, stir speed (S.S.) is 800～1000 rpms, 0.5～2 hour reaction time; promptly generate polyethylene glycol oxide, the hydrosulphate of polypropylene oxide or three kinds of materials of polyethylene glycol.
The carboxylated method of polyethylene glycol oxide, polypropylene oxide, polyethylene glycol is a lot, wherein a kind of method is the way by radical polymerization, use some to have hydroxyl, carboxyl or amino acrylic monomer or olefin monomer, carrying out graft reaction can be carboxylated with hydroxyl.
The amidized method of polyethylene glycol oxide, polypropylene oxide, polyethylene glycol is also a lot; wherein a kind of method is that polyethylene glycol oxide, polypropylene oxide, polyethylene glycol is water-soluble, at 0～10 ℃, adds thionyl chloride under protection of nitrogen gas; stirred 30 minutes; be warming up to 50 ℃, add potassium phthalimide, be warming up to 80 ℃; be incubated 2～3 hours; cooling at last adds hydrochloric acid, promptly obtains amidized polyethylene glycol oxide, polypropylene oxide, polyethylene glycol.
The method of the nitration of polyethylene glycol oxide, polypropylene oxide, polyethylene glycol is a lot, also can connect oxidation with above-mentioned amides is upright, obtains the nitration material.
Above-mentioned end-blocking polyethylene glycol oxide, end-blocking polypropylene oxide, end-blocking polyethylene glycol, those skilled in the art are easy to preparation.
Beneficial effect: method for transfer printing of the present invention, broken through intrinsic transfer printing thinking, saved this program of dewing, saved process time, reduced production cost, reduced the dye transfer difficulty.Because be that dry type shifts, its flower shape fineness is far superior to wet transfer printing, has thoroughly solved wet method and has shifted the difficult problem that can not be applied to the ready-made clothes stamp.
The specific embodiment
According to following embodiment, the present invention may be better understood.Yet, those skilled in the art will readily understand that the described concrete material proportion of embodiment, process conditions and result thereof only are used to illustrate the present invention, and should also can not limit the present invention described in detail in claims.
Embodiment 1:
With water-soluble polyester hot melting glue water-soluble, be made into 10% (w/w) solution, add 2% sodium carbonate, 7% urea is coated with the scraper type coating machine on the blank sheet of paper of 100 grams, oven dry, rolling is standby.Again with reactive black kn-b 20%, sodium alginate 5%, water 75% is made into ink by weight percentage, selects the flower type, behind the rotary screen printing machines impressing pattern, rolling.Above-mentioned printed transfer paper and all-cotton knitting cloth are fitted, together enter the pulley type heat transfer machine, temperature is transferred to 120 ℃, and pressure is transferred to 15Kg/cm
2, after the transfer printing, lining is put into steam box with transfer paper, 102 ℃ of temperature, evaporate under the 10 minutes time condition, tear base stock at last, postprocessing working procedures such as wash, finish transfer printing.
By test, every fastness index of the pattern behind the stamp sees Table 1, and is few with the weak effect of wet transfer printing.(GB19817-2005) (GB18401-2003), wherein light fastness is 8 grades with " national textile product basic security technical specification national standard " according to " textiles, FURNISHING FABRIC national standard ", and 1 grade the poorest, and 8 grades best.All the other are 5 grades, and 1 grade the poorest, and 5 grades best, and following form is identical.
Table 1
Embodiment 2:
Soluble polyurethane hot melt adhesive and polyethylene glycol were mixed by weight 5: 1, use water-soluble, be made into 30% (w/w) solution, add citric acid 3%, glycerine 15% is coated on the BOPP film that was coated with water wetted material with intaglio press, oven dry, rolling is standby.Again with weak acid red B 0.5%, polyvinyl acetal resin 10%, methyl alcohol 89.5% is made into printing ink by weight percentage, selects the flower type, behind the intaglio press impressing pattern, rolling.With above-mentioned printed transfer film with cut out sheet silk fabric fit, together put into flat transfer machine, temperature is transferred to 150 ℃, pressure is transferred to 25Kg/cm
2, after the transfer printing, lining to be put into steam box with transfer film evaporated 45 minutes, temperature is 102 ℃.At last, tear transfer film, postprocessing working procedures such as wash, finish transfer printing.
By test, every fastness index of the pattern behind the stamp sees Table 2, and is few with the weak effect of wet transfer printing.
Table 2
Embodiment 3:
Vinyl pyrrolidone-vinyl acetate copolymer (water-soluble EVA hot melt adhesive) and water-soluble polyester hot melting glue were mixed by weight 3: 2, be dissolved in water, be made into 15% solution, add 1.5% ammonium sulfate, 20% urea, with knife type coater solution is evenly coated on the PET film, the oven dry rolling is standby again.Buy ready-made reactive yellow ink-jet ink again, select the flower type, the rattan air brushing machine of useing force carries out ink-jet printed.Above-mentioned printed transfer film is cut into the ready-made clothes size, fits with the woollen sweater ready-made clothes of wetting oven dry in advance, put into flat transfer machine, temperature is transferred to 160 ℃, and pressure is transferred to 30Kg/cm
2, after the transfer printing, tear transfer film off, with lining with put into steam box and evaporated 60 minutes, temperature is 102 ℃.Postprocessing working procedures such as wash at last, finish transfer printing.
By test, every fastness index of the pattern behind the stamp sees Table 3, and is few with the weak effect of wet transfer printing.
Table 3
Embodiment 4:
Water-soluble poval hot melt adhesive and polyethylene glycol were mixed by weight 5: 1, in water-soluble and 2: 1 the solvent of alcohol volume ratio, be made into 20% solution, the malic acid of adding 1%, 4% urea is coated on the blank sheet of paper of 100 grams with coating machine again, and the oven dry rolling is standby.Again with cationic blue x-grrl 10%, sodium alginate 5%, water 85% is made into ink by weight percentage, selects the flower type, behind the intaglio press impressing pattern, rolling.Above-mentioned printed transfer paper is fitted with the acrylic fibers lining of wetting oven dry in advance, together put into the pulley type transfer machine, temperature is transferred to 75 ℃, and pressure is transferred to 50Kg/cm
2, after the transfer printing, lining to be put into steam box with transfer paper evaporated 60 minutes, temperature is 102 ℃.At last, tear transfer paper, postprocessing working procedures such as wash, finish transfer printing.
By test, every fastness index of the pattern behind the stamp sees Table 4, and is few with the weak effect of wet transfer printing.
Table 4
Embodiment 5:
Water soluble polyamide hot melt adhesive and polyethylene glycol oxide weight ratio are mixed at 10: 1, and with methyl alcohol 40%, the dissolving of water 60% volume content mixed solution is made into 20% (w/w) solution, coat on the nylon membrane with intaglio press, and oven dry, rolling is standby.Again with disperse red 2BL 5%, carboxymethyl starch 5%, water 90% is made into ink by weight percentage, selects the flower type, behind the flat screen printing machine impressing pattern, rolling.Above-mentioned printed transfer film and polyester knitting cloth are fitted, together enter the pulley type heat transfer machine, temperature is transferred to 120 ℃, and pressure is transferred to 30Kg/cm
2, after the transfer printing, nylon membrane is torn off, putting into temperature is that 230 ℃ of baking ovens baked 3 minutes, washing, transfer printing is finished in typing.
By test, every fastness index of the pattern behind the stamp sees Table 5, and is few with the weak effect of wet transfer printing.
Table 5
Embodiment 6:
Water-soluble polyester hot melting glue is mixed with the polyethylene glycol weight ratio at 1: 1, use water-soluble, be made into 2% (w/w) solution, add the niter cake of 2% (w/w), the urea of 8% (w/w) is coated on the blank sheet of paper with intaglio press, oven dry, and rolling is standby.Again with reactive black kn-b 20%, sodium alginate 5%, water 75% is made into ink by weight percentage, selects the flower type, behind the rotary screen printing machines impressing pattern, rolling.Above-mentioned printed transfer paper and marten hair fur coat are fitted, together enter the pulley type heat transfer machine, temperature is transferred to 120 ℃, and pressure is transferred to 15Kg/cm
2, after the transfer printing, fur coat is put into steam box with transfer paper, temperature is 95 ℃ again, the time is to evaporate under the condition in 20 minutes, tears blank sheet of paper at last, postprocessing working procedures such as washes, and finishes transfer printing.
By test, every fastness index of the pattern behind the stamp sees Table 6, and is few with the weak effect of wet transfer printing.
Table 6
Embodiment 7:
With water soluble polyamide hot melt adhesive water-soluble, be made into 10% (w/w) solution, add 2% sodium trichloroacetate, 20% urea is coated on the PET film paper with the scraper type coating machine, oven dry, rolling is standby.Again with reactive black kn-b 20%, sodium alginate 5%, water 75% is made into ink by weight percentage, selects the flower type, behind the rotary screen printing machines impressing pattern, rolling.Above-mentioned printed transfer film and cotton Woven Fabrics are fitted, together enter the pulley type heat transfer machine, temperature is transferred to 160 ℃, and pressure is transferred to 20Kg/cm
2, after the transfer printing that lining is with transfer paper reverse side dewing, good with plastic film wrapped again, prevent moisture loss, put into 15 ℃ of thermostatic chambers, cold dome 16 hours tears counterdie at last, postprocessing working procedures such as washes, and finishes transfer printing.
By test, every fastness index of the pattern behind the stamp sees Table 7, and is few with the weak effect of wet transfer printing.
Table 7
Embodiment 8:
Soluble polyurethane hot melt adhesive and polyethylene glycol were mixed by weight 5: 1, add V: V and be in 50: 50 the water and ethanol, be made into the solution of 10% (w/w), add ammonium sulfate 4% (w/w) again, calcium chloride 6% (w/w), with knife type coater polyethylene oxide solutions is evenly coated on the PET film, rolling is standby again.Buy the ready-made acid ink-jet ink of Hangzhou Hong Hua Digit again, select the flower type, the rattan air brushing machine of useing force carries out ink-jet printed.Above-mentioned printed transfer film is cut into the ready-made clothes size, fits with nylon swimsuit ready-made clothes, put into flat transfer machine, temperature is transferred to 160 ℃, and pressure is transferred to 30Kg/cm
2, after the transfer printing, tear transfer film off, with lining with put into steam box and evaporated 60 minutes, temperature is 102 ℃.Postprocessing working procedures such as wash at last, finish transfer printing.
By test, every fastness index of the pattern behind the stamp sees Table 8, and is few with the weak effect of wet transfer printing.
Table 8
Embodiment 9:
Polyethylene glycol oxide and vinyl pyrrolidone-vinyl acetate copolymer were mixed by weight 3: 1, mixed solution dissolving with ethanol 40% (v/v) and water 60% (v/v) is made into 20% (w/w) solution, coats on the nylon membrane with intaglio press, oven dry, rolling is standby.Again with disperse red 2BL 5%, carboxymethyl starch 5%, water 90% is made into ink by weight percentage, selects the flower type, behind the flat screen printing machine impressing pattern, rolling.Above-mentioned printed transfer film and polyester knitting cloth are fitted, together enter the pulley type heat transfer machine, temperature is transferred to 100 ℃, and pressure is transferred to 30Kg/cm
2, after the transfer printing, nylon membrane is torn off, putting into temperature is that 230 ℃ of baking ovens baked 3 minutes, washing, transfer printing is finished in typing.
By test, every fastness index of the pattern behind the stamp sees Table 9, and is few with the weak effect of wet transfer printing.
Table 9
Embodiment 10:
Water-soluble poval hot melt adhesive and polyethylene glycol were mixed by weight 3: 2, use water-soluble, be made into 15% (w/w) solution, the citric acid that adds 1% (w/w), the urea of 5% (w/w) is coated with the scraper type coating machine on the blank sheet of paper of 100 grams, oven dry, rolling is standby.Again with weak acid red B 2%, polyethylene glycol 10%, methyl alcohol 88% is made into printing ink by weight percentage, selects the flower type, behind the intaglio press impressing pattern, rolling.Above-mentioned printed transfer paper is fitted with the silk fabric of having cut out sheet, together put into flat transfer machine, temperature is transferred to 150 ℃, and pressure is transferred to 25Kg/cm
2, after the transfer printing, lining to be put into steam box with transfer paper evaporated 45 minutes, temperature is 102 ℃.At last, tear transfer paper, postprocessing working procedures such as wash, finish transfer printing.
By test, every fastness index of the pattern behind the stamp sees Table 10, and is few with the weak effect of wet transfer printing.
Table 10
Claims (10)
1. the transfer method of fabric or fur coat fleece flower type is characterized in that this method comprises the steps:
(1) mixed solution of polymer substance is water-soluble or water and organic solvent adds auxiliary agent according to one of following three kinds of modes of kind different choice of dyestuff and fabric or fur coat fleece and continues mixed solution that dissolving obtains that paper or plastic film are carried out coating, oven dry, clot is standby; Three kinds of modes are:
A when material to be transferred is cellulose base fiber fabric or real silk fabric, adds the water absorbing agent of the alkaline agent, 2～25% (w/w) of 0.5～10% (w/w) when dyestuff is a cotton reactive dye in the solution of above-mentioned polymer substance;
B when dyestuff be ACID DYES, reactive dye for wool, polyamide fibre with REACTIVE DYES or cation dyes, when material to be transferred is real silk fabric, wool fabric, nylon fabric, acrylic fabric or fur coat fleece, in the solution of above-mentioned polymer substance, add the water absorbing agent of the sour agent, 2～25% (w/w) of 0.5～10% (w/w);
It is DISPERSE DYES that c works as dyestuff, and material to be transferred is a dacron, does not add any auxiliary agent;
Wherein, described polymer substance is a water-soluble hot-melt adhesive, perhaps the mixture of any one or a few in polyethylene glycol, polypropylene oxide, polyethylene glycol oxide, end-blocking polyethylene glycol oxide, end-blocking polypropylene oxide and the end-blocking polyethylene glycol and water-soluble hot-melt adhesive;
(2) utilize dye ink or dyestuff ink that paper or the plastic film that step (1) obtains carried out stamp, make transfer paper or transfer film;
(3) with printing surface and the fabric or the applying of fur coat fleece of transfer paper or transfer film, together enter transfer machine, heating, pressurization realize stamp;
(4) earlier transfer paper or transfer film are peeled off, carried out the dyestuff set again; Perhaps, carry out the dyestuff set earlier, again transfer paper or transfer film are peeled off;
(5) transfer printing is finished in fabric or fur coat fleece are washed, finalized the design processing.
2. the transfer method of fabric according to claim 1 or fur coat fleece flower type is characterized in that described organic solvent is an intensive polar solvent in the step (1), comprises any one or a few the mixing in acetonitrile, methyl alcohol, acetone and the ethanol.
3. the transfer method of fabric according to claim 1 or fur coat fleece flower type is characterized in that in the step (1), and it is the solution of 1～40% (w/w) that described polymer substance mixed solution water-soluble or water and organic solvent forms concentration.
4. the transfer method of fabric according to claim 1 or fur coat fleece flower type, it is characterized in that in the step (1), described alkaline agent is the material that energy ionization generates hydroxide ion in solution, and it comprises inorganic base, organic base, basic salt or strong base-weak acid salt; Described water absorbing agent is the material of energy deliquescence suction in air, and it comprises urea, glycerine, calcium chloride or magnesium chloride; Described sour agent is for ionization producing hydrionic material in solution, it comprises organic acid, inorganic acid, acid salt or strong acid weak base salt.
5. the transfer method of fabric according to claim 1 or fur coat fleece flower type, it is characterized in that in the step (1), described water-soluble hot-melt adhesive is a water-soluble polyester hot melting glue, the soluble polyurethane hot melt adhesive, the water soluble polyamide hot melt adhesive, vinyl pyrrolidone-vinyl acetate copolymer, water-soluble poly vinyl acetate hot melt adhesive, the water-soluble poval hot melt adhesive, water-soluble ethylene-vinyl acetate copolymer hot melt adhesive, water-soluble poly oxirane graft copolymerization body heat melten gel, water-soluble vinyl acetate-ethylene alcohol hot melt adhesive, the combination of any one or a few in water-soluble vinyl acetate-butenol hot melt adhesive; Described end-blocking polyethylene glycol oxide is that hydroxyl in the polyethylene glycol oxide is by etherificate, esterification, carboxylated, amination or nitration; Described end-blocking polypropylene oxide is that hydroxyl in the polypropylene oxide is by etherificate, esterification, carboxylated, amination or nitration; Described end-blocking polyethylene glycol is that hydroxyl in the polyethylene glycol is by etherificate, esterification, carboxylated, amination or nitration.
6. the transfer method of fabric according to claim 1 or fur coat fleece flower type is characterized in that in the step (1) that described plastic film is PET film, BOPP film, PE film or nylon membrane.
7. the transfer method of fabric according to claim 1 or fur coat fleece flower type is characterized in that described dye ink comprises following components in weight percentage in the step (2): dyestuff 0.1～60% connects material 1～20%, organic solvent 20～98.9%.
8. the transfer method of fabric according to claim 1 or fur coat fleece flower type is characterized in that in the step (2), described dyestuff ink comprises following components in weight percentage: dyestuff 0.1～30% connects material 1～20%, water 50～98.9%.
9. the transfer method of fabric according to claim 1 or fur coat fleece flower type is characterized in that in the step (2) that the stamp mode is intaglio plate stamp, PLATE SCREAM PRINTING, ROTARY SCREAM PRINTING, flexographic plate stamp or ink-jet printed.
10. the transfer method of fabric according to claim 1 or fur coat fleece flower type is characterized in that in the step (3), after fabric to be transferred or fur coat fleece and transfer paper or transfer film together enter transfer machine, is heated to 70～250 ℃, is forced into 0.5～50Kg/cm
2
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110038659 CN102199888B (en) | 2010-09-28 | 2011-02-11 | Method for transferring patterns of fabrics or fur quilts |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201010298984 | 2010-09-28 | ||
| CN201010298984.8 | 2010-09-28 | ||
| CN201010576619 | 2010-11-26 | ||
| CN201010576619.9 | 2010-11-26 | ||
| CN 201110038659 CN102199888B (en) | 2010-09-28 | 2011-02-11 | Method for transferring patterns of fabrics or fur quilts |
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| CN102199888A true CN102199888A (en) | 2011-09-28 |
| CN102199888B CN102199888B (en) | 2013-03-20 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2010106214345A Expired - Fee Related CN102199887B (en) | 2010-09-28 | 2010-12-27 | Transfer printing method for textile pattern |
| CN 201110038659 Expired - Fee Related CN102199888B (en) | 2010-09-28 | 2011-02-11 | Method for transferring patterns of fabrics or fur quilts |
| CN 201110062531 Expired - Fee Related CN102191701B (en) | 2010-09-28 | 2011-03-09 | Method for transferring fabric or fur indumentum pattern |
| CN2011100891214A Expired - Fee Related CN102154857B (en) | 2010-09-28 | 2011-04-04 | Method for transferring patterns of fabric |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2010106214345A Expired - Fee Related CN102199887B (en) | 2010-09-28 | 2010-12-27 | Transfer printing method for textile pattern |
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| Application Number | Title | Priority Date | Filing Date |
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| CN 201110062531 Expired - Fee Related CN102191701B (en) | 2010-09-28 | 2011-03-09 | Method for transferring fabric or fur indumentum pattern |
| CN2011100891214A Expired - Fee Related CN102154857B (en) | 2010-09-28 | 2011-04-04 | Method for transferring patterns of fabric |
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| CN103790031A (en) * | 2014-01-21 | 2014-05-14 | 长兴新峰印染有限公司 | Process for dyeing and finishing seat cushion made of anti-static suede fabric |
| TWI738699B (en) * | 2016-01-04 | 2021-09-11 | 英商尼克瓦格斯有限公司 | Improved method of dye clearing textiles |
| CN111117360A (en) * | 2020-01-02 | 2020-05-08 | 张道亮 | Water-based hot melt adhesive ink for digital printing and digital printing manufacturing process |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102154857A (en) | 2011-08-17 |
| CN102199888B (en) | 2013-03-20 |
| CN102191701B (en) | 2013-05-08 |
| CN102191701A (en) | 2011-09-21 |
| CN102154857B (en) | 2012-05-09 |
| CN102199887A (en) | 2011-09-28 |
| CN102199887B (en) | 2012-07-11 |
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