CN102154857B - Method for transferring patterns of fabric - Google Patents
Method for transferring patterns of fabric Download PDFInfo
- Publication number
- CN102154857B CN102154857B CN2011100891214A CN201110089121A CN102154857B CN 102154857 B CN102154857 B CN 102154857B CN 2011100891214 A CN2011100891214 A CN 2011100891214A CN 201110089121 A CN201110089121 A CN 201110089121A CN 102154857 B CN102154857 B CN 102154857B
- Authority
- CN
- China
- Prior art keywords
- fabric
- transfer
- cellulose
- dyestuff
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 69
- 238000000034 method Methods 0.000 title claims abstract description 40
- 238000012546 transfer Methods 0.000 claims abstract description 75
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 28
- 238000007639 printing Methods 0.000 claims abstract description 21
- 229920000642 polymer Polymers 0.000 claims abstract description 17
- 239000000126 substance Substances 0.000 claims abstract description 16
- 239000003960 organic solvent Substances 0.000 claims abstract description 12
- 238000005406 washing Methods 0.000 claims abstract description 11
- 239000002985 plastic film Substances 0.000 claims abstract description 10
- 229920006255 plastic film Polymers 0.000 claims abstract description 10
- 239000011259 mixed solution Substances 0.000 claims abstract description 8
- 239000011248 coating agent Substances 0.000 claims abstract description 6
- 238000000576 coating method Methods 0.000 claims abstract description 6
- 238000010438 heat treatment Methods 0.000 claims abstract description 4
- 238000012545 processing Methods 0.000 claims abstract description 4
- 239000000975 dye Substances 0.000 claims description 66
- 238000010023 transfer printing Methods 0.000 claims description 35
- 239000000243 solution Substances 0.000 claims description 23
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 14
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 claims description 13
- 239000001863 hydroxypropyl cellulose Substances 0.000 claims description 13
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 claims description 13
- 239000000985 reactive dye Substances 0.000 claims description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 229920003086 cellulose ether Polymers 0.000 claims description 12
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 11
- 239000006096 absorbing agent Substances 0.000 claims description 10
- 239000000835 fiber Substances 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 9
- -1 hydroxypropyl hydroxybutyl Chemical group 0.000 claims description 9
- 150000003839 salts Chemical class 0.000 claims description 9
- 239000000986 disperse dye Substances 0.000 claims description 8
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 7
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 claims description 7
- 239000004952 Polyamide Substances 0.000 claims description 7
- 239000000980 acid dye Substances 0.000 claims description 7
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims description 7
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims description 7
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims description 7
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims description 7
- 229920002647 polyamide Polymers 0.000 claims description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 6
- 229920000742 Cotton Polymers 0.000 claims description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- 239000012752 auxiliary agent Substances 0.000 claims description 6
- 239000004202 carbamide Substances 0.000 claims description 6
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 6
- 150000001768 cations Chemical class 0.000 claims description 6
- 229920002678 cellulose Polymers 0.000 claims description 6
- 239000001913 cellulose Substances 0.000 claims description 6
- 210000002268 wool Anatomy 0.000 claims description 6
- RPZANUYHRMRTTE-UHFFFAOYSA-N 2,3,4-trimethoxy-6-(methoxymethyl)-5-[3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxyoxane;1-[[3,4,5-tris(2-hydroxybutoxy)-6-[4,5,6-tris(2-hydroxybutoxy)-2-(2-hydroxybutoxymethyl)oxan-3-yl]oxyoxan-2-yl]methoxy]butan-2-ol Chemical compound COC1C(OC)C(OC)C(COC)OC1OC1C(OC)C(OC)C(OC)OC1COC.CCC(O)COC1C(OCC(O)CC)C(OCC(O)CC)C(COCC(O)CC)OC1OC1C(OCC(O)CC)C(OCC(O)CC)C(OCC(O)CC)OC1COCC(O)CC RPZANUYHRMRTTE-UHFFFAOYSA-N 0.000 claims description 5
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 claims description 5
- 239000004677 Nylon Substances 0.000 claims description 5
- 101150107144 hemC gene Proteins 0.000 claims description 5
- 229920000609 methyl cellulose Polymers 0.000 claims description 5
- 235000010981 methylcellulose Nutrition 0.000 claims description 5
- 239000001923 methylcellulose Substances 0.000 claims description 5
- 229920001778 nylon Polymers 0.000 claims description 5
- 229920004934 Dacron® Polymers 0.000 claims description 4
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 4
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 4
- 239000012528 membrane Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 4
- 229920002799 BoPET Polymers 0.000 claims description 3
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 3
- 229920000896 Ethulose Polymers 0.000 claims description 3
- 239000001856 Ethyl cellulose Substances 0.000 claims description 3
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 claims description 3
- 239000001859 Ethyl hydroxyethyl cellulose Substances 0.000 claims description 3
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 3
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 229920006378 biaxially oriented polypropylene Polymers 0.000 claims description 3
- 239000011127 biaxially oriented polypropylene Substances 0.000 claims description 3
- 239000001110 calcium chloride Substances 0.000 claims description 3
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 3
- 229920003090 carboxymethyl hydroxyethyl cellulose Polymers 0.000 claims description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 3
- 229940105329 carboxymethylcellulose Drugs 0.000 claims description 3
- 235000019325 ethyl cellulose Nutrition 0.000 claims description 3
- 229920001249 ethyl cellulose Polymers 0.000 claims description 3
- 235000019326 ethyl hydroxyethyl cellulose Nutrition 0.000 claims description 3
- 235000010944 ethyl methyl cellulose Nutrition 0.000 claims description 3
- 239000001761 ethyl methyl cellulose Substances 0.000 claims description 3
- 235000011187 glycerol Nutrition 0.000 claims description 3
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 3
- 150000007522 mineralic acids Chemical class 0.000 claims description 3
- 150000007524 organic acids Chemical class 0.000 claims description 3
- 239000002798 polar solvent Substances 0.000 claims description 3
- RPAJSBKBKSSMLJ-DFWYDOINSA-N (2s)-2-aminopentanedioic acid;hydrochloride Chemical compound Cl.OC(=O)[C@@H](N)CCC(O)=O RPAJSBKBKSSMLJ-DFWYDOINSA-N 0.000 claims description 2
- 150000001447 alkali salts Chemical class 0.000 claims description 2
- 238000013461 design Methods 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 2
- 150000007529 inorganic bases Chemical class 0.000 claims description 2
- 238000010030 laminating Methods 0.000 claims description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 2
- 150000007530 organic bases Chemical class 0.000 claims description 2
- 238000013404 process transfer Methods 0.000 claims description 2
- 229920006184 cellulose methylcellulose Polymers 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 238000001035 drying Methods 0.000 abstract 1
- 239000001041 dye based ink Substances 0.000 abstract 1
- 239000000976 ink Substances 0.000 abstract 1
- 238000004513 sizing Methods 0.000 abstract 1
- 239000002699 waste material Substances 0.000 description 20
- 230000000052 comparative effect Effects 0.000 description 18
- 239000007788 liquid Substances 0.000 description 18
- 238000012360 testing method Methods 0.000 description 13
- 238000005096 rolling process Methods 0.000 description 12
- 239000002202 Polyethylene glycol Substances 0.000 description 10
- 229920001223 polyethylene glycol Polymers 0.000 description 10
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
- 238000005516 engineering process Methods 0.000 description 9
- 101000598921 Homo sapiens Orexin Proteins 0.000 description 8
- 101001123245 Homo sapiens Protoporphyrinogen oxidase Proteins 0.000 description 8
- 102100029028 Protoporphyrinogen oxidase Human genes 0.000 description 8
- 238000003912 environmental pollution Methods 0.000 description 6
- 238000012805 post-processing Methods 0.000 description 6
- 238000009736 wetting Methods 0.000 description 5
- 238000004043 dyeing Methods 0.000 description 4
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 3
- POJOORKDYOPQLS-UHFFFAOYSA-L barium(2+) 5-chloro-2-[(2-hydroxynaphthalen-1-yl)diazenyl]-4-methylbenzenesulfonate Chemical compound [Ba+2].C1=C(Cl)C(C)=CC(N=NC=2C3=CC=CC=C3C=CC=2O)=C1S([O-])(=O)=O.C1=C(Cl)C(C)=CC(N=NC=2C3=CC=CC=C3C=CC=2O)=C1S([O-])(=O)=O POJOORKDYOPQLS-UHFFFAOYSA-L 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- 235000015165 citric acid Nutrition 0.000 description 3
- LQJVOKWHGUAUHK-UHFFFAOYSA-L disodium 5-amino-4-hydroxy-3-phenyldiazenylnaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].OC1=C2C(N)=CC(S([O-])(=O)=O)=CC2=CC(S([O-])(=O)=O)=C1N=NC1=CC=CC=C1 LQJVOKWHGUAUHK-UHFFFAOYSA-L 0.000 description 3
- TUXJTJITXCHUEL-UHFFFAOYSA-N disperse red 11 Chemical compound C1=CC=C2C(=O)C3=C(N)C(OC)=CC(N)=C3C(=O)C2=C1 TUXJTJITXCHUEL-UHFFFAOYSA-N 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 238000009940 knitting Methods 0.000 description 3
- 235000010413 sodium alginate Nutrition 0.000 description 3
- 239000000661 sodium alginate Substances 0.000 description 3
- 229940005550 sodium alginate Drugs 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- DHKHKXVYLBGOIT-UHFFFAOYSA-N 1,1-Diethoxyethane Chemical compound CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000000370 acceptor Substances 0.000 description 2
- 239000011354 acetal resin Substances 0.000 description 2
- 125000003368 amide group Chemical group 0.000 description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 2
- 235000011130 ammonium sulphate Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 238000007731 hot pressing Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 229920006324 polyoxymethylene Polymers 0.000 description 2
- 238000010022 rotary screen printing Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229920002972 Acrylic fiber Polymers 0.000 description 1
- 241000345998 Calamus manan Species 0.000 description 1
- SREKYKXYSQMOIB-UHFFFAOYSA-N N-carbamoylsarcosine Chemical compound NC(=O)N(C)CC(O)=O SREKYKXYSQMOIB-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- SAQSTQBVENFSKT-UHFFFAOYSA-M TCA-sodium Chemical compound [Na+].[O-]C(=O)C(Cl)(Cl)Cl SAQSTQBVENFSKT-UHFFFAOYSA-M 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- HGAZMNJKRQFZKS-UHFFFAOYSA-N chloroethene;ethenyl acetate Chemical compound ClC=C.CC(=O)OC=C HGAZMNJKRQFZKS-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 238000010021 flat screen printing Methods 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 1
- 235000019799 monosodium phosphate Nutrition 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 235000012950 rattan cane Nutrition 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- YNJBWRMUSHSURL-UHFFFAOYSA-N trichloroacetic acid Chemical compound OC(=O)C(Cl)(Cl)Cl YNJBWRMUSHSURL-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Abstract
The invention discloses a method for transferring patterns of a fabric. The method comprises the following steps of: dissolving a polymer substance in water or a mixed solution of water and an organic solvent, coating paper or a plastic film, drying, and coiling for later use; printing on the paper or the plastic film with dye-based ink or dye-based water ink to obtain transfer paper or a transfer film; jointing the printing surface of the transfer paper or the transfer film with a fabric to be transferred, putting the transfer paper or the transfer film and the fabric into a transfer machine, heating and pressurizing to realize printing; stripping the transfer paper or the transfer film and fixing a dye; or fixing the dye and then stripping the transfer paper or the transfer film; and washing the fabric with water and sizing to finish transferring. By adopting the transferring method disclosed by the invention, the inherent transfer thought is broken through, the humidification procedure is eliminated, the processing time is saved, the production cost is lowered, and the printing difficulty is lowered.
Description
Technical field
The present invention relates to a kind of dyeing method of fabric, relate in particular to a kind of transfer method of fabric flower type.
Background technology
Traditional textiles thermal transfer printing method starts from late 1960s.It is that the DISPERSE DYES that will distil easily earlier are imprinted on the transfer printing base stock, and then with modes such as hot pressing, the DISPERSE DYES distillation is transferred on the fabric, forms a kind of printing method of pattern.It has, and colored type is true to nature, and technology is simple, advantage that three waste discharge is few or the like.It is only applicable to the stamp of dacron, at polyamide fibre, and acrylic fibers, and poor effect on the natural fabric.
In order to realize the TRANSFER PRINTING of natural fabric, the wet transfer printing of REACTIVE DYES and ACID DYES has obtained domestic and international many colourists' attention.Patent 200410041034.1, and patent 200510026661.2 all discloses a kind of wet transfer printing method of natural fabric separately.Patent 200710025329.3 also discloses the wet transfer printing method of a kind of natural fabric and nylon fabric.
But they all have more jointly, must be earlier that fabric to be transferred is wetting, more under pressure; Make on the lining with moisture dissolving transfer paper or the water-soluble dye on the transfer film, last or cold dome, or decatize; Or bake, dyestuff is combined with fiber, accomplish TRANSFER PRINTING.
And wet transfer printing is in implementation process, and the humidity control when fabric is wetting has suitable difficulty, because fabric variety is numerous; Thickness differs greatly; Institutional framework closely differs, and very easily because the wetting dye transfer that causes inadequately is bad, or humidity causes colored pattern to stick with paste drawbacks such as unclear too greatly.
Under this background; Chinese patent 201010519572.2 has proposed a kind of brand-new thermal transfer mode and has overcome the above problems, and proposes in this patent with coating paper or plastic film after polyethylene glycol oxide or PPOX dissolving or the fusion, as transfer substrate; To be printed on the transfer substrate with the corresponding dyestuff of fabric to be transferred through mode of printing again; Simultaneously fabric to be transferred is handled with water absorbing agent and sour agent or alkaline agent, under hot pressing, made polyethylene glycol oxide or PPOX fusion, be with dyestuff to get in the fabric fibre; Make the dyestuff set through post processing at last, accomplish TRANSFER PRINTING.
Yet the molecular formula of polyethylene glycol oxide is H-(OCH
2CH
2-)
n-OH, PPOX are HO-[(C
3H
6)-O-] n-H, contain a large amount of ehter bonds in their molecule.At first,, very strong hydrogen bond affinity is arranged, can form complex compound with the monomer or the polymer of some electron acceptors owing on the ether oxygen atom unshared electron pair is arranged in the polymerization long-chain.And all contain a large amount of electron acceptors in the dyestuff that uses in the printing and dyeing industry.Secondly, ehter bond also will with amido (NH
2) and hydroxyl (generation coordinate bond or hydrogen bonded OH).And all contain a large amount of amido (NH in the dyestuff that uses in the printing and dyeing industry
2) and hydroxyl (OH).Moreover particularly the terminal hydroxy group of two kinds of materials has very strong activity, also can consume a large amount of REACTIVE DYES during the cellulose fibre stamp.So, as base material, can combine a large amount of dyestuffs to cause the dyestuff dye-uptake low with polyethylene glycol oxide or PPOX, Dry Sack is shallow, and a large amount of wastes of dyestuff, gets in the waste water when finally washing, and pollutes.
In addition, in the thermal transfer printing method that Chinese patent 201010519572.2 proposes, being transferred fabric will anticipate with water absorbing agent and sour agent (or alkaline agent) earlier, the technology trouble.
Summary of the invention
Technical problem to be solved by this invention provides a kind of transfer method of fabric flower type and controls a difficult difficult problem with the humidity that the solution fabric wet transfer printing exists, and dye utilization rate is high, uses more convenient, more succinct thermal transfer printing mode.
For solving the problems of the technologies described above, thinking of the present invention is to select for use the polymer substance that is difficult for combining with dyestuff to replace polyethylene glycol oxide and PPOX, raising dye utilization rate, raising stamp tinctorial yield and stamp COLOR FASTNESS.Simplify printing technology in addition, be transferred fabric and need do not do preliminary treatment, directly transfer printing.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is following:
A kind of transfer method of fabric flower type comprises the steps:
(1) mixed solution of polymer substance is water-soluble or water and organic solvent adds auxiliary agent according to one of following three kinds of modes of the different choice of dyestuff and fabric types to be transferred and continues mixed solution that dissolving obtains that paper or plastic film are carried out coating, oven dry, clot is subsequent use; Three kinds of modes are:
It is cotton reactive dye that a works as dyestuff; When fabric to be transferred is cotton or real silk fabric; The water absorbing agent (the percentage implication is the ratio of weight of solution of weight and the polymer substance of single auxiliary agent) that in the solution of above-mentioned polymer substance, adds the alkaline agent, 1～20% (w/w) of 1～5% (w/w) preferably adds the water absorbing agent of the alkaline agent, 8～15% (w/w) of 2～4% (w/w);
It is that ACID DYES, reactive dye for wool, polyamide fibre are with REACTIVE DYES or cation dyes that b works as dyestuff; Fabric to be transferred is real silk, wool, polyamide fibre or acrylic fabric; The water absorbing agent (the percentage implication is the ratio of weight of solution of weight and the polymer substance of single auxiliary agent) that in the solution of above-mentioned polymer substance, adds the sour agent, 5～20% (w/w) of 0.5～6% (w/w) preferably adds the water absorbing agent of the sour agent, 8～15% (w/w) of 2～3% (w/w);
It is DISPERSE DYES that c works as dyestuff, and fabric to be transferred is a dacron, does not add any auxiliary agent;
Wherein, described alkaline agent is the material that ability ionization generates hydroxide ion in solution, and it generally comprises inorganic base, organic base, several types of basic salt or strong base-weak acid salts.What use was maximum in printing with reactive dye is strong base-weak acid salt, and it mainly contains following several kinds of materials: sodium bicarbonate, sodium trichloroacetate, saleratus, potash, tertiary sodium phosphate or soda ash.Described water absorbing agent is the material of ability deliquescence suction in air, and it generally comprises urea, glycerine, urea, calcium chloride or magnesium chloride.Described sour agent is for ionization producing hydrionic material in solution, it comprises organic acid, inorganic acid, and several types of acid salt or strong acid weak base salts etc., wherein organic acid is generally formic acid, acetate, oxalic acid, citric acid, malic acid, trichloroacetic acid or the like.Inorganic acid is generally hydrochloric acid, sulfuric acid, phosphoric acid, nitric acid or the like.Acid salt is generally niter cake, sodium dihydrogen phosphate or the like.Strong acid weak base salt is generally ammonium sulfate etc.
Wherein, described polymer substance is a cellulose ether, and can must have thermoplasticity as the cellulose ether of hot transfer printing, comprises any one or a few the mixture in single cellulose ether and the mixed cellulose ethers.Described single cellulose ether is methylcellulose (MC), ethyl cellulose (EC), CMC (HMC), hydroxyethylcellulose (HEC), hydroxypropyl cellulose (HPC), carboxymethyl cellulose (CMC) or cyanethyl cellulose (CEC) etc.; Mixed cellulose ethers is ethylhydroxyethylcellulose (EHEC); Ethylmethylcellulose (EMC); HEMC (HEMC); Hydroxypropyl methylcellulose (HPMC); Hydroxy butyl methyl cellulose (HBMC); Hydroxypropyl hydroxybutyl cellulose (HPHBC); Ethoxy CMC (HEHMC); Ethoxy hydroxypropyl cellulose (HEHPC); Carboxymethyl CMC (CMHMC); Carboxymethyl hydroxyethyl cellulose (CMHEC); Methylol hydroxypropyl cellulose (CMHPC); Methylol hydroxybutyl cellulose (CMHBC); Carboxy methyl cellulose (CMMC) or carboxymethylethylcellulose etc.
(2) utilize dye ink or dyestuff ink that paper or the plastic film that step (1) obtains carried out stamp, process transfer paper or transfer film;
(3) with the printing surface and the fabric laminating to be transferred of transfer paper or transfer film, together get into transfer machine, heating, pressurization realize stamp;
(4) earlier transfer paper or transfer film are peeled off, carried out the dyestuff set again; Perhaps, carry out the dyestuff set earlier, again transfer paper or transfer film are peeled off;
(5), accomplish transfer printing with the fabric processing of washing, finalize the design.
In the step (1), described organic solvent is an intensive polar solvent, comprises but is not limited to like acetonitrile, methyl alcohol, acetone and ethanol etc.
In the step (1), it is the solution of 1～40% (w/w) that said polymer substance mixed solution water-soluble or water and organic solvent forms concentration.
In the step (1), described plastic film is PET film, BOPP film, PE film or nylon membrane.
In the step (2), described dye ink comprises following components in weight percentage: dyestuff 0.1～60% connects material 1～20%; Organic solvent 20～98.9%; Preferably comprise following components in weight percentage: dyestuff 2～30% connects material 2～15%, organic solvent 55～96%.Wherein, dyestuff is REACTIVE DYES, ACID DYES, cation dyes or the DISPERSE DYES that are difficult for distillation; Connecting material is the polymer substance that can be dissolved in organic solvent and can form viscous solution, and it includes but not limited to polyvinyl acetal resin, vinyl chloride-vinyl acetate resin, polyethylene glycol and cellulosic plastics etc.; Organic solvent is the intensive polar solvent of ability dissolving dye, and it includes but not limited to methyl alcohol, ethanol, oxolane etc.
In the step (2), described dyestuff ink comprises following components in weight percentage: dyestuff 0.1～30%, connect material 1～20%, and water 50～98.9% preferably comprises following components in weight percentage: dyestuff 2～20% connects material 2～20%, water 60～96%.Wherein, dyestuff is REACTIVE DYES, ACID DYES, cation dyes or the DISPERSE DYES that are difficult for distillation; Connecting material is the polymer substance that can be dissolved in water and can form viscous solution, and it includes but not limited to sodium alginate, sodium carboxymethylcellulose, CMS etc.
In the step (2), the stamp mode is intaglio plate stamp, PLATE SCREAM PRINTING, ROTARY SCREAM PRINTING, flexographic plate stamp or ink-jet printed.
Those skilled in the art can prepare corresponding dye ink or ink according to the difference of fabric fibre kind to be transferred, select the stamp mode that is fit to.For example cellulose fibre, wool, polyamide fibre, real silk fabric can be used REACTIVE DYES; Polyamide fibre, wool, real silk fabric can be used ACID DYES; Acrylic fabric can be used cation dyes; Dacron can be used DISPERSE DYES; The use of printing ink or ink is accustomed to adjustment according to shop equipment and workman; These all are technology well known in the art.Technology of the present invention is not directed against certain specific fabric or limits the prescription and the stamp mode of printing ink, ink; And being intended to change the printing and dyeing flow process of being used to, fabric that uses in the existing transfering printing process and supporting dye formulation and stamp mode thereof all are applicable to process of the present invention.
In the step (3), be heated to 70～250 ℃, preferred 150～200 ℃, be forced into 0.5～50Kg/cm
2, preferred 15～30Kg/cm
2
In the step (3), fabric to be transferred can the rolling transfer printing, can the garment piece transfer printing, and also can the ready-made clothes transfer printing.
In the step (3), transfer machine can be a pulley type, also can be flat.
In the step (4), dyestuff set mode has dewing cold dome, decatize or bakes.Those skilled in the art can be according to the corresponding dyestuff set of the different choice of transfer printing fabric mode; For example three kinds of set modes of REACTIVE DYES all can adopt; ACID DYES and cation dyes only can adopt the set of decatize mode; DISPERSE DYES can adopt decatize or bake the mode set, and above-mentioned dyestuff set mode all is a technology well known to those skilled in the art.
Through technical scheme of the present invention; Those skilled in the art can not need carry out wetting, oven dry preliminary treatment to the fabric to be transferred in the step (3), promptly do not need to use in advance the Wetting Solution of different formulations to handle fabric to be transferred and need be to the process of its oven dry.Through technical scheme of the present invention, can make fabric to be transferred without any processing, printing surface direct and transfer paper or transfer film is fitted, and together gets into transfer machine, and heating, pressurization realize stamp.
Beneficial effect: method for transfer printing of the present invention, broken through intrinsic transfer printing thinking, saved this program of dewing, saved process time, reduced production cost, reduced the dye transfer difficulty.Because be that dry type shifts, its flower shape fineness is far superior to wet transfer printing, has thoroughly solved wet method and has shifted the difficult problem that can not be applied to the ready-made clothes stamp.
The specific embodiment
According to following embodiment, can understand the present invention better.Yet, those skilled in the art will readily understand that the described concrete material proportion of embodiment, process conditions and result thereof only are used to explain the present invention, and the present invention that should also can not limit in claims to be described in detail.
Embodiment 1:
Hydroxypropyl methylcellulose is used water-soluble, be made into 10% (w/w) solution, add 2% sodium bicarbonate, 6% urea is coated with the scraper type coating machine on the blank sheet of paper of 100 grams, oven dry, and rolling is subsequent use.Again with reactive black kn-b20%, sodium alginate 5%, water 75% is made into ink by weight percentage, selects the flower type, behind the rotary screen printing machines impressing pattern, rolling.Above-mentioned printed transfer paper and all-cotton knitting cloth are fitted, together get into the pulley type heat transfer machine, temperature is transferred to 120 ℃, and pressure is transferred to 15Kg/cm
2, after the transfer printing that lining is with transfer paper reverse side dewing, good with plastic film wrapped again, prevent moisture loss, put into 15 ℃ of thermostatic chambers, cold dome 16 hours tears base stock at last, postprocessing working procedures such as washes, and accomplishes TRANSFER PRINTING.
Through test, each item fastness index of the pattern behind the stamp is seen table 1.(GB19817-2005) (GB18401-2003), wherein light fastness is 8 grades with " national textile product basic security technical specification national standard " according to " textiles, FURNISHING FABRIC national standard ", and 1 grade the poorest, and 8 grades best.All the other are 5 grades, and 1 grade the poorest, and 5 grades best, and following form is identical.
Table 1
Comparative Examples 1:
Identical with embodiment 1, different is to replace hydroxypropyl methylcellulose with PPOX.
Through test, each item fastness index of the pattern behind the stamp is seen table 2.
Table 2
The washing waste liquid of embodiment 1 and Comparative Examples 1 is tested dye strength in the waste liquid through spectrophotometer; Detect according to GB 2393-80 " method of testing of thickening agent degree of fixation "; Following examples are identical; The dye-uptake of finding the reactive black kn-b of Comparative Examples 1 is 40%, and the dye-uptake of the reactive black kn-b of embodiment 1 is 85%.Significantly reduce the dye strength in the waste liquid, reduced environmental pollution.
Embodiment 2:
Methylcellulose and hydroxypropyl cellulose were mixed by weight 5: 1, with (V/V) dissolving in 1: 1 of second alcohol and water, be made into 30% (w/w) solution, add 7% glycerine, 2% citric acid is coated on the BOPP film with intaglio press, oven dry, and rolling is subsequent use.Again with weak acid red B 0.5%, polyvinyl acetal resin 10%, methyl alcohol 89.5% is made into printing ink by weight percentage, selects the flower type, behind the intaglio press impressing pattern, rolling.Above-mentioned printed transfer film is fitted with having cut out the sheet silk fabric, together put into flat transfer machine, temperature is transferred to 150 ℃, and pressure is transferred to 25Kg/cm
2, after the transfer printing, lining to be put into steam box with transfer film evaporated 45 minutes, temperature is 102 ℃.At last, tear transfer film, postprocessing working procedures such as wash, accomplish TRANSFER PRINTING.
Through test, each item fastness index of the pattern behind the stamp is seen table 3.
Table 3
Comparative Examples 2:
Identical with embodiment 2, different is with polyethylene glycol oxide replacement methylcellulose and hydroxypropyl cellulose.
Through test, each item fastness index of the pattern behind the stamp is seen table 4.
Table 4
The washing waste liquid of embodiment 2 and Comparative Examples 2 is tested dye strength in the waste liquid through spectrophotometer, find that the dye-uptake of the weak acid red B of Comparative Examples 2 is 60%, and the dye-uptake of the weak acid red B of embodiment 2 is 95%.Significantly reduce the dye strength in the waste liquid, reduced environmental pollution.
Embodiment 3:
With methyl alcohol 40%, the dissolving of water 60% volume content mixed solution is made into 20% (w/w) solution with hydroxypropyl methylcellulose, coat on the nylon membrane with intaglio press, and oven dry, rolling is subsequent use.Again with disperse red 2BL 5%, CMS 5%, water 90% is made into ink by weight percentage, selects the flower type, behind the flat screen printing machine impressing pattern, rolling.Above-mentioned printed transfer film and polyester knitting cloth are fitted, together get into the pulley type heat transfer machine, temperature is transferred to 120 ℃, and pressure is transferred to 30Kg/cm
2, after the transfer printing, nylon membrane is torn off, putting into temperature is that 230 ℃ of baking ovens baked 3 minutes, washing, TRANSFER PRINTING is accomplished in typing.
Through test, each item fastness index of the pattern behind the stamp is seen table 5.
Table 5
Comparative Examples 3:
Identical with embodiment 3, different is to replace hydroxypropyl methylcellulose with polyethylene glycol oxide.
Through test, each item fastness index of the pattern behind the stamp is seen table 6.
Table 6
The washing waste liquid of embodiment 3 and Comparative Examples 3 finds that through dye strength in the spectrophotometer test waste liquid dye-uptake of Comparative Examples 5 disperse red 2BL is 44%, and the dye-uptake of the disperse red 2BL of embodiment 5 is 89%.Significantly reduce the dye strength in the waste liquid, reduced environmental pollution.
Embodiment 4:
Hydroxypropyl cellulose is used water-soluble, be made into 2% (w/w) solution, add the sodium bicarbonate of 2% (w/w), the urea of 8% (w/w) is coated on the blank sheet of paper with intaglio press, oven dry, and rolling is subsequent use.Again with reactive red k-2bp20%, sodium alginate 3%, water 77% is made into ink by weight percentage, selects the flower type, behind the rotary screen printing machines impressing pattern, rolling.Above-mentioned printed transfer paper and all-cotton knitting cloth are fitted, together get into the pulley type heat transfer machine, temperature is transferred to 120 ℃, and pressure is transferred to 15Kg/cm
2, after the transfer printing, lining to be put into steam box with transfer paper evaporate, temperature is 105 ℃, 15 minutes time, tear blank sheet of paper at last, postprocessing working procedures such as wash, accomplish TRANSFER PRINTING.
Through test, each item fastness index of the pattern behind the stamp is seen table 7.
Table 7
Comparative Examples 4:
Identical with embodiment 3, different is with PPOX alkene replacement hydroxypropyl cellulose.
Through test, each item fastness index of the pattern behind the stamp is seen table 8.
Table 8
The washing waste liquid of embodiment 4 and Comparative Examples 4 is tested dye strength in the waste liquid through spectrophotometer, find that the dye-uptake of the reactive red k-2bp of Comparative Examples 4 is 46%, and the dye-uptake of the reactive red k-2bp of embodiment 4 is 78%.Significantly reduce the dye strength in the waste liquid, reduced environmental pollution.
Embodiment 5:
Hydroxypropyl cellulose and HEMC were mixed by weight 3: 2, use water-soluble, be made into 15% (w/w) solution; The citric acid that adds 1% (w/w), the urea of 5% (w/w) is coated with the scraper type coating machine on the blank sheet of paper of 100 grams; Oven dry, rolling is subsequent use.Again with cationic brilliant red B 2%, polyethylene glycol 10%, methyl alcohol 88% is made into printing ink by weight percentage, selects the flower type, behind the intaglio press impressing pattern, rolling.Above-mentioned printed transfer paper is fitted with the silk fabric of having cut out sheet, together put into flat transfer machine, temperature is transferred to 150 ℃, and pressure is transferred to 25Kg/cm
2, after the transfer printing, lining to be put into steam box with transfer paper evaporated 45 minutes, temperature is 102 ℃.At last, tear transfer paper, postprocessing working procedures such as wash, accomplish TRANSFER PRINTING.
Through test, each item fastness index of the pattern behind the stamp is seen table 9.
Table 9
Comparative Examples 5:
Identical with embodiment 5, different is with polyethylene glycol oxide replacement hydroxypropyl cellulose and HEMC.
Through test, each item fastness index of the pattern behind the stamp is seen table 10.
Table 10
The washing waste liquid of embodiment 5 and Comparative Examples 5 is tested dye strength in the waste liquid through spectrophotometer, find that the dye-uptake of the cationic brilliant red B of Comparative Examples 5 is 51%, and the dye-uptake of the cationic brilliant red B of embodiment 4 is 88%.Significantly reduce the dye strength in the waste liquid, reduced environmental pollution.
Embodiment 6:
With hydroxy butyl methyl cellulose, add V: V and be in 50: 50 the water and ethanol, be made into the solution of 10% (w/w), add ammonium sulfate 4% (w/w) again, calcium chloride 6% (w/w) is evenly coated solution on the PET film with knife type coater again, and rolling is subsequent use.Buy ready-made reactive yellow ink-jet ink again, select the flower type, the rattan air brushing machine of useing force carries out ink-jet printed.Above-mentioned printed transfer film is cut into the ready-made clothes size, fits with the woollen sweater ready-made clothes, put into flat transfer machine, temperature is transferred to 160 ℃, and pressure is transferred to 30Kg/cm
2, after the transfer printing, tear transfer film off, with lining with put into steam box and evaporated 60 minutes, temperature is 102 ℃.Postprocessing working procedures such as wash at last, accomplish TRANSFER PRINTING.
Through test, each item fastness index of the pattern behind the stamp is seen table 11.
Table 11
Comparative Examples 6:
Identical with embodiment 6, different is to replace hydroxy butyl methyl cellulose with PPOX.
Through test, each item fastness index of the pattern behind the stamp is seen table 12.
Table 12
The washing waste liquid of embodiment 6 and Comparative Examples 6 is tested dye strength in the waste liquid through spectrophotometer, find that the dye-uptake of the reactive yellow of Comparative Examples 6 is 55%, and the dye-uptake of the reactive yellow of embodiment 4 is 96%.Significantly reduce the dye strength in the waste liquid, reduced environmental pollution.
Claims (10)
1. the transfer method of a fabric flower type is characterized in that this method comprises the steps:
(1) mixed solution of polymer substance is water-soluble or water and organic solvent adds auxiliary agent according to one of following three kinds of modes of the different choice of dyestuff and fabric types to be transferred and continues mixed solution that dissolving obtains that paper or plastic film are carried out coating, oven dry, clot is subsequent use; Three kinds of modes are:
A when fabric to be transferred is cotton or real silk fabric, adds the water absorbing agent of the alkaline agent, 1～20% (w/w) of 1～5% (w/w) when dyestuff is a cotton reactive dye in the solution of above-mentioned polymer substance;
It is that ACID DYES, reactive dye for wool, polyamide fibre are with REACTIVE DYES or cation dyes that b works as dyestuff; Fabric to be transferred is real silk, wool, polyamide fibre or acrylic fabric, in the solution of above-mentioned polymer substance, adds the water absorbing agent of the sour agent, 5～20% (w/w) of 0.5～6% (w/w);
It is DISPERSE DYES that c works as dyestuff, and fabric to be transferred is a dacron, does not add any auxiliary agent;
Wherein, described alkaline agent is the material that ability ionization generates hydroxide ion in solution, comprises inorganic base, organic base, basic salt or strong base-weak acid salt; Described water absorbing agent is the material of ability deliquescence suction in air, comprises urea, glycerine, calcium chloride or magnesium chloride; Described sour agent is for ionization producing hydrionic material in solution, it comprises organic acid, inorganic acid, acid salt or strong acid weak base salt;
Wherein, described polymer substance is a cellulose ether;
(2) utilize dye ink or dyestuff ink that paper or the plastic film that step (1) obtains carried out stamp, process transfer paper or transfer film;
(3) with the printing surface and the fabric laminating to be transferred of transfer paper or transfer film, together get into transfer machine, heating, pressurization realize stamp;
(4) earlier transfer paper or transfer film are peeled off, carried out the dyestuff set again; Perhaps, carry out the dyestuff set earlier, again transfer paper or transfer film are peeled off;
(5), accomplish transfer printing with the fabric processing of washing, finalize the design.
2. the transfer method of fabric according to claim 1 flower type is characterized in that in the step (1), and described cellulose ether is any one or a few the mixture in single cellulose ether and the mixed cellulose ethers.
3. the transfer method of fabric flower type according to claim 2 is characterized in that described single cellulose ether is methylcellulose, ethyl cellulose, CMC, hydroxyethylcellulose, hydroxypropyl cellulose, carboxymethyl cellulose or cyanethyl cellulose.
4. the transfer method of fabric flower type according to claim 2 is characterized in that described mixed cellulose ethers is ethylhydroxyethylcellulose, ethylmethylcellulose, HEMC, hydroxypropyl methylcellulose, hydroxy butyl methyl cellulose, hydroxypropyl hydroxybutyl cellulose, ethoxy CMC, ethoxy hydroxypropyl cellulose, carboxymethyl CMC, carboxymethyl hydroxyethyl cellulose, methylol hydroxypropyl cellulose, methylol hydroxybutyl cellulose, carboxy methyl cellulose or carboxymethylethylcellulose.
5. the transfer method of fabric according to claim 1 flower type is characterized in that described organic solvent is an intensive polar solvent in the step (1), comprises any one or a few the mixing in acetonitrile, methyl alcohol, acetone and the ethanol.
6. the transfer method of fabric flower type according to claim 1 is characterized in that in the step (1), and it is the solution of 1～40% (w/w) that polymer substance mixed solution water-soluble or water and organic solvent forms concentration.
7. the transfer method of fabric flower type according to claim 1 is characterized in that in the step (1) that described plastic film is PET film, BOPP film, PE film or nylon membrane.
8. the transfer method of fabric flower type according to claim 1 is characterized in that described dye ink comprises following components in weight percentage in the step (2): dyestuff 0.1～60% connects material 1～20%, organic solvent 20～98.9%.
9. the transfer method of fabric flower type according to claim 1 is characterized in that in the step (2), described dyestuff ink comprises following components in weight percentage: dyestuff 0.1～30% connects material 1～20%, water 50～98.9%.
10. the transfer method of fabric flower type according to claim 1 is characterized in that after fabric to be transferred and transfer paper or transfer film together get into transfer machine, being heated to 70～250 ℃ in the step (3), is forced into 0.5～50Kg/cm
2
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| CN201010298984 | 2010-09-28 | ||
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| CN201010576619 | 2010-11-26 | ||
| CN2011100891214A CN102154857B (en) | 2010-09-28 | 2011-04-04 | Method for transferring patterns of fabric |
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| CN 201110038659 Expired - Fee Related CN102199888B (en) | 2010-09-28 | 2011-02-11 | Method for transferring patterns of fabrics or fur quilts |
| CN 201110062531 Expired - Fee Related CN102191701B (en) | 2010-09-28 | 2011-03-09 | Method for transferring fabric or fur indumentum pattern |
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| CN 201110062531 Expired - Fee Related CN102191701B (en) | 2010-09-28 | 2011-03-09 | Method for transferring fabric or fur indumentum pattern |
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- 2011-03-09 CN CN 201110062531 patent/CN102191701B/en not_active Expired - Fee Related
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Also Published As
| Publication number | Publication date |
|---|---|
| CN102191701B (en) | 2013-05-08 |
| CN102199888B (en) | 2013-03-20 |
| CN102154857A (en) | 2011-08-17 |
| CN102199888A (en) | 2011-09-28 |
| CN102199887B (en) | 2012-07-11 |
| CN102191701A (en) | 2011-09-21 |
| CN102199887A (en) | 2011-09-28 |
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