CN102965912B - Be suitable for cotton type fabric thermal transfer printing alkaline reaction type silicon titanium colloidal sol preparation method - Google Patents
Be suitable for cotton type fabric thermal transfer printing alkaline reaction type silicon titanium colloidal sol preparation method Download PDFInfo
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- CN102965912B CN102965912B CN201210516631.XA CN201210516631A CN102965912B CN 102965912 B CN102965912 B CN 102965912B CN 201210516631 A CN201210516631 A CN 201210516631A CN 102965912 B CN102965912 B CN 102965912B
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Abstract
The invention discloses a kind of cotton type fabric thermal transfer printing alkaline reaction type silicon titanium colloidal sol preparation method of being suitable for, belong to technical field of textile chemical engineering. After the thermal transfer printing of pretreated cotton type fabric, its color depth and colour brightness significantly improve, and fabric sofetening washable, wear comfortable. Simultaneously the method be without sewage discharge, clean printing technology to human body skin without injury, there are general promotion and application and be worth.
Description
Technical field
A kind of applicable cotton type fabric thermal transfer printing alkaline reaction type silicon titanium colloidal sol preparation method, belongs to weavingizationField learns a skill.
Background technology
Thermal transfer printing is to utilize the heat sublimation performance of disperse dyes by fabric and the figuratum transfer printing paper of sealContact, carry out hot pressing on transfer printing machine, disperse dyes leave transfer paper by sublimation, more solidifyingMagnificent to fabric, thus realize the transfer of dyestuff from calico paper to fabric. Not water consumption, also not of this printing techniqueProduce sewage, cleanliness without any pollution. But this printing technique can only be applied on dacron, because of disperse dyesTo cotton type fabric without affinity, so can not be applied on cotton type fabric. In order to realize the transfer of cotton type fabricStamp, patent CN02159176.81 discloses a kind of method of bafta thermal transfer printing, and the method is with fabricPad FY-3 bridging agent and carry out pretreatment, thereby realize pattern to the transfer on bafta. Heat shifts printingTextile design lovely luster, color pattern fastness is good, and fabric sofetening can be washed. Patent CN200710048901.8The preparation and the transfer printing that disclose a kind of surface modifier for transfer printing with dispersive cotton fabric dye are pretreatedMethod, for the method, bridging agent, pH adjusting agent, modifying agent, swelling agent and diluent carry out bafta in advanceProcess. The textile design of printing is bright-coloured, and color fastness is high, and harmless. At present existing to fabricPreconditioning technique generally adopt the organic polymer of complicated component or compound as bridging agent, its synthetic workSkill is more complicated, and has human body and Environmental security hidden danger, and therefore general promotion and application are worth and are restricted.
By sol-gel doping techniques, the alkylene oxide type quaternary ammonium salt of response type is hybridized to inorganic nanoparticlesIn silicon titanium colloidal sol for main component, preparation alkaline reaction type silicon titanium colloidal sol, and for fabric treating to realizeDisperse pattern on the transfer printing paper of dye transfer system to the transfer on cotton type fabric.
Summary of the invention
The object of the invention is to provide a kind of cotton type fabric thermal transfer printing alkaline reaction type silicon titanium colloidal sol system that is suitable forPreparation Method, specific experiment method is as follows:
1. in conical flask, add successively 21-30 weight portion ethyl orthosilicate, 9-21 weight portion absolute ethyl alcohol, stirMixing evenly, is solution A; By 10-25 weight portion absolute ethyl alcohol, 10-30 parts by weight of deionized water and 8-13 weightPart 1mol/L ammonia spirit mixes and stirs, and is solution B; By the coupling agent of 2-5 weight portion and 1-5 weightPart cation quaternary ammonium salt is at room temperature dissolved in 5-15 part deionized water, stirs, and be solution C; StirringUnder condition, solution B is dropwise added drop-wise in solution A, stirs 30min, then solution C is dropwise added drop-wise toState in mixed liquor, at room temperature continuous stirring 48h, obtains alkaline kation silicon dioxide gel;
Described coupling agent is polyethylene glycol, glycerine, urea;
Described cation quaternary ammonium salt is 2,3-epoxypropyltrimethylchloride chloride, glycidyl phenethyl two (18 acylsAmine ethyl) ammonium chloride, chlorination-2-hydroxyl-3-(three methylaminos) propyl group PEO cellulose ether, 3 '-methylene baseTwo [2,3-glycidyl dimethyl-4 '-hydroxybenzyl] ammonium chloride;
The butyl titanate of 5-12 weight portion is dissolved in the absolute ethyl alcohol of 8-15 weight portion, stirs, for moltenLiquid D; The deionized water of the acetic acid of the 0.5mol/L of 5-10 weight portion and 18-31 weight portion is mixed, stirs,For solution E; Get alkaline kation silicon dioxide gel 43-54 weight portion and be placed in conical flask, by above-mentioned solution DSlowly be added drop-wise to successively in alkaline kation silicon dioxide gel with solution E, under room temperature condition, stir 12h, soRear ageing 120h, obtains alkaline reaction type silicon titanium colloidal sol.
2. a kind of applied heat transfer printing alkaline reaction type silicon titanium colloidal sol described in, is characterized in that the cotton type of employing is knittedThing is cotton and blend fabric thereof.
3. described in, be suitable for its application on cotton type fabric of a kind of thermal transfer printing alkaline reaction type silicon titanium colloidal sol,It is characterized in that adopting the method for spraying or spin coating; After processing, fabric is at 50-60 DEG C of preliminary drying 15-40min.
4. the application of a kind of applied heat transfer printing alkaline reaction type silicon titanium colloidal sol described on cotton type fabric,Its heat transfer technics is: by figuratum seal transfer paper and pretreated cotton type fabric laminating, pave, soAfter at 200-220 DEG C heat treatment 25-40s.
Detailed description of the invention
To contribute to further to understand the present invention by following embodiment, but can not limit of the present invention inHold.
Method of testing, make a concrete analysis of as follows:
(1) K/S value test
By folding 4 layers of PRINTED FABRIC sample, use X-rite8400 type colour photometer CIE-lab chromatic measuring system to existD65 light source, test fabric color Apparent Depth (K/S value) under 10 ° of visual field conditions. Instrument selection before measuringMedium-sized aperture, and rectify an instrument through black and white plate. Each sample test 8 times, results averaged.
Embodiment 1
In conical flask, add successively 23 weight portion ethyl orthosilicates, 18 weight portion absolute ethyl alcohols, stir allEven, be solution A; By 11 weight portion absolute ethyl alcohols, 16 parts by weight of deionized water and 9 weight portion 1mol/LAmmonia spirit mixes and stirs, and is solution B; By the polyethylene glycol of 3 weight portions and 3 weight portions 2,3-Epoxypropyltrimethylchloride chloride is at room temperature dissolved in 15 parts by weight of deionized water, stirs, for moltenLiquid C; Under stirring condition, solution B is dropwise added drop-wise in solution A, stir 30min, then by moltenLiquid C is dropwise added drop-wise in above-mentioned mixed liquor, and at room temperature continuous stirring 48h, obtains alkaline kation dioxySiClx colloidal sol.
The butyl titanate of 6 weight portions is dissolved in the absolute ethyl alcohol of 11 weight portions, stirs, for moltenLiquid D; The deionized water of the acetic acid of the 0.5mol/L of 6 weight portions and 26 weight portions is mixed, stirs,For solution E; Get alkaline kation silicon dioxide gel 51 weight portions and be placed in conical flask, by above-mentioned solution DSlowly be added drop-wise to successively in alkaline kation silicon dioxide gel with solution E, under room temperature condition, stir 12h,Then ageing 120h,, obtain alkaline reaction type silicon titanium colloidal sol.
Pure cotton woven fabric is sprayed to pretreatment with above-mentioned alkaline reaction type silicon titanium colloidal sol, then fabric exists50 DEG C of preliminary drying 25min. Transfer paper and the pretreated pure cotton woven fabric of the red color lump of disperse dyes will be printed onFit, pave then heat treatment 35s at 205 DEG C.
After not pretreated pure cotton woven fabric thermal transfer printing, K/S value is 2.45, and through alkaline reaction type siliconAfter the pretreated pure cotton woven fabric thermal transfer printing of titanium colloidal sol, K/S value is 10.05.
Embodiment 2
In conical flask, add successively 28 weight portion ethyl orthosilicates, 14 weight portion absolute ethyl alcohols, stir,For solution A; By 14 weight portion absolute ethyl alcohols, 22 parts by weight of deionized water and 10 weight portion 1mol/L ammonia spiritsMixing and stir, is solution B; By 4 weight portion urea and 2 weight portion glycidyl phenethyls two (18Acid amides ethyl) ammonium chloride is at room temperature dissolved in 6 parts by weight of deionized water, stirs, be solution C; StirringMix under condition, solution B is dropwise added drop-wise in solution A, stir 30min, then solution C is dropwise added drop-wise toIn above-mentioned mixed liquor, at room temperature continuous stirring 48h, obtains alkaline kation silicon dioxide gel.
The butyl titanate of 10 weight portions being dissolved in the absolute ethyl alcohol of 14 weight portions, stirring, is solution D;The deionized water of the acetic acid of the 0.5mol/L of 7 weight portions and 23 weight portions being mixed, stir, is solution E;Get alkaline kation silicon dioxide gel 46 weight portions and be placed in conical flask, by above-mentioned solution D and solution E successivelySlowly be added drop-wise in alkaline kation silicon dioxide gel, under room temperature condition, stir 12h, then ageing 120h,Obtain alkaline reaction type silicon titanium colloidal sol.
Cotton-polyester blend fabric is carried out to spin coating pretreatment with above-mentioned alkaline reaction type silicon titanium colloidal sol, then fabric exists60 DEG C of preliminary drying 23min. The transfer paper and the pretreated cotton-polyester blend that are printed on the red color lump of disperse dyes are knittedFit, pave then heat treatment 28s at 210 DEG C.
After the thermal transfer printing of not pretreated cotton-polyester blend fabric, K/S value is 4.18, and through alkaline reaction typeAfter the thermal transfer printing of the pretreated cotton-polyester blend fabric of silicon titanium colloidal sol, K/S value is 11.67.
Embodiment 3
In conical flask, add successively 25 weight portion ethyl orthosilicates, 10 weight portion absolute ethyl alcohols, stir allEven, be solution A; By 20 weight portion absolute ethyl alcohols, 15 parts by weight of deionized water and 12 weight portion 1mol/LAmmonia spirit mixes and stirs, and is solution B; By the glycerine of 5 weight portions and 1 weight portion chlorination-2-Hydroxyl-3-(three methylaminos) propyl group PEO cellulose ether is at room temperature dissolved in 12 parts by weight of deionized waterIn, stir, be solution C; Solution A is under magnetic stirrer condition, by solution B dropwiseBe added drop-wise in solution A, stir 30min, then solution C is dropwise added drop-wise in above-mentioned mixed liquor, in chamberThe lower continuous stirring 48h of temperature, obtains alkaline kation silicon dioxide gel.
The butyl titanate of 9 weight portions is dissolved in the absolute ethyl alcohol of 15 weight portions, stirs, for moltenLiquid D; The deionized water of the acetic acid of the 0.5mol/L of 6 weight portions and 25 weight portions is mixed, stirs,For solution E; Get alkaline kation silicon dioxide gel 45 weight portions and be placed in conical flask, by above-mentioned solution DSlowly be added drop-wise to successively in alkaline kation silicon dioxide gel with solution E, under room temperature condition, stir 12h,Then ageing 120h, obtains alkaline reaction type silicon titanium colloidal sol.
Cotton ramie blended spinning fabric is sprayed to pretreatment with above-mentioned alkaline reaction type silicon titanium colloidal sol, then fabric exists55 DEG C of preliminary drying 24min. The transfer paper and the pretreated cotton ramie blended spinning that are printed on the blue color lump of disperse dyes are knittedThing is fitted, is paved then heat treatment 26s at 215 DEG C.
After the thermal transfer printing of not pretreated cotton ramie blended spinning fabric, K/S value is 5.32, and through alkaline reaction typeAfter the thermal transfer printing of the pretreated cotton ramie blended spinning fabric of silicon titanium colloidal sol, K/S value is 9.86.
Claims (4)
1. be suitable for a cotton type fabric thermal transfer printing alkaline reaction type silicon titanium colloidal sol, it is characterized in that adopting as followsMethod preparation:
In conical flask, add successively 21-30 weight portion ethyl orthosilicate, 9-21 weight portion absolute ethyl alcohol, stirEvenly, be solution A; By 10-25 weight portion absolute ethyl alcohol, 10-30 parts by weight of deionized water and 8-13 weight portion1mol/L ammonia spirit mixes and stirs, and is solution B; By the coupling agent of 2-5 weight portion and 1-5 weight portionCation quaternary ammonium salt is at room temperature dissolved in 5-15 part deionized water, stirs, and is solution C; Stirring barUnder part, solution B is dropwise added drop-wise in solution A, stirs 30min, then solution C is dropwise added drop-wise to above-mentionedIn mixed liquor, at room temperature continuous stirring 48h, obtains alkaline kation silicon dioxide gel;
Described coupling agent is glycerine, urea;
Described cation quaternary ammonium salt is 2,3-epoxypropyltrimethylchloride chloride, glycidyl phenethyl two (18 acylsAmine ethyl) ammonium chloride, chlorination-2-hydroxyl-3-(three methylaminos) propyl group PEO cellulose ether, 3 '-methylene baseTwo [2,3-glycidyl dimethyl-4 '-hydroxybenzyl] ammonium chloride;
The butyl titanate of 5-12 weight portion is dissolved in the absolute ethyl alcohol of 8-15 weight portion, stirs, for moltenLiquid D; The deionized water of the acetic acid of the 0.5mol/L of 5-10 weight portion and 18-31 weight portion is mixed, stirs,For solution E; Get alkaline kation silicon dioxide gel 43-54 weight portion and be placed in conical flask, by above-mentioned solution DSlowly be added drop-wise to successively in alkaline kation silicon dioxide gel with solution E, under room temperature condition, stir 12h, soRear ageing 120h, obtains alkaline reaction type silicon titanium colloidal sol.
2. a kind of applied heat transfer printing alkaline reaction type silicon titanium colloidal sol as claimed in claim 1, its featureThat the cotton type fabric adopting is cotton and blend fabric thereof.
3. a kind of applied heat transfer printing alkaline reaction type silicon titanium colloidal sol as claimed in claim 1 is knitted in cotton typeApplication on thing, is characterized in that employing sprays or the method for spin coating; After processing, fabric is at 50-60 DEG C of preliminary drying15-40min。
4. a kind of applied heat transfer printing alkaline reaction type silicon titanium colloidal sol as claimed in claim 1 is knitted in cotton typeApplication on thing, its heat transfer technics is: by the transfer paper with disperse dyes pattern and pretreated cottonType fabric laminating, pave then heat treatment 25-40s at 200-220 DEG C.
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| CN201210516631.XA CN102965912B (en) | 2012-11-20 | 2012-11-20 | Be suitable for cotton type fabric thermal transfer printing alkaline reaction type silicon titanium colloidal sol preparation method |
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| CN102965912B true CN102965912B (en) | 2016-05-25 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103640350A (en) * | 2013-11-25 | 2014-03-19 | 江南大学 | Method for giving turned edge painted design of jeans wear through reverse side transfer printing |
| CN105346295B (en) * | 2015-11-06 | 2018-06-05 | 苏州市智汇宝数码科技有限公司 | A kind of functional distillation transfer printing paper and its preparation method and application |
| CN105862414B (en) * | 2016-04-16 | 2018-06-26 | 山东黄河三角洲纺织科技研究院有限公司 | A kind of method for improving the rich and gaudy degree of pigment printing color and fastness |
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| US5296299A (en) * | 1988-04-23 | 1994-03-22 | Matsubishi Paper Mills Ltd. | Thermal transfer film |
| CN1417405A (en) * | 2002-12-30 | 2003-05-14 | 北京服装学院 | Cotton fabric thermal transfer printing method |
| CN1546781A (en) * | 2003-12-05 | 2004-11-17 | 东华大学 | Composite hydrosol color fixing finishing agent, synthesizing method and use thereof |
| CN101046060A (en) * | 2007-04-19 | 2007-10-03 | 四川大学 | Surface modifier for transfer printing with dispersive cotton fabric dye and its pre-treatment method |
| CN101117765A (en) * | 2007-07-23 | 2008-02-06 | 江南大学 | Gemini type positive ion collosol and method for improving fabric dyeing stability |
| CN101302730A (en) * | 2008-06-06 | 2008-11-12 | 陕西科技大学 | Method for preparing surface sizing strengthening agent |
| CN101363190A (en) * | 2008-09-26 | 2009-02-11 | 江南大学 | Preparation of gemini type composite colloidal sols and applications thereof in UV-preventing and anti-bacteria finishing |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3259078B2 (en) * | 1993-04-27 | 2002-02-18 | 倉庫精練株式会社 | Method for producing printing base fabric having microporous film |
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Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5296299A (en) * | 1988-04-23 | 1994-03-22 | Matsubishi Paper Mills Ltd. | Thermal transfer film |
| CN1417405A (en) * | 2002-12-30 | 2003-05-14 | 北京服装学院 | Cotton fabric thermal transfer printing method |
| CN1546781A (en) * | 2003-12-05 | 2004-11-17 | 东华大学 | Composite hydrosol color fixing finishing agent, synthesizing method and use thereof |
| CN101046060A (en) * | 2007-04-19 | 2007-10-03 | 四川大学 | Surface modifier for transfer printing with dispersive cotton fabric dye and its pre-treatment method |
| CN101117765A (en) * | 2007-07-23 | 2008-02-06 | 江南大学 | Gemini type positive ion collosol and method for improving fabric dyeing stability |
| CN101302730A (en) * | 2008-06-06 | 2008-11-12 | 陕西科技大学 | Method for preparing surface sizing strengthening agent |
| CN101363190A (en) * | 2008-09-26 | 2009-02-11 | 江南大学 | Preparation of gemini type composite colloidal sols and applications thereof in UV-preventing and anti-bacteria finishing |
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