A kind of disperse dye composition and application thereof
Technical field:
The present invention relates to a kind of disperse dye composition, particularly a kind of dispersed dye and application thereof that is applicable to have under alkaline condition good Color.
Background technology:
At present, the dyeing of trevira, more employing dispersed dye dye under solutions of weak acidity, and the defect that this dyeing process exists is: refining, the alkali decrement of trevira before dyeing, and soap boiling and reduction clearing after dyeing all carried out under alkaline condition.Therefore, easily cause that dyeing is uneven in acid bath while dyeing, dye bath pH value fluctuation range is large, can cause the variation of coloured light, and reproducibility is poor.
Also there is part producer to adopt dispersed dye to dye under alkaline condition, dispersed dye can effectively be removed slurry, the finish on polyester textile in alkaline condition dyeing, overcome other degradation production separates out and produces the shortcoming of dying defect as polyester oligomer in acid bath, bring the effect that cloth cover is clean and tidy, Fabric Style is good simultaneously, often do not need reduction clearing can meet fastness requirement.
But, at present, really can be applied to the dispersed dye that dye under alkaline condition very few, trace it to its cause: the one, existing alkaline dispersed dye have larger restriction in textile dyeing application, still can not be applicable to widely entirely wash, wash/cotton and wash spandex and, ultra-fine fibre etc., and obtain good Color; The 2nd, existing alkaline dispersed dye are applicable to the restriction of dyeing, and pre-treating technology and dyeing need to separately carry out, and energy consumption and environmental pollution are larger; The 3rd, the suitability aspect of existing alkaline dispersed dye and other reactive dyestuffs, has larger restriction.
Have based on this, applicant makes this invention, be intended to improve a kind of disperse dye composition, have under alkaline condition and can obtain good Color, and the fabric that is applicable to various styles as entirely washed, wash/cotton and wash spandex and, ultra-fine fibre etc., and can be suitable for One Bath Dyeing Process separately or together with other reactive dyestuffs, and can obtain good Color.
Summary of the invention:
A first aspect of the present invention is to provide a kind of the have fabric that can obtain good Color under alkaline condition and be applicable to various styles, the disperse dye composition that is applicable to One Bath Dyeing Process, comprise that mass ratio is dyestuff and the auxiliary agent of 1: 1~1: 2, described dyestuff be selected from dyestuff I, dyestuff II, dyestuff III, dyestuff IV any one or multiple, wherein:
Dyestuff I is selected from any one or a few of 73# DISPERSE ORANGE 30 200,61# DISPERSE ORANGE 30 200,44# DISPERSE ORANGE 30 200,30# DISPERSE ORANGE 30 200, SF-2G DISPERSE ORANGE 30 200;
Dyestuff II is selected from any one or a few of 356# Disperse Red, 183# Disperse Red, 179# Disperse Red, 145# Disperse Red, 127# Disperse Red, 143# Disperse Red, 82# Disperse Red, 92# Disperse Red, SF-2G Disperse Red, SF-4BN200% dispersed ruby, G-FS Disperse Red;
Dyestuff III is selected from 165# to disperse blue, 148# to disperse blue, 60# to disperse emerald green blue, 73# to disperse blue, 291# to disperse blue, HSF to disperse deep blue, UN-SE to disperse deep blue, 2BLN to disperse blue any one or a few;
Dyestuff IV is to be selected from any one or a few of 241# DISPERSE YELLOW, 211# DISPERSE YELLOW, 163# DISPERSE YELLOW, 114# DISPERSE YELLOW, 79# DISPERSE YELLOW, 64# DISPERSE YELLOW, 54# DISPERSE YELLOW;
Described auxiliary agent is alkaline levelling agent, for the pH value of controlling dyeing between 7-11.
Further: it is 20~70% dyestuff I, 30~80% dyestuff II that described dyestuff contains mass percent.
It is 10% dyestuff II, 90% dyestuff III that described dyestuff contains mass percent.
It is 5% dyestuff HI, 95% dyestuff IV that described dyestuff contains mass percent.
It is 10~70% dyestuff I, 5~75% dyestuff II, 5~85% dyestuff III that described dyestuff contains mass percent.
It is 5~85% dyestuff I, 5~75% dyestuff II, 5~85% dyestuff III, 5~70% dyestuff IV that described dyestuff contains mass percent.
Disperse dye composition of the present invention, according to the needs of the change of coloured light and fastness intensity, also can add one or more of following component:
Component V:9# Disperse Green.
Component VI: 63# 63 DISPERSE Violet 63,26# 63 DISPERSE Violet 63,93# 63 DISPERSE Violet 63;
Component VII: disperse black ECT.
Aforesaid dyestuff title means C.I. (Colour Index; C.I.) common name, corresponding chemical formula is as follows:
Alkaline levelling agent of the present invention, that pH value for controlling dyeing is between 7-11, alkalescence levelling agent mainly selects various tensio-active agents as dispersion agent, permeate agent, degreaser etc., specifically can application surface promoting agent 1227, chelated dispersants ZK-A, penetrating agent JFC, alkaline degreaser ZK-101, xylogen 83A, xylogen 85A, Dispersant MF, dispersion agent NNO one or more.
Another aspect of the present invention is to provide above-mentioned disperse dye composition in the complete technologic application of dyeing terylene, it is characterized in that: under room temperature, put into 100 grams of full polyester piece goods, then add alkaline levelling agent 0.5~2g/L, then regulate left and right, pH=7~11, running is more than 3 minutes, then add dispersed dye 2g/L of the present invention, directly be warmed up to after 80 DEG C, be warmed up to 130 DEG C with 1 DEG C~1.5 DEG C/min speed again, then insulation dyeing 30~60 minutes, is then cooled to 80 DEG C of left and right discharge opeings, with 80 DEG C~98 DEG C hot water wash 5min, dry.
Another aspect of the present invention is to provide above-mentioned disperse dye composition and scourings and bleaching with dispersion dyeing synchronously with the application on bath process in wash/cotton, it is characterized in that: under room temperature, put into 100 grams of wash/cotton fabrics, then add alkaline levelling agent 0.5~2g/L, regulate left and right, pH value pH=7~11, turn round after 3 minutes, add hydrogen peroxide, turn round 5 minutes, then add dispersed dye 2g/L of the present invention, be directly warming up to after 80 DEG C, be warming up to 130 DEG C with 1 DEG C~1.5 DEG C/min speed again, insulation dyeing 30 '~60 ', be then cooled to 80 DEG C of left and right discharge opeings, directly cotton is dyed in water inlet.
Another aspect of the present invention is to provide above-mentioned disperse dye composition in the technologic application of wash/cotton dispersion High Temperature Type Reactive Dyes single bath process, it is characterized in that: under room temperature, put into 100 grams of wash/cotton fabrics, then add alkaline levelling agent 0.5~2g/L to mix up left and right, pH=7~11, turn round 3 minutes, then add dispersed dye 2g/L of the present invention, turn round and within 5 minutes, add Sodium sulfate anhydrous.min(99)/salt, turn round and be directly warming up to 80 DEG C after 3 minutes, add High Temperature Type Reactive Dyes, turn round after 20 minutes, be warming up to 130 DEG C with 1 DEG C~1.5 DEG C/min speed again, insulation dyeing 30 '~45 ', then be cooled to 80 DEG C, turn round and within 5 minutes, start to add soda ash, 80 DEG C of insulation dyeing 30 '~60 ' discharge opeings, wash water soap boiling.
Another aspect of the present invention is to provide above-mentioned disperse dye composition in the technologic application of wash/cotton dispersion thermostatic type reactive dyestuffs one-bath two-step process, it is characterized in that: under room temperature, put into 100 grams of wash/cotton fabrics, then add special assistant 0.5~2g/L of the present invention to mix up left and right, pH pH=7~11 running 3 minutes, then the dispersed dye 2g/L that adds the embodiment of the present invention 1 to make, turn round and be directly warming up to after 80 DEG C after 3 minutes, again with 30 DEG C~60 DEG C of 1 DEG C~1.5 DEG C/min speed intensification degree to 130 DEG C insulation dyeing, then be cooled to 60 DEG C, add Sodium sulfate anhydrous.min(99)/salt and 1g/L soda ash simultaneously, turn round and within 5 minutes, add thermostatic type reactive dyestuffs, turn round after 30 minutes, start to add soda ash, 60 DEG C of insulation dyeing 30 '~60 ' discharge opeings, wash water soap boiling.
Principle of the present invention and beneficial effect are as follows:
1, disperse dye composition of the present invention, pH is interdependent, and scope is wider, can under the condition of pH value 7~11, dye, and obtains the outstanding dyeing and weaving thing of fastness properties, the especially fastnesss to sublimation such as form and aspect are full, washing fastness and has obtained increasing substantially.
2, disperse dye composition of the present invention, the fabric that goes for various styles as entirely washed, wash/cotton or wash spandex, ultra-fine fibre etc., all there is good Color.
3, disperse dye composition of the present invention, be applied to entirely wash, wash/cotton or while washing the dyeing of spandex, ultra-fine fibre etc., can realize pre-treating technology and dyeing synchronously carries out, like this, just greatly shorten the process time, raise labour productivity, save the energy and water consumption, alleviate sewage disposal burden.
4, disperse dye composition of the present invention, can be used alone, and also can be used in conjunction with other reactive dyestuffs, and as wash/cotton mixture fabric or blending thing are carried out, the disperse dyeing of scouring and bleaching/terylene of cotton is synchronous carries out with bathing; Or coordinate the one-bath process that carries out polyester/cotton blended fabric Dyeing with Disperse/Reactive with High Temperature Type Reactive Dyes, or dye with same thermostatic type reactive dyestuffs one-bath two-step process, all can obtain good Color, with a wide range of applications, be also conducive to the process time simultaneously and reduce production costs.
5, disperse dye composition of the present invention, while being applicable to dye under alkaline environment, can effectively preventing and remove fiber and dye oligopolymer on machine, thereby reducing production costs and machine cost.
Below in conjunction with the drawings and specific embodiments, the invention will be further described.
Brief description of the drawings:
Fig. 1 is the dyeing figure of the present invention while being applied to full terylene;
In Fig. 1: A is embryo cloth; B is alkaline levelling agent, and C is dispersed dye of the present invention.
Fig. 2 be the present invention be applied to wash/cotton scouring and bleaching and dispersion dyeing synchronously with bath process figure;
In Fig. 2: A is embryo cloth; B is alkaline levelling agent, and C is hydrogen peroxide; D is dispersed dye of the present invention.
Fig. 3 is that the present invention is applied to the wash/cotton High Temperature Type Reactive Dyes single bath process artwork that disperses;
In Fig. 3: A is embryo cloth; B is alkaline levelling agent, and C is dispersed dye of the present invention, and D is Sodium sulfate anhydrous.min(99)/salt, and E is High Temperature Type Reactive Dyes, and F is soda ash/other alkali (1/10) (3/10) (6/10).
Fig. 4 is that the present invention is applied to the wash/cotton thermostatic type reactive dyestuffs one-bath two-step process artwork that disperses.
In Fig. 4: A is embryo cloth; B is alkaline levelling agent, and C is dispersed dye of the present invention, and D is Sodium sulfate anhydrous.min(99)/salt, and E is soda ash, and F is thermostatic type reactive dyestuffs, and G is soda ash/other alkaline agent (1/10) (3/10) (6/10).
Embodiment:
Below in conjunction with specific embodiment, the present invention is described further, but protection scope of the present invention is not limited in this:
1, the preparation of disperse dye composition of the present invention
Embodiment 1:
By the component I of 100 grams of formulas (I-1), the multi-functional levelling agent SE of 200 grams, add water after 750 grams of Mixed Pinyins, grinding distribution, dry, get product, this dyestuff can provide fabric evenly and good orange of fastness ability.
Embodiment 2:
To, containing the component A of 50 grams of formulas (I-1), 50 grams of formulas (I-2), the multi-functional levelling agent SE of 100 grams, add water after 750 grams of Mixed Pinyins, grinding distribution, dry, get product, this dyestuff can provide fabric evenly and good orange of fastness ability.
Embodiment 3~36:
According to the method described in embodiment 1, structure and weight ratio and the auxiliary agent of different is in employing table 1 component I, component I I, component III, component IV, after the blending that adds water, make slurries, grinding distribution, dry, make finished product, thereby it is needed evenly and the good tone of fastness ability to offer fabric.
Table 1: different disperse dye composition compositions and corresponding tone
2, the application of disperse dye composition of the present invention
2.1. be applied to full dyeing terylene technique:
Dyeing route is as shown in Figure 1: measured normal water level, under room temperature, put into 100 grams of full polyester piece goods, then add special assistant 0.5~2g/L of the present invention, then regulate left and right, pH=7~11, turn round more than 3 minutes, the dispersed dye 2g/L that then adds the embodiment of the present invention 1 to make, directly be warmed up to after 80 DEG C, be warmed up to 130 DEG C with 1 DEG C~1.5 DEG C/min speed again, then insulation dyeing 30~60 minutes, is then cooled to 80 DEG C of left and right discharge opeings, with 80 DEG C~98 DEG C hot water wash 5min, dry.
According to the method described in above-mentioned dyeing embodiment, adopt the dyestuff of preparation in embodiment 1~36 to dye respectively, different is to change dyeing pH value, adopt that GB GB/T3920, GB/T3921, GB/T5718 test respectively its rub resistance, resistance toly soap, color fastness to sublimation, specifically in table 2.
Table 2: embodiment 1~36 is applied to the Color contrast of full terylene
As can be seen from Table 2, when disperse dye composition of the present invention is applied to full dyeing terylene, pre-treatment and dyeing carry out simultaneously, have effectively shortened the process time, have reduced process energy consumption, and there is good rub resistance, resistance toly soap, fastness to sublimation.
2.2. being applied to wash/cotton scourings and bleaching and the synchronous same bath process of dispersion dyeing:
Embodiment 17:
Process curve is as shown in Figure 2: measured normal water level, under room temperature, put into 100 grams of wash/cotton fabrics, then add special assistant 0.5~2g/L of the present invention, regulate left and right, pH value pH=7~11, turn round after 3 minutes, add hydrogen peroxide, turn round 5 minutes, then the dispersed dye 2g/L that adds the embodiment of the present invention 1 to make, is directly warming up to after 80 DEG C, then is warming up to 130 DEG C with 1 DEG C~1.5 DEG C/min speed, insulation dyeing 30 '~60 ', be then cooled to 80 DEG C of left and right discharge opeings.Directly cotton is dyed in water inlet.
According to the method described in above-mentioned dyeing embodiment, adopt the dyestuff of preparation in embodiment 1~36 to dye respectively, different is to change dyeing pH value, tests respectively its rub resistance, resistance toly soaps, color fastness to sublimation, specifically in table 3.
Table 3: embodiment 1~36 is applied to and washs/cotton scouring and bleaching and dispersion dyeing synchronously with the Color of bath process
As can be seen from Table 3, disperse dye composition of the present invention is applied to and washs/and cotton scourings and bleaching and dispersion dyeing during synchronously with bath process, and pre-treatment and dyeing carry out simultaneously, have effectively shortened the process time, reduced process energy consumption, and there is good rub resistance, resistance toly soap, fastness to sublimation.
2.3. be applied to the wash/cotton High Temperature Type Reactive Dyes single bath process that disperses:
Embodiment 18: process curve as shown in Figure 3: measured normal water level, under room temperature, put into 100 grams of wash/cotton fabrics, then add special assistant 0.5~2g/L of the present invention to mix up left and right, pH pH=7~11, turn round 3 minutes, then the dispersed dye 2g/L that adds the embodiment of the present invention 1 to make, turn round and within 5 minutes, add Sodium sulfate anhydrous.min(99)/salt, turn round and be directly warming up to 80 DEG C after 3 minutes, add High Temperature Type Reactive Dyes, turn round after 20 minutes, be warming up to 130 DEG C with 1 DEG C~1.5 DEG C/min speed again, insulation dyeing 30 '~45 ', then be cooled to 80 DEG C, turn round and within 5 minutes, start to add after soda ash/other alkaline agent, 80 DEG C of insulation dyeing 30 '~60 ' discharge opeings, wash water soap boiling.
According to the method described in above-mentioned dyeing embodiment, adopt the dyestuff of preparation in embodiment 1~36 to dye respectively, different is to change dyeing pH value, tests respectively its rub resistance, resistance toly soaps, color fastness to sublimation, specifically in table 4.
Table 4: embodiment 1~36 is applied to and washs/the cotton Color that disperses High Temperature Type Reactive Dyes single bath process
As can be seen from Table 4, disperse dye composition of the present invention is applied to and washs/and cotton while disperseing High Temperature Type Reactive Dyes single bath process technique, pre-treatment and dyeing carry out simultaneously, have effectively shortened the process time, reduced process energy consumption, and there is good rub resistance, resistance toly soap, fastness to sublimation.
2.4. be applied to the wash/cotton thermostatic type reactive dyestuffs one-bath two-step process that disperses:
Embodiment 19: process curve as shown in Figure 3: measured normal water level, under room temperature, put into 100 grams of wash/cotton fabrics, then add special assistant 0.5~2g/L of the present invention to mix up left and right, pH pH=7~11 running 3 minutes, then the dispersed dye 2g/L that adds the embodiment of the present invention 1 to make, turn round and be directly warming up to after 80 DEG C after 3 minutes, again with 30 DEG C~60 DEG C of 1 DEG C~1.5 DEG C/min speed intensification degree to 130 DEG C insulation dyeing, then cooling (simultaneously adding Sodium sulfate anhydrous.min(99)/salt and 1g/L soda ash) is to 60 DEG C, turn round and within 5 minutes, add thermostatic type reactive dyestuffs, turn round and after 30 minutes, start to add soda ash/other alkaline agent, 60 DEG C of insulation dyeing 30 '~60 ' discharge opeings, wash water soap boiling.
According to the method described in above-mentioned dyeing embodiment, adopt the dyestuff of preparation in embodiment 1~36 to dye respectively, different is to change dyeing pH value, tests respectively its rub resistance, resistance toly soaps, color fastness to sublimation, specifically in table 5.
Table 5: embodiment 1~36 is applied to and washs/the cotton Color that disperses High Temperature Type Reactive Dyes single bath process
As can be seen from Table 5, disperse dye composition of the present invention is applied to and washs/and cotton while disperseing High Temperature Type Reactive Dyes single bath process technique, pre-treatment and dyeing carry out simultaneously, have effectively shortened the process time, reduced process energy consumption, and there is good rub resistance, resistance toly soap, fastness to sublimation.