CN1198014C - Cotton fabric thermal transfer printing method - Google Patents

Cotton fabric thermal transfer printing method Download PDF

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Publication number
CN1198014C
CN1198014C CN 02159176 CN02159176A CN1198014C CN 1198014 C CN1198014 C CN 1198014C CN 02159176 CN02159176 CN 02159176 CN 02159176 A CN02159176 A CN 02159176A CN 1198014 C CN1198014 C CN 1198014C
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China
Prior art keywords
transfer printing
thermal transfer
cotton fabric
printing method
fabric
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Expired - Fee Related
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CN 02159176
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Chinese (zh)
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CN1417405A (en
Inventor
王红凤
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Beijing Institute Fashion Technology
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Beijing Institute Fashion Technology
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Priority to CN 02159176 priority Critical patent/CN1198014C/en
Publication of CN1417405A publication Critical patent/CN1417405A/en
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Publication of CN1198014C publication Critical patent/CN1198014C/en
Anticipated expiration legal-status Critical
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Abstract

The present invention discloses a thermal transfer printing method for a cotton fabric, which belongs to a printing and dyeing technique. A fabric dipping rolling and bridging agent is first preprocessed by the method, paper printed with a pattern or a metal foil, and a fabric preprocessed are mutually stuck, and are thermally pressed on a transfer printing machine for a short time, and a flower color pattern with bright and firm colors can be printed on the fabric. The fabric is soft and washable, and is comfortable to wear. The method is a clean printing and dyeing technique which has no damage to the skin of a human body and no environment pollution, and has general popularization and application value.

Description

A kind of thermal transfer printing method of COTTON FABRIC
Technical field
The invention belongs to the printing technology field, particularly can on fabric, carry out a kind of thermal transfer printing method of COTTON FABRIC of the cleaning dyeing and printing process of transfer printing
Background technology
Thermal transfer printing is a kind of in the textile printing process.It is that fabric is pasted mutually with the thermal transfer printing paper that is printed on floral designs, hot pressing on heat transfer machine, and the decorative pattern on the paper is transferred on the fabric.The outstanding advantage of this printing method be not water consumption, do not produce sewage.But this method can not be printed the fabric of including natural fibers such as cotton, because do not have adhesion between this kind fabric and the dyestuff that can heat shifts.In order to realize the thermal transfer printing of fabrics such as cotton, forefathers have done big quantity research.Chinese patent 96108188 (application number, still unauthorized) can be realized thermal transfer printing after having reported the finishing agent preliminary treatment of natural fabric via benzene dicarboxylic acid ester, polyethylene glycol and water composition.By the textile figured cloth that this method is printed, color wither dark and also soaping fastness undesirable.In addition; the somebody carries out the method for acetylation grafting, resin spraying and swelling to COTTON FABRIC; achieve thermal transfer printing, but these methods all because of fabric be badly damaged, poisonous or feel is hardened or dyefastness not as reason such as people's will, obtain as yet so far to use in batches.
Summary of the invention
The purpose of this invention is to provide a kind of thermal transfer printing method of COTTON FABRIC, it is characterized in that: described COTTON FABRIC is carried out preliminary treatment, hot transfer printing on heat transfer machine then through bridging agent FY-3 earlier; The prescription of described bridging agent FY-3 is:
Coupling agent 0.01-50%; Surfactant 2-20%; Preservative agent 0.3-10%; Modifying agent 0.02-30%; The diluent surplus.
Coupling agent in the described prescription is one or more mixtures in the following material: aliphatic acid and derivative thereof, such as: stearate, laurate; Polyalcohol and derivative thereof, such as: polyethylene glycol, glycerol, three acid anhydride alcohol, three acid anhydride alcohol esters; Acid amides and derivative thereof, such as: urea, acrylamide; Benzoic acid and derivative thereof, such as: propyl benzoate, methyl benzoate.
Surfactant in the described prescription is the chemical substance with effects such as infiltration and softnesses, such as: aliphatic acid polyethenoxy ether, fatty alcohol-polyoxyethylene ether, C 7-9Alkanol polyoxyethylene (5-6) ether, secondary octanol polyoxyethylene ether, open loop fatty amine salt type, primary, the second month in a season, uncle, quaternary amine all can, copolymer, octadecylamine derivative, long-chain fat amine, the organic silicon emulsion of lignosulfonates, acrylic acid and acrylamide.
Modifying agent in the described prescription can use one or both mixtures in organic or inorganic ultraviolet absorber or the screener: such as: hydroquinones, benzophenone, guaiac resin, tetra-butyl hydroxy anisole, magnesia.
Sterilization in the described prescription, preservative agent can use various low toxicities or the innocuous substance with anticorrosion and sterilizing function, such as: benzoic acid, sorbic acid and its esters; One or both mixtures in the p-hydroxybenzoate:
Diluent in the described prescription is a kind of in the following kind: running water; Underground water; Distilled water; Deionized water.
Described pretreating process is: on traditional padding machine and on traditional Tentering and Drying Machinery or the baker to the preliminary treatment of building bridge of the fabric of cotton and including natural fibers, can take soak to roll more, soak more according to equipment more and one roll, one soak and one roll, two soak two and roll, pretreatment condition is: room temperature is padded, 50 ℃ of-200 ℃ of dryings and/or bake.
Described caloric transfer printing technology is: temperature: 100 ℃-280 ℃; Time: 1s-120s; Pressure: 1-5atm. or vacuum 680mmHg, because of equipment different different.
The invention has the beneficial effects as follows that by this method the fabrics of printing such as cotton have gay colours, good dye fastness and dye and the comfortable performance of wearing, and can realize cleaner production.
The specific embodiment
The present invention is a kind of thermal transfer printing method of COTTON FABRIC, and promptly elder generation carries out preliminary treatment, hot transfer printing on heat transfer machine then to the fabric of cotton and including natural fibers through bridging agent FY-3.The prescription of described bridging agent FY-3 is: coupling agent 0.01-50%; Surfactant 2-20%; Preservative agent 0.3-10%; Modifying agent 0.02-30%; The diluent surplus.
Coupling agent in the described prescription is one or more mixtures in the following material: aliphatic acid and derivative thereof, such as: stearate, laurate; Polyalcohol and derivative thereof, such as: polyethylene glycol, glycerol, three acid anhydride alcohol, three acid anhydride alcohol esters; Acid amides and derivative thereof, such as: urea, acrylamide; Benzoic acid and derivative thereof, such as: propyl benzoate, methyl benzoate.
Surfactant in the described prescription is the chemical substance with effects such as infiltration and softnesses, such as: aliphatic acid polyethenoxy ether, fatty alcohol-polyoxyethylene ether, C 7-9Alkanol polyoxyethylene (5-6) ether, secondary octanol polyoxyethylene ether, open loop fatty amine salt type, primary, the second month in a season, uncle, quaternary amine all can, copolymer, octadecylamine derivative, long-chain fat amine, the organic silicon emulsion of lignosulfonates, acrylic acid and acrylamide.
Modifying agent in the described prescription can use one or both mixtures in organic or inorganic ultraviolet absorber or the screener: such as: hydroquinones, benzophenone, guaiac resin, tetra-butyl hydroxy anisole, magnesia.
Sterilization in the described prescription, preservative agent can use various low toxicities or the innocuous substance with anticorrosion and sterilizing function, such as: one or both mixtures in the following kind: benzoic acid, sorbic acid and its esters; P-hydroxybenzoate.
Diluent in the described prescription is a kind of in the following kind: running water; Underground water; Distilled water; Deionized water.
Described pretreating process is: on traditional padding machine and traditional Tentering and Drying Machinery or bake the preliminary treatment of building bridge of the fabric of including natural fibers such as cotton, can take soak to roll more, soak more according to equipment more and one roll, one soak and one roll, two soak two and roll, pretreatment condition is: room temperature is padded, 50 ℃ of-200 ℃ of dryings and/or bake.
Described caloric transfer printing technology is: temperature: 100 ℃-280 ℃; Time: 1s-120s; Pressure: 1-5atm. or vacuum 680mmHg, because of equipment different different.The embodiment that carries out pretreated bridging agent FY-3 for the fabric to cotton and including natural fibers is again illustrated the present invention below:
Embodiment 1
Coupling agent: stearate, 15%; Surfactant: aliphatic acid polyethenoxy ether 4%; Modifying agent: hydroquinones 0.5%; Preservative agent: benzoic acid 0.5%; Diluent: running water, 80%.
Embodiment 2
Coupling agent: polyethylene glycol, 20%; Surfactant: fatty alcohol-polyoxyethylene ether 5%; Modifying agent: UV-531,0.02%; Preservative agent: benzoic acid 0.3%; Diluent: running water, 74.68%.
Embodiment 3
Coupling agent: urea 10%; Surfactant: lignin sodium sulfonate 2%; Modifying agent: magnesia 3%; Preservative agent: p-hydroxybenzoate 1%; Diluent: underground water 84%.
Embodiment 4
Coupling agent: methyl benzoate 7%; Surfactant: lignin sodium sulfonate 2%; Modifying agent: benzophenone 1%; Preservative agent: p-hydroxybenzoate 1%; Diluent: underground water 89%.

Claims (7)

1. the thermal transfer printing method of a COTTON FABRIC is characterized in that: described COTTON FABRIC is carried out preliminary treatment, hot transfer printing on heat transfer machine then through bridging agent FY-3 earlier; The prescription of described bridging agent FY-3 is: coupling agent 0.01-50%; Surfactant 2-20%; Preservative agent 0.3-10%; Modifying agent 0.02-30%; The diluent surplus.
2. according to the thermal transfer printing method of the described COTTON FABRIC of claim 1, it is characterized in that: the coupling agent in the described prescription is one or more mixtures in the following material: aliphatic acid and derivative thereof: stearate, laurate; Polyalcohol and derivative thereof: polyethylene glycol, glycerol, three acid anhydride alcohol, three acid anhydride alcohol esters; Acid amides and derivative thereof: urea, acrylamide; Benzoic acid and derivative thereof: propyl benzoate, methyl benzoate.
3. according to the thermal transfer printing method of the described COTTON FABRIC of claim 1, it is characterized in that: the surfactant in the described prescription is: aliphatic acid polyethenoxy ether, fatty alcohol-polyoxyethylene ether, C 7-9Alkanol polyoxyethylene (5-6) ether, secondary octanol polyoxyethylene ether, open loop fatty amine salt type, primary, the second month in a season, uncle, quaternary amine all can, copolymer, octadecylamine derivative, long-chain fat amine, the organic silicon emulsion of lignosulfonates, acrylic acid and acrylamide.
4. according to the thermal transfer printing method of the described COTTON FABRIC of claim 1, it is characterized in that: the modifying agent in the described prescription can use one or both mixtures in organic or inorganic ultraviolet absorber or the screener: hydroquinones, benzophenone, guaiac resin, tetra-butyl hydroxy anisole, magnesia.
5. according to the thermal transfer printing method of the described COTTON FABRIC of claim 1, it is characterized in that: the sterilization in the described prescription, preservative agent are for using one or both mixtures in the following kind: benzoic acid, sorbic acid and its esters; P-hydroxybenzoate.
6. according to the thermal transfer printing method of the described COTTON FABRIC of claim 1, it is characterized in that: the diluent in the described prescription is a kind of in the following kind: running water; Underground water; Distilled water; Deionized water.
7. according to the thermal transfer printing method of the described COTTON FABRIC of claim 1, it is characterized in that: described caloric transfer printing technology is: carry out earlier pretreating process promptly on traditional padding machine and on traditional Tentering and Drying Machinery or the baker to the preliminary treatment of building bridge of the fabric of cotton and including natural fibers, can take soak to roll more, soak more according to equipment more and one roll, one soak and one roll, two soak two and roll, pretreatment condition is: room temperature is padded, 50 ℃ of-200 ℃ of dryings and/or bake; Again 100 ℃-280 ℃ of temperature; Time 1s-120s; Pressure 1-5atm.Or hot transfer printing on heat transfer machine under the vacuum 680mmHg.
CN 02159176 2002-12-30 2002-12-30 Cotton fabric thermal transfer printing method Expired - Fee Related CN1198014C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 02159176 CN1198014C (en) 2002-12-30 2002-12-30 Cotton fabric thermal transfer printing method

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Application Number Priority Date Filing Date Title
CN 02159176 CN1198014C (en) 2002-12-30 2002-12-30 Cotton fabric thermal transfer printing method

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CN1417405A CN1417405A (en) 2003-05-14
CN1198014C true CN1198014C (en) 2005-04-20

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100482884C (en) * 2007-04-19 2009-04-29 四川大学 Surface modifier for transfer printing with dispersive cotton fabric dye and its pre-treatment method

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100485122C (en) * 2004-11-15 2009-05-06 邹恒余 Transfer printing and dyeing process for cellulose fiber fabric needing no bridging agent
CN102199887B (en) * 2010-09-28 2012-07-11 刘静 Transfer printing method for textile pattern
CN102304862B (en) * 2011-07-15 2013-03-20 北京印月明印染新技术有限公司 Printing technology for pure cotton or polyester-cotton jean
CN102535209B (en) * 2011-12-16 2013-08-14 江南大学 Method for improving fluorescence properties of disperse fluorescent dye transfer printing of fabric by using ultraviolet light and epoxy-amine cationic resin joint method
CN102965912B (en) * 2012-11-20 2016-05-25 江南大学 Be suitable for cotton type fabric thermal transfer printing alkaline reaction type silicon titanium colloidal sol preparation method
CN103343462B (en) * 2013-06-26 2015-12-23 泗县恒星网印烫画机械有限公司 A kind of pure cotton toner and preparation method thereof
CN103461375A (en) * 2013-09-02 2013-12-25 朱文潮 Novel wool mothproofing agent and preparation method thereof
CN103757923B (en) * 2014-01-17 2015-11-25 许鲁 A kind of heat-transferring method based on COTTON FABRIC
CN103898778B (en) * 2014-04-28 2016-08-17 邢凤平 Sublimation transfer printing process of natural fabric or rayon
CN105926327A (en) * 2016-05-25 2016-09-07 南通富之岛寝具发展有限公司 Cotton fabric printing technology
CN109281197B (en) * 2018-09-11 2020-09-25 辽宁恒星精细化工有限公司 Acrylate emulsion modifier for thermal transfer printing of cotton fabric disperse dye and preparation method thereof
CN110130129B (en) * 2019-05-08 2022-05-17 北京印月明印染新技术有限公司 Natural fiber fabric heat transfer printing method and heat transfer printing system
CN111218826B (en) * 2020-03-05 2022-04-08 天津丽彩数字技术有限公司 Cotton fabric heat transfer printing pretreating agent and heat transfer printing method
CN115094652B (en) * 2022-07-04 2023-11-14 广州迅捷数码科技有限责任公司 Thermal transfer printing method for fabric

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100482884C (en) * 2007-04-19 2009-04-29 四川大学 Surface modifier for transfer printing with dispersive cotton fabric dye and its pre-treatment method

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